Combustion is often accompanied by environmental pollution due to incomplete reaction. A non-excited flame usually exhibits poor combustion performance with features of diffusion flame such as dual-peak temperature distributions and large combustion product concentrations. Efficient fuel-air mixing has been identified as a key factor in mitigating this issue. The present study investigated the effects of the acoustic excitation Strouhal number on the combustion performance of a backward-inclined jet flame in crossflow. A loudspeaker was used to induce jet pulsations with excitation Strouhal numbers ranging from 0.47 to 1.54 at a pulsation intensity of 0.90. Time-averaged and instantaneous flame images were captured using digital cameras. A customized R-type thermocouple and a commercial gas analyzer were employed to analyze the thermochemical structures. A critical excitation Strouhal number of approximately 0.9, distinguishing two characteristic flame modes: strongly affected flame (SA flame) and weakly affected flame (WA flame), was found. At excitation Strouhal numbers lower than the critical value, the SA flame featured single-peak temperature profiles and low unburned hydrocarbon, carbon monoxide, and nitric oxide emissions. The combustion performance was significantly improved due to the strong mixing effect induced by the acoustic excitation. The WA flame appeared at excitation Strouhal numbers higher than the critical value. It exhibited dual-peak temperature distributions and slightly improved combustion performance. The dynamic behavior and emissions of acoustically excited jet flames offered a fascinating insight into the influence of excitation Strouhal numbers on combustion characteristics. More excitation conditions were expected for future research.