Investigation Of Mass Transfer Research Articles

Mass transfer enhancement and hydrodynamic performance with wire mesh coupling solid particles in bubble column reactor

It is of vital significance to investigate mass transfer enhancements for chemical engineering processes. This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas–liquid mass transfer process in a bubble column. Particle image velocimetry (PIV) technology was employed to analyze the flow field and bubble motion behavior, and dynamic oxygen absorption technology was used to measure the gas–liquid volumetric mass transfer coefficient kLa. The effect of embedding wire mesh, adding solid particles, and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared. The results show that the gas–liquid interface area increases by 33% to 72% when using the wire mesh coupling solid particles strategy compared to the gas–liquid two-phase flow, which is superior to the other two strengthening methods. Compared with the system without reinforcement, kLa in the bubble column increased by 0.5–1.8 times with wire mesh coupling solid particles method, which is higher than the sum of kLa increases with inserting wire mesh and adding particles, and the coupling reinforcement mechanism for affecting gas–liquid mass transfer process was discussed to provide a new idea for enhancing gas–liquid mass transfer.

Experimental Investigations of Non-Stationary Heat and Mass Transfer with Reversible Air Flow through Fixed Layers of Absorbent and Heat-Accumulating Packing

Experimental Investigations of Non-Stationary Heat and Mass Transfer with Reversible Air Flow through Fixed Layers of Absorbent and Heat-Accumulating Packing

Laser-Doppler Anemometry for detection of the velocity field in the ventilated, asymmetrically heated channel - a case study

The topic of double-skin façades (DSFs) is re-emerging in the research environment, with studies ranging from architectural design concepts to specific investigations of heat and mass transfer in a vertical channel. These studies reflect a lack of comprehension of the phenomena taking place within the DSF cavities. This work presents a case study, where the Laser-Doppler Anemometry principle, combined with video registration of smoke movement, is used to establish the velocity and flow patterns in an asymmetrically heated ventilated channel in a controlled environment. The authors of this work contribute to the research field by addressing the pros and cons of the Laser-Doppler Anemometry approach for the measurement of the vertical velocity component in a DSF and presenting an example of obtained experimental results for the validation of CFD models. The results of this work address the velocity distribution for the vertical 2D cross plane of the DSF cavity. The analysis of the measurement data includes an assessment of the stability of the flow and fluctuations throughout the measurement period.

Investigations of mass transfer in simulated biomedical systems

The work motivation was to investigate in vitro system simulating drug release from Drug Eluting Stent (DES). The experiments were conducted in a custom designed unit simulating drug release from polymer covering DES in a simplified way. The active substance diffuses from a thin, internal annular layer of hydrogel (imitating “stent”) to the outer cylindrical layer of hydrogel (“artery wall”) and is at once drifted away by coaxially flowing solution (“blood”). The conducted research proved functionality of the experimental unit. The rate of mass transfer depends considerably on the mass driving force and on the affinity of substance-hydrogel. The volumetric flow rate and liquid viscosity did not affect the process significantly. The effective diffusion coefficient was calculated as a process parameter and then used in the other variants. Diffusion in hydrogel is the mechanism limiting the mass transfer in the examined system. For the first attempt, the diffusive model used in literature was employed. The provided calculations are consistent with experimental data and therefore show that despite its simplifications the model allows to estimate the amount of released substance. In conclusion, the relative substance mass, changing over time, was estimated in the respective parts of the unit. The prospect of determining the relative mass of the substance appearing in the subsequent parts of the system over time provides the opportunity to adjust the respective process parameters, which will facilitate control over the rate of mass release.

Experimental analysis of an innovative internally cooled dehumidifier

To address the absence of balance in existing heat and mass transfer structures and enhance their adaptability in high-temperature and humid environments, a new internally cooled dehumidifier has been developed. This innovative dehumidifier incorporates corrugated fins to increase disturbance and contact area, along with a multichannel flat tube to improve cooling efficiency and compatibility. Experimental research was conducted to investigate mass transfer characteristics under different air, solution, and cooling water conditions in a high-temperature and humidy climate, and the Sh number correlation was derived. The findings indicated that compared to previous designs, the new dehumidifier's performance is less influenced by air temperature due to the corrugated fins' disturbance and cooling efficiency of the multi-channel flat tube. Additionally, its dehumidification capacity is positively correlated with air humidity, making it well-suited for high-temperature, high-humidity regions; The presence of corrugated fins enhances the disturbance on the solution surface, leading to a non-linear improvement in dehumidification performance when increasing solution flow; Lowering solution and water temperatures is more effective in improving dehumidification performance than increasing the flow rate, resulting in maximum increases of 60 % and 18.3 %, respectively, in mass transfer coefficients. Therefore, temperature adjustments are recommended for operational optimization; The Sh number correlation demonstrates high accuracy, within ±25 %, ensuring reliability. This study provides technical support and a foundational dataset for the dehumidifier's application in buildings located in high-temperature and high-humidity areas.

Investigating mass transfer around spatially-decoupled electrolytic bubbles

Electrolytic bubbles have a profound impact on mass transport in the vicinity of electrodes and greatly influence the electrolyzer efficiency and cell overpotential. However, experimental measurements of concentration fields around electrolytic bubbles with high spatio-temporal resolution is challenging. In this study, a succession of spatially-decoupled electrolytic bubbles growing in an initially quiescent electrolyte is simulated. The bubbles grow and depart from a hydrophobic cavity at the center of a ring microelectrode. The gas-liquid interface is modeled using a moving mesh topology. A geometric cutting protocol is developed to handle topology changes during bubble departure. The simulated bubbles show good agreement with the bubble growth dynamics observed in experiments. The bubbles in this spatially-decoupled system outgrow the region of electrolyte that is saturated with dissolved hydrogen. This leaves the apex of the bubble interface exposed to an undersaturated region of the electrolyte which leads to an outward flux of hydrogen gas. This is shown to limit the gas evolution efficiency of bubbles even though that they grow at a constant volumetric rate. By analyzing the distribution of the flux of dissolved hydrogen along the bubble interface along with the development of dissolve hydrogen concentration profiles around the bubble, we show that the magnitude of the outward diffusive flux at the apex of the bubble decreases with increasing electrolysis current.

Theoretical study on thermal efficiencies of Sutterby ternary-hybrid nanofluids with surface catalyzed reactions over a bidirectional expanding surface

The key focus of this study is to explore the flow and heat transfer characteristics of a blood-based composite nanoparticles consisting of the Al2O3, SiC, and MWCNT on a Sutterby fluid over a bidirectional porous stretching surface. These ternary-hybrid nanomaterials (Al2O3, SiC, and MWCNT) exhibits remarkable thermal conductivity attributes and enhances heat transfer in fluids. In the presence of modified heat flux model and surface-catalyzed reactions, the investigation of heat and mass transfer is carried out. Further, the impact of velocity partial slip and thermal convective conditions are taken into description at the surface of the bidirectional expanding surface. The developed flow model is converted into set of couple nonlinear ODEs with suitable transformation and use the bvp4c approach on MATLAB to get the numerical solution. The analysis considers for ternary-nanoparticles (Al2O3+SiC + MWCNT) and unary (Al2O3) nanoparticles, and provides comprehensive description among both for various emerging parameters. The graphical finding shows that in the presence of Darcy-Forchheimer, the reduction is occurred in the fluid velocity significantly for tri-hybrid and unary nanofluid, also same trend is seen for the slip parameter.

Investigation of mass transfer in valve-controlled gas–liquid segmented flow

Segment flow is widely employed in gas–liquid microreactor systems owing to its enhanced mass transfer through the biphasic interface. Previous studies evaluating an increased fluid flow rate (F) have reported an increased volumetric mass transfer coefficient (kLa) and reduced segment length (L). In a conventional microsystem, manipulating L without varying the residence time of the fluids is challenging. Hence, the relationship between kLa and L has not been systemically investigated under the same F. In this study, L control without changing F is implemented by introducing a high-speed valve into a gas–liquid microchannel system, and the influence of L on kLa is investigated by altering the valve frequency (f). The results indicate that kLa in the segmented flow is negatively correlated with L at constant F and reaches 0.149 s–1 (332.6 times larger than that in the bubble), whereas the specific area (a) of the segmented flow increases with increasing f before the liquid phase is saturated. Moreover, a and instinct kLa can be predicted using f, F, and the microchannel diameter. The outcomes of this research will improve the understanding of the mass transfer phenomenon in gas–liquid segmented flows and provide support for the design of microreactor systems.

Application of acoustic levitation for studying convective heat and mass transfer during droplet evaporation

The observation of acoustically levitated droplets offers great potential for studying their evaporation characteristics under well-defined ambient conditions. In contrast to alternatives such as sessile droplets or droplets suspended by a tiny fiber, the key advantage of acoustic levitation is the contact-free nature of the experimental method. However, acoustic streaming effects or droplet deformation by acoustic forces may affect the heat and mass transfer considerably. Consequently, the droplet evaporation process is usually dominated by these intrusive effects of the acoustic field. The main objective of this study is to present an experimental setup, which minimizes the disturbing effects of the levitation technique in order to enable a solid investigation of convective heat and mass transfer during droplet evaporation. To achieve this goal, a high resonance frequency of 100kHz is chosen and the investigation is limited to substantially smaller droplets compared to other studies in the literature. Moreover, an air flow is injected through a hole pattern in the reflector in order to control the relative velocity between the droplet and the gas phase. Particle Shadow Velocimetry is used to characterize the gas flow field in a stepwise approach, initially without any levitated droplet. Subsequently, the vortex structures around non-evaporating droplets are discussed. Eventually, evaporating water droplets are studied. The applied optical diagnostics offer the distinct advantage that the droplet size can be measured simultaneously with the surrounding gas flow field. Hence, the evaporation rate can be evaluated for different combinations of droplet size and relative velocity to the gas phase. For the entire range of resulting Reynolds numbers, the experimentally obtained evaporation rates were found to agree very well with results of a numerical evaporation model when a well-established correlation is used to account for convective heat and mass transfer.

Investigation of Heat and Mass Transfer in the Process of Convective Heat Treatment and Drying of Thermal Insulation Materials and Approximate Equation of the Drying Curve

The results of the study of heat treatment in the drying processes of thin thermal insulation materials based on the most general laws of convective drying of wet bodies with the establishment of the equation of the drying curve are presented. The numerical values of heat and mass transfer Biot numbers for the period of decreasing drying rate are established, too. Based on the study and analysis of numerous sources, the ranges of changes in the Lykov, Posnov, and phase transformation criteria for the processes of heat treatment of ceramics, asbestos, felt, and clay plates have been approximately determined. It is demonstrated that for values of Biot numbers less than one, for Lykov criteria value of 0.05–0.13 and for Posnov criteria value of 0.03–0.08 for drying modes with a temperature of 90–120 ° C, the task of drying, as a heat and mass transfer process, is external, and internal transfer does not affect the conditions of interaction of the material surface with the environment. It is also shown that the drying of thin materials takes place when the Biot number is less than one and, under the conditions of an external problem, the similarity criteria do not affect convective drying. The intensity of moisture evaporation from the body surface is determined by the value of the heat transfer coefficient in the Biot number and the regime parameters of the process. It has been established that the processes of drying materials are low-intensity processes. Based on the elements of the theory of thermal regular regime, the rate of heating of a wet body and the rate of decrease in moisture content are determined. The problem of constructing drying curves without conducting experiments to determine the duration of drying of thermal insulation materials based on approximate equations is considered; this problem is of interest for the practice of drying. The constructed drying curves do not coincide with the actual curve with an error of 4–5 %.

Significance role of dual porosity and interfacial nanolayer mechanisms on hybrid nanofluids flow: A symmetry flow model

The investigation of heat and mass transfer between two porous disks containing porous media is the focus of this paper. In this research, (Ag–Al2O3/water)-based hybrid nanofluid is used. Governing partial differential equations are converted to nonlinear ordinary differential equations by similarity transformations. Numerical solutions to nonlinear systems of equations are achieved using the shooting technique. It is examined how the particle’s diameter and nanolayer thickness affect the thermal conductivity of a hybrid nanofluid. Due to the increment of nanolayer thickness, the Nusselt number increases and vice versa for the radius of the particle. Tables and graphs show how the governing parameters influence velocity, temperature, and mass concentration profiles, as well as physical quantities such as skin friction coefficient and Nusselt number. As the values of the porous medium parameters ([Formula: see text]–13) and nanolayer thickness ([Formula: see text]–12) elevate, the flow of skin friction coefficient and Nusselt number escalate in both porous disks. Moreover, as the values of the particle radius ([Formula: see text]% to 12%) and Reynolds number ([Formula: see text]1 to 2) amplify, the flow of heat transfer rate is diminished in the lower disk. Porous materials have a high surface area, which increases the contact area between the nanofluids and the porous medium. Porous materials can enhance the permeability of the fluid, reducing the pressure drop in the system. This can be advantageous in applications where high flow rates and low-pressure drops are desired, such as in heat exchangers or cooling systems. Porous materials can provide trapping sites or adhesion points for the nanoparticles, enhancing their dispersion and stability within the hybrid nanofluids. The porosity of the flow medium can therefore influence the purification and filtration efficiency of the hybrid nanofluids, ensuring their cleanliness and functionality. Understanding and controlling the porosity can help optimize the flow characteristics of the nanofluids in various applications. Overall this field will focus on refining hybrid nanofluid compositions, improving modeling techniques, validating experimental findings, optimizing system designs, and exploring new applications.

English

English

Numerical investigation of heat and mass transfer of the Sisko fluid in a wire-coating process with variable fluid properties

The fundamental and essential objective of the wire coating process is to reduce the shear stress and extraction force exerted on the wire from the die in order to achieve practical benefits. Therefore, the purpose of the present work is to develop a mathematical model for the wire coating process withdrawal of the wire from the die. The Sisko fluid model and the temperature-dependent thermophysical properties are taken into consideration for modelling the constitutive equation. The basic equations governing the flow are solved with the aid of the numerical method. The impact of key factors is scrutinized. The influence of shear stress on the surface of the wire and fluid flow rate are delineated. The linear regression model is formulated to explore the significance of the relationship between the amount of force required to pull the wire and flow control variables. Moreover, the heat transfer rate and shear stress rate of molten polymer are modeled using quadratic correlation models obtained through the Central Composite Design (CCD) technique. To simultaneously achieve maximum heat transfer rate and minimum shear stress rate for the melt, the ideal values of the variable viscosity parameter, Sisko fluid parameter, and Brinkman number are determined. The study reveals that the required result occurs for a low level of the variable viscosity parameter, Sisko fluid parameter, and the Brinkman number. Additionally, a sensitivity analysis has been performed. The result reveals that the shear stress rate and heat transfer rate exhibit the highest sensitivity to variations in the viscosity parameter.

Numerical investigation of heat and mass transfer of variable viscosity Casson nanofluid flow through a microchannel filled with a porous medium

Thermal behaviours and hydrodynamics of non-Newtonian nanofluids flow through permeable microchannels have large scale utilizations in industries, engineering and bio-medicals. Therefore, this paper presents the numerical investigation of heat and mass transfer of variable viscosity Casson nanofluid flow through a porous medium microchannel with the Cattaneo-Christov heat flux theory. The highly nonlinear PDEs corresponding to the continuity, momentum, energy and concentration equations are formulated and solved numerically via the second order implicit finite difference scheme known as the Keller-Box method. Accordingly, the numerical simulations reveal that variable viscosity parameter, thermal Grashof number, solutal Grashof number, thermophoresis parameter, Schmidt number and Casson fluid parameter show increasing effects on both velocity and temperature of the nanofluid. Furthermore, the temperature profile escalates with increasing values of the Eckert number and the thermal relaxation time parameter. Thus, the Cattaneo-Christov heat flux model is beneficial in warming the transport system of microfluidics when compared to that of the classical Fourier heat conduction law. The temperature profile however, indicates a retarding behavior with increasing values of the Brownian motion parameter, Prandtl number and porous medium parameters namely Forchheimer number and porous medium shape parameter and hence, the porous medium quite effectively controls the nanofluid temperature distribution which plays substantial roles in cooling the transport system of microfluidics. Moreover, the concentration profile shows an increasing pattern with escalating values of the Prandtl number, Schmidt number and thermophoresis parameter but it demonstrates a decreasing trend with the Casson fluid, variable viscosity, thermal relaxation time and solutal relaxation time parameters. It is also observed that coefficient of the skin friction increases with increasing values of the pressure gradient parameter, Eckert number, Forchheimer number and injection/suction Reynolds number. Besides, the heat transfer rate at both walls of the microchannel enhances with rising values of the Eckert number, variable viscosity, parameter and injection/suction Reynolds number. The Casson fluid and thermal relaxation time parameters reveal opposite scenarios on the heat transfer rate at the left and right walls of the microchannel. In addition, the mass transfer rate at both walls of the microchannel shows an increasing pattern as the Eckert number, variable viscosity parameter, Schmidt number and suction/injection Reynolds number increase.

Investigating Mass Transfer Relationships in Stereolithography-Based 3D Printed Electrodes for Redox Flow Batteries

Redox flow batteries are a promising option for large-scale energy storage but remain too costly for widespread deployment. One approach to increase cost competitiveness is to improve the power density and efficiency of the electrochemical cell. Porous electrodes determine the performance of the cell, and their three-dimensional structure determines the electrolyte transport, fluid pressure drop, and the available surface area for electrochemical reactions [1]. Conventional porous electrodes are fibrous mats assembled in coherent structures [2]; however, they are repurposed from fuel cell gas diffusion electrodes and have not been tailored for redox flow batteries. Hence, an effective means to improve the performance of redox flow batteries is by engineering porous electrode structures to sustain the requirements of liquid-phase electrochemistry. To this purpose, there is a need to develop new manufacturing techniques affording a higher degree of control over the electrode microstructure and resulting properties. Additive manufacturing, or 3D printing, can be employed to manufacture customized, controlled, and deterministic architectures, enabling the fine-tuning of the electrical and hydraulic performance of porous electrodes [3].In this study, we manufacture model grid structures using stereolithography 3D printing followed by carbonization (Figure 1a) to tune the physiochemical properties of electrodes to be used in redox flow batteries. We employ a suite of microscopy, tomography, spectroscopy, fluid dynamics, and electrochemical diagnostics to understand the impact of the electrode structure on the mass transport and hydraulic performance of ordered lattice structures in flow cells. Here, the influence of the printing direction, pillar geometry (Figure 1b), and flow field type on mass transport is investigated using an organic electrolyte. We elucidate correlations between the electrode structure and performance metrics, namely surface area, pressure drop, and mass transfer correlations. We find that the printing orientation impacts the electrode performance through a change in electrode morphology caused by resin spreading and surface roughness, affecting the shrinking direction upon carbonization, internal surface area, and thus the charge transfer, mass transfer, and hydraulic resistances. Furthermore, we find that mass transfer rates within the electrode are enhanced by using an interdigitated flow field or by altering the pillar shape to a helical or triangular design, which we hypothesize improves mixing. Compared to commercial carbon-fiber electrodes, the pressure drop is significantly reduced (Figure 1c) as expected due to larger pore sizes (~500 μm for the grids vs. 2-100 μm for the Freudenberg H23 paper electrode and 2-300 μm for the ELAT Cloth electrode). Even though the commercial electrodes feature a superior internal surface area compared to the 3D printed electrodes, their area normalized mass transfer coefficients are lower (Figure 1d). Going forward, the use of printing technologies enabling finer features in combination with carbonization at elevated temperatures can be used to manufacture multiscale electrodes simultaneously providing low hydraulic resistance and excellent electrochemical performance. Additive manufacturing in combination with emerging computational approaches in topology optimization [4] might enable the bottom-up design and manufacturing of advanced electrode materials.

Investigation of Heat and Mass Transfer in the Process of Fuel Preparation from Biomass Particles with High Moisture

Currently, in a number of countries an urgent task for development of fuel and energy complexes is to increase the share of generation by involving solid fuels in circulation. Among such projects, those that allow the disposal of waste from various industries are particularly significant. Expired food products in this context are represented as a renewable local energy resource. However, such products require serious activities to prepare them for incineration or other type of high-temperature processing in order to obtain energy. The purpose of the present work is to improve methods of preparing fuel from recycled carrot fruits (unsuitable for use in the food sector). During the fuel preparation of carrots, the drying stage is limiting for the rational organization of its processing in boilers. In addition, the drying stage is extremely energy-consuming, so reliable prediction of its kinetics largely determines the efficiency of the entire technological process. In the course of the study, the following tasks were solved: a numerical method was developed for describing the processes of internal and external heat and mass transfer problems using an explicit difference approximation of differential equations of heat and mass transfer; parametric identification of the proposed one-dimensional mathematical model was performed using empirical dependencies known from literature sources; empirical verification of the proposed mathematical model was carried out by comparing the calculated forecasts obtained with the results of their own field experiments. The fact that the proposed mathematical model and the results of the full-scale experiment are independent, while the calculated forecasts and experimental data are in good agreement, makes us possible to consider the proposed calculation method as a reliable scientific basis for a computer method for calculating of heat and mass transfer processes when organizing the preparation of fuel from carrot fruits.

Investigating mass transfer coefficients in lean methane combustion reaction through the morphological and geometric analysis of structured open cell foam catalysts

In this work, we characterized ceramic open cell foams made of zirconia, silicon carbide and alumina of different nominal pore densities (30–45 ppi) using X-ray computed microtomography. This technique allowed the comprehensive and quantitative extraction of morphological and geometrical characteristics of the structures (pore size, strut diameter and length, node diameter, open porosity and specific geometrical surface area). An empirical model was proposed to determine the specific surface area from parameters easily accessible with standard laboratory equipment. Moreover, lean CH4 combustion tests were performed on ceramic foams coated with PdO/Co3O4 at 3 wt%. Mass transfer coefficients of the foams were measured by monitoring the oxidation reaction under diffusional control conditions. We derived a dimensionless correlation of the type Sh = A∙Rem∙Sc1/3. Finally, the pressure drop across the foams as a function of surface velocity was evaluated and compared with various experimental data and models available in the literature.

Investigating Mass Transfer Relationships in Stereolithography 3D Printed Electrodes for Redox Flow Batteries

AbstractPorous electrodes govern the electrochemical performance and pumping requirements in redox flow batteries, yet conventional carbon‐fiber‐based porous electrodes have not been tailored to sustain the requirements of liquid‐phase electrochemistry. 3D printing is an effective approach to manufacturing deterministic architectures, enabling the tuning of electrochemical performance and pressure drop. In this work, model grid structures are manufactured with stereolithography 3D printing followed by carbonization and tested as flow battery electrode materials. Microscopy, tomography, spectroscopy, fluid dynamics, and electrochemical diagnostics are employed to investigate the resulting electrode properties, mass transport, and pressure drop of ordered lattice structures. The influence of the printing direction, pillar geometry, and flow field type on the cell performance is investigated and mass transfer vs. electrode structure correlations are elucidated. It is found that the printing direction impacts the electrode performance through a change in morphology, resulting in enhanced performance for diagonally printed electrodes. Furthermore, mass transfer rates within the electrode are improved by helical or triangular pillar shapes or by using interdigitated flow field designs. This study shows the potential of stereolithography 3D printing to manufacture customized electrode scaffolds, which could enable multiscale structures with superior electrochemical performance and low pumping losses.

Understanding the Transition from High-Selective to High-Efficient Chiral Separations by Changing the Organic Modifier with Zwitterionic-Teicoplanin Chiral Stationary Phase.

The retention behavior of small molecules and N-protected amino acids on a zwitterionic teicoplanin chiral stationary phase (CSP), prepared on superficially porous particles (SPPs) of 2.0 μm particle diameter, has shown that efficiency and enantioselectivity, and so enantioresolution, dramatically change depending on the employed organic modifier. In particular, it was found that while methanol permits the boost of enantioselectivity and resolution of the amino acids, at the cost of efficiency, acetonitrile allows for the ability to reach extraordinary efficiency even at high flow rates (with reduced plate height <2 and up to 300,000 plates/m at the optimum flow rate). To understand these features, an approach based on the investigation of mass transfer through the CSP, the estimation of the binding constants of amino acids on the CSP, and the assessment of compositional properties of the interfacial region between bulk mobile phase and solid surface has been adopted.

Investigation of External Mass Transfer during Biodegradation of Congo Red Dye in a Recirculating Packed Bed Bioreactor

Investigation of External Mass Transfer during Biodegradation of Congo Red Dye in a Recirculating Packed Bed Bioreactor