This paper presents a macroscopic fundamental diagram model with volume–delay relationship (MFD-VD) for road traffic networks, by exploring two new data sources: license plate cameras (LPCs) and road congestion indices (RCIs). We derive a first-order, nonlinear and implicit ordinary differential equation involving the network accumulation (the volume) and average congestion index (the delay), and use empirical data from a 266 km2 urban network to fit an accumulation-based MFD with R2>0.9. The issue of incomplete traffic volume observed by the LPCs is addressed with a theoretical derivation of the observability-invariant property: The ratio of traffic volume to the critical value (corresponding to the peak of the MFD) is independent of the (unknown) proportion of those detected vehicles. Conditions for such a property to hold are discussed in theory and verified empirically. This offers a practical way to estimate the ratio-to-critical-value, which is an important indicator of network saturation and efficiency, by simply working with a finite set of LPCs. The significance of our work is the introduction of two new data sources widely available to study empirical MFDs, as well as the removal of the assumptions of full observability, known detection rates, and spatially uniform sensors, which are typically required in conventional approaches based on loop detector and floating car data.