Lath Martensite Research Articles

Effects of Tempering on Microstructure and Properties of Additive Manufacturing Cu-Bearing AISI 431 Steel.

AISI 431 martensitic stainless steels (MSS) with 2.5 wt% Cu were fabricated via laser-directed energy deposition additive manufacturing followed by single-step tempering treatment. The influences of different tempering times at 600 °C on microstructure and mechanical properties of the as-deposited 431-2.5Cu MSS have been explored and analyzed. The as-deposited MSS specimen primarily consisted of lath martensite, austenite and M23C6 carbide. After the single-step tempering treatment at 600 °C, Cu-enriched (ԑ-Cu) nano-precipitates and reverse austenite can be formed and promoted by extending the tempering treatment. The microhardness, strength and elongation can be improved with increasing the tempering time up to 1.0 h, and subsequently reduced with the tempering time prolonging to 2.0 h. Compared to 431 MSS that requires a multiple-step heat treatment for excellent performance, the 431-2.5Cu MSS specimen presented superior tensile properties after single-step tempering at 600 °C for 1.0 h in the present work. The ultimate tensile strength (UTS), yield strength (YS) and elongation (EL) of one-hour tempered MSS were 1611 MPa, 1334 MPa and 16.3%, respectively. This study provides a quantitative theoretical reference and experimental basis for realizing short-process fabrication of the Cu-bearing MSS with high strength and ductility.

The Microstructure, Mechanical Properties, and Precipitation Behavior of 1000 MPa Grade GEN3 Steel after Various Quenching Processes

This study examines the microstructure, mechanical properties, and precipitation behavior of 1000 MPa grade GEN3 steel when subjected to various quenching processes, with a focus on the quench and partition (Q&P) technique. The Q&P-treated samples achieved 1300 MPa tensile strength and demonstrated superior yield strength, attributed to their refined substructure and their large amounts of precipitates. The quenched samples exhibited the thinnest martensite laths due to the highest martensite volume. Despite the as-annealed samples having the smallest grain size, the Q&P treatment resulted in optimal microstructural refinement results and a high dislocation density, reaching 1.15 × 1015 m−2. Analysis of the precipitates revealed the presence of V8C7, M7C3, M2C, and Ti(C, N) across various heat treatments. The application of the McCall–Boyd method and the Ashby–Orowan correction model indicated that quench and tempered (Q&T) samples contained the largest volume of fine precipitates, contributing to their high yield strengths. These findings offer valuable insights for optimizing heat treatment processes to develop advanced high-strength steels for industrial applications.

Analyzing the effect of different shielding atmospheres on fiber laser welding parameters for modified 9Cr-1Mo steel

The present research aims to investigate the influence of and the relationship between welding speed ( v), focal position ( FP), and laser power ( LP) as input parameters for fiber laser to weld P91 under pure argon and CO2 shielding atmospheres using response surface methodology and using the desirability approach; optimization of input parameters has been performed to maximize the depth of penetration ( DP) while minimizing the top bead width ( TW) and heat-affected zone width ( HW). The results indicate that laser power ( LP) has the most significant impact on depth of penetration ( DP), whereas welding speed ( v) affects top bead width ( TW) and heat-affected zone width ( HW). The optimal combination of parameters under argon shielding results in a significantly low heat input of 48 J/mm (0.048 kJ/mm) and 50 J/mm (0.050 kJ/mm) pure argon and CO2 shielding atmospheres, respectively. Despite the difference in heat input being only 4.08%, an 11.618% increase in DP is observed under the CO2 shielding atmosphere. Due to the high-speed nature of the welding process (argon: 82.65 mm/s and CO2: 79.283 mm/s) combined with the significant reduction in heat input, the heat-affected zone is limited to a mere width of 0.203 mm under an argon shielding atmosphere and 0.263 mm under the CO2 shielding atmosphere compared with that reported in the other welding processes without the dissolution of precipitates in the fusion boundary of heat-affected zone. Microstructural characterization of the fusion zone has revealed the presence of an untempered lath martensite structure with precipitate dissolution. The precipitate dissolution has resulted in grain coarsening of 47.76% in argon weld and 39.65% in CO2 weld compared with the base metal grain size of 6.07 µm.

Microstructure, hardness and creep properties for P91 steel after long-term service in a ultra-supercritical power plant

3 P91 pipes enduring 5∼6 × 104 h service had been found in an ultra-supercritical power plant. Hardness tests, microstructure observation(OM, SEM/EBSD, TEM/EDS) and creep rupture tests were performed, and the relationship between hardness, microstructure and creep rupture strength were discussed. Results showed that 1 of the 3 pipes still featured lath martensite, and its mechanical properties complied with relevant criteria. Other 2 pipes were characteristic of a mixture of ferrite and highly recovered martensite. Their hardness and creep rupture strength experienced severe degradation. Laves phase was observed in all 3 pipes. The most distinctive feature of the 2 low hardness pipes was their coarse and intragranularly distributed M23C6. This might be caused by abnormal heat treatments which could lead to the mixed microstructure of martensite and ferrite, and this kind of microstructure would degrade fast during service. Thus the low hardness had nothing to do with the precipitation of Laves phase.

Dissimilar joining of aluminum alloy and low-alloy carbon steel by resistance spot welding

In this work, the resistance spot welding (RSW) process was performed to join aluminum alloy and low-alloy carbon steel plates. The macro characteristics including nugget diameters and indentation rates, microstructure and tensile-shear strength of RSW joints were investigated. The results showed that the nugget of the RSW joints comprises a ‘bowl’ shape nugget on the aluminum side and an elliptical shape nugget on the steel side. Also, the intermetallic compound (IMC) layers containing Fe4Al13 and Fe2Al5 were formed around the aluminum/steel interface with the steel side having a tongue-shape and the aluminum side having a needle-shape. According to metallurgical evaluation and temperature distribution of RSW joints analyzed by the finite element method, the nugget on the aluminum side contained the dendritic grains and equiaxed dendritic grains. The nugget on the steel side consisted of a large amount of bainite and a small amount of coarse lath martensite. The nugget diameters and the indentations rates of RSW joints increased when increasing either welding current or welding time, and decreased when increasing the electrode pressure. The maximum values of nugget diameter and indentation rate of RSW joints were 9.076 mm and 4.144% when using the welding current of 16 kA, welding time of 450 ms and electrode force of 3 kN. In tensile-shear tests, the RSW joints showed a shear-off fracture mode. When increasing the welding current, welding time or electrode force, the tensile-shear strength of RSW joints increased first, and then reached a maximum, and finally decreased. The welding current of 16 kA, the welding time of 300 ms, and the electrode pressure of 3 kN were considered as the optimal welding parameters in the present study which resulted in the maximum tensile-shear strength of 2.24 kN. In addition, the IMC layers of the RSW joints exhibited a uniform and continuous appearance with a thickness of approximately 1.9 μm, and the IMC layer in the central area was thicker than that in the edge area.

The effect of welding speed on the microstructure, mechanical properties, and fatigue failure of Q690D high-strength steel

This study analyzes the effect of welding speed on the microstructure and mechanical properties of CO2 gas-shielded welded joints of 4 mm thick Q690D high-strength steel. The results show that the weld zone is mainly composed of acicular ferrite. The coarse-grained zone and fine-grained zone contain lath bainite and lath martensite. As the welding speed increases, the degree of recrystallization in the weld zone initially increases and then decreases. At the optimal welding speed of 38 cm/min, the tensile strength of the welded joint reached 692.1 MPa, with an elongation of 9.63 %. The maximum microhardness of the welded joint was 303 HV, and the residual stress was a tensile stress of 167 MPa. After fitting the S-N curve, the ultimate fatigue strength of the welded joint was 210 MPa. Both fatigue and tensile fracture surfaces displayed second-phase precipitate particles, impacting the mechanical properties.

Mechanical and Metallurgical behavior of Manual Metal Arc Welded P91 Ferritic Martensitic Steel Joints

In the nuclear power plant industry, Cr-Mo ferritic steels are indispensable due to their high-temperature tensile strength, creep strength, and resistance to stress corrosion cracking. This study evaluated and analyzed the mechanical properties and metallurgical behavior of indigenously developed filler (over matched with base metal) manual metal arc welded Cr-Mo ferritic steel (hereafter referred as P91 steel). The analysis revealed that the ultimate tensile properties of the weld joint exceed those of the unwelded metal, being 6% higher than the base metal. Consequently, the joint efficiency for the weld joint is 106%. However, the impact toughness of the weld pad is significantly lower compared to the unwelded metal, nearly 2.5 times less than the base metal. The weld metal region’s microstructure is characterized by untempered lath martensite pinned with dense dislocations, which is attributed to rapid cooling from the liquidus range. Furthermore, a distinct Heat-Affected Zone (HAZ) was identified adjacent to the weld metal region, which results from the elevated temperature experienced in this area.

Dislocation accumulation-induced strength-ductility synergy in TRIP-aided duplex stainless steel

In this study, we investigate the intrinsic mechanism of intensive and progressive transformation-induced plasticity (TRIP) effects and their different strength-ductility synergies using a resource-efficient 15Cr-2Ni duplex stainless steel. The progressive TRIP material exhibits a ductility that is more than twice that of the intensive TRIP material, as well as, a larger product of the ultimate tensile strength and ductility. This is attributed to the dislocation accumulation caused by different grain sizes of strain-induced martensite depending on the stability of the γ phase, which determines the strength and work hardening of steel. When the stability is low, the γ phase is sensitive to loaded stress and transformed into dispersed fine martensite immediately after yielding at a high rate. It induces a sigmoid-shaped dislocation accumulation to an approximately 10-fold increase in the dislocation density at a limited strain, resulting in intensive work hardening and a large ultimate tensile strength. As the stability is adequate, the γ phase is transformed into coarse martensite laths with a high critical load stress, which is initiated from a delayed strain at an extremely low rate and steadily accelerated as the strain increases. This process induces a gradually increased dislocation accumulation to a 2–3-fold increase in the dislocation density at large strains, resulting in progressive work hardening and an excellent ductility.

Effect of multi-element synergistic addition on the microstructure evolution and performance enhancement of laser hot-wire cladded Fe-based alloy

To satisfy the requirements of hardness and corrosion resistance for laser additive manufacturing of hydraulic supports, this study applied the synergistic addition of C, B, Cr, Ni, Nb and Mo elements in Fe-based alloys. The multi-phases, martensite + austenite + ferrite were designed. The microstructure, hardness and corrosion resistance of the coatings were analyzed. Increasing the C and B contents could significantly increase the hardness of the coatings, while the corrosion resistance was decreased. The corrosion resistance of the coatings was determined by the Cr contents. However, increasing the Cr contents to 20.0 wt % resulted in the ferrite structure with lower hardness (21 HRC). The coatings with 0.25 wt % C, 1.2 wt % B and 19.0 wt % Cr showed the optimal matching of hardness (56 HRC) and corrosion resistance (survived in neutral salt spray test≥300h). The resulted coatings were mainly consisted of dendritic structure. Fine lath martensite phase was dominant in the dendrite regions. The interdendritic regions were consisted of nano-sized intermetallics with a mixture of σ+Nb + FeNb + Cr2Nb+(Fe,Cr)2B + NbC compounds. These interdendritic regions (14.2 GPa) showed higher hardness than that of the dendritic regions (7.1 GPa). The high Cr contents with finer dendritic structures were the major mechanisms for the excellent combination of hardness and corrosion resistance. The precipitation and growth mechanisms of the interdendritic phases were elaborated. This work provides a valuable reference for laser hot-wire cladding to prepare Fe-based alloys with high hardness and excellent corrosion resistance.

Effect of Trace Element B on the Microstructure and Mechanical Properties of 8Cr4Mo4V Bearing Steel

By means of salt‐bath austempering treatment, microstructure observation, X‐Ray diffraction analysis, microhardness measurement, and friction and wear performance tests for 8Cr4Mo4V steels with standard composition and with trace addition of 0.005% boron, the effect of boron on the phase composition and mechanical properties of the steel is studied. The results show that trace element boron greatly increases the content of needle‐like lower bainite in the quenched microstructure, promotes the dissolution of undissolved carbides, reduces the content of M/A island, but coarsens grains. After tempering, trace element B increases the amount of bainite generation, refines the lath martensite, and significantly promotes the precipitation of carbides, whose size is finer, and the distribution is more dispersed. In terms of mechanical properties, trace element B improves the hardness by promoting the precipitation of the second phase and refining the lath martensite, and the increase in the bainite content changes the wear mechanism and enhances the wear resistance.

Effect of heat input on the microstructure and hydrogen embrittlement susceptibility of the coarse-grain heat-affected zone of CrMo steels generated using a Gleeble 3500 welding simulator

The changes in microstructure and hydrogen embrittlement (HE) susceptibility of the simulated coarse-grain heat-affected zone (CGHAZ) of CrMo steels under three distinct heat input conditions were investigated. The cooling time from 800 °C to 500 °C, represented by t8/5, increased from 100 s to 200 and 400 s.. The sample with t8/5 = 100 s has a microstructure consisting of martensite and a small amount of lower bainite. When the t8/5 was increased to 200 s and 400 s, the HAZ consisted of 65.43 % martensite and 34.57 % lower bainite and 4.53 % martensite with 95.47 % bainite, respectively. The HE susceptibility was assessed by slow strain rate tensile (SSRT) testing of hydrogen-charged samples, and the HE susceptibility index (IHE) declined from 87.89 % to 61.37 % when t8/5 increased from 100 to 400 s. The high dislocation density and hydrogen concentration in the sample with t8/5 = 100 s led to intergranular fracture and incresaed HE susceptibility. The martensite lath and cementite/ferrite interface are the sites of crack initiation in the sample with t8/5 = 200 s. In the sample with a cooling time of 400 s, the martensite/ferrite interfaces are the main crack initiation sites under hydrogen charging.

The Effect of Ultrafast Heating on the Microstructure and Mechanical Properties of the 2.2 GPa Grade Hot Forming Steel

The aim of the present work is to evaluate the effect of ultrafast heating on the microstructure and mechanical properties of hot forming steel. The initial microstructure utilized in this study was a cold-rolled microstructure, and the test steel was heated to full austenitization at a rate of 200 °C/s, followed by water quenching. It was observed that the ultrafast heating process significantly refines both the prior austenite grains and martensite laths while inheriting high-density dislocations from the initial cold-rolled microstructure. Consequently, the coupling mechanism between dislocation strengthening and grain refinement strengthening remarkably enhanced both the yield strength and ultimate tensile strength of the test steel. Eventually, the yield strength of the hot forming steel reached 1524 MPa, along with an ultimate tensile strength of 2221 MPa and uniform elongation of 5.2%.

Effects of resistance spot welding parameters on microstructure and mechanical properties of the dissimilar welded joint of quenching and partitioning steels

Abstract In this study, the effect of welding currents and welding times on the microstructure and mechanical properties of the dissimilar welded joints of Q&P980 and Q&P1180 steel was investigated. The macrostructure and microstructure of the dissimilar welded joints were characterized and the relationship between the welding parameters and the mechanical performance was analyzed using confocal laser scanning microscope, scanning electron microscope, and mechanical properties testers. Results show that with the increasing welding current and welding time, the nugget diameter, indentation rate, and maximum shear force of the dissimilar joint increase. The absorption energy of the dissimilar joint increases when the welding current rises, while it increases first and then decreases with elevating welding time. All the hardness distributions of the dissimilar Q&P980/Q&P1180 joints exhibit the highest hardness value in the fusion zone and a gradually decreasing hardness value in the heat-affected zone. Moreover, with increasing current and time, much higher hardness occurs at the FZ/HAZ boundary. The microstructure characterization illustrates the martensite fraction in the intercritical heat-affected zone of the Q&P1180 side is higher than that of the Q&P980 side after the welding process. With the increase of welding current and time, the lath martensite in the fusion zone gradually coarsens. The coarsening martensite and the nugget diameter are responsible for the change in the shear force and energy absorption of the dissimilar Q&P980/Q&P1180 joints.

Study on the influence mechanism of austenitizing temperature on the surface of corrosion-resistant mold steel

Abstract The microstructure of 4Cr13 corrosion-resistant plastic mold steel was studied. The martensitic experimental steel obtained by different heat treatment processes was used as the object. The effect of austenitizing temperature on its corrosion behavior was studied by microstructure characterization and electrochemical test. The results show that the microstructure of the test steel is mainly composed of martensite laths. Under the same experimental conditions, the corrosion resistance of the test steel decreases with the increase of austenitizing temperature, and the corrosion products are mainly composed of iron-containing oxides. The austenitizing temperature of 1000°C improves the corrosion resistance of the material, because the precipitation of a large number of small-sized Cr-containing carbides hinders the further erosion of the material and improves the surface quality.

In-situ electron channeling contrast imaging of local deformation behavior of lath martensite in low-carbon-steel

In-situ tensile Electron Channeling Contrast Imaging (ECCI) observations were performed on low-carbon steel lath martensite to elucidate its plastic deformation mechanisms under tensile loading. Two key deformation processes were identified through the direct observation of dislocation activity: intra-lath crystallographic slip and boundary sliding. The initial dislocation movement signifies the onset of microscopic yielding in lath martensite. As the applied stress increases, macroscopic yielding occurs when dislocations overcome internal barriers like high-dislocation-density walls within the laths. Out-of-lath-plane slip systems exhibit a strong interaction with the lath boundary, hindering their activity after initial small plastic deformation. In contrast, in-lath-plane slip systems predominantly contribute to plastic deformation. After the work hardening triggered by these slip systems, boundary sliding takes over the plastic deformation. The boundary sliding was found to accompany a rapid movement of the dislocation network adjacent to the boundary.

The influence of ferrite content, ferrite-austenite morphology, and orientation relationship on bainite transformation in intercritically annealed bainitic steels

This manuscript elucidates the influence of varying ferrite/tempered martensite (TM) content, morphology and orientation relationship (OR) between ferrite/TM with reverted austenite (γ) resulting at different intercritical temperatures on the subsequent bainite transformation behaviour. A comprehensive analysis was conducted using scanning electron microscopy, electron backscattered diffraction, and dilatometry. TM/bainite and ferrite/bainite steels were produced through intercritical annealing at 735 °C, 745 °C, and 765 °C, followed by austempering at 310 °C, using initially quenched and cold-deformed martensite, respectively. In samples without cold rolling, TM and bainite are alternately distributed at all intercritical temperatures. The γ reversion process in these samples led to the formation of acicular γ at prior martensite blocks and laths while globular γ was formed at prior γ boundaries and packet boundaries. Notably, a lower TM content correlated with increased globular γ formation. The acicular γ exhibited a Kurdjumov–Sachs (K-S) OR with prior γ. The globular γ formed at prior γ grain boundaries showed the K-S OR with the prior γ where it grows. However, globular γ formed at packet boundaries maintained the K-S OR with one of its surrounding blocks in prior γ where it lies. In the subsequent austempering process, bainite formed from reversed γ followed the K-S OR with TM. The TM and bainite shared the same variant in the same block. In samples with cold rolling, polygonal ferrite and bainite were distributed at all intercritical temperatures. Decreasing the ferrite content showed a coarsening of the microstructure. All polygonal samples revealed an irrational OR between bainite/martensite and ferrite. In samples with and without cold rolling, the bainitic formation rate decreased with increasing ferrite/TM, likely due to the high C and Mn content at the α/γ interface. Comparatively, the samples without cold rolling showed faster bainitic transformation than samples with cold rolling at similar ferrite/TM percentages, particularly noticeable at higher ferrite/TM content. The alternately arranged elongated TM and reversed γ lamellae increased the α/γ interfacial density for bainitic nucleation. Moreover, K–S oriented α/γ interfaces exhibited a lower activation energy for bainite nucleation. In samples without cold rolling, both high density of α/γ interfaces and K–S oriented α/γ interfaces collectively facilitate the bainitic transformation.

The defects and compressive behavior of NiTi alloy fabricated by laser powder bed fusion under a wide process space

A wide process space with laser power (P) of 50 ～ 400 W and scanning speed (s) of 50 ～ 2400 mm/s with the energy density (ED) range of 93–556 J/mm3 has been employed to fabricate NiTi alloy using laser powder bed fusion (LPBF). The optimal process window for near-full dense materials free of geometrical and metallurgical defects was determined. The characteristics of microstructures and compressive behaviors were comprehensively investigated. The results have shown that the process combinations of “high P + low s” and “high P + high s” are prone to bulging and warping defects due to rapid heating and cooling, respectively. A combination of “low P + low s” produces a relatively shallow melt pool without keyhole formation even at ED as high as 556 J/mm3. The austenite-martensite phase transition temperature (TTs) variations of ～80℃ were obtained with the process window free of porosity. The pre-existing martensite lath probably formed by plastic distortion (bulging) was responsible for the lowest critical stress of induced martensite (σSIM). The texture and nano-sized NiTi2/Ni2Ti4Ox precipitates also contribute to the variation of σSIM and residual strain among the samples with the same level of TTs upon compressive loading.

Abnormal martensitic transformation and morphology induced by chemical heterogeneity in additively manufactured maraging steel

We report on the effect of chemical heterogeneity on martensitic transformation in a maraging steel produced through laser-based directed energy deposition. Unlike conventional maraging steels with lath martensitic microstructures, the maraging steel exhibited an abnormal morphology, which was refined and elongated in the building direction. The growth direction of the abnormal lath martensite did not occur along the habit plane, while the lath martensite morphology corresponded to the cellular dendritic microstructure of the maraging steel. Among the elements partitioned to the interdendritic region, Ni played a major role in the reduction of the martensitic transformation start temperature (Ms temperature), thereby interfering with the martensitic transformation across the interdendritic region. The interdendritic region acted as a new domain boundary of martensitic transformation, where incomplete martensitic transformation in the region resulted in the retention of austenite.

The formation control and microstructure evolution of macrosegregation in laser offset welding on steel-nickel dissimilar alloy

To precisely control the melting of two base metals, laser offset welding is an effective method for managing the interfacial microstructure in dissimilar metal welds. Macrosegregation exhibits a markedly different morphology near the steel-nickel fusion line, which plays an important role in premature creep failure. In this study, it was found that an offset of the laser beam towards the nickel correlated with an increase in macrosegregation. When the laser beam was biased towards the steel, the partially mixed zone (PMZ) and transition zone (TZ) of 9Cr steel were identifiable within the macrosegregation, displaying a distinct solidification mode. Lath martensite and fine austenite formed in the PMZ, with alternating distributions of martensite and austenite observed in the TZ. Conversely, when the laser beam was biased towards the nickel, the unmixed zone (UMZ) of 9Cr steel was observed within the macrosegregation. Nanoindentation tests revealed that the maximum nanohardness in macrosegregation reached 5.90 GPa in the PMZ due to the formation of lath martensite, while the minimum nanohardness was 1.30 GPa in the TZ due to reduced martensite formation. Additionally, the TZ exhibited a significant reduction in resistance to plastic deformation. The various microstructures of macrosegregation were attributed to the solidification process and the dilution rate of 9Cr steel. When the liquidus temperature of WM exceeded 1455℃, a wide TZ formed in the macrosegregation due to adequate mixing. In contrast, when the WM had a significantly lower liquidus temperature than the 9Cr steel, only UMZ and PMZ formed in the macrosegregation due to preferential solidification and insufficient mixing. To minimize macrosegregation and eliminate the softening TZ, a laser beam offset towards the steel between 0.1 mm and 0.2 mm is recommended.

Thermokinetics driven microstructure and phase evolution in laser-based additive manufacturing of Ti-25wt.%Nb and its performance in physiological solution

A bio-compatible Ti-25 wt% Nb alloy fabricated from a blend of pure elemental powders using laser powder bed fusion additive manufacturing technique. The present work investigated the effects of processing conditions on the evolution of microstructures and its consequential material attributes, such as mechanical properties and corrosion performance. Thermal management strategies comprising laser powers of 200 W and 300 W in complement with a shorter scan length (1 mm) and substrate preheating above β-transus temperature (1123 K) were considered to achieve complete dissolution of niobium particles. The microstructure in the 200 W sample showed thin α′′ martensite needles in β matrix while martensite laths in the 300 W condition appear coarse and were twice the area fraction compared to that in 200 W build. On the other hand, microstructures in the heated substrate sample exhibited the evolution of α and β phases. A multi-scale finite element method based thermo-kinetic model spanning from melt pool scale to the component scale was incorporated to understand the mechanism of the evolution of microstructures during liquid–solid and solid–solid state transformation. Electrochemical performance in the simulated body fluid of the printed alloys was found to be significantly affected by the presence of martensite fractions. Both mechanical and corrosion behaviors were favorably influenced by adoption of the substrate preheating during additive manufacturing due to promotion of diffusional transformation of β to α at the expense of martensitic transformation.