Jet Fuel Research Articles

Hydrodeoxygenation of Isoeugenol-Derived Model Compound over Carbon-Supported Pt and Pt-SnS Catalysts for the Production of Sustainable Jet Fuel.

This study focuses on the sustainable production of bio-jet fuel through the catalytic hydrodeoxygenation (HDO) of isoeugenol (IE). Sucrose-based activated carbon supported bimetallic Platinum-Tin metal sulphides (PtO-SnS/AC) catalyst was prepared for HDO process. Physicochemical properties of catalysts with different spraying synthesis methods (in situ and ex situ metal doping) and Pt loading (0.1-1.0 %) were further investigated. The PtO-SnS/AC catalysts were characterised using various techniques such as X-ray absorption spectroscopy (XAS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), field-emission scanning electron microscopy (FESEM) and thermogravimetric analysis (TGA). Both HRTEM and FESEM results show the successful preparation of a spherical nanoparticles doped over activated carbon, and Pt was dispersed on the outer shell of the particles. The catalytic HDO of IE was evaluated in a batch system and showed a high yield and conversion as follows: IE conversion of 100 %, liquid-phase mass balance of 95.92 %, dihydroeugenol (DH) conversion of 99.32 %, propylcyclohexane (PCH) yield of 88.94 % and 2-methoxy-4-propylcyclohexanol (HYD) yield of 76.19 %. Moreover, the PtO-SnS/AC catalyst exhibited high reusability with low metal leaching and high coke resistance for 10 cycles. The catalyst was evaluated in a continuous flow reactor for 100 h at different reaction temperatures, and interestingly, the catalyst showed low deactivation with a high half-time.

Biofuel production from palm oil deoxygenation using nickel-molybdenum on zirconia catalyst using glycerol as a hydrogen donor

The growing demand for renewable energy has generated interest in biofuels as alternatives to fossil fuels. Second-generation biofuels, derived from deoxygenating fats and oils, have garnered a higher level of interest from industry and academia due to their potential for direct replacement of diesel and jet fuels. Palm oil, mostly cultivated in Thailand and composed of C16 and C18 fatty acids, is a primary feedstock sought for biofuel production. Palm oil deoxygenation contains several pathways that may or may not require hydrogen gas. This study aimed to produce biofuels in different fuel ranges, such as gasoline, jet fuel, and diesel, through palm oil deoxygenation using glycerol as a hydrogen source. Glycerol, a low-value byproduct, was used as a hydrogen donor, whereas nickel-molybdenum-supported catalysts were chosen for their high efficiency in deoxygenation and cost-effectiveness. The study investigated the impact of reaction time, temperature, and catalyst activation method on palm oil deoxygenation. Catalyst characterization methods, including XRD, SEM, TEM, XPS, FTIR, TGA, and N2-sorption, were employed to understand the role of catalysts’ activity during palm oil upgrading. Findings indicated that alkane hydrocarbons are the major components in liquid products. The presence of excess H2 in post reaction gaseous phase proves the hydrogen donation capability of glycerol. Increased reaction time and temperature facilitated the removal of oxygen from palm oil. Nickel-molybdenum on zirconia activated by sulfidation demonstrated higher stability than by reduction activation.

Within-chain parallelization-Giving Stan Jet Fuel for population modeling in pharmacometrics.

Stan is a powerful probabilistic programming language designed mainly for Bayesian data analysis. Torsten is a collection of Stan functions that handles the events (e.g., dosing events) and solves the ODE systems that are frequently present in pharmacometric models. To perform a Bayesian data analysis, most models in pharmacometrics require Markov Chain Monte Carlo (MCMC) methods to sample from the posterior distribution. However, MCMC is computationally expensive and can be time-consuming, enough so that people will often forgo Bayesian methods for a more traditional approach. This paper shows how to speed up the sampling process in Stan by within-chain parallelization through both multi-threading using Stan's reduce_sum() function and multi-processing using Torsten's group ODE solver. Both methods show substantial reductions in the time necessary to sufficiently sample from the posterior distribution compared with a basic approach with no within-chain parallelization.

A Rapid Analysis Method for Determination of Hydrocarbon Types in Aviation Turbine Fuel by Gas Chromatography-Mass Spectrometry.

A rapid analysis method for determination of hydrocarbon types in aviation turbine fuel was investigated in this study. A kind of reversible adsorption material packed as an unsaturated trap was used to separate saturated hydrocarbons and unsaturated hydrocarbons in the GC-MS system. No manual process or organic reagent was needed during the entire analysis process. The contents of 13 kinds of hydrocarbons, including paraffins, monocycloparaffins, dicycloparaffins, tricycloparaffins, monoolefins, cycloolefins, alkylbenzenes, CnH2n-8 aromatics, CnH2n-10 aromatics, naphthalenes, CnH2n-14 aromatics, CnH2n-16 aromatics, and CnH2n-18 aromatics were calculated by the characteristic mass fragments detected by MS with the modified matrices of ASTM D2425. The overall analysis time was less than 10 min. The precision of this test method has been conducted with 8 laboratories attended and 16 samples analyzed. The performance of this new method was demonstrated by comparing the results tested by ASTM D1319, ASTM D2425, and ASTM D6379. This rapid analysis method can provide hydrocarbon compositions of aviation turbine fuels or other liquid hydrocarbon samples within the same distillation range.

Comparative Analysis of Performance and Exhaust Emissions from Jet A1 Blends with Various Aviation Biofuels

The aviation industry is a significant contributor to greenhouse gas emissions. Given the growing demand for air travel and the unsustainable use of fossil fuels, it is crucial to develop and commercialize renewable fuels to reduce these emissions. Conventional jet fuels like Jet A1 release harmful pollutants such as carbon monoxide (CO) and nitrogen oxides (NOx) into the atmosphere. In contrast, biofuels offer a renewable, biodegradable, and non-toxic alternative that emits fewer pollutants, excluding NOx, and is easier to treat than fossil fuels. Due to their eco-friendly characteristics, biofuels have garnered attention in recent years. This study focuses on producing biofuels from jatropha oil and waste cooking oil. Jatropha oil, aside from its medicinal benefits such as antimicrobial and anticancer properties, can be effectively used in industrial applications, particularly for biofuel production. The production of biofuels from jatropha and waste cooking oil is of growing interest due to their environmental and economic benefits. The study investigates the production of these biofuels using appropriate catalysts under controlled experimental conditions, followed by blending the biofuels with Jet A1 fuel to achieve similar engine performance while mitigating the environmental impact of greenhouse gases from petroleum-based fuels.

Burner and Flame Transfer Matrices of Jet-Stabilized Flames: Influence of Jet Velocity and Fuel Properties

Abstract To achieve the decarbonization of electrical power generation, gas turbines need to be upgraded to combust high-hydrogen content fuels reliably. One of the main challenges in this upgrade is the burner design. A promising burner concept for a high-hydrogen fuel mixture are jet burners, which are highly flashback resistant thanks to their high bulk velocity. Due to its nonacoustically compact extension and the presence of hydrogen in the fuel mixture, new challenges arise in assessing the (thermo)acoustic response of this burner design. A burner transfer matrix (BTM) and the flame transfer function (FTF) or transfer matrix (FTM) are typically measured with the multimicrophone method (MMM) to assess the performance of new burner types in relation to thermoacoustic stability. With the switch toward hydrogen, the fuel/air mixture is significantly altered in its properties regarding the speed of sound and density, which are of fundamental importance for acoustic waves propagation and their reconstruction via the MMM, as highlighted in recent work. In this work, we extend this discussion by studying the influence of the gas composition within the burner when measuring BTMs, and its indirect effect on the assessment of FTFs. Experimentally, we achieve this by adapting the preheating temperature during the measurement of the BTM with a nonreactive mixture in order to match the speed of sound of the hydrogen–air mixture required to flow in the burner under reactive conditions. Additionally, we present an analytical model for the jet burner transfer matrix, which is validated against the experimental data. Since the BTM is fundamental for the assessment of the FTM and FTF, the propagation of the error of changing fuel mixtures in the burner is evaluated. The influence of the variation in reactant composition of the BTM on the FTM assessment is noticeable, particularly in the gain of the FTFs. Furthermore, the influence of the total mass flow and, thus, the bulk flow velocity on the FTF is analyzed.

Physiochemical View of Fuel Jet Impingement and Ignition Upon Contact with a Cylindrical Hot Surface

This study delves into ignition and flame dynamics involving a cylindrical hot surface impact. Previous studies have focused on the flat-wall hot surface interacting with fuel spray, leaving gaps in understanding the effects of cylindrical hot surfaces on fuel-air mixing and ignition. Using high-fidelity large-eddy simulations (LES), this study investigates how fluid elements, upon contacting an electronically activated glow plug structure, exhibit mixing and thermochemical properties. The analysis examines how this type of structure enhances fuel-air mixing and subsequently influences the thermochemistry behavior in conjunction with the fuel-specific combustion behavior. The study includes scenarios with free spray and non-thermal deposit cases to assess their mixing impact, alongside testing five different electric voltage inputs to study the thermally assisted ignition process. Results demonstrate that the cylindrical structure hinders flow, reducing its inertia and increasing flow residence time. Moreover, a significant Coandă effect due to the circular wall structure is identified, potentially serving as a mechanism for enhancing flame-holding. Furthermore, varying the input voltage notably affects ignition timing, revealing a non-monotonic ignition delay pattern with lower voltages. Detailed analysis highlights the critical role of negative temperature coefficient (NTC)-driven low-temperature chemistry (LTC) in the ignition process.

Investigating the oxidation characteristic of a hydro-processed bio-jet fuel: Experimental and modeling study

A rapid transition from conventional jet fuels to sustainable aviation fuels (SAFs) is imperative in order to reduce carbon emissions. Hydro-processed esters and fatty acids synthetic paraffinic kerosene (HEFA-SPK), as a type of SAF, exhibits broad applications. In this study, a new HEFA-SPK named ZH-HEFA was investigated. The fuel comprises 14% n-alkanes, 85% iso-alkanes and only 1% cycloalkanes by weight, with the majority of alkanes ranging from C9 to C17. Oxidation experiments of the fuel were conducted using an atmospheric pressure flow reactor at temperatures ranging from 550 K to 1075 K under three equivalence ratios (0.5, 1.0 and 1.5). Species mole fraction profiles were measured by an on-line gas chromatographic (GC). For comparison purposes, an experiment was also performed on RP-3, a conventional jet fuel commonly used in China, under the equivalence of 0.5. Compared to RP-3, ZH-HEFA exhibited significantly stronger low temperature reactivity and higher combustion conversion rates while demonstrating considerably lower yields of aromatics at high temperatures. The kinetic simulation of ZH-HEFA was achieved by proposing two surrogates and their corresponding kinetic models. Surrogate S-1 consisted solely of n-dodecane, while S-2 comprised 35% n-dodecane and 65% 2,6,10-trimethyl dodecane by weight. Both surrogate models were validated by the experimental data. S-1 exhibited a closer resemblance to the global oxidation characteristics of ZH-HEFA, whereas S-2 demonstrated improved accuracy in predicting the formation of small hydrocarbon intermediates during the fuel oxidation. Rate of production analysis revealed that the branched alkane component in S-2 possessed more pathways and greater capability than S-1 in generating C3 intermediates, which are important for the generation of aromatics. Furthermore, both models displayed good predictive performance for the auto-ignition properties of HEFA-SPK fuels.-

Aircraft performance of a novel SAF: Lower costs, lower environmental impact, and higher aircraft performance

Investing in Sustainable Aviation Fuel (SAF) is crucial for reducing the aviation industry’s carbon footprint and mitigating climate change. As global air travel demand increases, SAF offers a viable solution to significantly lower greenhouse gas emissions and enhance energy security, ensuring a more sustainable future for aviation. Additionally, converting biomass, particularly waste materials, into SAF adds value by turning potential environmental liabilities into valuable energy resources, promoting a circular economy and reducing overall waste. This study evaluates the aircraft performance of a novel sustainable aviation fuel (SAF) derived from multiple feedstocks in a hybrid biorefinery. SAF performance is compared to two conventional jet fuels, specifically a blend of 30% kerosene and 70% gasoline and JET-A1. The results demonstrated that the optimal SAF outperformed conventional fuels in terms of both thrust and range. Specifically, SAF exhibited a 17% increase in thrust and a 10% increase in range compared to conventional Jet A1 fuel. This novel fuel did not only mitigate CO2 emissions and achieve a cost reduction of 0.13 to 8.08%, but also exhibited superior aircraft performance. In addition, this fuel also meets the criteria of a “drop-in fuel” as it does not necessitate significant alterations to the currently existing CFM56-7B turbofan engine. This is due to its similar key thermodynamic indicators, such as heat capacities and combustion temperature, which are comparable to those of conventional jet fuels. In addition, this paper identifies the sensitivity of the CFM56–7B turbofan engine fuelled by the novel fuel.

Furanic jet fuels – Water-free aldol condensation of furfural and cyclopentanone

A method for the water-free, large-scale synthesis of bio-jet fuel precursors, distinct from traditional fossil-based sources, is introduced. This approach involves the aldol condensation of furfural with cyclopentanone, producing C10-C15 fuel precursors eligible for further hydrodeoxygenation to high-performance diesel and jet fuel hydrocarbons. In the context of process integration, aldol condensation reactions were conducted under water-free conditions, utilizing excess furfural as the solvent. Evaluation of various commercial catalysts confirmed the feasibility of running in excess furfural. Both basic and acidic catalysts demonstrated significant activity, with CaO and amorphous silica-alumina achieving ≥80 mol% conversion of cyclopentanone and yielding ≥80 mol% selectivity towards the desired fuel components within 5 h of reaction. However, an overlooked aspect is the notable formation of undesired heavy side products. Observations indicated that the high furfural concentration, combined with the use of strong acidic catalysts, were the primary cause of heavy side product formation. The strong base catalyst, CaO, significantly reduced the formation of these oligomers, but did not appear to stop it completely. Interestingly, water content did not appear to play a major role in byproduct selectivity. To further suppress the formation of oligomers, the use of process-owned intermediates as solvents is proposed.

Towards hydrogen gas turbine engines aviation: A review of production, infrastructure, storage, aircraft design and combustion technologies

This study explores the potential of hydrogen gas turbine engines for sustainable aviation, with a particular focus on their development for low subsonic to transonic flight regimes. Hydrogen offers notable advantages, including zero CO2 emissions and high energy density. However, its widespread adoption is prevented by significant challenges in production, infrastructure, storage, aircraft design, and combustion technology. The limited availability of green hydrogen – the global production totaled only 127 kt in 2023, with 76% produced in China - raises concerns about the feasibility of a rapid shift to hydrogen-powered general aviation. Despite numerous pledges for hydrogen adoption in the Western world, major aircraft manufacturers have primarily engaged in marketing activities rather than substantial product innovation. To date, the only hydrogen aircraft demonstrator from this century is the 2012 Boeing Phantom Eye, which utilized modified hydrogen internal combustion engines rather than a gas turbine engine. The only hydrogen aircraft demonstrator with a gas turbine engine was the 1988 hybrid Tupolev Tu-155 which coupled one hydrogen gas turbine engine to other two jet fuel engines. This paper evaluates the current state of hydrogen gas turbine technology, comparing its combustion characteristics with traditional jet fuels and examining various NOx emission control techniques. It also investigates the potential of micro-mix lean combustion and staged combustion to achieve efficient and low-emission hydrogen combustion in gas turbines. Given the more extensive experience with terrestrial gas turbines compared to their aeronautical counterparts, the review includes insights from terrestrial power generation applications. Additionally, it considers hythane - a blend of hydrogen and natural gas - as a transitional solution for significantly reducing CO2 emissions while progressing towards net-zero targets. The review underscores the urgent need for advancements in green hydrogen production, technology, and infrastructure to overcome existing barriers and enable a more sustainable aviation future powered by hydrogen. Importantly, the review emphasizes the need to move beyond mere virtue signaling and make tangible progress toward a hydrogen economy.

Integrating microwave pyrolysis and hydrotreating for converting low-density polyethylene into jet fuel

With the increasing plastic waste and its environmental impact, finding effective recycling solutions is essential. Cracking plastic waste followed by hydrogenation could be a promising method for producing jet fuels. In the present work, microwave-assisted pyrolysis (MAP) with MgO combined with hydrotreating with a Ni/Biochar catalyst was firstly proposed to convert low-density polyethylene (LDPE) into jet fuel. The pyrolysis process yielded 48.5 wt% of liquid product, with C5−C15 hydrocarbons and olefins accounting for 87.6% and 65.5%, respectively. During the hydrotreating process with 10% Ni/Biochar at 300°C of temperature and 2 MPa of initial H2 pressure, the pyrolysis oil was successfully hydrotreated, resulting in 98.4% paraffins and 1.6% aromatics with liquid yield of 80.6 wt%. Among them, C5−C15 hydrocarbons created 96.1%. The kinetic analysis indicated an activation energy of 89.9 kJ/mol for hydrogenated LDPE pyrolysis oil (HPPO). Characterization of the Ni/Biochar catalyst after reaction showed a BET surface area of 438 m2/g, similar to that of the fresh catalyst, with minimal coke formation noted via XRD, TEM, and TG analyses. XPS and FTIR indicated negligible oxidation of Ni0 during hydroprocessing. After 6 cycles, the catalyst remained high abundance for paraffins and C5−C15 hydrocarbons, namely, 98.4% and 94.0%, respectively, demonstrating its stability.

Comparative analysis of the combustion and emission characteristics of biojet and conventional Jet A‐1 fuel: a review

AbstractConventional jet fuels derived from fossil sources contribute to greenhouse gas emissions and air pollution, leading to climate change. Recent studies have shown that biobased jet fuels from different feedstocks offer a more sustainable alternative to conventional fuels as they are derived from renewable biomass, reducing greenhouse gas emissions. The major feedstocks reviewed are jatropha curcas, camelina, karanja oil, waste cooking oil, and municipal solid waste. They offer diverse benefits for sustainable aviation fuel development. As a comparative analysis, this review examined jet fuel characteristics based on their physicochemical properties, namely energy content, viscosity, calorific value, cetane number, and freezing and flash points. The objective was to understand the influence of the properties on performance evaluation, environmental impact, and combustion characteristics. The properties of biojet fuels are compared with their fossil counterparts to validate their suitability as renewable alternatives and their benefits in terms of emissions reduction and engine performance. Biojet fuels perform better in terms of lower sulfur content, lower soot content, and a lower freezing point, their aromatic content, and their high cetane number. This study enhances the understanding of biojet fuels and their quality, and supports the development of sustainable fuel options. Overall, adherence to the American Society for Testing and Materials (ASTM) D7566‐18 standard is crucial for the acceptance and integration of biojet fuels into the aviation sector. Future research should explore feedstocks such as wood biomass, wastepaper, and agricultural residues for biojet fuels. It should also investigate the combustion and emission characteristics of biosourced aviation fuel at higher blending ratios (>50% by volume) with fossil Jet A‐1.

Fuzzy Rule-based Comparison of Alternative Jet Fuels

In today's aviation alternative jet fuels play an increasingly important role. Their application incurs new engineering and environmental protection challenges. The key properties of their feasibility of integration are from technological point of view aging behavior and applicability as well as from environmental protection point of view the carbon footprint. During the comparison process experts can evaluate the above characteristics with linguistic variables. The application of linguistic variables always results in some degree of uncertainty – by their subjectivities. Fuzzy calculation methods are used to mathematically describe these uncertainties. The purpose of this study as a pilot project is to gain experience in developing a methodology of a multi-level fuzzy rule-based jet fuel qualification process.

Insight of low flammability limit on sustainable aviation fuel blend and prediction by ANN model

Sustainable aviation fuel (SAF) blend has been confirmed to benefit for greenhouse gases reduction, and thus the property of blend fuel should be understanded the detail to support the utilization in aircraft. Low flammability limit (LFL) is a key property of jet fuel which should be sufficiently flammable to burn in combustor of aeroengine and meanwhile should be non-flammable for safety storage in fuel tank of aircraft. LFL of fuel could be influenced by integrating effects including molecule structure, intramolecular chemical bond energy and binding energy of molecule to molecule. Three types of theoretical models, based on different individual view including LFL of every pure hydrocarbon, stoichiometric concentration, and combustion enthalpy, present unsatisfactory simulation results, which can be deduced without integrating all potential influence factors together. The artificial neural network (ANN) approaches have been involved to bridge the relationship of the complex compositions in jet fuels with LFL. For providing adequate and available composition input, the boundary of fuel compositions has been extracted based on constrains of boiling point, flash point and freeze point coupling with statistic petroleum-based jet fuels. By clustering analysis, 43 critical classes of compositions, extracted as surrogate hydrocarbons based on with similar LFL within 1 % deviation, have been deployed as input matrix. ANN-LFL model, trained by only drop-in fuel with feature of Sigmoid function as an activation function, can distinguish drop-in fuel with non-drop-in fuel. ANN LFL model can predict LFL of drop-in fuel with 0.988 accuracy. The predict output value of non-drop-in fuel could present obvious deviation with traditional jet fuel. The optimization methodologies of ANN-LFL model could be improved the understanding of LFL and extend ANN in SAF utilization.

Jet Fuel as a Source of Soil Pollution: A Review

Kerosene is widely used in various types of anthropogenic activities. Its environmental safety is mainly discussed in the context of aerospace activities. At all stages of its life cycle, aerospace activity impacts the environment. In aviation, the pollution of atmospheric air and terrestrial ecosystems is caused, first of all, by jet fuel and the products of its incomplete combustion and is technologically specified for a number of models in the case of fuel leak during an emergency landing. In the rocket and space activities, jet fuel enters terrestrial ecosystems as a result of fuel spills from engines and fuel tanks at the crash sites of the first stages of launch vehicles. The jet fuel from the second and third stages of launch vehicles does not enter terrestrial ecosystems. The fuel components have been studied in sufficient detail. However, the papers with representative data sets and their statistical processing not only for the kerosene content, but also for the total petroleum hydrocarbons in the soils affected by aerospace activity are almost absent. Nevertheless, the available data and results of mathematical modeling allow us to assert that an acceptable level of hydrocarbons, not exceeding the assimilation potential, enters terrestrial ecosystems during a regular aerospace activity. Thus, the incoming amount of jet fuel disappears rapidly enough without causing any irreversible damage.

Typical Deterioration Process of Jet Fuel Quality During Maritime Storage and Transportation

Typical Deterioration Process of Jet Fuel Quality During Maritime Storage and Transportation

Performance of Hydrothermally Prepared NiMo Dispersed on Sulfated Zirconia Nano-Catalyst in The Conversion of Used Palm Cooking Oil into Jet Fuel Range Bio-Hydrocarbons

Human efforts to overcome environmental problems from using fossil fuels continue, such as hydroconversion of biomass into bio-jet fuel. Research on producing a jet fuel range of bio-hydrocarbons from used palm cooking oil catalyzed by sulfated zirconia impregnated with nickel-molybdenum bimetal has been successfully conducted. The hydrothermal method synthesized the nano-catalyst material in the sulfation and impregnation processes. The hydroconversion process was carried out at atmospheric pressure and a temperature of 300–600 °C for 2 h with a hydrogen gas flow rate of 20 mL/min and a catalyst-to-feed ratio of 1:100 (wt%). Compared with zirconia and sulfated zirconia, NiMo-impregnated sulfated zirconia showed the best activity and selectivity in bio-jet fuel production with liquid product and selectivity of 61.07% and 43.49%, respectively. This catalyst also performed well in three consecutive runs, with bio-jet fuel selectivity in the second and third runs of 51.68% and 30.86%, respectively. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Rapid analysis of spilled petroleum oils by direct analysis in real time time-of-flight mass spectrometry with hydrophobic paper sample collection

BackgroundOil spills are widespread and can cause devastating environmental consequences. Rapid oil identification is critical to find the origin of the spill, monitor the environment, and lead to informed mitigation measures. The current standard methods in oil spill identification are precise and reliable, but require extensive sample preparation, long instrument runs, and time-consuming data processing. Direct analysis in real time time-of-flight mass spectrometry (DART-ToF MS) has been employed to screen for spilled petroleum oils, with results obtained in mere hours. The present study introduced an innovative, simple, and fast oil sampling method using hydrophobic filter paper and demonstrated its compatibility with DART-ToF MS analysis. Motor oils, jet fuels, marine diesels, crude oils, intermediate fuel oils, heavy fuel oils, and diluted bitumen were collected using the filter paper sampling method. Classification models were constructed from the spectral data by heat map inspection followed by principal component analysis (PCA) and discriminant analysis of principal components (DAPC). Oil slicks and weathered oil slicks were prepared from five oil types, and samples from each slick were collected using filter paper.ResultsThe filter paper technique allowed for effective oil sampling and data acquisition by DART-ToF MS for diluted source oils, oil slicks and weathered oil slicks. Classification via the constructed DAPC models indicated that the DART-ToF MS instrument in tandem with filter paper sampling and multivariate statistics can accurately identify common oil types, with significant improvement of sample collection and turnaround time.ConclusionsThe promising classification results, simple sample collection, and rapid data analysis illustrate the potential use of hydrophobic filter paper and DART-ToF MS as tools in managing large scale oil spill emergency situations.

Jet Fuel Contamination: Forms, Impact, Control, and Prevention

This paper describes commonly used processes to produce aviation fuel and alternative routes with potential production yields for sustainable aviation fuels (SAF) like HEFA and ATJ. It also presents the possible sources (crude oil, refinery processes), causes (filter clogging, engine failure), and forms of contamination in both conventional and alternatively produced aviation fuels. Special attention is focused on the threats of fuel contamination with solid particles/trace elements, water, microorganisms, and fatty acid methyl esters (FAME). This review also presents the standard and novel advanced methods (ICP-MS, MALDI, ViPA) for identifying contaminations in aviation fuel. It also identifies possible ways to control and eliminate the risk of contamination, such as the fallowing coherent JIG system to ensure the quality of aviation fuel. Another approach that is very interesting and worth considering for future development is the idea of predictive maintenance and machine learning in monitoring and detecting contamination.