AbstractIn this work, we developed a novel method to prepare a hydrogel‐based electronic skin by self‐assembling cross‐linking. The conductive hydrogel (named PGRS) integrates multiple properties. The hydrogel has good moisture retention (70 °C, 14 days), adhesion, and high elongation (2799 %). When the hydrogel is damaged externally, it can repair itself without external stimulation. The hydrogel adheres to the skin surface and monitors large strain movements, such as finger joints, wrist joints, elbow joints, head lowering and head lifting. It can also detect small movements, such as drinking and talking. It is used as an adhesive in liquid nitrogen (−196 °C). PGRS conductive hydrogel with multiple synergistic functions. It has great potential in the direction of flexible electronic skin. It indicates that PGRS conductive hydrogels have highly prospective applications in wearable devices.