Ion Cyclotron Research Articles

Conjugate Observations of Magnetospheric and Ionospheric Phenomena During a Substorm Event

AbstractThis study investigates the comprehensive magnetospheric and ionospheric phenomena during a substorm event on 14 December 2013. The methodology involves analyzing data from satellites located within the plasmasphere at dusk‐side of the Earth, as well as data from ionospheric satellites mapped in the subauroral region. Magnetospheric data were analyzed to identify key features during the substorm event. Proton injection into the ring current, presence of proton and helium band electromagnetic ion cyclotron (EMIC) waves with different polarization characteristics, and harmonic structures in these EMIC waves were identified. These harmonic structures coincided with the appearance of magnetosonic waves characterized by rising tone structures and heating of low‐energy protons (<100 eV). Ionospheric satellites (DMSP F17 and POES 15) recorded enhanced proton precipitation contributing to the intensification of subauroral proton arcs. The analysis revealed that these enhanced proton fluxes were associated with variations in field‐aligned currents (FACs) and drove dynamics within the Sub‐Auroral Polarization Streams (SAPS). By combining and analyzing the magnetospheric and ionospheric data sets, this study provides a comprehensive understanding of magnetosphere‐ionosphere coupling during substorms, particularly on the duskside. The complex interdependence and causal relationships among EMIC waves, proton precipitation, subauroral proton arcs, FAC variations, and SAPS dynamics were highlighted.

Peatlands Versus Permafrost: Landscape Features as Drivers of Dissolved Organic Matter Composition in West Siberian Rivers

AbstractWest Siberia contains some of the largest soil carbon stores on Earth owing to vast areas of peatlands and permafrost, with the region warming far faster than the global average. Organic matter transported in fluvial systems is likely to undergo distinct compositional changes as peatlands and permafrost warm. However, the influence of peatlands and permafrost on future dissolved organic matter (DOM) composition is not well characterized. To better understand how these environmental drivers may impact DOM composition in warming Arctic rivers, we used ultrahigh resolution Fourier‐transform ion cyclotron resonance mass spectrometry to analyze riverine DOM composition across a latitudinal gradient of West Siberia spanning both permafrost‐influenced and permafrost‐free watersheds and varying proportions of peatland cover. We find that peatland cover explains much of the variance in DOM composition in permafrost‐free watersheds in West Siberia, but this effect is suppressed in permafrost‐influenced watersheds. DOM from warm permafrost‐free watersheds was more heterogenous, higher molecular weight, and relatively nitrogen enriched in comparison to DOM from cold permafrost‐influenced watersheds, which were relatively enriched in energy‐rich peptide‐like and aliphatic compounds. Therefore, we predict that as these watersheds warm, West Siberian rivers will export more heterogeneous DOM with higher average molecular weight than at present. Such compositional shifts have been linked to different fates of DOM in downstream ecosystems. For example, a shift toward higher molecular weight, less energy‐rich DOM may lead to a change in the fate of this material, making it more susceptible to photochemical degradation processes, particularly in the receiving Arctic Ocean.

Simulation of ion cyclotron wave heating in the EXL-50U spherical tokamak based on dispersion relations

This study investigates the single-pass absorption (SPA) of ion cyclotron range of frequency (ICRF) heating in hydrogen plasma of the EXL-50U spherical tokamak, which is an upgraded EXL-50 device with a central solenoid and a stronger magnetic field. The reliability of the kinetic dispersion equation is confirmed by the one-dimensional full-wave code, and the applicability of Porkolab's simplified theoretical SPA model is discussed based on the kinetic dispersion equation. Simulations are conducted to investigate the heating effects of the fundamental and second harmonic frequencies. The results indicate that with the design parameters of the EXL-50U device, the SPA for second harmonic heating is 63%, while the SPA for fundamental heating is 13%. Additionally, the optimal injection frequencies are 23 MHz at 0.9 T and 31 MHz at 1.2 T. The wave vector of the antenna parallel to the magnetic field, with a value of , falls within the optimal heating region. Simulations reveal that the ICRF heating system can play an important role in the ion heating of the EXL-50U.

Electromagnetic Ion Beam Instability in the Solar Corona

Remote-sensing measurements indicate that heavy ions in the corona undergo an anisotropic and mass-charge dependent energization. A popular explanation to this phenomenon is the damping of the Alfvén/ion cyclotron waves. In this paper, we propose that the ion beam instability can be an important source of the Alfvén/ion cyclotron waves, and we study the excitation of the ion beam instability in the corona at the heliocentric distance ∼3R ⊙ and the corresponding energy transfer process therein based on plasma kinetic theory. The results indicate that the existence of the motionless heavy ions inhibits the ion beam instability. However, the anisotropic beams of heavy ions promote the excitation of the ion beam instability. Besides, the existence of α beams can provide a second energy source for exciting beam instability. However, when both the proton beam and the α beam reach the instability excitation threshold, the proton beam driven instability excites preferentially. Moreover, the excitation threshold of the Alfvén/ion cyclotron instability driven by ion beam is of the local Alfvén speed or even less in the corona.

Photolysis of Dissolved Organic Matter over Hematite Nanoplatelets.

Solar photoexcitation of chromophoric groups in dissolved organic matter (DOM), when coupled to photoreduction of ubiquitous Fe(III)-oxide nanoparticles, can significantly accelerate DOM degradation in near-surface terrestrial systems, but the mechanisms of these reactions remain elusive. We examined the photolysis of chromophoric soil DOM coated onto hematite nanoplatelets featuring (001) exposed facets using a combination of molecular spectroscopies and density functional theory (DFT) computations. Reactive oxygen species (ROS) probed by electron paramagnetic resonance (EPR) spectroscopy revealed that both singlet oxygen and superoxide are the predominant ROS responsible for DOM degradation. DFT calculations confirmed that Fe(II) on the hematite (001) surface, created by interfacial electron transfer from photoexcited chromophores in DOM, can reduce dioxygen molecules to superoxide radicals (•O2-) through a one-electron transfer process. 1H nuclear magnetic resonance (NMR) and electrospray ionization Fourier-transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) spectroscopies show that the association of DOM with hematite enhances the cleavage of aromatic groups during photodegradation. The findings point to a pivotal role for organic matter at the interface that guides specific ROS generation and the subsequent photodegradation process, as well as the prospect of using ROS signatures as a forensic tool to help interpret more complicated field-relevant systems.

Controls of Mineral Solubility on Adsorption-Induced Molecular Fractionation of Dissolved Organic Matter Revealed by 21 T FT-ICR MS.

Mineral adsorption-induced molecular fractionation of dissolved organic matter (DOM) affects the composition of both DOM and OM adsorbed and thus stabilized by minerals. However, it remains unclear what mineral properties control the magnitude of DOM fractionation. Using a combined technique approach that leverages the molecular composition identified by ultrahigh resolution 21 T Fourier transform ion cyclotron resonance mass spectrometry and adsorption isotherms, we catalogue the compositional differences that occur at the molecular level that results in fractionation due to adsorption of Suwannee River fulvic acid on aluminum (Al) and iron (Fe) oxides and a phyllosilicate (allophane) species of contrasting properties. The minerals of high solubility (i.e., amorphous Al oxide, boehmite, and allophane) exhibited much stronger DOM fractionation capabilities than the minerals of low solubility (i.e., gibbsite and Fe oxides). Specifically, the former released Al3+ to solution (0.05-0.35 mM) that formed complexes with OM and likely reduced the surface hydrophobicity of the mineral-OM assemblage, thus increasing the preference for adsorbing polar DOM molecules. The impacts of mineral solubility are exacerbated by the fact that interactions with DOM also enhance metal release from minerals. For sparsely soluble minerals, the mineral surface hydrophobicity, instead of solubility, appeared to be the primary control of their DOM fractionation power. Other chemical properties seemed less directly relevant than surface hydrophobicity and solubility in fractionating DOM.

Mediation of collisionless turbulent dissipation through cyclotron resonance

The dissipation of turbulence in astrophysical systems is fundamental to energy transfer and heating in environments ranging from the solar wind and corona to accretion disks and the intracluster medium. Although turbulent dissipation is relatively well understood in fluid dynamics, astrophysical plasmas often exhibit exotic behaviour, arising from the lack of interparticle collisions, which complicates turbulent dissipation and heating in these systems. Recent observations by NASA’s Parker Solar Probe mission in the inner heliosphere have shed new light on the role of ion cyclotron resonance as a potential candidate for turbulent dissipation and plasma heating. Here, using in situ observations of turbulence and wave populations, we show that ion cyclotron waves provide a major pathway for dissipation and plasma heating in the solar wind. Our results support recent theoretical predictions of turbulence in the inner heliosphere, known as the helicity barrier, that suggest a role of cyclotron resonance in ion-scale dissipation. Taken together, these results provide important constraints for turbulent dissipation and acceleration efficiency in astrophysical plasmas.

Persistent free radicals of activated carbon induce highly toxic by-products formation during chlorination

Both activated carbon (AC) and chlorine are commonly used in water treatment processes and thus the exposure of chlorine to AC surface is unavoidable under some circumstances. Therefore, evaluating the effects of AC, particularly the persistent free radicals (PFRs) of AC on the chlorination by-products is critical for drinking water safety. Here, through comparison of the chlorination process of different ACs with similar pore structure but different PFR intensities, it was found that AC with more PFRs generated more unknown by-products with lower relative cell viability (85%). The Fourier transform ion cyclotron resonance- mass spectrometry results showed that the proportions of one-chlorine and nitrogen containing by-products generated by AC with higher PFR intensity were 19.6% and 16.9%, respectively, which were higher than those generated by AC with lower PFR intensity. Furthermore, the polycyclic aromatic compounds and polyphenols with high toxicity were only found in the chlorination products of AC with high PFR intensity. The PFRs of AC could promote the chlorine decay and induce the generation of superoxide radical and chlorine radical, and thus led to the formation of more toxic by-products. This study provides new insights into the risks of water chlorination process and by-product formation in the presence of AC.

Molecular insights into the microbial degradation of sediment-derived DOM in a macrophyte-dominated lake under aerobic and hypoxic conditions

The mineralization of dissolved organic matter (DOM) in sediments is an important factor leading to the eutrophication of macrophyte-dominated lakes. However, the changes in the molecular characteristics of sediment-derived DOM during microbial degradation in macrophyte-dominated lakes are not well understood. In this study, the microbial degradation process of sediment-derived DOM in Lake Caohai under aerobic and hypoxic conditions was investigated using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) and metagenomics. The results revealed that the microbial degradation of sediment-derived DOM in macrophyte-dominated lakes was more intense under aerobic conditions. The microorganisms mainly metabolized the protein-like substances in the macrophyte-dominated lakes, and the carbohydrate-active enzyme genes and protein/lipid-like degradation genes played key roles in sediment-derived DOM degradation. Organic compounds with high H/C ratios such as lipids, carbohydrates, and protein/lipid-like compounds were preferentially removed by microorganisms during microbial degradation. Meanwhile, there was an increase in the abundance of organic molecular formula with a high aromaticity such as tannins and unsaturated hydrocarbons with low molecular weight and low double bond equivalent. In addition, aerobic/hypoxic environments can alter microbial metabolic pathways of sediment-derived DOM by affecting the relative abundance of microbial communities (e.g., Gemmatimonadetes and Acidobacteria) and functional genes (e.g., ABC.PE.P1 and ABC.PE.P) in macrophyte-dominated lakes. The abundances of lipids, unsaturated hydrocarbons, and protein compounds in aerobic environments decreased by 58 %, 50 %, and 44 %, respectively, compared to in hypoxic environments under microbial degradation. The results of this study deepen our understanding of DOM biodegradation in macrophyte-dominated lakes under different redox environments and provide new insights into nutrients releases from sediment and continuing eutrophication in macrophyte-dominated lakes.

Modeling the Simultaneous Dropout of Energetic Electrons and Protons by Magnetopause Shadowing

AbstractMagnetopause shadowing (MPS) effect could drive a concurrent dropout of radiation belt electrons and ring current protons. However, its relative role in the dropout of both plasma populations has not been well quantified. In this work, we study the simultaneous dropout of MeV electrons and 100s keV protons during an intense geomagnetic storm in May 2017. A radial diffusion model with an event‐specific last closed drift shell is used to simulate the MPS loss of both populations. The model well captures the fast shadowing loss of both populations at L* > 4.6, while the loss at L* < 4.6, possibly due to the electromagnetic ion cyclotron wave scattering, is not captured. The observed butterfly pitch angle distributions of electron fluxes in the initial loss phase are well reproduced by the model. The initial proton losses at low pitch angles are underestimated, potentially also contributed by other mechanisms such as field line curvature scattering.

Hydrological alteration drives chemistry of dissolved organic matter in the largest freshwater lake of China (Poyang Lake)

As the largest reactive organic carbon pool, dissolved organic matter (DOM) plays an important role in various biogeochemical processes in lake ecosystems. Recently, climate change-induced extreme events (e.g., floods and droughts) have significantly modified the hydrological patterns of lakes worldwide, and regulated the quality and quantity of DOM. However, the responses of DOM chemistry to hydrological alteration in lakes remain poorly understood. Here we investigated the influences of hydrological alteration on sources, composition, and characteristics of DOM in Poyang Lake, the largest freshwater lake in China, using a combination of bulk chemical, optical and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) techniques. Results show various sources of DOM (autochthonous, allochthonous, and anthropogenic inputs) and significant variations in DOM chemistry across four hydrological periods (the retreating, dry, rising, and flooding periods) in Poyang Lake. During the retreating, rising, and flooding periods, DOM was characterized by higher aromaticity, humification degree, and recalcitrance, and exhibited pronounced allochthonous signatures. In contrast, DOM contained more S-containing molecules and aliphatic compounds during the dry period, displaying relatively stronger autochthonous features. Terrestrial inputs and the lignin-CHOS formation process are likely the primary underlying mechanisms shaping the differences in DOM chemistry in Poyang Lake. Our research demonstrates the significant impacts of hydrological alteration on DOM dynamics, and provides an improved understanding of DOM biogeochemical cycles and carbon cycling in large aquatic systems under global climate change.

Mass spectrometric analysis of unprecedented high levels of carbonaceous aerosol particles long-range transported from wildfires in the Siberian Arctic

Abstract. Wildfires in Siberia generate large amounts of aerosols, which may be transported over long distances and pose a threat to the sensitive ecosystem of the Arctic. Particulate matter (PM) of aged wildfire plumes originating from Yakutia in August 2021 was collected in Nadym and on Bely Island (both in northwestern Siberia). An advanced analysis of the chemical composition of aerosol particles was conducted through a multi-wavelength thermal–optical carbon analyzer (TOCA) coupled to resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (REMPI-TOFMS) as well as through ultra-high-resolution Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS). In Nadym, concentrations of organic carbon (OC) and elemental carbon (EC) peaked at 100 and 40 µg m−3, respectively, associated with Angström absorption exponents for 405 and 808 nm (AAE405/808) between 1.5 and 3.3. The weekly average on Bely Island peaked at 8.9 µg m−3 of OC and 0.3 µg m−3 of EC and AAE405/808 close to unity. In particular, ambient aerosol in Nadym had a distinct biomass burning profile with pyrolysis products from carbohydrates, such as cellulose and hemicellulose, as well as lignin and resinoic acids. However, temporarily higher concentrations of five- and six-ring polycyclic aromatic hydrocarbons (PAHs), different from the PAH signature of biomass burning, suggest a contribution of regional gas flaring. FT-ICR MS with electrospray ionization (ESI) revealed a complex mixture of highly functionalized compounds, containing up to 20 oxygen atoms, as well as nitrogen- and sulfur-containing moieties. Concentrations of biomass burning markers on Bely Island were substantially lower than in Nadym, flanked by the appearance of unique compounds with higher oxygen content, higher molecular weight, and lower aromaticity. Back-trajectory analysis and satellite-derived aerosol optical depth suggested long-range transport of aerosol from the center of a Yakutian wildfire plume to Nadym and from the plume periphery to Bely Island. Owing to lower aerosol concentrations in the plume periphery than in its center, it is demonstrated how dilution affects the chemical plume composition during atmospheric aging.

Fast-ion orbit origin of neutron emission spectroscopy measurements in the JET DT campaign

In the JET DTE2 deuterium-tritium campaign, neutron diagnostics were employed to measure 14 MeV neutrons originating from D(T,n)4He reactions. In discharge 99965, a diamond matrix detector (KM14) and a magnetic proton recoil (MPRu) detector with a vertical and an oblique line-of-sight were used, respectively. At the timepoints of interest, a significant decrease in the expected diagnostic signals can be observed as electromagnetic wave heating in the ion cyclotron range of frequencies (ICRF) is switched off. Utilizing only TRANSP simulation data, the fast-ion distribution is found to have been likely composed mostly of trapped orbits. In contrast, analysis performed using orbit weight functions revealed that the majority of neutrons in the KM14 Ed=9.3 MeV and MPRu Xcm=33 cm measurement bins are to have originated from fast deuterium ions on co-passing orbits. This work explains the perhaps surprising results and shows that the relative signal decrease as ICRF heating is switched off is largest for counter-passing orbits. Finally, for the magnetic equilibria of interest, it is shown how stagnation orbits, corresponding to ∼1 % of the fast-ion distribution, were completely unobservable by the KM14 diagnostic.

Polyphenols, Antioxidants, and Wound Healing of Lecythis pisonis Seed Coats.

To better use the Lecythis pisonis Cambess. biomass, this study investigates whether Sapucaia seed coats present wound healing properties. We analyzed the antibacterial, antioxidant, and wound healing-promoting potentials, plus cytotoxicity and stimulation of vascular endothelial growth factor-A. The chemical composition was analyzed by positive ion mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. A total of 19 compounds were identified, such as proanthocyanidin A1, procyanidins A1, B2, and C1, epigallocatechin, and kaempferol (p-coumaroyl) glycoside. Potent antioxidant strength/index was verified for 2,2-diphenyl-1-picrylhydrazyl radical (IC50 = 0.99 µg/mL) and ferric reducing antioxidant power (IC50 = 1.09 µg/mL). The extract did not present cytotoxicity and promoted significant cell migration and/or proliferation of fibroblasts (p < 0.05). Vascular endothelial growth factor-A was stimulated dose-dependently at 6 µg/mL (167.13 ± 8.30 pg/mL), 12.5 µg/mL (210.3 ± 14.2 pg/mL), and 25 µg/mL (411.6 ± 29.4 pg/mL). Platelet-derived growth factor (PDGF) (0.002 µg/mL) was stimulated at 215.98 pg/mL. Staphylococcus aureus was susceptible to the extract, with a minimum inhibitory concentration of 31.25 µg/mL. The identified compounds benefit the antioxidant activity, promoting hemostasis for the wound healing process, indicating that this extract has the potential for use in dermatological cosmetics.

Nonlinear structure and growth rate of solitary waves for extended Zakharov-Kuznetsov equation in plasma having (r, q) distribution electrons

The Reductive Perturbation Technique (RPT) is used to investigate ion acoustic waves (IAWs) in magnetized plasmas made up of electrons obeying the generalized form of ( r,q ) distribution. The analysis makes use of the Extended Zakharov-Kuznetsov (EZK) equation and the hydrodynamic theory of plasmas. The study investigates the effects of electron flatness ( r ) at low energy and superthermal ( q ) at high energy on the characteristics of IAWs, and the solutions to the EZK equation are plotted for different values of the plasma characteristics, such as the total ion cyclotron frequency, the ion to electron temperature ratio, and the ion-specific heat. The research goes into great detail to estimate the instability threshold and growth rate of these waves by applying a small-k perturbation technique. Overall, this investigation contributes to the better understanding of ion acoustic structures in space plasmas.

Ultrahigh resolution lipid mass spectrometry imaging of high-grade serous ovarian cancer mouse models.

No effective screening tools for ovarian cancer (OC) exist, making it one of the deadliest cancers among women. Considering that little is known about the detailed progression and metastasis mechanism of OC at a molecular level, it is crucial to gain more insights into how metabolic and signaling alterations accompany its development. Herein, we present a comprehensive study using ultra-high-resolution Fourier transform ion cyclotron resonance matrix-assisted laser desorption/ionization (MALDI) mass spectrometry imaging (MSI) to investigate the spatial distribution and alterations of lipids in ovarian tissues collected from double knockout (n = 4) and triple mutant mouse models (n = 4) of high-grade serous ovarian cancer (HGSOC). Lipids belonging to a total of 15 different classes were annotated and their abundance changes were compared to those in healthy mouse reproductive tissue (n = 4), mapping onto major lipid pathways involved in OC progression. From intermediate-stage OC to advanced HGSC, we provide direct visualization of lipid distributions and their biological links to inflammatory response, cellular stress, cell proliferation, and other processes. We also show the ability to distinguish tumors at different stages from healthy tissues via a number of highly specific lipid biomarkers, providing targets for future panels that could be useful in diagnosis.

Changeover between helium and hydrogen fueled plasmas in JET and WEST

The pre-fusion power operation (PFPO) phase of ITER, as described in the ITER research plan with Staged Approach,22ITER Organization, “ITER Research Plan within the Staged Approach,” ITR-18–003, Aug. 2018. includes both hydrogen (H) and helium (He) plasma operations. In preparation for PFPO, both WEST and JET ran He plasma campaigns to study plasma-wall interactions in a tungsten environment. The campaigns included a back-and-forth transition between H or deuterium (D) and He plasma operation allowing the assessment of the achievable plasma content as well as the accessible wall reservoirs for respective species. The WEST changeovers included tokamak pulses with a fixed divertor configuration. The JET changeovers applied ion cyclotron wall conditioning (ICWC) and tokamak pulses including limiter phases and four different divertor configurations. Glow discharge conditioning (GDC) was applied to complete the changeovers. The results are characterized by subdivertor optical and mass spectrometric gas analyzers and spatially resolved optical emission spectroscopy. A He content of 96–97 % after H operations is achieved by tens of ICWC pulses (JET) and several dedicated diverted plasmas (WEST and JET), while a fivefold is estimated to be required for the back transition. Effective pumping of the wall released species is a key parameter for a fast changeover. Upon applying higher heating power, the relative content of the fueled plasma species decreases. The JET gas balance analysis indicates that He operation may increase H retention. WEST divertor spectroscopy indicates a larger He inventory near the inner divertor strike line. He GDC has a clear effect on the He recycling light at the WEST divertor while D GDC did not reduce the long lasting He content observed in D pulses after the JET He campaign.

Molecular signatures and formation mechanisms of water-soluble chromophores in particulate matter from Karachi in Pakistan

Excitation-emission matrix (EEM) fluorescence spectroscopy is a widely-used method for characterizing the chemical components of brown carbon (BrC). However, the molecular basics and formation mechanisms of chromophores, which are decomposed by parallel factor (PARAFAC) analysis, are not yet fully understood. In this study, we characterized the water-soluble organic carbon (WSOC) in aerosols collected from Karachi, Pakistan, using EEM spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). We identified three PARAFAC components, including two humic-like components (C1 and C2) and one phenolic-like species (C3). We determined the molecular families associated with each component by performing Spearman correlation analysis between FT-ICR MS peaks and PARAFAC component intensities. We found that the C1 and C2 components were associated with nitrogen-enriched compounds, where C2 with the longest emission wavelength exhibited a higher level of aromaticity, N content, and oxygenation than C1. The C3 associated formulas have fewer nitrogen-containing species, a lower unsaturation degree, and a lower oxidation state. An oxidation pathway was identified as an important process in the formation of C1 and C2 components at the molecular level, particularly for the assigned CHON compounds associated with the gas-phase oxidation process, despite their diverse precursor types. Numerous C2 formulas were found in the “potential BrC” region and overlapped with the BrC-associated formulas. It can be inferred that the compounds that fluoresce C2 contributed considerably to the light absorption of BrC. These findings are essential for future studies utilizing the EEM-PARAFAC method to explore the sources, processes, and compositions of atmospheric BrC.

Dissolved organic matter composition and characteristics during extreme flood events in the Yangtze River Estuary

Understanding the molecular composition and fate of dissolved organic matter (DOM) during transport in estuaries is essential for gaining a comprehensive understanding of its role within the global biogeochemical cycle. In 2020, a catastrophic flood occurred in the Yangtze River basin. It is currently unknown whether differences in hydrologic conditions due to extreme flooding will significantly impact the estuarine to oceanic DOM cycle. We determined the DOM composition in the Yangtze River estuary (YRE) to the East China Sea by using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) during the high discharge and the flood period (monthly average discharge was 1.2 times higher) on the same trajectory. Our study found that the composition of DOM is more diverse, and more DOM molecules were introduced to the YRE during the flood, especially in the freshwater end member. The result revealed that the DOM was significantly labile and unstable during the flood period. A total of 1840 unique molecular formulas were identified during the flood period, most of which were CHON, CHONS, and CHOS compounds, most likely resulting from anthropogenic inputs from upstream. Only 194 of these molecules were detected in the seawater end member after transporting to the sea, suggesting that the YRE served as a ‘filter’ of DOM. However, the flood enhances the transport of a group of terrigenous DOM, that is resistant to photodegradation and biodegradation. As a result, YRE experienced ~1.6 times higher terrigenous DOC flux than high discharge period. Considering the increased frequency of future floods, our study provides a preliminary basis for further research on how floods affect the composition and characteristics of estuarine DOM. With the help of the FT-ICR MS technique, we can now better understand the dynamic of DOM composition and characteristics in large river estuaries.

A Triggering Process for Nonlinear EMIC Waves Driven by the Compression of the Dayside Magnetosphere

AbstractUsing the Arase and Van Allen Probes satellite observations, we investigate the nonlinear electromagnetic ion cyclotron (EMIC) rising‐tone (RT) emissions with an increase of the solar wind dynamic pressure in the dayside magnetosphere. We find that EMIC RT emissions are accompanied by the extended dayside uniform zone (DUZ) over |MLAT| &lt; 25° due to the dayside magnetospheric compression by an increase in Pdyn. Using the observed plasma and magnetic field data, we modeled the threshold amplitude for the nonlinear EMIC waves and compared it with the observation. The small gradient of the ambient magnetic field strongly contributes to the reduction in the threshold amplitude of nonlinear wave growth compared to other parameters. When the threshold amplitude falls to comparable level of pre‐existing EMIC waves, EMIC RT emissions are immediately triggered, suggesting direct evidence that the DUZ is the preferred condition to cause the nonlinear EMIC RT emission in the dayside magnetosphere.