Temporal variations and evaporation control effect of the stable isotope composition of precipitation in the subtropical monsoon climate region, Southwest China

Abstract

Stable hydrogen and oxygen isotopes in precipitation, which are sensitive to climate change and the water cycle, are widely used as natural tracers to investigate hydrological processes and paleoclimate reconstruction. High resolution event-based precipitation sampling was conducted in Guilin, a subtropical monsoon climate region in Southwest China, from 2010 to 2016 to identify the temporal variability of stable isotopes of precipitation and its dominant meteorological factors. The results showed that the stable isotopes of precipitation exhibited significant seasonal variability, with lower values in the wet season and higher values in the dry season, reflecting the changes in the character of precipitation in response to seasonal variability of the moisture sources and atmospheric dynamics. δ18O values were significantly negatively correlated with temperature and potential evapotranspiration (ET0) on the daily and monthly timescales; however, there was no significant correlation between monthly δ18O and the amount of rainfall. Multivariate regression analysis showed that when temperature, precipitation amount and ET0 were considered, 39% of the variability of the monthly oxygen isotope composition of precipitation was explained. Monthly mean temperature had a higher covariation with precipitation δ18O, indicating that the variations of precipitation isotope were more dependent on temperature, but not substantially dependent on the amount effect of rainfall. Howerver, the main influence of meteorological factors on the isotopic variations of precipitation varied seasonally. Temperature strongly influenced the isotopic composition of precipitation in summer, while the amount effect was prominent due to the enhanced convective activity characterized by more depleted δ18O values. Although evapotranspiration is a minor contributor of precipitation isotope variability, the impact of evapotranspiration on the enrichment of precipitation isotopes in autumn is a substantial control and should be considered, which makes a major contribution to compensate for the depletion in heavy isotopes of rainfall. The non-linear relationship between d-excess and ET0 was attributed to the variable contribution of large-scale convective moisture and local evaporation, as well as water vapor transfer processes. The response of precipitation stable isotopes to convective events was characterized by distinct stage patterns, associated with the water vapor sources and physical processes during rainout. The significant depletion of precipitation δ18O values during convective events was not due to the ‘amount effect’, but due to large-scale convection activity. These findings provide further insight into intraevent-scale isotopic variations associated with organized convection and their key influencing factors, which ultimately improves our interpretation of the paleoclimate records in subtropical monsoon regions.