In the context of intelligent wastewater interception systems, the enhancement of decision control capability heavily relies on precise water quality classification outcomes. Nonetheless, conventional classification techniques encounter challenges in attaining satisfactory accuracy because of the intricate interplay between feature parameters of water quality and the imbalanced distribution of samples across different classes. In this paper, a least squares wavelet support vector machine (LSWSVM) is proposed with a double-transfer learning (DTL) strategy and an enhanced adaptive differential evolution (EADE) algorithm, referred to as DTL-EADE-LSWSVM. Firstly, the radial basis function is replaced by a wavelet function with multiresolution analysis to enhance the generalization ability of the LSWSVM. Secondly, three adaptive adjustment strategies for mutation factor, crossover probability and population size are designed in the EADE algorithm. Then, the EADE algorithm is adopted to obtain the optimal penalty factor and the parameter of the wavelet kernel function of the LSWSVM. Thirdly, the DTL strategy is developed to transfer the classification labels and model knowledge of the LSWSVM as well as the optimal population and optimal parameters of the EADE in the source domain to the target domain to improve the optimization efficiency and classification performance of the model in the target domain. Finally, the classification accuracy of the class imbalance samples is improved by reshaping the objective function. The experimental results indicate that the accuracy of the proposed DTL-EADE-LSWSVM classification model on balanced and imbalanced datasets is 92.5 % and 92.4 %, respectively, which is better than that of neural networks, stochastic deep forests and classical SVMs. In addition, the proposed DTL strategy has a stronger knowledge transfer capability than the single transfer learning strategy. The proposed DTL-EADE-LSWSVM is fully capable of classifying water quality in wastewater intercepting systems.