Adapting to wide load range variations is always one of the main goals pursued by megahertz (MHz) wireless power transfer (WPT) systems. For this, the nonlinear phenomenon of the rectifier has become a problem that must be solved. Compared with the method of optimizing the efficiency around the maximum power point in the traditional design, this paper proposes a global load optimization method. Meanwhile, a novel configurable compensated near-zero impedance angle rectifier (NIAR) is proposed to take full advantage of the global optimization method. The NIAR not only realizes the compression of a wide range of impedance angles, but also solves the classic problems of Class E rectifiers such as large stress, voltage asymmetry, and low real part of input impedance. The configurable design allows the system to adjust the rectifier unit according to the output index, thereby fully improving the coil efficiency, and providing a solution for the application of high-voltage and high-power MHz WPT systems in the future. To verify the effectiveness of the proposed NIAR and design method, a 60 W prototype was built, and a traditional full-wave rectifier was used for comparison. The results show that the proposed NIAR system exhibits better characteristics in terms of system efficiency, voltage stress, and symmetry.