Urban air mobility (UAM) is expected to offer new travel options for passengers to and from airports in the near future, despite uncertainties associated with regulatory issues, environmental concerns, and societal impacts. This paper analyzes the socioeconomic and behavioral factors that could influence users’ modal choices (including UAM services) for accessing and egressing airports. Using revealed and stated preference data collected at Milan airports (Italy), mixed logit and hybrid choice modeling specifications are estimated and compared with profile potential UAM passengers. Our findings suggest that the level of service, socioeconomic factors, and trip-related variables explain passengers’ choices better than latent traits such as fear of flying, propensity for technological advances, and expectations about the safety of UAM services. In other words, the additional complexity of hybrid choice modeling is not justified by the slight gain in likelihood compared with the estimated mixed logit model. The results also indicate that high-income individuals traveling for business purposes are the most likely demand segment to use UAM services, at least initially. Moreover, highly educated individuals and employees who have their travel expenses reimbursed for work trips are less likely to choose UAM services for airport access or egress, preferring traditional ground taxis.