Diamond Structure Research Articles

Lattice optimization of fiber-reinforced polymer parts fabricated by additive manufacturing: the impact of Bezier curve order on mechanical properties

PurposeLattice structures are widely used for achieving optimal topology in additive manufacturing. However, the use of different lattices in a single design can result in stress concentrations at the transition points. This study aims to investigate the influence of Bezier curves on mechanical properties during the transformation from one lattice structure to another. It specifically focuses on the transition from a hexagonal to diamond lattice, using Bezier curves of various orders.Design/methodology/approachThe curves were designed by passing them through the same control points for different orders, such as third, fifth and seventh. The samples were sliced for 3D printing, and a tensile test was conducted. Young’s modulus and energy absorption abilities were measured to compare the mechanical properties of the models created with Bezier curves for the transformation between hexagonal and diamond models.FindingsThe analysis revealed a gradual change in mechanical properties from the hexagonal to the diamond lattice. Moreover, different orders of Bezier curves exhibited varying mechanical properties during the transformation between the two lattices. As the order of the Bezier curve increased, the mechanical properties smoothly changed from the hexagonal to diamond lattice. This prevented stress concentrations or mechanical behavior mismatch caused by sudden deformations at the transitions between the curves used in the design.Originality/valueThe study’s innovative use of Bezier curves of different orders to smoothly transformation between hexagonal and diamond lattices in additive manufacturing offers a practical solution to prevent stress concentrations and mechanical inconsistencies during such design transitions.

Thermal-hydraulic performance of TPMS-based regenerators in combined cycle aero-engine

The existing regenerator structure in aero-engine cannot satisfy the requirements with the development of hypersonic vehicles. The triply periodic minimal surface (TPMS) with superior thermal and mechanical performances has great potential for the regenerator. However, the study on TPMS structures as heat exchangers with high compactness and high power-to-weight ratio is still lacking. This study presents a complete workflow for evaluating the performances of TPMS heat exchangers. Based on this workflow, the thermal–hydraulic performances of Diamond, Fischer-Koch S (FKS), and printed circuit heat exchangers (PCHE) at different Reynolds numbers are investigated. Compared with the PCHE, the performance evaluation criteria of Diamond and FKS structures increased by 11.3–26% and 10.9–32.5%, respectively. This can be mainly attributed to the intensive turbulent mixing, large wall shear stress and high specific surface area of the TPMS structures. The thermal–hydraulic performance is also well explained by the field synergy principle. Based on the developed thermal and hydraulic correlations, the TPMS regenerators are designed and the results indicate that the power-to-weight ratio is improved by about 4 times with half volume of a PCHE. In summary, the TPMS regenerators can save space, reduce weight, and increase payload of aircrafts and have great application potential in the field of aerospace.

Characterization of a HPHT boron ion-implanted diamond X-ray mirror following high vacuum annealing

The incorporation of boron into a diamond lattice holds the potential to advance X-ray optics, offering the capability to manipulate various parameters of the lattice. This includes enhancing near-infrared absorption relative to pure diamond, thereby enabling Q-switchable optics. The use of MeV boron implantation emerges as a promising method for precisely doping the diamond lattice. However, for these optics to function effectively as Bragg-reflecting mirrors, ion implantation must be executed with meticulous attention to maintaining a strain-free, perfect diamond lattice. This study aimed to investigate the feasibility of utilizing a 9 MeV ion beam for high energy boron implantation. Different areas of a high-pressure, high-temperature (HPHT) diamond sample were subjected to irradiation with 9 MeV Boron ions, ranging in fluences from 5×1015 to 2.5×1016ions/cm2. Following boron implantation, high-temperature vacuum annealing was performed to restore the diamond lattice. Our assessment utilized X-ray rocking curve imaging, surface profilometry, and micro-Raman spectroscopy, with additional observations on near-infrared transmission properties. Our measurement of high-quality Bragg reflection through X-ray rocking curve imaging, sensitive to implantation-induced strain and defects, served as an key diagnostic for the effectiveness of this ion-implanted sample as a Bragg-reflecting optic.

A hands-on activity to introduce the structure of NV-center quantum bits in diamond

For the start of a secondary school level lesson series on quantum computing, we designed a hands-on modeling activity where students construct a model diamond lattice with a nitrogen vacancy (NV) defect. NV centers find application as qubits and sensitive magnetometers. This activity aims to help students visualize the structure of such NV centers within the diamond lattice, making the subject matter more tangible. The activity has proven to be challenging but feasible. It features both collaborative and competitive elements thereby surely creating an energizing buzz in the classroom.

Impacts of permeability and effective diffusivity of porous scaffolds on bone ingrowth: In silico and in vivo analyses

The permeability and the effective diffusivity of a porous scaffold are critical in the bone-ingrowth process. However, design guidelines for porous structures are still lacking due to inadequate understanding of the complex physiological processes involved. In this study, a model integrating the fundamental biological processes of bone regeneration was constructed to investigate the roles of permeability and effective diffusivity in regulating bone deposition in scaffolds. The in silico analysis results were confirmed in vivo by examining bone depositions in three diamond lattice scaffolds manufactured using selective laser melting. The findings show that the scaffolds with better permeability and effective diffusivity had deeper bone ingrowth and greater bone volume. Compared to permeability, effective diffusivity exhibited greater sensitivity to the orientation of porous structures, and bone ingrowth was deeper in the directions with higher effective diffusivity in spite of identical pore size. A 4.8-fold increase in permeability and a 1.6-fold increase in effective diffusivity by changing the porous structure led to a 1.5-fold increase in newly formed bone. The effective diffusivity of the porous scaffold affects the distribution of osteogenic growth factor, which in turn impacts cell migration and bone deposition through chemotaxis effects. Therefore, effective diffusivity may be a more suitable indicator for porous scaffolds because our study shows changes in this parameter determine changes in bone distribution and bone volume.

Researching on the Effect of Input Parameters on the Quality and Manufacturability of 3D-Printed Cellular Samples from Nylon 12 CF in Synergy with Testing Their Behavior in Bending.

The study of cellular structures and their properties represents big potential for their future applications in real practice. The article aims to study the effect of input parameters on the quality and manufacturability of cellular samples 3D-printed from Nylon 12 CF in synergy with testing their bending behavior. Three types of structures (Schwarz Diamond, Shoen Gyroid, and Schwarz Primitive) were selected for investigation that were made via the fused deposition modeling technique. As part of the research focused on the settings of input parameters in terms of the quality and manufacturability of the samples, input parameters such as volume fraction, temperature of the working space, filament feeding method and positioning of the sample on the printing pad were specified for the combination of the used material and 3D printer. During the experimental investigation of the bending properties of the samples, a three-point bending test was performed. The dependences of force on deflection were mathematically described and the amount of absorbed energy and ductility were evaluated. The results show that among the investigated structures, the Schwarz Diamond structure appears to be the most suitable for bending stress applications.

On the selective formation of cubic tetrastack crystals from tetravalent patchy particles.

Achieving the formation of target open crystalline lattices from colloidal particles is of paramount importance for their potential application in photonics. Examples of such desired structures are the diamond, tetrastack, and pyrochlore lattices. Here, we demonstrate that the self-assembly of tetravalent patchy particles results in the selective formation of cubic tetrastack crystals, both in the bulk and in the systems subjected to external fields exerted by the solid substrate. It is demonstrated that the presence of an external field allows for the formation of well-defined single crystals with a low density of defects. Moreover, depending on the strength of the applied external field, the mechanism of epitaxial growth changes. For weakly attractive external fields, the crystallization occurs in a similar manner as in the bulk, since the fluid does not wet the substrate. Nonetheless, the formed crystal is considerably better ordered than the crystals formed in bulk, since the surface induces the ordering in the first layer. On the other hand, it is demonstrated that the formation of well-ordered cubic tetrastack crystals is considerably enhanced by the increase in external field strength, and the formation of the thick crystalline film occurs via a series of layering transitions.

First-Principles Calculations of P-B Co-Doped Cluster N-Type Diamond

To achieve n-type doping in diamond, extensive investigations employing first principles have been conducted on various models of phosphorus doping and boron–phosphorus co-doping. The primary focus of this study is to comprehensively analyze the formation energy, band structure, density of states, and ionization energy of these structures. It is observed that within a diamond structure solely composed of phosphorus atoms, the formation energy of an individual carbon atom is excessively high. However, the P-V complex substitutes 2 of the 216 carbon atoms, leading to the transformation of diamond from an insulator to a p-type semiconductor. Upon examining the P-B co-doped structure, it is revealed that the doped impurities exhibit a tendency to form more stable cluster configurations. As the separation between the individually doped atoms and the cluster impurity structure increases, the overall stability of the structure diminishes, consequently resulting in an elevation of the ionization energy. Examination of the electronic density of states indicates that the contribution of B atoms to the impurity level is negligible in the case of P-B doping.

Mechanical Behaviour of Photopolymer Cell-Size Graded Triply Periodic Minimal Surface Structures at Different Deformation Rates.

This study investigates how varying cell size affects the mechanical behaviour of photopolymer Triply Periodic Minimal Surfaces (TPMS) under different deformation rates. Diamond, Gyroid, and Primitive TPMS structures with spatially graded cell sizes were tested. Quasi-static experiments measured boundary forces, representing material behaviour, inertia, and deformation mechanisms. Separate studies explored the base material's behaviour and its response to strain rate, revealing a strength increase with rising strain rate. Ten compression tests identified a critical strain rate of 0.7 s-1 for "Grey Pro" material, indicating a shift in failure susceptibility. X-ray tomography, camera recording, and image correlation techniques observed cell connectivity and non-uniform deformation in TPMS structures. Regions exceeding the critical rate fractured earlier. In Primitive structures, stiffness differences caused collapse after densification of smaller cells at lower rates. The study found increasing collapse initiation stress, plateau stress, densification strain, and specific energy absorption with higher deformation rates below the critical rate for all TPMS structures. However, cell-size graded Primitive structures showed a significant reduction in plateau and specific energy absorption at a 500 mm/min rate.

Picometer-Scale Atomic Shifts Governing Subdisordered Structures in Diamond.

Diamond is considered the most promising next-generation semiconductor material due to its excellent physical characteristics. It has been more than three decades since the discovery of a special structure named n-diamond. However, despite extensive efforts, its crystallographic structure and properties are still unclear. Here, we show that subdisordered structures in diamond provide an explanation for the structural feature of n-diamond. Monocrystalline diamond with subdisordered structures is synthesized via the chemical vapor deposition method. Atomic-resolution scanning transmission electron microscopy characterizations combined with the picometer-precision peak finder technology and diffraction simulations reveal that picometer-scale shifts of atoms within cells of diamond govern the subdisordered structures. First-principles calculations indicate that the bandgap of diamond decreases rapidly with increasing shifting distance, in accordance with experimental results. These findings clarify the crystallographic structure and electronic properties of n-diamond and provide new insights into the bandgap adjustment in diamond.

Molecular dynamics simulation study of nitrogen vacancy color centers prepared by carbon ion implantation into diamond

Nitrogen vacancy (NV) color centers in diamond have useful applications in quantum sensing and fluorescent marking. They can be generated experimentally by ion implantation, femtosecond lasers, and chemical vapor deposition. However, there is a lack of studies of the yield of NV color centers at the atomic scale. In the molecular dynamics simulations described in this paper, NV color centers are prepared by ion implantation in diamond with pre-doped nitrogen and subsequent annealing. The differences between the yields of NV color centers produced by implantation of carbon (C) and nitrogen (N) ions, respectively, are investigated. It is found that C-ion implantation gives a greater yield of NV color centers and superior location accuracy. The effects of different pre-doping concentrations (400–1500 ppm) and implantation energies (1.0–3.0 keV) on the NV color center yield are analyzed, and it is shown that a pre-doping concentration of 1000 ppm with 2 keV C-ion implantation can produce a 13% yield of NV color centers after 1600 K annealing for 7.4 ns. Finally, a brief comparison of the NV color center identification methods is presented, and it is found that the error rate of an analysis utilizing the identify diamond structure + coordination analysis method is reduced by about 7% compared with conventional identification methods.

Suppression of thermal diffusion of vacancies across p + -n junction structures in diamond. Application to SnV centers by ion implantation

This work reports on defect engineering related to optical centers in diamond by ion implantation. In particular, we demonstrate that thermal diffusion of vacancies to a few micrometers in depth can be effectively suppressed provided these are electrically charged and located within the depletion region of an abrupt p+ -n junction. The observed effect is complementary to the observations in the previous study (Favaro et al 2017 Nat. Commun. 8 15409) showing that charging of implantation-induced vacancies at such junction structures in diamond inhibits the formation of vacancy complexes in proximity to the targeted optical centers. In the present work we first generate vacancies near the surface of a low nitrogen doped CVD diamond substrate by He and C ion implantation before these are diffused by annealing at 1200∘C into the bulk. In the next step the depth distribution of NV centers generated by trapping of these vacancies is analyzed on a micron scale. For precise tuning of the implantation conditions we derived data on the boron and nitrogen doping by step etching of planar p+ resistors and p+ -n- p+ diode structures combined with electrical characterization and modeling. In the next step, tin-vacancy (SnV) centers were produced by 40 keV Sn implantation across the same junction structures at optimized conditions. In this way we observe an enhancement of the SnV yield and noticeable suppression of NV centers by diffusion and trapping of vacancies along the tracks of tin ions. Such ‘subsidiary’ NVs could significantly affect the emission of SnV and potentially other centers in the same spectral range.

Synthetic photonic lattices based on three-level giant-atom arrays

Simulating photonic lattices remains to be an interesting and important goal for quantum technologies. Here, we propose several simulation schemes of one- and quasi-one-dimensional photonic lattices based on arrays of diverse three-level giant-atom dimers. The resulting models, including diamond, Su-Schrieffer-Heeger, and ladder lattices, exhibit protected nearest-neighbor and greatly inhibited next-nearest-neighbor interactions, which are challenging with most state-of-the-art experimental platforms. Our proposals based on circuit quantum electrodynamics are tunable, scalable, and reconfigurable, thus providing opportunities for simulating more advanced photonic lattices and exploring unprecedented phenomena with no counterparts in conventional condensed matter physics.

Thermal performance against gravity of an AlSi10 AM heat pipe with a diamond lattice structure

Metal Additive Manufacturing has gained momentum as a viable production technique for specialized heat transfer devices, in particular for industrial sectors characterized by small production numbers associated with high-performance requirements. Within the space industry, ESA is leading and funding several applied research programs to explore the possibility to employ AM for building electronic boxes with embedded heat pipes, in order to reduce manufacturing post-processing steps and contact thermal resistances. In the context of tender 1-10238, the project “Heat Pipe Solutions for High Power Systems” (HPS2) has developed and tested lattice-based heat pipes, that are intended to be integrated in electronic modules. In this paper, the heat transfer performances as function of input power and tilt angle against gravity of a 150 mm long heat pipe with a 20 mm evaporator section and a 40 mm condenser section are presented and compared with the results of the models of performance limits, based on the measured properties of the lattice.

Real-time X-ray diffraction measurement on laser shock-loaded hexanitrostilbene (HNS)

Understanding the lattice evolution of hexanitrostilbene (HNS) is crucial for ensuring its safety and reliability under shock loading. However, the lack of in situ, real-time diagnostics has limited the availability of lattice parameters for shock-loaded explosives. In this study, we utilized dynamic X-ray diffraction technology to obtain the diffraction spectrum of laser shock-loaded HNS and to determine its temporal evolution. Additionally, by improving the laser energy, we initiated HNS and obtained the diffraction spectrum of detonation products during the detonation process. The experimental results showed the presence of a diamond structure in the detonation product, suggesting the existence of either diamond or diamond-like carbon. Our research not only elucidates the crystal structure of shock-loaded HNS and its detonation products but also provides an avenue for laboratory-scale investigations into dynamically loaded explosives, which furnishing an opportunity to unveil the underlying mechanism governing explosive dynamic response behavior.

Study on the crashworthiness of multi-cell thin-walled tubes filled with triply periodic minimal surface lattices

To improve energy absorption and efficiency and develop a structure with outstanding energy absorption capability, this study proposed designing multi-cell tubes filled with triply periodic minimal surface (TPMS) lattices. Based on experimental and simulation methods, the crashworthiness of multi-cell tubes filled with three types of TPMS lattices (Diamond, Gyroid, and Primitive) was investigated. Five multi-cell tube structures were fabricated by increasing the thin-walled tube corner units, improving the energy absorption efficiency by 67.98%. The results show that due to the coupling between TPMS lattices and thin-walled tubes, multi-cell tubes filled with TPMS lattices exhibited better crashworthiness performance. The energy absorption of multi-cell tubes filled with Diamond, Gyroid, and Primitive lattices increased sequentially. The energy absorption per unit mass and energy absorption capability were most notably enhanced for the multi-cell tubes filled with Diamond lattice, with energy absorption efficiency 17.24% higher and energy absorption 104.26% greater than empty multi-cell tubes. This inspires crash designs of rail vehicles and automotive fronts.

Pentamode Structures Optimized by Machine Learning with Adaptive Sampling

Pentamode structures, gain increasing interest as insulation or stealth material. The enhancements in computers and clusters make it possible to investigate those structures not only in theory but also with simulations. Their applicability to mechanical wave dampening is the main focus of the present work, which leads to a structure with good damping and enough strength as the goal. Therefore, a parametrized geometry based on the diamond lattice is examined within a design space. A factorial testing plan investigates the boundaries and gives first hints on the structure's behaviour under compressive and oscillatory loading and also reveals the necessity of a multi objective optimization. Feed‐forward neural networks are then trained to predict the material properties action and mass specific stiffness utilizing adaptive sampling in order to save time and computational cost. An optimization procedure to gain the structure with lowest mass, highest stiffness, and best damping capabilities, which means lowest action, is successfully implemented and yields the best compromise solution for an equally balanced optimization. This structure is then investigated by finite element simulations and confirms the optimization as well as the neural network training, thus being the best trade‐off of all optimization targets.

The effect of geometrical parameters on dimensional deviation in LPBF produced TPMS lattices: a numerical simulation based study

Triply periodic minimal surface (TPMS) lattices have drawn great attention both in academic and industrial perspective due to their outstanding mechanical behaviours. Additive manufacturing (AM) modalities enable the production of these lattices very easily. However, dimensional inaccuracy is still one of the problems that AM still faces with. Manufacturing of these lattices with AM modalities, then measuring the critical dimensions and making design changes accordingly is a costly process. Therefore, it is necessary to predict the dimensional deviation of TPMS lattices before print is a key topic. This study focused on prediction of dimensional deviation of laser powder bed fusion (LPBF) produced gyroid, diamond, primitive, IWP and Fisher-Koch lattices by using thermomechanical simulations. TPMS type, unit cell size, volume fraction, functional grading and part orientation were selected as design variables. Results showed that all the design inputs have effects on dimensional accuracy of LPBF produced parts and TPMS type has the most critical factor. Based on analysis of variance analysis, an optimum lattice configuration was proposed to obtain the lowest dimensional deviation after LPBF build.

The near surface damage and recovery of low nitrogen diamond implanted with MeV phosphorus ions

The purpose of this work is to provide a novel perspective for investigating the damage of diamond surfaces implanted by MeV phosphorus (P) ions and recovery of the surfaces after high-temperature annealing. SRIM simulation and low-temperature luminescence spectroscopy were performed to analyze the properties of the samples comprehensively. The results revealed that a certain degree of diamond lattice damage was caused without graphitization by the irradiation of 1 MeV P ions with a fluence value of 1015 ions/cm2. The SRIM simulation revealed that the ions that were implanted into the lattice collided with carbon atoms. These ions stopped at a depth of approximately 0.55 μm and generated intrinsic diamond defects on the diamond near the surface. The simulated defects were confirmed by the appearance of neutral single vacancy (GR1) centers in the photoluminescence (PL) spectrum after annealing at 400 °C. In addition, the annealing behavior of optical centers at 900 °C indicated significant damage recovery, including the disappearance of GR1 centers, combined with the increased intensity, slightly blue-shifted peak position, and narrowed FWHM of the nitrogen-vacancy (NV) center.

Controlling TPMS lattice deformation for enhanced convective heat transfer: A comparative study of Diamond and Gyroid structures

This study investigates the enhancement of convective heat transfer in Triply Periodic Minimal Surfaces (TPMS), focusing on Gyroid and Diamond lattice structures. An innovative lattice structure control method, employing a Deform-Control parameter (β), is proposed to modulate lattice deformation within their mathematical frameworks. Numerical simulations validated by experimental measurements were conducted to analyze the impact of varying β values from 0 to 0.75 on the thermo-hydraulic performance of both lattice types at flow rates ranging from 0.4 m3/h to 2 m3/h. The results indicate significant improvements in heat transfer efficiency with increasing β. For Gyroid structures, increasing β from 0.1 to 0.75 led to a 3.8% to 32.7% rise in convective heat transfer coefficients and a 3.2% to 23.7% increase in Nusselt numbers. Diamond structures also demonstrated enhancements, with coefficients and Nusselt numbers climbing by 2.9% to 10.4% and 3% to 7%, respectively. Notably, both Gyroid and Diamond structures showed increase in flow resistance at higher β values, highlighting a critical balance between heat transfer efficiency and fluid flow considerations. This research presents a promising control method for optimizing heat transfer in TPMS structures, offering opportunities for more efficient and effective heat dissipation solutions.