Radio Frequency Ion Research Articles

Measurements of the Reaction Rate Coefficients of Atomic Hydrogen with Astrochemical Anions: CN− and C3N−

We present the temperature-dependent reaction rate coefficients of CN− and C3N− with atomic hydrogen in the temperature range from 7 to 290 K, measured in a 16-pole radio-frequency ion trap. The rate of C3N− with H steadily increases toward lower temperatures, while the rate coefficients for the CN− + H system show a sudden change around 160 K. Fits to the data were performed to determine temperature-dependent reaction rate coefficients. The fits reveal a rate coefficient of 4.1(3)×10−10(T/300)−0.31(6) cm3 s−1 for C3N− + H. For CN−, we determined a rate coefficient for the temperature regime below 160 K of 3.2(4)×10−10(T/300)−0.31(11) cm3 s−1. Given our present results, higher rate coefficients than previously reported must be assumed for the modeling of cold interstellar environments involving these H atom reactions.

Plasma discharge experiments of a Faraday shieldless driver for high-power and long-pulse radio frequency ion source for NBI application.

Due to the high stability and less maintenance, the radio frequency (RF) driven ion source is preferred for the neutral beam injection (NBI) system. In a popular design of the RF ion source for NBI application, a Faraday shield (FS) is installed inside the RF plasma driver to protect the discharge tube. However, the FS also brings some drawbacks, such as lowering the RF power transfer and increasing the processing difficulty. A prototype of the RF plasma driver without FS and with mature manufacturing technology has been developed by using a water-cooled discharge tube. After basic testing, this prototype was further tested under the RF plasma discharge experiments in views of high power, long pulse, and long term. The reliability and its plasma characteristics were the focus of these experiments, also for the hidden issues. The results show that the prototype could generate stable and high-density plasma without any damage or sputtering mark. An RF plasma discharge of 50 kW and 20s has been achieved. The expected frequency tuning was equally effective on the prototype. Moreover, compared to the RF plasma driver with FS, the prototype could produce higher electron density in the extraction region under the same RF power. Of course, some of the shortcomings of the prototype have also been exposed in the experiments and will be improved in subsequent experiments.

Investigation in improving the Cs-free negative hydrogen ion production with short-pulse low power in the afterglow of pulse-power-modulated plasma sources

Abstract Pulse plasma ion sources have been shown to be capable of achieving high negative hydrogen ion densities ( n H − ) or currents. The fast cooling of the electrons and reduction in the electron density (n e) provide favorable plasma conditions to improve the H− production, with a high density ratio of negative hydrogen ions to electrons during the pulse-off period. The purpose of this research is to further improve the performance of volume-produced H− ion sources based on the pulse power modulation. In this study, a time-modulated negative hydrogen plasma sustained by 10 kHz pulse power at the typical gas pressure of 0.3 Pa was numerically investigated using a global model. The model is compared with measurements obtained in a pulsed radio frequency ion source and shows a reasonable agreement. A steplike low-high power strategy in the active glow period and a short-pulse low power in part of the afterglow period are employed to mitigate overshoot of the electron temperature (T e) in the initial stage of the pulse period and to optimize H− production in the afterglow, respectively. The model predicts that a small-magnitude, short-duration low power operation in the afterglow increases n H − and decreases n e from the onset of the low power until the beginning of the next high power pulse, due to a modest temporary increase in the T e (less than 2 eV). It facilitates dissociative electron attachments and thus H− formation. The reduction in the n e indicates that positive ions lost to the walls cannot be compensated by weak ionization. H− production with a low number of co-extracted electrons can be optimized by adjusting the magnitude and duration of the low power in the afterglow.

Resolved-sideband cooling of a single Be+9 ion in a cryogenic multi-Penning-trap for discrete symmetry tests with (anti-)protons

Manipulating the motion of individual trapped ions at the single quantum level has become standard practice in radio-frequency ion traps, enabling sweeping advances in quantum information processing and precision metrology. The key step for motional-state engineering is ground-state cooling. Full motional control also bears great potential to explore another regime of sensitivities for fundamental physics tests in Penning traps. Here we demonstrate the key enabling step by implementing resolved-sideband cooling on the axial mode of a single Be+9 ion in a 5 Tesla cryogenic Penning trap. The system has been developed for the implementation of high-precision antimatter experiments to test the fundamental symmetries of the standard model with the highest accuracy in the baryonic sector. We measure an axial phonon number of n¯z=0.10(4) after cooling and demonstrate that the axial heating rate in our system is compatible with the implementation of quantum logic spectroscopy of (anti-)protons. Published by the American Physical Society 2024

Development and Evaluation of Ferrite Core Inductively Coupled Plasma Radio Frequency Ion Source for High-Current Ion Implanters in Semiconductor Applications.

This study presents the development of a ferrite core inductively coupled plasma (ICP) radio frequency (RF) ion source designed to improve the lifetime of ion sources in commercial ion implanters. Unlike existing DC methods, this novel approach aims to enhance the performance and lifetime of the ion source. We constructed a high-vacuum evaluation chamber to thoroughly examine RF ion source characteristics using a Langmuir probe. Comparative experiments assessed the extraction current of two upgraded ferrite core RF ion sources in a commercial ion implanter setting. Additionally, we tested the plasma lifetime of the ICP source and took temperature measurements of various components to verify the operational stability and efficiency of the innovative design. This study confirmed that the ICP RF ion source operated effectively under a high vacuum of 10-5 torr and in a high-voltage environment of 30 kV. We observed that the extraction current increased linearly with RF power. We also confirmed that BF3 gas, which presents challenging conditions, was stably ionized in the ICP RF ion sources.

Characteristics of inductively coupled plasma radio-frequency ion source of ion implanters for high number density dopant generation

In this study, we developed an inductively coupled plasma ion source that can be applied to implanters in semiconductor production. We employed an infrared camera and thermocouples to assess the temperature properties of the ion source operated at temperatures below 500 °C. This reduced temperature is expected to facilitate the adoption of various materials as the ion source. Ion densities of the direct current ion source measured using a double Langmuir probe were found to range from 1.66 × 1016 to 5.06 × 1016 m−3 within an input power range of 682–895 W. In contrast, the ion densities of a radio-frequency ion source ranged from 7.86 × 1016–9.58 × 1016 m−3 within an input power range of 700–900 W. This proposed ion source can serve as a next-generation solution because of its low operating temperature and high ion density.

Engineering design and manufacturing of a radio frequency plasma driver without Faraday shield for NBI application

A radio frequency (RF) driven ion source is favorable for high-power and long-pulse neutral beam injection (NBI) system. To reduce the damage caused by the isotropic heat and particle fluxes from the plasma, the traditional RF plasma driver of the NBI ion source introduces a Faraday shield (FS) for protection. However, the simulations and experiments show that the FS seriously affects the RF coupling and around 50 % of the input power deposits on the FS. The water-cooled discharge tubes with a double-layer ceramic structure have been developed to avoid using the FS structure. It's expected to improve the RF power transfer efficiency and to promote the development of high-power and long-pulse RF ion source. To verify the feasibility of the double-layer ceramic structure, the paper has carried out the fluid-thermal-structural coupling analysis and the fracture mechanical analysis on two proposed types: the alumina ceramic brazing structure and the silicon nitride ceramic bonding structure. The sample tests and the prototype manufacturing have been completed. Preliminary tests of the plasma discharge on the prototype of the alumina ceramic brazing structure have been launched. A plasma discharge of 30 kW and 20 s have been achieved.

Simple 3D PIC Analysis for Beam Phase Space Oscillation in RF Driven Negative Hydrogen Ion Source

Temporal oscillation of the negative hydrogen ion (H−) beam in the Radio Frequency (RF) ion source is investigated by a simple 3D3V Particle-In-Cell (PIC) model. The model solves electron, proton, and H− transport processes in the extraction region. The calculation domain is from the vicinity of the beam aperture to the ground electrode. To understand the relation between the plasma density oscillation and the extracted H− beam characteristics, the input electron and proton fluxes from the driver region are varied parametrically with the fundamental J-PARC RF frequency (2 MHz). The numerical results give an idea of the main physical processes between the oscillations of the plasma parameters and the extracted H− ion trajectories depending on the plasma meniscus shape in the different RF phases.

Development of a novel Internal Radio-frequency Ion Source for Cyclotrons (IRISC)

IRISC (Internal Radio-frequency Ion Source for Cyclotrons) is an innovative design of an internal ion source, primarily for producing H− ions, in which 2.45 GHz radio-frequency power is supplied to its electrodes for achieving electron emission. Theoretical work indicates that lower electrode sputtering and higher extraction efficiency of H− may be achieved as compared to its standard cold-cathode direct current (DC) Penning Ionization Gauge (PIG) counterparts. If achieved, IRISC would arise as a ground-breaking ion source with significant importance for compact cyclotrons. IRISC dimensions have been matched to CIEMAT’s AMIT cold-cathode DC PIG ion source so that, in the future, side-by-side testing can be carried out and, eventually, both types can be used in AMIT cyclotrons. This contribution presents IRISC key design aspects, outcome from simulations, its dedicated test bench and first low-power test results from a prototype.

Investigation of plasma chamber erosion in an RF ion source

Filament driven plasma sources are widely used to produce ion beams, but they require frequent maintenance due to the limited filament lifetime. External radio-frequency (RF) coupled ion source offers a filament-free plasma and hence better maintenance. However, one of the issues encountered during the development of a planar external RF-powered ion source at D-Pace was the erosion of its copper plasma chamber and subsequent formation of copper deposits on the Aluminum Nitride (AlN) RF window. The copper deposits on the RF window deteriorate the power coupling between the external antenna and the plasma. This paper investigates the erosion of the plasma chamber and describes some of the methods used to control the deposition of copper on the RF window.

Power transfer efficiency in an air-breathing radio frequency ion thruster

Abstract Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit missions due to its high specific impulse and efficiency. In this paper, the power transfer efficiency of the radio frequency ion thruster with different gas composition is studied experimentally, which is obtained by measuring the radio frequency power and current of the antenna coil with and without discharge operation. The results show that increasing the turns of antenna coils can effectively improve the radio frequency power transfer efficiency, which is due to the improvement of Q factor. In pure N2 discharge, with the increase of radio frequency power, the radio frequency power transfer efficiency first rises rapidly and then exhibits a less steep increasing trend. The radio frequency power transfer efficiency increases with the increase of gas pressure at relatively high power, while declines rapidly at relatively low power. In N2/O2 discharge, increasing the N2 content at high power can improve the radio frequency power transfer efficiency, but the opposite was observed at low power. In order to give a better understanding of these trends, an analytic solution in limit cases is utilized, and a Langmuir probe was employed to measure the electron density. It is found that the evolution of radio frequency power transfer efficiency can be well explained by the variation of plasma resistance, which is related to the electron density and the effective electron collision frequency.

Particle-in-Cell simulation of radio-frequency ion thruster RIT-1.0

Ion propulsion systems with a small thrust can be used in space missions for highly accurate controllability while possessing low power and propellant consumption. At the University of Giessen, radio-frequency ion thrusters are miniaturized with thrusts in the order of micro-Newtons (μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\mu$$\\end{document}N-RIT). As the size of the thruster becomes smaller the plasma properties can not be measured inside a closed plasma chamber. The simulations are needed to investigate plasma properties like temperature, density profile which would aid further opimization. In this work, we discuss kinetic simulations of plasma inside the RIT-1.0 thruster using in-house developed PlasmaPIC code that incorporates Monte-Carlo collisions (MCC) and Direct Simulation Monte Carlo (DSMC) for neutral gas distribution. We briefly present the features of PlasmaPIC and simulation of stable plasma generation. We also show the influence of neutral gas and extraction properties for the RIT-1.0 thruster under consideration.

Hydrogen Tag Shifts as Vibrational Reporters for Positional Isomers of Formylphenides: Surprising Mobility of the Carbanion Center upon Collisional Decarboxylation of the Parent Benzoates.

Infrared photodissociation of weakly bound "mass tags" is widely used to determine the structures of ions by analyzing their vibrational spectra. Molecular hydrogen is a common choice for tagging in cryogenic radio-frequency ion traps. Although the H2 molecules can introduce distortions in the target species, we demonstrate an advantage of H2 tagging in the analysis of positional isomers adopted by the molecular anions derived from decarboxylation of formylbenzoates. Attachment of H2 to the carbanion centers of three such isomers yields distinct shifts in the H2 stretch, which can be used to determine the distribution of isomers in an unknown sample. Electronic structure calculations indicate that the position-dependent shifts are due to different reactivities of the carbanion sites with respect to an intracluster proton-transfer reaction with the H2 molecule. We exploit this spectroscopic method to quantify the surprisingly facile migrations of the anionic center that have been previously reported for phenide rearrangements.

Experimental study of ion beam interaction with target surface aimed at developing a contactless method for space debris removal by an ion beam

Research and development in the field of space debris (SD) removal technologies is one of the most important and urgent tasks facing all spacefaring nations. By now, a large number of different concepts of removal have already been proposed. One of them is the SD removal by ion beam generated by an ion source installed on board a service spacecraft (SSC). A detailed understanding of the process of ion beam interaction with the SD surface is required to develop an optimal control algorithm for the virtual SSC-SD mated configuration in order to improve this method of SD removal. In addition, when designing the SSC, it is necessary to take into account back flows of the material sputtered from the surface of removed SD by the ion beam, which can contaminate the SSC operating surfaces during the removal maneuver. Within the framework of the presented work, experimental studies were performed to determine the coefficient of accommodation of the ion impulse during the ion beam interaction with the surface of the target simulating the external surface of the removed object. Besides, the flow density of the sputtered target material was experimentally evaluated during its exposure to the ion beam. To do this, we used the radio-frequency ion source (injector) with a beam diameter of 160 mm, which is supposed to be used as an actuating unit on board the SSC designed for transporting the SD objects to the disposal orbit or to the orbits with limited life. When measuring the ion beam accommodation coefficient, the presence of additional force arising on the target due to the flow of sputtered material leaving its surface, and the ion-electron emission process on the target, which could distort the experimental data, were taken into account. To estimate the magnitude of the flows of sputtered target material under the influence of the ion beam, a special experimental design was developed for simulating the presence of a point source of sputtered material. The results obtained in this work will be used for modeling the impact of the ion beam on the surface of real SD objects with complex geometry using the finite element method, for refining the control algorithm of the virtual SSC-SDO mated configuration and for developing proposals on the SSC layout, which should reduce or completely eliminate the negative impact associated with the material sputtering from the SDO surface onto the SSC elements. Successful implementation of the developed method of SDO removal will contribute to improving the safety of space activities for all countries and to the development of the rocket-and-space industry in the Russian Federation, in particular.

Kinetic simulations of low-pressure inductively coupled plasma: an implicit electromagnetic PIC/MCC model with the ADI-FDTD method

Low-pressure inductively coupled plasma (ICP) is promising for space electric propulsion. For the first time, an implicit electromagnetic particle-in-cell Monte Carlo collision model based on the alternating-direction-implicit finite-difference time-domain (ADI-FDTD) method is developed to investigate low-pressure xenon plasma characteristics of a miniature ICP source. The induced simulated electric field is well consistent with that calculated by the finite element method, indicating that this method can provide an accurate estimation of the electromagnetic field. The simulation time step used in the ADI-FDTD method is no longer restricted by the Courant–Friedrichs–Lewy constraints. Compared with the FDTD method, the ADI-FDTD method increases the size of the time step and significantly improves computational efficiency. The method is validated by comparing the simulated and measured electron density and plasma potential profile and reasonable agreement is reached. Therefore, the model is used to investigate the temporal and spatial distribution of plasma properties and the influence of the current amplitude of radio frequency (RF) coil, applied frequency of RF coil and neutral gas pressure on the plasma dynamics in the ionization chamber of a miniature gridded RF ion thruster. To explain the influence of the operating parameters, a concept called ‘the energy relaxation characteristics of electrons in response to the change of electric field’ is proposed and verified. The simulations also find that the oscillation frequency of plasma properties is twice the applied frequency of RF coil. The oscillation characteristics reveal the dynamic energy balance in the ICP. The experiment on the gridded RF ion thruster BHRIT-4 confirms the oscillation by measuring the plasma sheath potential.

Discoloration of RF antenna coil surface after long-term operation of J-PARC ion source

In J-PARC (Japan Proton Accelerator Research Complex) center, the continuous operation period of the Radio Frequency (RF) negative hydrogen ion (H−) source equipped with the internal RF antenna coil is extended step by step in these 6–7 years for the goal to supply stable beam during the entire period of J-PARC user operation each year. In 2022, the continuous ion source operation for 4,001 hours (5.5 months) was achieved with 60 mA H− beam current at the ion source exit, 25 Hz repetition, mainly 500 μs beam pulse width, and 25 kW RF power injection. As the lifetime of the RF ion source is mainly limited by the deterioration of the enamel coating on the RF antenna coil, a detailed evaluation of the antenna surface is required to ensure the feasibility of the further extension of the operation period. In the present study, surface discoloration on the RF antenna coil observed after 5 months of operation is investigated by the application of a digital microscope and SEM/EDS analyses. The EDS analyses show that depositions of the sputtered stainless steel elements and the injected cesium are the most possible candidates for impurities on the enamel coating. The dimension measurements of the RF antenna thickness before and after the long-term operation also support the assumption that the discoloration is due to the deposited elements and hence insulation of the RF antenna coil by enamel coating is maintained. Possible mechanisms leading to antenna deterioration starting from element depositions on the antenna coating are also discussed in the summary part of this manuscript.

Underground nuclear astrophysics: Status and recent results from Felsenkeller laboratory

For almost three decades it has been known that the study of astro-physically important nuclear reactions between stable nuclei requires the use of low-background, underground accelerator laboratories. The Felsenkeller shallow-underground laboratory in Dresden, shielded by a 45 m thick rock cover, hosts a 5 MV Pelletron ion accelerator with an external sputter ion source (mainly able to provide carbon and oxygen beams) and an internal radio-frequency ion source (providing proton and alpha beams). The reduced muon, neutron and gamma-ray background achieved both with natural and active shielding situate the laboratory well in line with deep underground accelerator labs worldwide and allows highly sensitive nuclear reaction experiments. Currently, measurements affecting the solar fusion and Big Bang nucleosynthesis are ongoing. In addition to in-house research by HZDR and TU Dresden, the lab is an open facility for scientific users worldwide, with beam time applications reviewed by an independent science advisory board. Furthermore, EU-supported transnational access is available via the ChETEC- INFRA network for nuclear astrophysics. A brief introduction to underground nuclear astrophysics, status of the Felsenkeller shallow-underground laboratory and some preliminary results are discussed.

A 22-pole radiofrequency ion trap setup for laboratory astrophysical studies.

The formation of large interstellar molecules starting from small reactants constitutes the bottom-up approach in astrochemistry. An experimental setup wherein the ionic reactant is prepared and allowed to react with neutral reactants within a confined interaction space is most desirable for this approach. Here, we present our efforts in constructing a 22-pole radio-frequency ion trap experimental setup that could act as a reaction chamber for the neutral reactant and trapped ions. A compact piezo-based pulsed supersonic expansion discharge source was developed to achieve efficient production of anions, particularly metal-bearing ions. In addition, two other ion sources, namely, the electron impact ion source and the plasma supersonic discharge ion source, were developed to cater to the production of specific ions. The geometry of this experimental setup facilitates photo excitation of trapped ions. The trapping efficiency was studied by trapping SF5+ and SF6- for a few seconds. The control exhibited by various parameters on the efficiency of the trapping is discussed in detail. Potential studies that could be performed with this new experimental setup are also discussed.

Mathematical modeling of the ion extraction system of a radio-frequency ion source

In order to ensure space debris removal from the near-Earth space, the world scientific community is developing various technical means potentially capable of transporting the spent spacecraft to disposal orbits. The so-called Ion Beam Shepherd is among them. According to this method, in order to transfer momentum efficiently from an ion beam generated by a radio-frequency ion source mounted on board a service spacecraft, it is necessary to ensure the generation of an ion beam with the minimum divergence angle. In order to provide generation of a highly collimated ion beam for a system of contactless removal of technogenic space debris, an ion extraction system was modeled with the aim to study the influence of its geometric parameters on the angle of ion beam divergence at the ion source exit plane. Based on the preliminary study, a model of 28 full factorial experiment was developed for two types of electrodes in an ion extraction system. The regression coefficients have been defined that allow, without performing a large array of numerical studies, to assess the influence of various geometric parameters on the ion beam divergence angle.

Ion flux measurements using a Mach-Langmuir probe in the ITER prototype neutral beam injection ion source

Neutral beam injection systems as foreseen for ITER use radio-frequency (RF) ion sources at low pressure, where negative hydrogen ions are mainly produced via surface conversion of neutral atoms and positive ions at a plasma facing grid (PG). Up to now there is only limited knowledge about how fluxes and directed velocities of the positive ions are affected by external parameters such as power, pressure and the horizontal magnetic filter field which causes plasma drifts and vertical asymmetries in the vicinity of the PG. For this reason a combined Mach-Langmuir-probe diagnostic is used at multiple positions in the expansion and close to the extraction system in the prototype RF ion source (1/8 of the full ITER ion source size) to measure the positive ions directed velocity and flux as well as the plasma parameters simultaneously. With increasing RF power the flux towards the PG is found to increase linearly, its magnitude being controlled by the plasma density. Towards ITER-relevant pressures the ion flux decreases, in contrast to the directed velocity, which increases non-linearly, reaching around 5 km s−1 at a pressure of 0.3 Pa. The magnetic filter field is discovered to strongly bent down the ion flow in front of the PG. As a result, the ions at the lower half of the PG flow almost exclusively parallel to it, wherefore the flux which impinges onto the lower PG half is reduced by around one order of magnitude.