The main goal of this work was to assess the analytical capabilities of the full external reflection X-Ray Fluorescence Spectrometry method (TXRF) in the analysis of tea leaves and their infusions. As objects of the research, 19 samples of various sorts of Krasnodar tea were used. Two techniques of sample preparation were employed based on an open vessel acid digestion and a preparation of the suspension. The results of the certified standard tea sample analysis confirmed the possibility of the quantitative determination for the following elements: Mg, P, S, K, Ca, Fe, Ni, Cu, Zn, Br, Rb, Sr, Ba, and Pb. The best measurement results were achieved using the acid digestion technique. The analysis of the suspension could be carried out during the determination of elements such as Ca, Ni, Cu, Zn, Br, Rb, and Sr; for other elements, matrix effects were the interfering quantification factor. It was also found that the reliable determination of volatile elements, such as Cl and Br, was possible only when analyzing suspensions. The overall measurement uncertainty, including all stages of analysis, for most of the elements averaged to no more than 16%. The wavelength dispersive X-Ray Fluorescence method was used as a comparison method for the obtained measurement data of Krasnodar tea samples. The comparison was made using the Student's criterion and the convergence evaluation, based on which it was concluded that the data was in the good agreement for most of the elements. In addition, the analysis of tea infusions prepared according to the consumer procedure was carried out in order to study the solubility of the various elements and assess the quality and safety of tea. The results could be used in the laboratories for the quality control and for the assessment of the chemical composition of tea. Key words : X-ray fluorescence, TXRF, WDXRF, tea, infusion, multielement analysis DOI: http://dx.doi.org/10.15826/analitika.2019.23.2.009 (Russian) A.S. Maltsev 1, 2 , D.S. Sharykina 1 , E.V. Chuparina 3 , G.V. Pashkova 1 , A.G. Revenko 1 1 Institute of the Earth’s Crust, SB RAS, Lermontov st., 128, Irkutsk, 664033, Russian Federation 2 Kazan National Research Technological University, Marksa st., 68, Kazan, 420012, Russian Federation 3 Vinogradov Institute of Geochemistry, SB RAS, Favorsky st., 1A, Irkutsk , 664033, Russian Federation
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