Isotopic Composition Of Precipitation Research Articles

Local Meteoric Water Lines in a Semi-Arid Setting of Northwest China Using Multiple Methods

The local meteoric water lines (LMWLs) reflect water sources and the degree of sub-cloud evaporation at a specific location. Lanzhou is a semi-arid city located at the margin of the Asian monsoon, and the isotope composition in precipitation around this region has aroused attention in hydrological and paleoclimate studies. Based on an observation network of stable isotopes in precipitation in Lanzhou, LMWLs at four stations (Anning, Yuzhong, Gaolan and Yongdeng) are calculated using the event-based/monthly data and six regression methods (i.e., ordinary least squares, reduced major axis, major axis regressions, and their counterparts weighted using precipitation amount). Compared with the global meteoric water line, the slope and intercept of LMWL in Lanzhou are smaller. The slopes and intercepts calculated using different methods are slightly different. Among these methods, precipitation-weighted least squares regression (PWLSR) usually had the minimum average value of root mean sum of squared error (rmSSEav), indicating that the result of the precipitation weighted method is relatively stable. Higher precipitation amount and lower air temperature result in larger slopes and intercepts on an annual scale, which is out of accordance with the summertime.

Geochemical Study on the Annual Variation of Oxygen Isotope and Chemical Composition of Groundwater in the Sho River Alluvium Fan, Toyama, Japan, as an Investigation of Selected Qualitative Aspects of Efficient Utilization of Groundwater Heat

Seasonal variations of water temperature, electric conductivity, and oxygen isotope and chemical composition of shallow groundwaters and river waters were determined in the Sho River alluvial fan, western Toyama Prefecture, Japan, to examine groundwater heat utilization for indoor climate control. Samples were collected at 31 sites every 2 months for 1 year and at 11 representative sites monthly. In addition, the results of monthly precipitation amount and oxygen isotope composition of precipitation collected within the region during the same period were also taken into account. The sources of the shallow groundwaters are a mixture of river water and precipitation. The contribution of precipitation to groundwater is generally small along the Sho River but reaches as much as 80% along the Oyabe River and in the south and west of the alluvial fan. Though the origin of the groundwater differs regionally, water temperature is fixed at around 15 °C throughout the year in the northern part of the alluvial fan, and open-type ground source heat pump systems can be used for cooling and heating there, if adequate quantitative aquifer properties (exploitable groundwater amounts) are present.

Moisture source identification based on the seasonal isotope variation of precipitation in the Poyang Lake Wetland, China

Study regionThe wetland ecosystem of Poyang Lake, the largest freshwater lake in China. Study focusThe focus of this study is to understand the climatic influence on precipitation isotopic composition and the mechanism underlying the seasonal isotope variation of precipitation in the Poyang Lake Wetland. New hydrological insights for the regionThe Local Meteoric Water Line was established as δ2H = (8.83 ± 0.18) × δ18O + (12.77 ± 0.86) (R2 = 0.93, p < 0.01, n = 186). A total of seven moisture sub-sources contributing to precipitation were identified using the HYSPLIT model, among which distinct differences in isotopic signatures were revealed. The seasonal isotopic variation of precipitation in the study area was found not to respond to local meteorological factors. An increase in the relative occurrence frequency and relative contribution to precipitation of the continental source was found from summer to winter, which explains the seasonal variation in precipitation δ18O and d-excess. Combining the results of back trajectory analysis and isotopic statistics for the sub-source classification, the seasonal evolution of precipitation isotopes is considered to be caused by variations in the contribution from various moisture sources with distinct isotopic characteristics, which are further controlled by monsoon activities. This study highlights the importance of regional-scale moisture source dynamics and atmospheric circulation for the seasonal isotope variation of precipitation in the Poyang Lake Wetland.

Measurements and applications of δ2H values of wood lignin methoxy groups for paleoclimatic studies

Stable hydrogen isotope values of wood lignin methoxy groups (δ2HLM) are increasingly applied to reconstruct the stable hydrogen isotope composition of precipitation (δ2Hprecip) and mean annual temperatures (MAT) of mid latitudes regions. Recently, the analytical procedure for measuring δ2HLM values was considerably improved by the availability of new reference materials that are in full accordance with the requirements of normalising stable isotope measurements. Using this improved procedure we determined the δ2HLM values of tree rings from 40 geographical locations. Using these values, we present a revised relationship between δ2HLM and δ2Hprecip which is: δ2Hprecip [mUr] = (δ2HLM [mUr] + 206 mUr)/0.67. In addition, a new equation for reconstructions of MAT is: MAT [°C] = (δ2HLM [mUr] + 272 mUr)/3.04 [mUr/°C]. We provide a simple numerical model that explains the observed biosynthetic isotope fraction pattern between δ2HLM and δ2Hprecip. Finally, we applied the new equations to a previous data set for wood samples collected close to the Hohenpeißenberg Meteorological Observatory in Germany. The data set included a 100-year-chronology (1916–2015) from nine tree ring cores removed from four beech trees. The MAT from δ2HLM values reconstructed for this geographical location was 7.96 ± 2.17 °C and in very good agreement with the observed mean MAT of 7.82 ± 0.75 °C during this time period. Therefore, we conclude that the revised relationships between δ2HLM, δ2Hprecip and MAT provide the basis for reliable application for paleoclimate reconstructions.

Isotopic composition of precipitation and groundwater onshore of the Rio del Rey Basin, southwest Cameroon: local meteoric lines and recharge

The link between rainfall and groundwater recharge in the Rio del Rey Basin, which is of socio-economic importance to Cameroon, is poorly understood. Accordingly, the stable isotopes in monthly rainfall from January to December 2012 (in Lobe and Mundemba) and 52 surface water and groundwater samples were investigated. High values of δ18O and δD were recorded in the dry period (February to March), and the least values of δ18O and δD were observed in the wet period (September). This indicates that different condensation processes primarily influenced stable isotopes in rainfall as a function of the difference in moisture sources. The relationship between δD and δ18O defined the Lobe meteoric water line as δD = 7.97 δ18O + 12.48 and Mundemba water line as δD = 7.75 δ18O + 10.79. The similarity of their slopes to the global meteoric line suggests that the isotopic composition of investigated rains was not significantly affected by evaporation during precipitation. The ranges in deuterium-excess of precipitation from 5.8 to 16.56‰ suggest the source of vapour is from the Atlantic Ocean. The groundwater isotope values (ranging from −3.81 to −2.52‰ for δ18O) plotted close to and along the GMWL, showing that its isotopic composition is of meteoric origin under rapid recharge conditions. The isotopic similarity between groundwater and June–August rains suggests a significant recharge during this period.

ISODRIP, a model to transfer the δ18O signal of precipitation to drip water — Implementation of the model for Eagle Cave (central Spain)

The isotope signature of cave waters provides an excellent opportunity to better understand the recharge in karst regions and the complexity of drainage systems in the vadose zone. We have developed a cave isotope hydrological model (ISODRIP) that requires entering basic hydrometeorological information and a precipitation δ18O record to simulate the discharge and δ18O signals of different drip sites. The model includes four different modules to simulate various flow route regimes: continuous and discontinuous drips under diffuse or preferential flows. We use precipitation and cave water δ18O records that were obtained in Eagle Cave (central Spain) during a 5-year period to test our model and to better understand the dynamics of karst aquifers. Eagle Cave waters do not record evaporation. The δ18O signals do not have seasonality, although they record intra-annual and inter-annual variability. Additionally, cave water δ18O signal falls within the range of the annual average weighted isotope composition of precipitation. Well-mixed cave waters, that characterize diffuse flows, record 1‰ δ18O variability, whereas partially-mixed waters, that flow along preferential drainage routes, have up to 3‰ δ18O variability. The results suggest that precipitation takes on average 15 months to reach the cave through the diffuse flow network, whereas under preferential flow the transit time is highly variable depending on the previous condition of the system. ISODRIP includes a soil layer above the vadose zone that controls large recharge events, together with direct recharge components that bypass the soil layer enabling at least some recharge all year round. Thus, the simulations reproduce the observed lack of seasonal bias in the cave water δ18O composition in relation to the average weighted isotope composition of precipitation. This research highlights the importance of understanding recharge dynamics and the configuration of particular drips sites to properly interpret speleothem δ18O records.

National Stable Isotope Baseline for Precipitation in Malawi to Underpin Integrated Water Resources Management

With the resurgence of water-isotope tracing applications for Integrated Water Resource Management in developing countries, establishing a stable isotopic baseline is necessary. Developing countries, including Malawi, continue to struggle with the generation of consistent and long-term isotopic datasets due to non-existent or inadequate in-country water-isotope capacity. Malawi has made significant advances in its quest to establish a stable isotopic baseline through the establishment of the Malawi Network of Isotope in Precipitation. This study provides the first results for the isotopic characterization of precipitation in Malawi with a view to reinforcing understanding of the country’s hydrological cycle. Error-in-variables regression defined a Local Meteoric Water Line as δ2H = 8.0 (±0.3) δ18O + 13.0 (±2.0) using stable isotopic records of 37 monthly samples from 5 stations between 2014 and 2019. Local precipitation (isotopic composition) is consistent with global precipitation expectations, its condensation-forming process occurring under equilibrium conditions and a higher intercept (d-excess) above the 10‰ for Global Meteoric Water Line, implying that air moisture recycling significantly influences local precipitation. Wider variations observed in local precipitation isotopic signatures are largely attributed to different moisture-bearing systems and diverse geographic factors across the country. Additional stations are recommended to improve spatial coverage that, together with longer temporal records, may help understanding and resolving uncertainties such as the altitude effect. This pioneering study is expected to facilitate Malawi’s ambition to achieve integrated use and improved protection of its surface water and groundwater resources in response to mounting climate change, growing population and land-development concerns.

Precipitation isotope time series predictions from machine learning applied in Europe

Hydrogen and oxygen isotope values of precipitation are critically important quantities for applications in Earth, environmental, and biological sciences. However, direct measurements are not available at every location and time, and existing precipitation isotope models are often not sufficiently accurate for examining features such as long-term trends or interannual variability. This can limit applications that seek to use these values to identify the source history of water or to understand the hydrological or meteorological processes that determine these values. We developed a framework using machine learning to calculate isotope time series at monthly resolution using available climate and location data in order to improve precipitation isotope model predictions. Predictions from this model are currently available for any location in Europe for the past 70 y (1950-2019), which is the period for which all climate data used as predictor variables are available. This approach facilitates simple, user-friendly predictions of precipitation isotope time series that can be generated on demand and are accurate enough to be used for exploration of interannual and long-term variability in both hydrogen and oxygen isotopic systems. These predictions provide important isotope input variables for ecological and hydrological applications, as well as powerful targets for paleoclimate proxy calibration, and they can serve as resources for probing historic patterns in the isotopic composition of precipitation with a high level of meteorological accuracy. Predictions from our modeling framework, Piso.AI, are available at https://isotope.bot.unibas.ch/PisoAI/.

Multi isotope systematics of precipitation to trace the sources of air pollutants in Seoul, Korea

Multiple sulfur (δ34Ssulfate, Δ33Ssulfate, & Δ36Ssulfate), nitrogen and oxygen (δ15Nnitrate & δ18Onitrate) and strontium (87Sr/86Sr) isotope compositions of precipitation collected from Seoul, South Korea were analyzed to study the sources, transportation and deposition of air pollutants in East Asia. The δ34Ssulfate values (from 1.9 to 14.6‰ with a median of 4.7‰) and the δ15Nnitrate values (from −2.0 to 13.3‰ with a median of 1.0‰) suggest that fossil fuel use (emission from coal combustion and vehicle exhaust) is a predominant source for sulfur and nitrogen, but other natural sources including biogenic contributions of DMS also add to their total budget. The seasonal variations are observed in δ34Ssulfate and δ15Nnitrate values (both higher in winter season), which is likely to result from the increase of coal use for domestic heating in China. The δ18Onitrate values also varied seasonally depending on the NOx oxidation pathway, being about 20‰ higher in winter than in summer season. The Δ33Ssulfate and Δ36Ssulfate values are not anomalous, showing the absence of MIF signals in precipitation of Seoul. The 87Sr/86Sr ratio of the precipitation samples range from 0.70988 to 0.71487 with a median of 0.71073, indicating the influence of at least three end-member (silicate dust, carbonate dust and anthropogenic emission). Ionic ratios such as (K++NH4+)/(Ca2++Mg2+) and Cl−/Na+ suggest the overwhelming effect of anthropogenic input rather than carbonate dust on the end-member with lower 87Sr/86Sr ratios.

Distribution of hydrogen and oxygen stable isotope of water in soil-plant-atmosphere continuum (SPAC)system of a typical forest area

Water cycle in the soil-plant-atmosphere continuum (SPAC) is an important research topic in hydrology and ecology. The differences in the composition of hydrogen and oxygen stable isotopes in different water bodies can indicate water cycle process. Based on the measurements of isotopic compositions in precipitation, soil water, and plant water, we analyzed water isotope evolution in a SPAC system located in a subtropical evergreen broad-leaved forest in Chengdu Plain. The different interface processes of regional water cycle was revealed. The results showed that the local meteoric water line (LMWL) equation was δD=7.13 δ18O+2.35 (R2=0.99), and the soil evaporation line (SEL) equation was δD=6.98δ18O-0.32 (R2=0.92). In the water transportation process of precipitation-soil water-plant water, hydrogen and oxygen isotopes were gradually enriched. The δ18O in water of the surface soil layer (0-35 cm) was sensitive to precipitation input, as it was directly affected by precipitation. In contrast, the δ18O in water of the middle and deep layers (35-100 cm) was relatively stable. The isotopes of plant xylem water were slightly more enriched than those of soil water, indicating the possibility of slight evaporation or transpiration through phloem or bark in plant water transportation. The estimation of plant water intake from different soil layers was performed by direct correlation method. Cinnamomum camphora mainly used water from the middle layer, Broussonetia papyrifera mainly used that from the surface layer, and Parathelypteris glanduligera tended to use surface soil water and precipitation intercepted by plants because of the shallow root system. Compared with P. glanduligera, C. camphora and B. papyrifera experienced stronger water evaporation and the isotopes were influenced by more intense dynamic fractionation.

Isotopic tracers of sources of water for springs from the Edwards Aquifer, Central Texas, USA

Abstract The Edwards Aquifer (EA) in Central Texas provides water supply for over two million people and contains springs that are hydrologically and ecologically important to the region. The residence time of groundwater in the EA ranges from a few days to many thousands of years, since water in the aquifer is contained and transported within both matrix porosity and large conduits. In this study, stable isotopes of water from five springs are investigated for tracing the origin of water and hydrological processes in the EA system during 2017–2019. There is a quick response of the isotopic signals measured at these springs to changes in the isotopic compositions of precipitation. By utilizing an isotope mixing model, we have identified sources of water for these springs with a bi-modal distribution of groundwater supply in the EA: water supplied from deep groundwater with a longer residence time (an average of 67%) and supplemental epikarst interflow with a shorter residence time (an average of 33%). The evolution of hydrochemical water types from HCO3–Ca to HCO3·Cl–Ca·Mg along the EA flowpaths indicates that inputs from epikarst interflow are greater in springs within the artesian zone than the springs within the contributing zone.

Stable isotope compositions of precipitation over Central Asia.

Central Asia is one of the driest regions in the world with a unique water cycle and a complex moisture transport process. However, there is little information on the precipitation δ18O content in Central Asia. We compiled a precipitation δ18O database from 47 meteorological stations across Central Asia to reveal its spatial-temporal characteristics. We determined the relationship between precipitation δ18O and environmental variables and investigated the relationship between δ18O and large-scale atmospheric circulation. The Central Asia meteoric water line was established as δ2H = 7.30 δ18O + 3.12 (R2 = 0.95, n = 727, p < 0.01), and precipitation δ18O ranged from +2‰ to −25.4‰ with a mean of −8.7‰. The precipitation δ18O over Central Asia was related to environmental variables. The δ18O had a significant positive correlation with temperature, and the δ18O-temperature gradient ranged from 0.28‰/°C to 0.68‰/°C. However, the dependence of δ18O on precipitation was unclear; a significant precipitation effect was only observed at the Zhangye and Teheran stations, showing δ18O-precipitation gradients of 0.20‰/mm and −0.08‰/mm, respectively. Latitude and altitude were always significantly correlated with annual δ18O, when considering geographical controls on δ18O, with δ18O/LAT and δ18O/ALT gradients of −0.42‰/° and −0.001‰/m, respectively. But both latitude and longitude were significantly correlated with δ18O in winter. The relationship between δ18O and large-scale atmospheric circulation suggested that the moisture in Central Asia is mainly transported by westerly circulation and is indirectly affected by the Indian monsoon. Meanwhile, the East Asian monsoon may affect the precipitation δ18O content in westerly and monsoon transition regions. These results improve our understanding of the precipitation δ18O and moisture transport in Central Asia, as well as the paleoclimatology and hydrology processes in Central Asia.

Lake water based isoscape in central-south Chile reflects meteoric water

Warming across the globe is expected to alter the strength and amount of regional precipitation, but there is uncertainty associated with the magnitude of these expected changes, and also how these changes in temperature and the hydrologic cycle will affect humans. For example, the climate in central-south Chile is projected to become significantly warmer and drier over the next several decades in response to anthropogenically driven warming, but these anthropogenic changes are superimposed on natural climate variability. The stable isotope composition of meteoric water provides significant information regarding the moisture source, pathways, and rain-out history of an air mass, but precipitation samples suitable for stable isotope measurements require long-term placement of field equipment making them difficult to obtain. The International Atomic Energy Agency (IAEA) Global Network of Isotopes in Precipitation (GNIP) stations generate isotopic and ancillary data of precipitation from many locations around the world, but remote areas of developing countries like Chile typically have sparse networks of meteorological stations, which inhibit our ability to accurately model regional precipitation. Central-south Chile, in particular, has a sparse network of GNIP stations and, as a result, the isotopic composition of meteoric water is underrepresented in the global database complicating efforts to constrain modern day hydroclimate variability as well as paleohydrologic reconstruction for southern South America. In this study, we measured the stable isotope compositions of hydrogen (δ2H) and oxygen (δ18O) in surface lacustrine waters of central-south Chile to determine what physical and/or climatic features are the dominant controls on lacustrine δ18O and δ2H composition, assess whether or not the isotopic composition of the lakes record time-averaged isotope composition of meteoric water, and determine whether an isoscape map based on lake surface waters could predict the H and O isotope compositions of precipitation at the few GNIP stations in the region.

Changes in Below‐Cloud Evaporation Affect Precipitation Isotopes During Five Decades of Warming Across China

AbstractBased on daily meteorological records for 651 sites across China during the period 1960–2018, we estimated the changes in isotopic variations in raindrops as they descend from cloud base to ground over past decades, and tested the sensitivity of isotopic variations to climate parameters like air temperature and relative humidity. Air temperature correlates positively and relative humidity correlates negatively with below‐cloud isotopic variation. Generally, the below‐cloud evaporation effect on precipitation isotopes in the arid and semi‐arid regions of China is much greater than that in the humid and semi‐humid regions, although the impact might be reduced under cold‐arid or hot‐humid conditions. With aridity increasing with distance from the coast, the continental effect of precipitation isotopes is modified due to the below‐cloud evaporation. The seasonal pattern of the measured isotopic composition in precipitation near the ground and estimated at cloud base, is still similar in most regions, although the seasonal range is higher at the ground. During the last five decades, the below‐cloud evaporation effect has enhanced for the cold and arid regions of China especially across Qinghai‐Tibet Plateau and Inner Mongolia, due to combined effects of increasing air temperature and decreasing relative humidity. Although the below‐cloud evaporation effect is not always the dominant factor influencing the variability of stable isotopes, it needs to be considered as one of the contributing factors. This enhanced effect may impact the interpretation of past climate based on stable water isotopes, particularly in paleoclimate studies using speleothems and tree rings.

Stable isotope and anthropogenic tracer signature of waters in an Andean geothermal system

In the present study, we combined stable isotopes and anthropogenic tracers to investigate the origin, residence times, and evolution of thermal waters in the Lonquimay-Tolhuaca Volcanic Complex (LTVC) of the southern Chilean Andes. A total of 20 water samples from springs discharging at a broad range of temperatures (8–96 °C) were collected and analyzed for major ion geochemistry, stable isotope ratios (δ2H, δ18O, δ13CTDIC), dissolved chlorofluorocarbons (CFCs) and sulfur hexafluoride (SF6). In addition, we compiled all available data on the isotopic composition of precipitation in the region to derive the local meteoric water line. Coupled with a Rayleigh-fractionation model of precipitation, we provide constraints on the elevation at which infiltration and recharge to the system is produced. δ13CTDIC values are consistent with the bulk of dissolved inorganic carbon being derived from the addition of soil CO2 to an atmospheric source, while magma degassing and boiling processes are evidenced in samples discharging directly on the flanks of volcanoes. The isotopic composition of thermal water, once heated at depth, is further modified by CO2 degassing and carbonate precipitation during ascent. All geothermal samples contain low but detectable concentrations of CFC-11, CFC-12, CFC-113, and SF6, suggesting the addition of only a small fraction (2–22%) of modern meteoric water. The discharge temperature of naturally outflowing springs in the LTVC correlates directly with the age distribution of the water samples. This difference in residence times is attributed to the distinct subsurface circulation pathways of each water type—i.e., the shallow, diffuse flow of cold groundwater vs. the deep, focused circulation of thermal water along fault zones. Conduit flow along high vertical permeability networks allows hydrothermal fluid to remain relatively unmixed with shallow meteoric water during ascent. Data from this study confirm that fault-fracture meshes with different orientations exert a first order control on the residence times, ascent, and mixing rates of thermal waters in this segment of the Andean Cordillera, thus modulating their chemical and isotopic signature. Additionally, our results show that the combined use of conventional hydrogeochemical and isotopic data with environmental tracers, including anthropogenic CFCs and SF6, is a powerful tool to better understand the dynamics of geothermal systems.

Temporal variations and evaporation control effect of the stable isotope composition of precipitation in the subtropical monsoon climate region, Southwest China

Stable hydrogen and oxygen isotopes in precipitation, which are sensitive to climate change and the water cycle, are widely used as natural tracers to investigate hydrological processes and paleoclimate reconstruction. High resolution event-based precipitation sampling was conducted in Guilin, a subtropical monsoon climate region in Southwest China, from 2010 to 2016 to identify the temporal variability of stable isotopes of precipitation and its dominant meteorological factors. The results showed that the stable isotopes of precipitation exhibited significant seasonal variability, with lower values in the wet season and higher values in the dry season, reflecting the changes in the character of precipitation in response to seasonal variability of the moisture sources and atmospheric dynamics. δ18O values were significantly negatively correlated with temperature and potential evapotranspiration (ET0) on the daily and monthly timescales; however, there was no significant correlation between monthly δ18O and the amount of rainfall. Multivariate regression analysis showed that when temperature, precipitation amount and ET0 were considered, 39% of the variability of the monthly oxygen isotope composition of precipitation was explained. Monthly mean temperature had a higher covariation with precipitation δ18O, indicating that the variations of precipitation isotope were more dependent on temperature, but not substantially dependent on the amount effect of rainfall. Howerver, the main influence of meteorological factors on the isotopic variations of precipitation varied seasonally. Temperature strongly influenced the isotopic composition of precipitation in summer, while the amount effect was prominent due to the enhanced convective activity characterized by more depleted δ18O values. Although evapotranspiration is a minor contributor of precipitation isotope variability, the impact of evapotranspiration on the enrichment of precipitation isotopes in autumn is a substantial control and should be considered, which makes a major contribution to compensate for the depletion in heavy isotopes of rainfall. The non-linear relationship between d-excess and ET0 was attributed to the variable contribution of large-scale convective moisture and local evaporation, as well as water vapor transfer processes. The response of precipitation stable isotopes to convective events was characterized by distinct stage patterns, associated with the water vapor sources and physical processes during rainout. The significant depletion of precipitation δ18O values during convective events was not due to the ‘amount effect’, but due to large-scale convection activity. These findings provide further insight into intraevent-scale isotopic variations associated with organized convection and their key influencing factors, which ultimately improves our interpretation of the paleoclimate records in subtropical monsoon regions.

Influence of below-cloud secondary evaporation on stable isotope composition in precipitation and its relationship with meteorological factors in Shiyang River Basin, Northwest China

In arid regions, the process of precipitation from the cloud base to the ground is often affected by the below-cloud secondary evaporation, which changes the ratios of hydrogen and oxygen stable isotopes in falling raindrops. Based on stable isotopes of 670 precipitation samples and meteorological records at 11 stations in the Shiyang River Basin, and combined with the improved Stewart model, this study discussed the impact of different meteorological factors on below-cloud secondary evaporation. The result showed that the Local Meteoric Water Line (LMWL) of the Shiyang River Basin is δD = 7.70δ18O + 8.90 (r2 = 0.98, p < 0.01, n = 670). The secondary evaporation is stronger in spring and summer and weaker in autumn and winter, and it is stronger in the mid-downstream than that in the upstream. When temperature ranges from 10 °C to 20 °C, precipitation is less than 10 mm, and relative humidity is lower than 30%, the phenomenon of isotope dynamic fractionation caused by the secondary evaporation is more obvious. As temperature increases, relative humidity, precipitation amount, or raindrop diameter decreases, the linear relationship between the evaporation remaining ratios of raindrops (f) and the difference of deuterium excess from cloud base to ground (Δd) weakens gradually. Δd has a stronger response to the changes in relative humidity than that in temperature and precipitation intensity, and the impact of raindrop diameters more than 1.2 mm on Δd is very limited.

\u03b42Hn-alkane and \u03b418Osugar biomarker proxies from leaves and topsoils of the Bale Mountains, Ethiopia, and implications for paleoclimate reconstructions

The hydrogen isotopic composition of leaf wax–derived n-alkane (δ2Hn-alkane) and oxygen isotopic composition of hemicellulose–derived sugar (δ18Osugar) biomarkers are valuable proxies for paleoclimate reconstructions. Here, we present a calibration study along the Bale Mountains in Ethiopia to evaluate how accurately and precisely the isotopic composition of precipitation is imprinted in these biomarkers. n-Alkanes and sugars were extracted from the leaf and topsoil samples and compound–specific δ2Hn-alkane and δ18Osugar values were measured using a gas chromatograph–thermal conversion–isotope ratio mass spectrometer (GC–TC–IRMS). The weighted mean δ2Hn-alkane and δ18Osugar values range from − 186 to − 89‰ and from + 27 to + 46‰, respectively. Degradation and root inputs did not appear to alter the isotopic composition of the biomarkers in the soil samples analyzed. Yet, the δ2Hn-alkane values show a statistically significant species dependence and δ18Osugar yielded the same species–dependent trends. The reconstructed leaf water of Erica arborea and Erica trimera is 2H– and 18O–enriched by + 55 ± 5 and + 9 ± 1‰, respectively, compared to precipitation. By contrast, Festuca abyssinica reveals the most negative δ2Hn-alkane and least positive δ18Osugar values. This can be attributed to “signal–dampening” caused by basal grass leaf growth. The intermediate values for Alchemilla haumannii and Helichrysum splendidum can be likely explained with plant physiological differences or microclimatic conditions affecting relative humidity (RH) and thus RH–dependent leaf water isotope enrichment. While the actual RH values range from 69 to 82% (x̄ = 80 ± 3.4%), the reconstructed RH values based on a recently suggested coupled δ2Hn-alkane –δ18Osugar (paleo–) hygrometer approach yielded a mean of 78 ± 21%. Our findings corroborate (i) that vegetation changes, particularly in terms of grass versus non–grassy vegetation, need to be considered in paleoclimate studies based on δ2Hn-alkane and δ18Osugar records and (ii) that the coupled δ2Hn-alkane –δ18Osugar (paleo–) hygrometer approach holds great potential for deriving additional paleoclimatic information compared to single isotope approaches.

Isotope and chemical composition of monthly precipitation collected at Sapporo, northern part of Japan during 2015-2019

The aim of this study is to measure tritium concentrations, δ2H, δ18O and ion concentration in monthly precipitation collected at Sapporo, the northern part of Japan and to understand the regional precipitation chemistry. Tritium concentrations of monthly precipitation in Sapporo from July 2015 to the end of 2019 ranged from 0.24 to 1.59 Bq/L with a mean value (±S.D.) of 0.68 ± 0.30 Bq/L. Tritium seasonal patterns were determined with higher tritium concentrations in spring and lower tritium concentrations in summer. It was higher than the reported values in the southern area of Japan. It seemed that tritium concentrations changed with the meteorological conditions depending on the air masses of continental or marine origin and the contribution of cosmogenic tritium from the upper atmosphere. The strong correlation was found between tritium concentrations and NO3− and NH4+ (p < 0.05). It is necessary to accumulate more data as to long-term monitoring for a reliable analysis of ambient tritium concentrations.

Comprehending the groundwater recharge of a coastal city in humid tropical setting using stable isotopes

Unscientific urbanization in coastal cities has enforced the need for understanding groundwater recharge sources and processes for sustainable development. In this paper, stable isotope compositions of precipitation, groundwater and river water were determined to understand the significant recharge sources of phreatic aquifers in the two differently urbanized environments, viz. urban and peri urban clusters of Kozhikode District, Kerala, and southern India. The two monsoon systems viz., southwest and northeast, are the major source of groundwater recharge in the region, but due to change in landuse pattern in the last decade has significantly altered groundwater recharge. Hence with the aid of stable isotope ratios of water, estimation of point recharge of rainwater to the groundwater in different hydrgeological setting of the area was done. The monsoon rains contributed 35% in the urban alluvial aquifers, up to 39% in the urban laterite aquifer and 42% in the peri urban laterite aquifer. An attempt was made to correlate the landuse changes in the past decade in the region with the groundwater availability.