2H-NMR spin-lattice relaxation times T1 of phenyl ring deuterated toluene have been measured as a function of temperature (75–290 K) at Larmor frequencies between 13.8 and 55.8 MHz. The results are interpreted by assuming a Cole–Davidson rotational correlation time distribution for the α process dominating T1 at temperatures down to about 20 K above the glass transition (Tg=117 K) and one further process at lower temperatures. The latter is analyzed below Tg using a model with temperature dependent librational angles ΔΦ<13° and mean correlation times τ≳10−9 s. Self-diffusion coefficients are determined at temperatures down to 136 K (D=1.5×10−14 m2 s−1) using a static field gradient 1H-NMR method. The product of D and the mean rotational correlation time shows a tendency to increase at the lowest temperatures.
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