Light plays a key role in shaping the quality and atmosphere of interior spaces, and its importance and contradictions are amplified in the design of libraries. This study focuses on the problems associated with both insufficient natural light and excessive light. In both cases, visual discomfort is the result. The reason for these problems lies in the use of translucent structures with different parameters and properties in library architecture. This study analyzed the lighting environment in the main reading rooms of two university libraries in Warsaw. The research methods were based on a field survey of objects and an analysis of the architectural and construction parameters of the premises, as well as the physical and mechanical properties of various types of translucent materials used in the reading rooms. The results of this study shed light on the relationship between the interior space of the reading room and the geometry of transparent structures, as well as the effectiveness of daylighting in libraries in the natural conditions of Warsaw. The key point of the present study was to recognize the critical role that transparent materials and structures play in mitigating potential operational problems in library spaces. Wise selection of these elements at the design stage can help minimize problems related to thermal energy regulation, ventilation control, acoustic insulation, and increased visual comfort. The importance of this research area lies in its potential to optimize library buildings by increasing energy efficiency and reducing reliance on artificial lighting, heating, and air conditioning. Careful consideration of transparent materials at the design stage promises long-term benefits in the form of sustainable library spaces that not only meet functional requirements, but also contribute to a more environmentally conscious architectural landscape.