This paper is concerned with investigation of the influence of pre-stress and pre-polarization on the decay of Saint-Venant end effects in piezoelectric solids. This issue is examined within the framework of incremental anti-plane shear states for prestressed and prepolarized solids. Attention is confined to a specific class of materials, namely those of hexagonal 6mm or 4mm symmetry. It is shown that the mechanical and electrical fields uncouple in this case, and the governing system of coupled second-order linear partial differential equations uncouple to a single homogeneous second-order equation with constant coefficients for the displacement and a Poisson equation for the electric potential. The exact decay rate for mechanical and electrical end effects is determined and the influence of pre-stress and pre-polarization is assessed. Motivation for this work arises from the current rapid developments in smart materials technology.