Nanofluids hold great promise in improving transport processes in energy systems including hybrid fuel cells. In this present work, a mathematical model is developed for laminar free convection flow of Ag-water nano-additives in an enclosure in a porous medium with complex boundary conditions. Additionally, heat generation/absorption and viscous dissipation effects are included. Via appropriate scaling transformations, the conservation equations for mass, primary and secondary momentum, energy, and nanoiparticle vorticity with wall boundary conditions are rendered dimensionless. A finite-difference computational scheme known as the marker and cell (MAC) method, developed by Harlow and Welch, is occupied to solve the dimensionless, nonlinear coupled boundary value problem. A mesh independence study is included. The impact of parameters such as Eckert number (Ec), Darcy number (Da), Grashof number (Gr), Prandtl number (Pr), Reynolds number (Re), and Richardson number (Ri) are observed with physical framework. Graphical plots are presented for the impact of key control parameters on streamline contours, isotherm contours, and local Nusselt number. By heat sink (absorption), the Nusselt number is increased, whereas by heat generation it is reduced since there is a decrease in heat transferred to the boundary. The presence of viscous dissipation effects moves the streamlines toward the blue core and allows the temperature to increase in the neighborhood of the hot wall of the envelope. An increase in Richardson number induces a flip in vortex cell structures from an initially strong circulation cell on the left and weaker cell on the right, to the opposite distribution. Significant cooling is also induced in the core zone with an increasing Richardson number, and a decrease in vorticity is observed.
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