This paper discusses the general concept of Bayesian Network classifier and the optimisation of a predictive spatial model using Naive Bayes (NB) on secondary mineral deposit data. A different NB modelling approaches to mineral distribution data was used to predict the occurrence of a particular mineral deposit in a given area, which include; predictive attributes sub-selection, normalised attributes selection, NB dependent attributes and the strictness to NB model assumptions of attributes independence selection. The performance of the model was determined by selecting a model with the best predictive accuracy. The NB classifier that violates assumptions of attributes independence was used to compare with other forms of NB. The aim is to improve the general performance of the model through the best selection of predictive attribute data. The paper elaborates the workings of a Bayesian Network learning model, the concept of NB and its application to predicting mineral deposit potentials. The result of the optimised NB model based on predictive accuracies and the Receivr Operating Characteristics (ROC) value is also determined.