Leakage in operating tunnels is a serious problem during operating stage. In order to realize non-destructive detection of leakage in an operating shield tunnel, an optical fiber temperature measurement method based on Raman scattering and infrared thermal imaging technology is developed. The working principle of leakage monitoring with Distributed Fiber Optic Temperature Sensor (DTS) combined with time domain reflectometry (OTDR) technology are introduced. The distributed measurement of temperature field is realized in a typical tunnel. Infrared thermal imager is used to perform thermal imaging on the leakage area, and the temperature difference between the leakage area and the non-leakage area is 3.6 °C, which can meet the requirements of distributed optical fiber side leakage temperature accuracy. This illustrates the feasibility of quantitative monitoring of leaks in distributed optical fiber temperature sensing systems. The reasonable arrangement of leakage monitoring fiber in distributed fiber temperature sensing system is discussed in practical engineering.