Substrate Layer Research Articles

Adsorption isotherm and kinetics of diffusion of water accumulated between polypropylene thin film and Si substrate: Neutron reflectivity investigation

Isotactic polypropylene (PP) thin films deposited on Si substrates were subjected to neutron reflectivity (NR) measurements under various humidity conditions to evaluate the isothermal adsorption of water accumulated between the PP layer and Si substrate, with focus on the temperature-dependence of the adsorption isotherm. The adsorption of accumulated water followed a single type II isotherm according to the Brunauer-Emmett-Teller (BET) classification, regardless of temperature. This can be attributed to the weak interactions between the PP layer and Si substrate, and between the PP layer and water molecules. Hydrophobic PP does not significantly interact with water molecules and the hydrophilic Si surface. Therefore, the interfacial water molecules are simply adsorbed on the native oxide layer on Si via simple interaction between the water molecules and the silicon oxide surface without being affected by the PP layer. Consequently, the adsorption isotherm of the accumulated water follows the single type II adsorption isotherm regardless of temperature, similar to the adsorption isotherm of water simply adsorbed on exposed silica surfaces. These weak interactions of the PP layer with the Si surface and water molecules also lead to fast diffusion kinetics for the accumulated water along the interface.

Fluorescent Aromatic Polyether Sulfones: Processable, Scalable, Efficient, and Stable Polymer Emitters and Their Single-Layer Polymer Light-Emitting Diodes.

In this study, fully aromatic polyether sulfones were developed, bearing blue, yellow, and orange-red π-conjugated semiconducting units. Carbazole-, anthracene-, and benzothiadiazole-based fluorophores are copolymerized with a diphenylsulfone moiety. A diphenylpyridine comonomer was additionally utilized, acting as both a solubilizing unit and a weak blue fluorescent group. Using this rationale, fluorescent polyarylethers with high molecular weights, up to 70 kDa, were developed, showing film formation ability and high thermal stability, while preserving excellent solubility in common organic, nonvolatile, and nonchlorinated solvents. Fine-tuning of the emission color was achieved through subtle changes of the comonomers' type and ratio. Single-chromophore-bearing copolymers emitted in the blue or the yellow region of the visible spectrum, while the dual-chromophore-bearing terpolymers emitted throughout the visible spectrum, resulting in white light emission. Solutions of 20 wt% in polar aprotic solvents at ambient conditions allowed the deposition of fluorescent copolyethers and printing from non-chlorinated solvents. All polyethers were evaluated for their structural and optoelectronic properties, and selected copolymers were successfully used in the emitting layer (EML) of organic light-emitting diode (OLED) devices, using either rigid or flexible substrates. Remarkable color stability was displayed in all cases for up to 15 V of bias voltage. The Commission Internationale de L'Eclairage (CIE) of the fabricated devices is located in the blue (0.16, 0.16), yellow (0.44, 0.50), or white region of the visible spectrum (0.33, 0.38) with minimal changes according to the ratio of the comonomers. The versatile methodology toward semiconducting polyethersulfones for polymer light-emitting diodes (PLEDs) developed herein led to the scaled-up production of luminescent polymers of up to 25 g of high-molecular-weight single batches, demonstrating the effectiveness of this approach as a straightforward tool to facilitate the synthesis of flexible and printable EMLs for large-area PLED coverage.

Thermoelectric properties of monolayer GeTe with Au, Ni, and Co substrates

Since the basic thermoelectric (TE) units must be integrated on substrates to form large-scale devices, it would be more practical to study the TE properties of the TE devices with substrates. Based on the first-principles calculation and nonequilibrium Green’s function method, we comparatively investigate the TE properties of the GeTe monolayer with its leads deposited on Au, Ni, and Co substrates, which are called GeTe-X (X = Au, Ni, and Co). It is shown that in comparison with the pristine GeTe monolayer, the figures of merit ZTs of the GeTe-X are seriously changed with one ZT peak appearing near zero chemical potential. The GeTe-Au and GeTe-Ni are of higher TE performance near zero chemical potential than the GeTe-Co, indicating one can choose Au or Ni as the substrate. Moreover, we show that the TE properties of the GeTe-X are sensitively dependent on the substrate layer number, the central scattering length, and the temperature, which necessitates the synergistic optimization of the related parameters to obtain the best TE performance. This work should be an important reference for designing practical GeTe-based TE devices.

Tribological behavior of graphene/h-BN vdW heterostructures: the role of defects at the BN layer

Molecular dynamics simulations and first principles calculations were performed to study the tribological behavior of graphene/h-BN (G/h-BN) heterostructures with vacancy and Stone–Wales (SW) defect under uniform normal load, revealing the mechanism of the effect of defect types on friction, and discussing the coupling effect of temperature and interfacial defects on the tribological behavior of G/h-BN heterostructures. Under the normal force of 0.2 nN/atom, the friction force of the four systems is 0.0057, 0.0096, 0.0077, and 0.26 nN, respectively. The friction force of SW defect heterostructure is 45 times that of perfect interface heterostructure. The influence of defect type on friction force is SW > SV > DV. By observing the dynamic change of the Z-direction coordinate position of the sliding layer atoms, the slip potential energy curves and the evolution law of the moiré pattern, the relationship between the structural morphology and the energy change of different defective heterostructures and the frictional behavior was investigated comprehensively and intuitively for the first time. From the perspective of atomic strain, the deformation of heterostructures at the atomic level was quantified. The results showed that at 300 K and 0 K, the maximum strain of atoms in the sliding layer was 11.25% and 9.85%, respectively. The thermal perturbation mainly occurs in the out-of-plane direction, which in turn affects the friction. Through density functional theory, it is found that under uniform load, it is difficult to form bonds between the graphene sliding layer and the substrate layer when the defects are in the h-BN substrate layer, which has less influence on the friction of the system, thus making the defective heterostructures also remainsuperlubricity state. These results provide a new understanding of the interfacial friction of G/h-BN defective heterostructure.

Coupled vibration and frequency response of a micropillar-enhanced QCM sensor

A theoretical model of a quartz crystal microbalance carrying a layer of substrate and an array of micropillars based on the classical and modified Timoshenko beam theory was established. By choosing specific substrate thickness and micropillar height, this composite sensor approaches the coupled resonance state, and thus significantly improving the mass sensitivity. The intentionally designed sensor is extremely sensitive to tiny mass. However, with increasing mass, the mass sensitivity decreases sharply and then tends to be constant. The frequency shifts calculated by two models have some differences, but their mass sensitivity is almost the same.

3D-Layers: Bringing Layer-Based Color Editing to VR Painting

The ability to represent artworks as stacks of layers is fundamental to modern graphics design, as it allows artists to easily separate visual elements, edit them in isolation, and blend them to achieve rich visual effects. Despite their ubiquity in 2D painting software, layers have not yet made their way to VR painting, where users paint strokes directly in 3D space by gesturing a 6-degrees-of-freedom controller. But while the concept of a stack of 2D layers was inspired by real-world layers in cell animation, what should 3D layers be? We propose to define 3D-Layers as groups of 3D strokes, and we distinguish the ones that represent 3D geometry from the ones that represent color modifications of the geometry. We call the former substrate layers and the latter appearance layers. Strokes in appearance layers modify the color of the substrate strokes they intersect. Thanks to this distinction, artists can define sequences of color modifications as stacks of appearance layers, and edit each layer independently to finely control the final color of the substrate. We have integrated 3D-Layers into a VR painting application and we evaluate its flexibility and expressiveness by conducting a usability study with experienced VR artists.

Patterning optimization for device realization of patterned GaAsSbN nanowire photodetectors

Vertically grown nanowires (NWs) are a research interest in optoelectronics and photovoltaic applications due to their high surface to volume ratio and good light trapping capabilities. This study presents the effects of process and design parameters on self-catalyzed GaAsSbN NWs grown by plasma-assisted molecular beam epitaxy on patterned silicon substrates using electron beam lithography. Vertical alignment of the patterned NWs examined via scanning electron microscopy show the sensitivity of patterned NW growth to the parameters of NW diameter, pitch, dose time, etching techniques and growth plan. Diameters range from 90 nm to 250 nm. Pitch lengths of 200 nm, 400 nm, 600 nm, 800 nm, 1000 nm, and 1200 nm were examined. Dry etching of the oxide layer of the silicon substrate and PMMA coating is performed using reactive ion etching (RIE) for 20 s and 120 s respectively. Comparisons of different HF etch durations performed pre and post PMMA removal are presented. Additionally, the report of an observed surfactant effect in dilute nitride GaAsSbN NWs in comparison to non-nitride GaAsSb is presented. Optimizations to patterning, RIE, and HF etching are presented to obtain higher vertical yield of patterned GaAsSbN NWs, achieving ∼80% of the expected NW µm2. Room temperature and 4 K photoluminescence results show the effect of nitride incorporation for further bandgap tuning, and patterned pitch on the optical characteristics of the NWs which gives insights to the compositional homogeneity for NWs grown at each pitch length.

Large-scale 2D heterostructures from hydrogen-bonded organic frameworks and graphene with distinct Dirac and flat bands

The current strategies for building 2D organic-inorganic heterojunctions involve mostly wet-chemistry processes or exfoliation and transfer, leading to interface contaminations, poor crystallizing, or limited size. Here we show a bottom-up procedure to fabricate 2D large-scale heterostructure with clean interface and highly-crystalline sheets. As a prototypical example, a well-ordered hydrogen-bonded organic framework is self-assembled on the highly-oriented-pyrolytic-graphite substrate. The organic framework adopts a honeycomb lattice with faulted/unfaulted halves in a unit cell, resemble to molecular “graphene”. Interestingly, the topmost layer of substrate is self-lifted by organic framework via strong interlayer coupling, to form effectively a floating organic framework/graphene heterostructure. The individual layer of heterostructure inherits its intrinsic property, exhibiting distinct Dirac bands of graphene and narrow bands of organic framework. Our results demonstrate a promising approach to fabricate 2D organic-inorganic heterostructure with large-scale uniformity and highly-crystalline via the self-lifting effect, which is generally applicable to most of van der Waals materials.

Displacement damage effect of proton irradiation on vertical β-Ga2O3 and SiC Schottky barrier diodes (SBDs)

In this study, we fabricated vertical Schottky barrier diodes (SBDs) based on wide bandgap semiconductor beta-phase gallium oxide (β-Ga2O3) and silicon carbide (SiC), respectively, and conducted proton irradiation experiments to analyze the radiation hardness of the SBDs comparatively. The effects of proton radiation on the performance of SBDs were assessed through measurements of forward current, capacitance, and breakdown characteristics. Both devices exhibited degradation in current and capacitance characteristics following proton irradiation, attributed to displacement damage (DD). Notably, the β-Ga2O3-based SBD demonstrated more pronounced deterioration compared to the SiC-based device despite similar vacancy distributions as confirmed by SRIM simulation. Moreover, a decrease in contact radius correlated with exacerbated degradation in the current characteristics of the β-Ga2O3-based SBD. Following proton irradiation, breakdown voltages of both devices increased due to elevated resistance induced by displacement damage. While both β-Ga2O3 and SiC-based SBDs experienced displacement damage under high fluence proton irradiation, the extent of performance degradation varied depending on the dimensions and quality of epitaxial and substrate layers.

A Fully Biodegradable and Ultra‐Sensitive Crack‐Based Strain Sensor for Biomechanical Signal Monitoring

AbstractA fully biodegradable, ultra‐sensitive, and soft strain sensor is pivotal for temporary, real‐time monitoring of microdeformations, crucial in disease diagnosis, surgical precision, and prognosis of muscular, and vascular conditions. Nevertheless, the strain sensitivity of previous biodegradable sensors, denoted by gauge factor (GF) up to ≈100, falls short of requirements for complex biomedical monitoring scenarios, specifically monitoring cardio‐cerebrovascular diseases with microscale variations in vascular surface strain. Here, a fully biodegradable, ultra‐sensitive crack‐based flexible strain sensor is introduced achieving GF of 1355 at 1.5% strain through integration of molybdenum (Mo) film, molybdenum trioxide (MoO3) adhesion layer, and polycaprolactone (PCL) substrate. Analysis of crack morphology of biodegradable thin‐film metals, including Mo, tungsten (W), and magnesium (Mg), reveals material‐dependent sensitivity and repeatability of crack‐based strain sensors. The effect of the adhesion layer and polymer substrate is also investigated. Overall morphological studies on the sensor present a comprehensive understanding of metal film cracking behavior and corresponding performance characterization, showing significant potential for highly sensitive sensors. A hybrid membrane composed of candelilla wax (Cw), beeswax (Bw), and polybutylene adipate‐co‐terephthalate (PBAT) is introduced to provide hydrophobic, yet flexible encapsulation. In vivo, short‐term (≈3 days) monitoring of vascular pulsatility underscores the potential of the sensing tool for rapid, accurate, and temporal disease diagnosis and treatment.

Wideband, polarization-insensitive rectangular-shaped with thin wire MXene-based resonator solar absorber for solar energy harvesting application

Solar absorbers are used in many different applications to collect solar energy. The Rectangular-Shaped with Thin Wire MXene-based resonator (RSWTWMR) is a unique solar absorber design that is proposed in this study. Aluminium and MXene are the materials used in the substrate and resonator layers of the RSWTWMR, respectively. MXene allows for the absorption of a large amount of solar light because of its remarkable absorption qualities and unique optical properties. The MXene-based resonator has a unique design with a thin wire and a rectangular box that makes it insensitive to polarization. RSWTWMR shows an astounding 95.67 % average absorption over three different wide bands. It is noteworthy that the absorption values in the 920 nm and 720 nm bandwidths exceed 90 % and 94 %, respectively. In addition, the absorption is more than 96 % at wavelengths of 550 nm. Additional research examined how well the system performs in air mass (AM1.5) conditions and examined how different factors, such as substrate and resonator thickness, affect absorption properties. Furthermore, the research looks at the impact of an angle of incidence, which is unaffected between 0 and 70°. This study suggests the RSWTWMR solar absorber has great promise for applications in solar energy harvesting.

Enhancing mechanical properties of GFRP–aluminum joints through Z pinning: a low velocity shear impact study

Studying the mechanical responses of GFRP and aluminum samples under varying loads is crucial for developing methods to enhance their mechanical properties. This research investigates the impact of z-pinning on single-lap adhesive joints through low-velocity shear impact tests. The study involves testing two types of joints: single-lap adhesive joints and single-lap hybrid pin-adhesive joints with six reinforcing pins, subjected to drop weight tests at load levels of 22.5, 27.5, and 32.4 J. The findings demonstrate that z-pinning can increase the joints’ load-bearing capacity by up to 18.87% and energy absorption by 20.58%. This enhancement is attributed to the additional composite substrate layers in the hybrid joint, which help absorb impact loads. In contrast, in the single-lap adhesive joint, only the layer adjacent to the adhesive bears the impact load. Observations from the tests indicate that in the single-lap adhesive joint, the first composite layer next to the adhesive undergoes complete delamination, whereas in the hybrid joint, all laminates fracture at the steel pins. In summary, this study underscores the significant potential of z-pinning to improve single-lap adhesive joints, providing an innovative approach to enhance their load-bearing capacity and energy absorption.

Reversible Intercalation of Organic Solvents in Graphite and Its Hindrance by a Strongly Adsorbing Supramolecular Monolayer

AbstractAt elevated temperatures, the prototypical organic solvents used to study the self‐assembly of supramolecular monolayers at liquid–solid interfaces alter a graphite substrate by intercalation. As a consequence, less strongly bound supramolecular monolayers become thermodynamically unstable, as probed by scanning tunneling microscopy. Complementary characterization by atomic force microscopy, confocal Raman spectroscopy and low energy electron microscopy consistently points to subsurface changes in the top few layers of the graphite substrate due to solvent intercalation. High‐temperature annealing at 900 °C in the vacuum restores the adsorption properties of the graphite substrates, indicating a high activation energy for deintercalation. However, strongly adsorbing hydrogen‐bonded monolayers of trimesic acid inhibit solvent intercalation and thus protect the graphite substrate. Mildly solvent‐intercalated graphite may prove useful as an easily prepared graphitic material with further weakened adsorption properties.

Tamm-cavity terahertz detector

Efficiently fabricating a cavity that can achieve strong interactions between terahertz waves and matter would allow researchers to exploit the intrinsic properties due to the long wavelength in the terahertz waveband. Here we show a terahertz detector embedded in a Tamm cavity with a record Q value of 1017 and a bandwidth of only 469 MHz for direct detection. The Tamm-cavity detector is formed by embedding a substrate with an Nb5N6 microbolometer detector between an Si/air distributed Bragg reflector (DBR) and a metal reflector. The resonant frequency can be controlled by adjusting the thickness of the substrate layer. The detector and DBR are fabricated separately, and a large pixel-array detector can be realized by a very simple assembly process. This versatile cavity structure can be used as a platform for preparing high-performance terahertz devices and opening up the study of the strong interactions between terahertz waves and matter.

Recent Developments and Challenges in Solid-Contact Ion-Selective Electrodes.

Solid-contact ion-selective electrodes (SC-ISEs) have the advantages of easy miniaturization, even chip integration, easy carrying, strong stability, and more favorable detection in complex environments. They have been widely used in conjunction with portable, wearable, and intelligent detection devices, as well as in on-site analysis and timely monitoring in the fields of environment, industry, and medicine. This article provides a comprehensive review of the composition of sensors based on redox capacitive and double-layer capacitive SC-ISEs, as well as the ion-electron transduction mechanisms in the solid-contact (SC) layer, particularly focusing on strategies proposed in the past three years (since 2021) for optimizing the performance of SC-ISEs. These strategies include the construction of ion-selective membranes, SC layer, and conductive substrates. Finally, the future research direction and possibilities in this field are discussed and prospected.

Optical constants and thickness gradients for light intensities in glass substrate layers and for complex electric fields in indium tin oxide (ITO) transparent conductor thin film layer, using Bode and Nyquist wavelength-dependent diagrams

Abstract The optical constants of a thin film layer of transparent conductive indium tin oxide (ITO), deposited on a thick glass substrate (G), were obtained for an ITO-G sample using a multilayer matrix method by fitting the regular transmittance and specular reflectance measurements to the collimated equations of the four-flux model, once the optical constants of the glass substrate layer had previously been obtained from a G sample of a single glass substrate layer. The accuracy of the results was validated using a feedback system called the three-extinction matching requirement, that is, obtaining the same extinction coefficients from the optical constants and from the forward and backward collimated differential equations of the four-flux model. To calculate the extinction coefficients of the glass from optical constants, the compression of the wavelength of the incident light in the glass substrate and in the thin ITO film layer was demonstrated, with a thickness less than the wavelength of incident light. The thickness gradients of the forward and backward collimated light intensities, on the glass substrate of the ITOG sample, were compared with those obtained for the single-layer G sample. Then, the thickness gradients for the complex forward and backward electric fields of the ITO thin film layer were obtained and plotted using spectral magnitude and phase Bode plots and new Nyquist plots, i.e. imaginary versus real parts, dependent on wavelength.

Wide‐angle band‐pass FSS with high‐frequency selectivity based on SIW cavity technology

AbstractThis work proposes and investigates a wide‐angle band‐pass frequency selective surface (FSS) with two sharp sidebands. The presented FSS element is made up of three metallic layers and two substrate layers in between, which are surrounded by a substrate‐integrated waveguide (SIW) cavity. The top metallic layer is identical to the bottom layer, composed of a square patch etched with a hexagonal groove, while the middle layer is a similar patch but with rectangular notch edges. This structure achieves a second‐order band‐pass response with highly frequency selectivity on either side of the passband. At the same time, this FSS demonstrates excellent stability for both transverse electric and transverse magnetic polarizations with incident angles between 0° and 60°. The electric current and field distributions are demonstrated for deep analysis. Furthermore, an equivalent circuit model is developed to further understand the operating mechanisms. To verify the validity of the design, we construct a prototype of the SIW‐based FSS (SIW‐FSS) and measured it. There is a fair degree of agreement between the measured and simulated results. Finally, we loaded it onto the horn antenna and tested its application in filtering antennas.

An isogeometric analysis of solar panels with a bio-inspired substrate

We in this paper propose a high-performance design using bio-inspired metamaterials for multilayered perovskite solar cell (MPSC) plates. The static bending and free vibrational responses of the newly designed MPSC panels with the presence of the triply periodic minimal surface (TPMS) substrate are subsequently investigated numerically. The displacements of the present plate model are then approximated by five-variable higher-order shear deformation theories (HSDTs). The weak forms are established for both the static bending and free vibration problems and subsequently derive the discrete forms using the NURBS-based isogeometric approach. To enhance the operational efficiency of solar panels in challenging environments, we integrate advanced lightweight architectures based on bio-inspired TPMS structures as a substrate layer into the original solar panel design. In this research, three widely employed TPMS structures: Primitive, Gyroid, and I-graph and Wrapped Package-graph (IWP), are examined in conjunction with two functional grading patterns implemented through the thickness direction. For the first time, the static bending performance of MPSC plates integrated into a TPMS-based substrate layer and subjected to wind pressure as well as thermal conditions is comprehensively studied. In addition, the influence of several significant factors on the free vibration behavior of MPSC plates is also elucidated. The findings show a promising and intriguing design avenue, particularly in the application of high-performance metamaterials to address contemporary challenges in renewable energy usage and environmental protection.

Reflective Surface for Linear-to-Linear and Linear-to-Circular Polarization Conversion at Multiple Frequencies

In this paper, a thin multiband reflective polarization converter surface is proposed that can reflect a circularly polarized (CP) wave in the following frequency bands: 7.8-8.10 GHz, 8.32-10.04 GHz, 10.80-13.75 GHz, 14.19-14.53 GHz, 16.22-16.52 GHz, and 16.77-17.18 GHz. It can also convert a linearly polarized (LP) incident electromagnetic wave into its orthogonal LP reflection wave in these bands: 8.14-8.25 GHz, 10.23-10.60 GHz, 13.90-14.08 GHz, and 16.59-16.71 GHz. With slotted semicircles supported by a metallic ground plane, the suggested unit cell of the periodic structure has significant stability in all frequency ranges, even at oblique incidence within a 75° angle limit. Furthermore, the suggested polarizer has an easy-to-manufacture construction that only needs one substrate layer and does not include any via holes. A sample prototype consisting of 30×30 unit cells was fabricated and tested, validating our design and simulations.

Synthesis of multilayered h-BN film on the molten Ni–B and the influence of underneath W substrate

High-quality two-dimensional hexagonal boron nitride (h-BN) film with tens of layers has been used as a universal substrate and capping layer for the van der Waals devices. Various approaches have been carried out for the synthesis of multilayered h-BN. Among them, the metal flux method is reliable in yielding h-BN crystals with high crystalline quality. However, this time- and energy-demanding method hinders its scale application. Herein, inspired by the metal flux method, we reported the time-effective growth of high-quality multilayered h-BN film (ca. 20 nm) on a molten Ni–B layer wetting on W substrate with chemical vapor deposition method. The film exhibits an excellent stacking sequence and a full-width at half maximum of the Raman E2g peak narrow to 9.5 cm−1. Cross-sectional high-resolution transmission electron microscopy and in-situ x-ray diffraction spectroscopy were carried out to investigate the crystal structure evolution of Ni–B layer wetting on W substrate. It is found that the low surface tension caused by the spreading of Ni–B alloy on the W substrate and the presence of the Ni subsurface may be responsible for the formation of multilayered h-BN with excellent crystalline quality. Meanwhile, the W diffusion in Ni–B-based melt can hinder the formation of h-BN under certain growth conditions. The approach demonstrates the feasibility of large-scale growth of multilayered h-BN, paving the way to future applications in van der Waals electronic and optoelectronic devices.