Silver Layer Research Articles

Temperature and thickness-dependent silver hillock generation mechanism and surface morphology nature of direct plated silver layers onto copper substrates

This study delves into the formation of hillocks on Ag surfaces, particularly those resulting from heat-induced processes. We investigate the Ag hillock generation mechanisms in direct Ag plating layers on copper (Cu) substrates, employing a combination of experimental and numerical approaches for comprehensive quantification. In the Ag layer system directly plated on Cu, the strain inside the grain system significantly increases as the temperature increases, but the energy level of the system drops due to the relaxation of the internal strain starting from a certain critical temperature. Namely, the Ag hillock growth mechanisms on Ag plated Cu substrate originated from the microstructural development with thermomechanical behaviors. Nevertheless, the Ag layer directly plated on Cu suffered Ag-Cu diffusion through the grain boundary due to heat, which contaminated the Ag plating surface. Hillock formation is possible even in an Ag layer directly plated on a Cu substrate, but Ag-Cu diffusion may be a factor that inhibits the development and growth of Ag hillocks. In this study, the major feature of the Ag hillock formation on the direct Ag layer plated on Cu substrate was systematically clarified in terms of the microstructures and mechanics of materials.

Large-area (50 cm × 50 cm) optically transparent electromagnetic interference (EMI) shielding of ZTO/Ag/ZTO: an analytical/numerical and experimental study of optoelectrical and EMI shielding properties

Transparent conducting oxides (TCOs), exhibiting both high optical transparency and low electrical resistivity, are commonly employed in optoelectronic devices. However, acquiring a balance between these optical and electrical properties in a uniform way over large areas has been a pending challenge, which is essential to achieving optically transparent electromagnetic interference (EMI) shielding surfaces. In this study, we propose and demonstrate a stratified thin film structure consisting of zinc-doped tin oxide (Zn2SnO4, ZTO) as TCO along with a metal layer of silver (Ag) deposited on a large area of 50 cm × 50 cm polycarbonate (PC) substrate enabled by a scanning magnetron sputtering gun. We achieved high EMI shielding of 99.9% at the optical transparency of 68% in the visible spectrum by engineering the stratified architecture of ZTO/Ag/ZTO. The Ag layer of 18 nm in thickness with a sheet resistance of 10 Ω/sq yields shielding effectiveness (SE) of 27 dB in a wide frequency range of 2–20 GHz. The bottom and top ZTO layers, 20 and 40 nm thick, respectively, provide the lowest optical loss of 13% across 400–700 nm. The structure’s EMI shielding, optical and structural performances were systematically characterized through a free-space focused-beam system, UV–Vis spectrophotometer, ellipsometry, focused ion-beam cross-sectional sampling and imaging, transmission electron microscopy, atomic force microscopy and secondary ion mass spectroscopy. EMI shielding and optical performances were validated by CST Microwave Studio and the transfer matrix method, respectively. These findings indicate that the proposed multi-layer architecture holds great promise for large-area EMI shielding and other optoelectronic applications.

Chiral photothermoelectric effect driven by high-Q quasi-bound states in the continuum

Bound states in continuum (BIC) have been proposed as a means to efficiently improve light-matter interactions in metasurfaces. While breaking the mirror symmetry of structure and developing BIC into a reachable and observable quasi-BIC, it is usually accompanied by the chiral phenomenon with high quality (Q) factor. Here, we report a spin-sensitive photodetector in the infrared (NIR) region comprising a silicon metasurface with chiral quasi-BIC, a silver layer, and a thermoelectric layer. A chiral quasi-BIC supported by a silicon metasurface can be realized under normal incidence. Based on finite element method simulations, a silicon metasurface with a silver layer shows a high Q-factor of 958.6 with a giant absorption circular dichroism of 0.83. Subsequently, we study the thermal performance of the chiral absorbers by using the heat transfer module of COMSOL. Combined with the thermoelectric material bismuth telluride, we calculate the differential photothermoelectric effects of the system under circular-polarized light irradiation. When the incident flux is 100 W cm−2, the output voltage under right-circular-polarization (left-circular-polarization) light reaches 0.59 mV (0.08 mV), which can be used for polarization detection. Therefore, our designed structure incorporating thermoelectricity broadens the applications of chiral BIC in sensors and detectors.

Surface segregation of rigid polyarylene ether amidoxime on polyurethane nanofiber into hierarchical membranes as substrate of flexible SERS nanosensor for sulfamethoxazole detection

Electrospun polymeric nanofibrous membranes are emerging as the promising substrates for preparation of flexible SERS nanosensors due to their intrinsic nanoscale surface roughness, easy scalability as well as rich surface reactivity. Although the nanofiber membranes prepared from high performance thermoplastics exhibit good mechanical stability, the SERS nanosensors based on these substrates normally have lower signal-to-noise ratio because of the interference from background Raman signals of aromatic moieties. Herein, we synthesized an optically transparent polyurethane (PU) and rigid polyarylene ether amidoxime (PEA), which were electrospun into core-shell nanofibers membranes with a “beads-on-web” morphology. Furthermore, the PU-PEA membranes were coated with ultra-thin silver layer and thermally annealed to prepare the flexible SERS nanosensor without any background noises. In addition, the Raman enhancement of SERS nanosensor can be readily improved by tuning of PU-PEA composition, silver thickness as well as thermal annealing temperature. Finally, the optimized SERS nanosensor enables label-free detection of sulfamethoxazole as low as 0.1 nM with a good reproducibility and detection performance in real water sample. Meanwhile, the optimized SERS nanosensor shows long term anti-biofouling capacity. Thanks to its facile fabrication, competitive analytical performance and resistance to biofouling, the current work basically open new way for design of flexible SERS nanosensors for biomedical applications.

Investigation on Thermally Evaporated Aluminium Contact Layers for Perovskite Solar Cell Applications

Perovskite solar cells (PSCs) have gained wide interest due to their high device efficiency of up to 22.1%. Perovskite solar cells are comprised of five main layers: fluorine-doped tin oxide (FTO) glass, titanium dioxide (TiO2) electron transport layer (ETL), perovskite active layer, Spiro-OMeTAD hole transport layer (HTL), and a metal contact layer. The metal contact layer plays a significant role in collecting and transporting the generated current and hence governs the performance of the device. Aluminium (Al) is more cost-efficient than the commonly used silver (Ag) or gold (Au) contact layers in perovskite solar cells. The aim of this work is to investigate the influence of different thicknesses and surface morphologies on the electrical properties of the Al thin film contact layers for perovskite solar cell applications. The Al contact layers were deposited using a thermal evaporator with varying Al wire source lengths at constant deposition duration and pressure. The deposited films were characterised for thickness, morphology, and electrical properties using a stylus profilometer, an atomic force microscope, and a four-point probe, respectively. Results showed that thicker Al films have larger particle sizes as compared to the thinner films, demonstrating a more continuous film morphology. Resistivity and conductivity show a variance with different film thickness. Based on literature, higher conductivity and larger particle sizes of the metal contact layers can improve charge transportation, which contributes to the performance of the perovskite solar cell.

Bonding of ceramics to silver-coated titanium-A combined theoretical and experimental study.

It would be very beneficial to have a method for joining of ceramics to titanium reliably. Although several techniques have been developed and tested to prevent extensive interfacial chemical reactions in titanium-ceramic systems, the main problem of the inherent brittleness of interfaces was still unsolved. To overcome this problem also in dental applications, we decided to make use of an interlayer material that needs to meet the following requirements: First, it has to be biocompatible, second, it should not melt below the bonding temperatures, and third, it should not react too strongly with titanium, so that its plasticity will be maintained. Considering possible material options only the metals: gold, platinum, palladium, and silver, fulfill the first and second requirements. To find out-without an extensive experimental testing program-which of the four metals fulfills the third requirement best, the combined thermodynamic and reaction kinetic modeling was employed to evaluate how many and how thick reaction layers are formed between the interlayer metals and titanium. With the help of theoretical modeling, it was shown that silver fulfills the last requirement best. However, before starting to test experimentally the effect of the silver layer on the mechanical integrity of dental ceramic/Ag/Ti joints it was decided to make use of mechanical analysis of the three-point bending test, the result of which indicated that the silver layer increases significantly the bond strength of the joints. This result encouraged us to develop a new technique for plating silver on titanium. Subsequently, we executed numerous three-point bending tests, which demonstrated that silver-plated titanium-ceramic joints are much stronger than conventional titanium-ceramic joints. Hence, it can be concluded that the combined thermodynamic, reaction kinetic, and mechanical modeling method can also be a very valuable tool in medical research and development work.

Thermo‐Optical Switches Based on Spin‐Crossover Molecules with Wideband Transparency

AbstractIn this work, a thermally tunable optical resonator operating in the visible wavelength range is reported, which consists of a bilayer structure composed of a thin silver layer and a dielectric coating of [Fe(HB(1,2,4‐triazol‐1‐yl)3)2] switchable spin‐crossover (SCO) molecules. White light is coupled to the resonant structure using a prism and the resulting resonance spectra are investigated as a function of the incident angle and temperature. Switching the SCO molecules from the low‐spin to the high‐spin state gives rise to a substantial blueshift of the resonances reaching up to 30 nm (associated with a reflectance modulation of up to 70%), which can be linked, through transfer‐matrix simulations, to the variation of the optical thickness of the molecular layer. Interestingly, the study demonstrated that the large thermal tunability of the device also gives rise to a photothermal nonlinearity, which can be leveraged for achieving optical limiting applications. Overall, through the present study, it is shown that molecular SCO nanomaterials can be superior to commonly used thermo‐optical switches and well‐established optical phase‐change materials for applications requiring high broadband optical transparency in the visible spectral domain.

Wearable sensor for real-time monitoring of oxidative stress in simulated exhaled breath

High concentrations of H2O2, indicative of increased oxidative stress in the lung, are observed in the exhaled breath of individuals affected by different respiratory diseases. Therefore, measuring H2O2 in exhaled breath represents a promising and non-invasive approach for monitoring the onset and progression of these diseases. Herein, we have developed an innovative, inexpensive, and easy-to-use device for the measurement of H2O2 in exhaled breath. The device is based on a silver layer covered with an electrodeposited thin film of chitosan, that ensures the wettability of the sensor in a humid atmosphere. The s-ensor was calibrated in the aerosol phase using both phosphate buffer solution and cell culture medium. In the buffer, a sensitivity of 0.110 ± 0.0042 μA μM−1 cm−2 (RSD: 4%) and a limit of detection of 30 μM were calculated, while in the cell culture medium, a sensitivity of 0.098 ± 0.0022 μA μM−1 cm−2 (RSD 2%) and a limit of detection of 40 μM were obtained. High selectivity to different interfering species was also verified. The sensor was further tested versus an aerosol phase obtained by nebulizing the culture medium derived from human bronchial epithelial cells that had been exposed to pro-oxidant and antioxidant treatments. The results were comparable with those obtained using the conventional cytofluorimetric method. Finally, sensor was tested in real exhaled breath samples and even after undergoing physical deformations. Data herein presented support that in future applications this device can be integrated into face masks allowing for easy breath monitoring.

An ultralight, pulverization-free integrated anode toward lithium-less lithium metal batteries.

The high-capacity advantage of lithium metal anode was compromised by common use of copper as the collector. Furthermore, lithium pulverization associated with "dead" Li accumulation and electrode cracking deteriorates the long-term cyclability of lithium metal batteries, especially under realistic test conditions. Here, we report an ultralight, integrated anode of polyimide-Ag/Li with dual anti-pulverization functionality. The silver layer was initially chemically bonded to the polyimide surface and then spontaneously diffused in Li solid solution and self-evolved into a fully lithiophilic Li-Ag phase, mitigating dendrites growth or dead Li. Further, the strong van der Waals interaction between the bottommost Li-Ag and polyimide affords electrode structural integrity and electrical continuity, thus circumventing electrode pulverization. Compared to the cutting-edge anode-free cells, the batteries pairing LiNi0.8Mn0.1Co0.1O2 with polyimide-Ag/Li afford a nearly 10% increase in specific energy, with safer characteristics and better cycling stability under realistic conditions of 1× excess Li and high areal-loading cathode (4 milliampere hour per square centimeter).

Low temperature soldering technology based on superhydrophobic copper microlayer

Cu–Cu soldering is realized under certain pressure and low temperature conditions by using a surface silver film to modify the copper microlayer structure, thus solving the problems of high thermal stress and signal delay aggravation caused by high temperature in the traditional reflow soldering process. The copper microlayer modified with silver film is obtained by electrodeposition. The surface substructure of the Cu microlayer is a nano cone-shaped protrusion. The diameter of the bottom of the cone is 500 nm∼1 μm, and the height of the cone is 1∼2 μm. The thickness of the silver film is about 320 nm, and the modification of the copper layer with silver film can effectively prevent the oxidation of the copper layer. Two silver-modified copper microlayers are placed in face-to-face contact as a soldering couple. A certain pressure and low temperature are applied to the contact area to realize the soldering and interconnection.The morphology of the soldered interface and the average shear strength of the soldered joints are analyzed by scanning electron microscopy, transmission electron microscopy and solder joint tester. It is found that under the optimal soldering parameters of soldering temperature 220 °C, soldering pressure 20 MPa and soldering time 20 min, the nano-conical projections of the Cu micrometer layer are inserted into each other to produce a physical blocking effect. The highly surface-meltable silver film effectively connects the surrounding copper layer as an intermediate buffer layer. The average shear strength of soldering joints is significantly increased. Heat treatment experiments have shown that the average shear strength can be effectively increased by heat treatment for an appropriate period of time. Prolonged exposure to heat has little effect on the average shear strength. With the special morphology of the copper microlayer structure and the nano-size effect of the silver layer, soldering can be done at low temperatures. The quality of the soldering interface is good and small soldering dimensions can be obtained.

Homemade copper-silver plates as an alternative for cleaning mercury-contaminated tailings from artisanal and small-scale gold mining in Colombia

Over 300,000 artisanal and small-scale gold mining operate in almost all Colombia. Despite the poverty alleviation characteristic of the operations in rural regions, these practices have been affecting the environment and health of operators as well as neighboring communities, mainly due to the misuse of mercury and cyanide. The most impacting activity is when processing centers use cyanide to leach Hg-contaminated tailings. This generates toxic mercury-cyanide complexes that are not frequently removed from effluents, and it is very toxic for aquatic life. A study to remove metallic mercury from tailings before cyanidation was conducted with 300 to 500 kg tailings from 15 different mining sites in Colombia using homemade copper plates covered with an electrolytic layer of silver. The experiments resulted in an average of 63% of Hg removed, and a maximum of 85%. The final Hg concentrations in the tailings reached an average of 27 to 47 ppm (depending on the analytical method) from the original grades of 75 to 125 ppm. Mercury droplets from old tailings, with acid generation, were difficult to trap by the plates. The article gives a detailed description on how to make these homemade plates and set up a zigzag cascade configuration for better results. Additional methods to adsorb or precipitate mercury from the cyanide solutions are necessary and they have been discussed.

Multilayer coatings of periodically co-deposited graphene and ag substrate: Improving the electrified friction interface by modifying the strength-ductility combination

Multifunctional and highly adaptable multilayer coatings are considered the future development trend in the field of protective coating design. To enhance wear resistance when subjected to an electric current and to reduce internal stresses, we developed a multilayer structure in which graphene nanoplatelets (GNPs) were deposited within pure silver using a dual electrolyte alternating deposition technique, resulting in the creation of Ag-Ag/GNP multilayer coatings. In this multilayer coating design, the continuous conductive silver layer enhances the overall electrical properties of the coating, and the soft silver layers absorb part of the internal stress in the coating. The deposited GNPs provide crucial structural reinforcement to the coating, thereby improving its mechanical and tribological properties. These coatings were characterized with respect to their structure and mechanical properties using X-ray diffraction, hardness testing, and electronic tensile testing, and their current-carrying tribological performance was studied. Experiments revealed that the crystal structure of single-layer composite coatings changed with increasing GNP content, whereas the multilayer coatings exhibited improved strength and toughness. In current-carrying tribological tests, the multilayer coatings demonstrated significant adaptability to increasing wear depth and current. The wear mechanism of multilayer coatings transitioned from adhesive to abrasive wear. The results indicate that the multilayer coating design effectively enhances friction stability, reduces electrical contact resistance, and decreases wear volume. The findings of this study provide new insights for the design of multilayer structured coatings and will help reduce the loss of rare metals in electrified friction applications.

Thermochromic Nanocellulose Films for Temperature-Adaptive Passive Cooling.

Energy efficiency in habitation spaces is a pivotal topic for maintaining energy sufficiency, cutting climate impact, and facilitating economic savings; thus, there is a critical need for solutions aimed at tackling this problem. One viable approach involves complementing active cooling methods with powerless or passive cooling ones. Moreover, considerable scope remains for the development of passive radiative cooling solutions based on sustainable materials. Cellulose, characterized by its abundance, renewability, and biodegradability, emerges as a promising material for this purpose due to its notable radiative cooling potential exploiting the mid-infrared (MIR) atmospheric transmission window (8-13 μm). In this work, we propose the utilization of thermochromic (TC) materials in conjunction with cellulose nanofibrils (CNF) to confer temperature-dependent adaptivity to hybrid CNF films. We employ a concept where high reflection, coupled with MIR emission in the heated state, facilitates cooling, while high visible light absorption in the cold state allows heating, thus enabling adaptive thermal regulation. CNF films were doped with black-to-leuco TC particles, and a thin silver layer was optionally applied to the films. The films exhibited a rapid transition (within 1 s) in their optical properties at ∼22 °C, becoming transparent above the transition temperature. Visible range transmittance of all samples ranged from 60 to 90%, with pronounced absorption in the 8-13 μm range. The cooling potential of the films was measured at 1-4 °C without any Ag layer and ∼10 °C with a Ag layer. In outdoor field testing, a peak cooling value of 12 °C was achieved during bright sunshine, which is comparable to a commercial solar film. A simulation model was also built based on the experimental results. The concept presented in this study extends beyond applications as standalone films but has applicability also in glass coatings. Overall, this work opens the door for a novel application opportunity for green cellulose-based materials.

Thickness Effect of Copper Clips on Power Module Packaging Design

The superior switching performance of SiC MOSFETs compared to Si devices is limited by packaging-related issues. High electromagnetic parasitics which lead to high voltage overshoots, and higher power losses are the main challenges of high frequency operation. Hence, packaging design modification and optimisation are necessary to accommodate faster switching. Copper clips replacing the bonding wires show promising results in reducing stray inductances, while enhancing the current conduction and heat dissipation since the clip are in contact with a larger area of the semiconductor chip. Silver sintering instead of soldering further improves the electrothermal behaviour. This paper investigates numerically various thicknesses of the copper clips and their effect on double-sided silver sintering, half-bridge 1200V/400A SiC MOSFET power module. Moreover, the silver layer thickness is varied to reduce th maximum stresses on the chip - silver interface.

An Experimental Investigation of a Flexible Sintered Silver Joint for Micro-Joining Based on a Design of Experiments

The increasing electrification of vehicles requires the use of ever higher voltages and electrical power. The thermal stresses to which the assembly joints of electronic chips are subjected are becoming increasingly severe. As a result, thermal stresses acting on the electronic assembly, and particularly on the electrical interconnections, are becoming increasingly severe. The objective of this study is to create, characterize and optimize the structure and properties of a porous silver sintered joint using the design of experiments (DoE) method. Joints consisting of a porous network of silver particles are obtained, showing remarkable flexibility allowing for thermal stresses accommodation and having sufficient tensile strength to ensure a correct bonding of the components. Depending on the selected levels for the sintering process parameters, the microscopy analysis shows a transition of the mode of rupture from the silver layer to the intermetallic compounds forming at the interface with the substrate.

High Accuracy of Clinical Verification of Electrohydrodynamic-Driven Nanobox-on-Mirror Platform for Molecular Identification of Respiratory Viruses.

The molecular detection of multiple respiratory viruses provides evidence for the rational use of drugs and effective health management. Herein, we developed and tested the clinical performance of an electrohydrodynamic-driven nanobox-on-mirror platform (E-NoM) for the parallel, accurate, and sensitive detection of four respiratory viral antigens. The E-NoM platform uses gold-silver alloy nanoboxes as the core material with the deposition of a silver layer as a shell on the core surfaces to amplify and enable a reproducible Raman signal readout that facilitates accurate detection. Additionally, the E-NoM platform employs gold microelectrode arrays as the mirror with electrohydrodynamics to manipulate the fluid flow and enhance molecular interactions for an improved biosensing response. The presence of viral antigens binds the nanobox-based core-shell nanostructure on the gold microelectrode and creates the nanocavity with extremely strong "hot spots" to benefit sensitive analysis. Significantly, in a large clinical cohort with 227 patients, the designed E-NoM platform demonstrates the capability of screening respiratory infection with achieved clinical specificity, sensitivity, and accuracy of 100.0, 96.48, and 96.91%, respectively. It is anticipated that the E-NoM platform can find a position in clinical usage for respiratory disease diagnosis.

Tunable Microwave Absorbing Devices Enabled by Reversible Metal Electrodeposition.

Tunable microwave absorbers have gained significant interest due to their capability to actively control microwaves. However, the existing architecture-change-based approach lacks flexibility, and the active-element-based approach is constrained by a narrowband operation or small dynamic modulation range. Here, a novel electrically tunable microwave absorbing device (TMAD) is demonstrated that can achieve dynamic tuning of the average reflection amplitude between -13.0 and -1.2 dB over a broadband range of 8-18 GHz enabled by reversible metal electrodeposition. This reversible tunability is achieved by electrodepositing silver (Ag) layers with controlled morphology on nanoscopic platinum (Pt) films in a device structure similar to a tunable Salisbury screen, employing Ag electrodeposited on Pt films as the modifiable resistive layer. Furthermore, this TMAD possesses a simple device architecture, excellent bistability, and multispectral compatibility. Our approach offers a new strategy for dynamically manipulating microwaves, which has potential utility in intelligent camouflage and communication systems.

Silver Alloy Surface Modification for Mechanical Property Enhancement in Aviation and Transportation

Silver alloys are often used for electrical switches in railway transportation. However, a well-known issue with these switches is their relatively short application period due to certain disadvantages of silver alloys, mainly their low hardness and low resistance to abrasive wear, in contrast to their excellent electrical conductivity. Therefore, the main goal of this study was to increase or maintain the hardness of the surface layer in order to extend the life of worn parts without compromising their electrical properties. Instead of ceramic particles, as in other studies, metallic powders were used, which could increase the electrical and/or thermal properties of silver alloys. The following work presents the use of laser processing as a relatively new technique for metal and metal alloy surface processing technology. In particular, a process based on the melting of silver (Ag) with metallic powders, such as chromium (Cr) and nickel (Ni) particles, is presented. The aim was for these powders to create intermetallic phases with a silver matrix in the obtained surface layer, significantly improving the mechanical properties based on the formation of the phases coherent or semi-coherent with the silver matrix. Regarding the original practical implications of this work, it was important to investigate the possibility of applying fibre laser for surface property enhancement. The scientific aim was to describe the changes in microstructure and compounds that occurred in the laser-remelted surface silver layer after Ni and Cr particles were fed into the basic silver material. It was concluded that the surface layer obtained after chromium application was without cracks and defects and had a higher hardness than the untreated material. A three-zone structure was also found in the obtained surface layer: (1) the remelted zone, (2) the heat-affected zone, and (3) the matrix material. The remelting zone revealed a higher hardness compared to the untreated material, reaching 92 HV0.3, which is more than twice the initial hardness value.

An electroplated Ag/AgCl quasi-reference electrode based on CMOS top-metal for electrochemical sensing

The integration and mass-production of reference electrodes for CMOS-based electrochemical sensing systems pose a challenge for the accessibility and commercial-viability of such devices. In this paper, a method of electroplating an Ag/AgCl quasi-reference electrode using CMOS top-metal as a base is presented for the first time. The aluminium bond-pad of a CMOS microchip was zincated, an electroless nickel immersion gold layer applied, and a thick silver layer electroplated and chemically chlorinated. The resulting reference electrode was able to provide a stable potential with a drift rate of 0.3mV/h for up to 18h. This validates the approach of a fully electroplated bond-pad reference electrode, which offers simplified post-processing and greater scalability of production. Further work towards an entirely electroless process is envisaged.

Design and investigation on polarization insensitive dual band graphene based tunable absorber for THz applications

In this communication, a metal-free graphene-based Absorber is designed and examined in the THz regime. The graphene layer is coated over the SiO2 substrate, while the silver layer is used on the other side of the substrate. The designed absorber works in two frequency bands i.e. 2.2–2.91 THz (11–14 μm) and 4.85–5.83 THz (51–62 μm), having more than 90% absorption. Peak absorption is obtained 2.55 THz and 5.05 THz with 97.78% and 99.71% absorption. With the help of circular sectoring, the designed absorber shows wide polarization and wide incident angle (up to 60°) insensitivity for both TE and TM modes. Change in chemical potential of graphene provides the tunable characteristics in the designed absorber. All these outcomes confirm that the designed metal-free graphene-based metamaterial absorber works efficiently in THz regime and can be used in different applications such as, sensing and imaging.