Color-tunable white organic light-emitting diodes (CT-WOLEDs) have attracted widespread attention given their large color variation to meet the different daily scenarios from the perspective of circadian rhythm. However, most reported CT-WOLEDs, especially the tri-color devices, exhibit poor performances and sophisticated structures. Here, a simple structure tri-color CT-WOLED is demonstrated that simultaneously exhibits high efficiency, ultralong operation lifetime, and wide color-tunable range for dynamic sunlight emulation. The design is based on a newly developed platinum complex that can emit light efficiently in both monomer and aggregation states, providing voltage-dependent green-to-red phosphorescence emission, not only ensuring tunable colors in WOLEDs but also simplifying the device structure. Combining with a blue delayed fluorescence material, this hybrid device exhibits a wide range of tunable colors with Commission Internationale de l'Eclairage 1931 (CIE)coordinatesand correlated color emperature (CCT) shifts from (0.502, 0.474) and 2628 K at 2.6V to (0.211, 0.334) and 14860 K at 8V, achieving good visual alignment with sunlight color throughout the day. This same device also shows high external quantum efficiencies from 28.8% at maximum to 26.2% at 5000cdm-2. Furthermore, an impressively long time of 21,144h is achieved to decay to 90% of the initial luminance at 100cdm-2, being the longest among recorded CT-WOLEDs.
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