Intermetallic Research Articles

Rapid fabrication and corrosion behavior of 3D-porous Cu-Al-Si compounds via low-energy self-exothermic reaction

In this study, porous Cu-Al-Si intermetallic compounds with three-dimensional structures were rapidly prepared by a novel self-exothermic reaction. By this method, Si was successfully solid-solved into CuAl intermetallic compounds and achieved better fusion with them. The effects of Si addition on their oxidation resistance and corrosion resistance were compared. The findings indicate that the minimum weight gain of the Cu-Al-Si product is only 1.48% after oxidation at 800 °C for 288h. Si facilitates the creation of a continuous Al2O3 protective layer on the surface of the porous Cu-Al-Si intermetallics skeleton, thereby preserving its internal structure while significantly enhancing its oxidation resistance. The incorporation of Si to Cu-Al intermetallics enhances the stability of the passivation film on the material's surface, increases the resistance of the passivation film, and effectively restricts the electrochemical reaction between the material and the corrosive medium.

Cauliflower-like Pd/MoC||Mo2C/C heterostructure as an efficient trifunctional catalyst for formic acid oxidation, hydrogen evolution, and oxygen reduction reactions

The use of Pd-based catalytic materials as electrocatalysts for formic acid oxidation reaction (FAO), hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR) has been well-established for some time. The incorporation of a second phase can markedly enhance the electronic properties of the composites. The combination of different compounds with superior electronic properties is crucial for the design and preparation of catalysts with optimal catalytic activity and stability. In this study, a novel cauliflower-like Pd/MoC||Mo2C/C composite with heterostructure is synthesised, which exhibits excellent catalytic activity and long-term stability against FAO, HER, and ORR. The high-temperature treatment results in the formation of small-sized Mo₂C and MoC nanoparticles on the carbonaceous substrate, thereby exposing a greater number of Mo and Mo-C active sites. The formation of heterostructures between Mo₂C and MoC optimises the electronic structure of the composite, thereby facilitating enhanced reaction processes. In terms of FAO, the mass activity of Pd/MoC||Mo2C/C is 1.87A mgPd-1, which is 2.75 times higher than that of Pd/C (0.68A mgPd-1). As for the HER, a much lower overpotential of 28mV is required to achieve a current density of 10mAcm-2 compared to Pd/C (40mV). Fortunately, Pd/MoC||Mo2C/C also shows excellent ORR activity with a half-wave potential of 0.798V and the maximum current density of approximately 5.73mAcm-2 in alkaline electrolyte. These findings may contribute to the development of other noble metal-based materials loaded on intermetallic compounds with stable and effective electrocatalytic performance.

Ab initio molecular dynamics simulations on the combustion mechanism of Al/Fe2O3 nanothermite at various temperatures

Acquiring a comprehensive understanding of the combustion mechanism of nanothermites is crucial for elucidating phenomena and enhancing performance. The ab initio molecular dynamics method was employed to investigate the reaction process of the Al/Fe2O3 nanothermite at various temperatures. The complex combustion behavior and reaction mechanism were qualitatively described in terms of dynamic morphologies, potential energy, atomic density distribution, etc. Results suggest the initial reaction of Al/Fe2O3 is initiated by the migration of interfacial O atoms and the dissociation of Fe-O bonds, subsequently leading to the formation of alumina at the interface, which impedes the further progression of the thermite reaction. The increase in temperature enhances atomic diffusion and provides sufficient energy for the reaction. The interfacial metal Al layer undergoes melting and diffuses into the iron oxide layer, while vacancies generated during the reaction process sustain the continuous migration of internal oxygen atoms. At 2000 K and 3200 K, the initial structures completely collapse, facilitating the inward propagation of the thermite reaction, which subsequently results in the formation of alumina, iron clusters, and intermetallic compounds (AlFe, AlFe3, and Al6Fe). These findings offer significant insights into the combustion reaction mechanisms of nanothermites.

Laser microwelding of NiTi/PtIr alloys with laser beam offset

The NiTi and PtIr alloy joint has been employed in biomedical devices to combine the superelasticity of NiTi alloy with the X-ray visibility of PtIr alloy. Laser microwelding is usually used for the joints, but there is a risk of forming brittle intermetallic compounds (e.g., Ni3Ti, Ti2Ni, and Ti3Pt) in the fusion zone (FZ), which could deteriorate joint strength. In this study, laser beam offset (laser offset) was implemented for a butt joint of Ni-49.8 at.% Ti and Pt-10.0 at.% Ir alloy wires to control the intermetallic compound formation in the FZ. Welding with 300 μm laser offset on the NiTi side achieved 2.3 times higher joint breaking stress and 13.0 times higher joint breaking strain than welding without laser offset. The joint breaking stress and strain were enhanced from 221 MPa and 0.9% to 502 MPa and 11.7% by 300 μm laser offset on the NiTi side, respectively. In the absence of laser offset, the dissolution of Pt and Ir into the FZ facilitated the M3Ti (M = Ni, Pt, Ir) formation in the FZ, resulting in crack propagation within the M3Ti. In contrast, the 300 μm offset on the NiTi side inhibited the M3Ti formation by mitigating Pt and Ir dissolution into the FZ. Laser offset on the NiTi side can be an attractive option to enhance the strength and ductility of NiTi and PtIr butt joints.

Microstructure and mechanical properties of CP780 steel - 7075 aluminum alloy laser welded joint assisted by rotating magnetic field

Abstract This study uses a rotating magnetic field for laser welding on 1 mm thick CP780 high-strength steel and 1.5 mm thick 7075 aluminum alloy. The effects of different welding parameters (B = 0 mT, B = 65 mT with V = 0°/s, B = 65 mT with V = 10°/s) on the morphology, microstructure, and tensile properties of welded joints are analyzed. At B = 0 mT, the weld shape is V-shaped, with the intermetallic compounds primarily consisting of needle-like brittle Al-rich (Fe, Si)Al2 phase and fewer granular ductile Fe-rich (Fe, Si)Al phase, resulting in poor mechanical properties. With the application of the rotating magnetic field, the laser energy becomes more concentrated, forming a ‘T’ shape weld. The rotating magnetic field (B = 65 mT with V = 10°/s) generates a constantly changing Lorentz force, promoting molten pool flow and enhancing Fe diffusion within the weld. This process reduces needle-like brittle Al-rich (Fe, Si)Al2 phase and increases granular ductile Fe-rich (Fe, Si)Al phase. It also accelerates the weld cooling rate and inhibits the reaction time and grain growth of intermetallic compounds, thereby reducing the thickness and content of the intermediate transition layer and significantly improving mechanical properties. A comprehensive comparison shows that the best mechanical properties are achieved at B = 65 mT with V = 10°/s. This study offers new insights and a theoretical foundation for achieving cost-effective, high-performance welded joints in advanced high-strength steel and high-strength aluminum alloy for automobiles, thereby facilitating lightweight vehicle development.

КИНЕТИКА РОСТА ДИФФУЗИОННЫХ ПРОСЛОЕК В СКМ 20880+АД1+ВТ1-0

It is shown that the diffusion zone at the interlayer boundary of steel 20880 + aluminum AD1 consists of two layers: the Fe2Al5 intermetallic compound located on the steel side and constituting the main part of the diffusion zone, and a thin (up to 10 μm) layer of the FeAl3 intermetallic compound on the aluminum side. Microhardness of the diffusion zone ~ 12 GPa. It has been established that the intensity of growth of the diffusion zone at the interlayer boundary of aluminum AD1 + titanium VT1-0 with the phase composition TiAl3 is almost one and a half times lower than at the interlayer boundary of steel 20880 + aluminum AD1. Its microhardness is ~5 GPa.

Optimization of Joining Parameters in Pulsed Tungsten Inert Gas Weld Brazing of Aluminum and Stainless Steel Based on Response Surface Methodology

Combining aluminum and steel offers a promising solution for reducing structural weight and fuel consumption across various industries. Pulse in tungsten inert gas (TIG) weld brazing effectively suppresses interfacial brittle intermetallics and enhances joint strength by influencing pool stirring and heat input during aluminum-to-steel joining. However, optimizing the pulsed TIG weld brazing process is challenging due to its numerous welding parameters. This study established statistical models for Al/steel joint strength without reinforcement using response surface methodology (RSM) based on central composite design (CCD). The models’ adequacy and significance were verified through analysis of variance (ANOVA). The four welding parameters influence weld strength in the following descending order: pulse on time > base current > pulse current > pulse frequency. Additionally, interactions between pulse current and pulse frequency, and between pulse on time and base current, were observed. Numerical optimization using RSM determined the optimal pulsed GTA weld brazing parameters for aluminum and stainless steel. With these optimized parameters, the joint strength reached 155.73 MPa, and the intermetallic compound (IMC) thickness was reduced to 3.4 μm.

Graphene‐Transition Metal Electrocatalysts for Sustainable Water Electrolysis

AbstractTransition metal compounds (TMCs) are potentially fruitful substitutes for noble metals for electrocatalytic splitting of water due to their intrinsic electrocatalytic activity, modifiable morphology, tunable electronic structure and their earth‐abundance. The combination of TMCs with graphene improves the dispersion of loaded catalysts, providing more catalytic active sites, enhancing the conductivity of hybrids, affording accelerated charge‐transfer kinetics, and minimizing catalyst bleaching, aggregation, and sintering under harsh reaction conditions. Additionally, graphene incorporation into TMCs modulates the electronic structure of active centers because of the synergistic interaction between them, thereby improving their catalytic performance. This review paper focuses on the recent progress made in designing different graphene‐transition metal‐based materials that can be used in the hydrogen evolution reaction (HER), the oxygen evolution reaction (OER), and overall water splitting (OWS). In‐situ characterization methodologies and DFT calculations that facilitate catalyst development are discussed elaborately. Finally, the advancements made in the development of graphene‐supported transition metal compounds for use in a functional water electrolyzer have been explored. In conclusion, a few specific recommendations have been made about the current challenges related to the widespread production of effective HER/OER electrocatalysts for water electrolysis.

Progress in direct recycling of spent lithium nickel manganese cobalt oxide (NMC) cathodes

With the widespread use of lithium-ion batteries (LIBs) in portable electronics and electric vehicles (EVs), the end-of-life (EOL) LIBs are projected to reach 1336 GWh by 2040 under the sustainable development scenario. Proper recycling is urgently needed to minimize the release of hazardous waste and reduce mining activities by reintroducing critical minerals into the supply chain. Lithium nickel manganese cobalt oxide (LiNixMnyCozO2, NMCs) cathodes have become dominant in the LIB market, especially with the increasing production of EVs, which are also the most valuable components in EOL LIBs. Unlike pyrometallurgical and/or hydrometallurgical methods, which convert spent NMCs into metals or metal compounds, direct recycling technologies aim to maximize the value of spent cathodes by restoring their degraded structure and composition. This review summarizes direct recycling methods for NMC cathodes published in the last decade and provides insights into the challenges and future development of direct recycling techniques.

Evolution of ferromagnetism and electrical resistivity in Sb-doped Cr4PtGa17

We describe the doping effects on a metallic breathing pyrochlore compound, Cr4PtGa17. Upon doping with Sb, i.e., Cr4Pt(Ga1-xSbx)17, it was found that a selective doping on one of the seven Ga sites occurs. With increasing dopant level, the ferromagnetism in the parent compound is gradually suppressed, along with a decrease in fitted Curie-Weiss temperature (from 61 (1) K to −1.8 (1) K) and effective moment (from ∼2.26 μB/f.u. to ∼0.68 μB/f.u.). Low-temperature heat capacity measurements confirm the absence of magnetic ordering above 0.4 K for the three most doped samples. Meanwhile, electrical resistivity measurements display a metal-semiconductor transition with increasing Sb contents, which is attributed to an increase of Fermi energy based on the calculations of electronic band structure and density of states. Moreover, we have speculated that the ferromagnetism in Cr4PtGa17 is governed by itinerant electrons according to our observations. This study of Sb-doping effect on Cr4PtGa17 provides deeper understanding of magnetism of this system and possibilities for future modifications.

Refinement of eutectic structure and precipitates of Cu–20Ag alloy due to Y microalloying

Copper-silver alloy rod with high mechanical properties and stable conductivity are the key materials for the preparation of microfilaments used in endoscopy and other medical fields. In this paper, the microstructure of Cu–20Ag rod was regulated by adding trace rare earth Y in order to improve the comprehensive performance of copper-silver alloy further. and studies the distribution and existence of rare earth Y as well as the influence on the performance of copper-silver alloy rod billet. The results of research show that: rare earth Y mainly exists in the branching nodes of the eutectic organization, so that the alloy in the solidification of constitutional supercooling increases, thus refining the eutectic structure, and make it uniformly distributed. After addition of 0.01 wt%Y, Cu4Y was precipitated in the eutectic structure of the rod. After adding 0.03 wt%Y, the precipitates types increased to trace intermetallic compound AgY and nanoparticles Cu4Y. The increase of the interface between eutectic structure and Cu matrix decreases the electron scattering probability. This is the main factor to lead to the decrease of electrical conductivity. The precipitation hardening of precipitated phase and the increase of interface between eutectic structure and Cu matrix are the main factors for the increase of tensile strength of bar billet. The main factor of the decrease in the conductivity of rod billet is the increase of Ag phase dissolved in eutectic structure and the interface between eutectic structure and Cu matrix.

Investigation of corrosion resistance offered by the Fe-based clad layer under salt spray and electrochemical workstations

The present work aims to evaluate the electrochemical characteristics of the Fe–based alloy coating formed on the 27SiMn steel substrate under neutral salt spray and 3.5 wt% NaCl environments. By adopting the high-speed laser cladding technique, the Fe-based clad layer was fabricated to perform microstructural and electrochemical characterizations. The microstructure and phase of the coating were analyzed using a scanning electron microscope (SEM), electron backscatter diffraction (EBSD) and X-ray diffraction (XRD), and its corrosion performance was also discussed using the salt spray corrosion chamber and the electrochemical workstation. The results show that the microstructure of the coating surface contains equiaxed crystals and long dendritic crystals which arise due to the higher solidification rate after the cladding process. The Fe–based coating was rich in FeCr phase throughout its microstructure without the formation of the intermetallic compounds. Compared to the substrate, the corroded surface of the coating tends to be compact containing a few corrosion pits after different corrosion times, which is attributed to the formation of Cr oxide on it. The electrochemical tests on the potentiodynamic polarization curve (PPC) and electrochemical impedance spectrum (EIS) indicate that the corrosion resistance of the coating is superior to the substrate, presenting a higher corrosion potential (−0.298 V), lower passive current density (1.36 × 10−6 A•cm2), and higher charge transfer resistance (8.23 × 106 Ω·cm2). Additionally, the corrosion mechanism of coating in salt spray and electrochemical tests is the local pitting corrosion due to the autocatalytic effect on the localized region, which facilitates Cl− ions penetrating the coating and leads to the dissolution of Fe and Cr oxides.

Effective reduction of iron impurities in recycled aluminium-silicon alloy type LM-6 through sedimentation and filtration with synthesized Mn, Cr and Zr transition metal powders

Abstract In secondary aluminium recycling, impurity reduction, especially of iron, is a significant challenge as it deteriorates the material quality in the aluminium melt. Recycled aluminium alloys are widely used in various industries, including automotive, marine, and structural engineering. Specifically, LM-6 aluminium alloy is commonly used in automotive engine parts and transmission cases. This research focused on reducing the excessive iron content in LM-6 alloy scrap. Elements like manganese (Mn), chromium (Cr) and zirconium (Zr) were added to the melt in form of synthesized powders to form intermetallic compounds. These powders will also act as grain refiners, neutralizers and reducing the detrimental effects on the alloys. The powders were synthesized using the ball milling method with a ball to powder ratio of (5:1) to enhance mixing and amalgamation with the melt. The melt was held at an optimized temperature of 640 ± 10 °C to promote the formation of intermetallic sludge, encouraging the sedimentation of aluminium-iron (Al-Fe) intermetallic phases. XRD confirmed the formation of AlMn, AlCr, AlZr with other phases. After sedimentation, a glass fabric mesh with a pore size of 200 μm was used to effectively filter out β-iron during the filtration process. This technique reduced iron impurity in the melt by 50%–60%. As a result, the mechanical properties of the recycled aluminium improved significantly: hardness increased by 14%, and tensile strength increased by 36%. The wear and corrosion resistance of the material also improved due to the incorporation of the synthesized powders. SEM analysis revealed the plate-like formation of iron structures and confirmed the presence of the manganese, chromium, and zirconium powders in the metallographic analysis.

Advanced multi-component FeCoCuAlMo intermetallic electrocatalysts for efficient and sustainable hydrogen evolution in alkaline freshwater and seawater

Electrolyzing seawater to produce hydrogen is a promising sustainable energy production technology. The current non-precious metal-based hydrogen evolution reaction (HER) electrocatalysts demonstrate inadequate catalytic activity and poor stability in seawater electrolyte. Therefore, developing stable and efficient non-precious metal-based HER electrocatalysts is a major challenge for achieving sustainable green energy development. This work reports a multi-component intermetallic catalyst FeCoCuAlMo prepared by arc melting and chemical dealloying methods. The electrocatalytic hydrogen evolution performance of catalysts with varying atomic ratios (FeCoCu)20(Al70Mo30)80, (FeCoCu)30(Al70Mo30)70, (FeCoCu)40(Al70Mo30)60, and (FeCoCu)50(Al70Mo30)50 in alkaline seawater and alkaline electrolyte was studied. The findings indicate that these catalysts primarily consist of AlMo3 and (Cu0.35Fe0.35Co0.3)Al, among which the dealloyed (FeCoCu)30(Al70Mo30)70 exhibits excellent catalytic activity with overpotentials of 137.54 and 116.91 mV at a current density of 100 mA/cm2 in alkaline seawater and alkaline electrolyte, respectively, outperforming most catalysts. Additionally, it demonstrated long-term stability in alkaline seawater and alkaline electrolyte for 250 and 400 h without significant decay at overpotentials of 236 mV and 276 mV, respectively. This improved performance can be attributed to the unique structure of the multi-component intermetallic compound, which provides good thermodynamic stability and synergistic effects among its constituents, thereby enhancing HER performance. Within this multi-component intermetallic compound, AlMo3 particles serve as the primary conductive medium to accelerate electron transfer, while (Cu0.35Fe0.35Co0.3)Al serves as the main active site, resulting in a stable structure that provides the catalyst with high catalytic activity and good stability. Thus, the (FeCoCu)30(Al70Mo30)70 electrocatalyst is a promising candidate for seawater electrolysis aimed at hydrogen production.

Cu-Al-Ni Nanocrystalline Compacts Obtained by Spark Plasma Sintering of Mechanically Alloyed Powders.

The aim of this work is to obtain Cu-13.5Al-4Ni alloy for use as shape memory alloy by Spark Plasma Sintering (SPS) of mechanically alloyed powder. The study investigates the structural and microstructural changes in terms of crystal parameters, crystallite sizes, and phases evolution during mechanical alloying and spark plasma sintering of Cu-13.5Al-4Ni powders. We obtained alloyed powders with a structure composed of α(Cu), AlNi intermetallic compound and small amounts of elemental Al through the mechanical alloying technique. After spark plasma sintering at 900 °C, the microstructure consists of an AlNi compound distributed at the edge of α(Cu) grains. The crystallite sizes of both, α(Cu) and AlNi are in nanoscale order after 16 h of milling (9 and 6.5 nm respectively). After sintering at 900 °C (in Ar atmosphere, without holding time), the crystallite sizes increase to 46 nm for α(Cu) and to 40 nm for AlNi compound. Also, the Cu-13.5Al-4Ni compacts achieve a final density after sintering at 900 °C of around 80% from the theoretical density.

Microstructural evaluation and optimization of wear behaviour of vacuum arc melted AlFeCrNiSi high entropy alloy

High-entropy alloys (HEA) are equiatomic, multi-element systems that, while having several elements with various crystal geometries to form a single phase. In this study, a novel equiatomic AlFeCrNiSi HEA is prepared using the vacuum arc melting process. The resulting microstructure featured dendritic and inter-dendritic structures with formations of intermetallic compounds such as Al₃Fe₂Si, NiAl, and AlCrNi phases. EDS analysis confirmed the presence of alloying elements and EBSD analysis revealed refined grains with an average size of 1 ± 0.15 µm size. Pin-on-Disc wear test with varying test parameters is conducted to optimize the wear parameters. Signal-to-noise ratio and analysis of variance identified the most significant wear parameters, with load being the most influential, followed by sliding distance and velocity. The wear rate is minimum at the lowest conditions of applied load, sliding distance, and sliding velocity. The improved microhardness also contributed to the improved wear resistance of the cast alloy. The subsequent worn morphology revealed the formation of grooves, microcracks, and oxide layers on the worn surface.

Development and characterization of carbon fiber reinforcement in Aluminium metal matrix composites

Abstract Carbon fibers (CF) possess exceptional mechanical properties and the highest degree of chemical stability. However, carbon reinforcement in metal matrix composites is extremely scarce due to production difficulties, particularly in obtaining a uniform distribution. Carbon fiber reinforced composites are typically made using high temperature processing processes. However, the fibers must be coated with Ni or Cu in order to achieve effective particle dispersion; otherwise, there is a larger likelihood of intermetallic compound formation, which reduces the chances for enhanced properties. In this work, the metallurgical, mechanical, and tribological characteristics of the carbon fiber reinforcement in AA 7050 are examined. Uncoated carbon fibers are reinforced into the Aluminium matrix using a low temperature processing technique known as powder metallurgy. The AA 7050 matrix reinforced with carbon fibers at various weight percentages between 0 and 1.5. The samples undergone mechanical and metallurgical testing in accordance with ASTM guidelines. The findings indicate that the 0.25 weight percent carbon fiber reinforcement in the matrix increased the material’s hardness by 30% over the monolithic alloy, making it an excellent alternative for structural applications.

Synthesis mechanism and interface contribution towards the strengthening effect of in-situ Ti5Si3 reinforced Al matrix composites

As a titanium-silicon intermetallic compound, Ti5Si3 can offer great potentials as a reinforcement agent in metal matrix composites due to its exceptional mechanical and physical properties. In this study, Ti5Si3 particles are successfully in-situ synthesized in Al-Si-Ti system through the interdiffusion reaction between Ti-Si using a powder metallurgy approach. The composites interface structure is transformed from Al/Ti5Si3 non-coherent interface to Al/TiSi/Ti5Si3 coherent/semi-coherent interface with the formation of TiSi transition layer. It enhances the interface bonding between Ti5Si3 particles and Al matrix, mitigates the mechanical differences between the matrix and the reinforcements, thereby enhancing the coordinated deformation ability. Simultaneously, the generated gradient interface between Ti@Ti5Si3 core-shell structure particles and Al matrix suppresses the rapid propagation of cracks in brittle reinforcement. As a result, the mechanical performance of AMCs is improved to 96.1 GPa for elastic modulus and 327 MPa for strength while maintaining a fracture elongation of 6.5%, which shows significantly enhancement compared with Al-5Si and Al-2.37Ti matrix. These findings establish a robust microstructural foundation for fully harnessing the strengthening effects of the reinforcements and provide a feasible technical route of utilizing the in-situ synthesized reinforcing particles for improving the mechanical performance of Al matrix composites.

A facile synthesis of N-doped carbon encapsulated multimetallic carbonitride as a robust electrocatalyst for oxygen evolution reaction

Electrocatalytic water splitting is a promising solution for generating clean hydrogen. Transition metal compounds are among the most extensively investigated catalysts developed to date for water oxidation in alkaline media, a process also known as the oxygen evolution reaction (OER). However, the application of these catalysts was constrained by insufficient stability arising from surface oxidation and metal dissolution under high OER potential. In this work, we developed a facile approach using urea-based gel as the precursor of preparing a series of multimetallic carbonitride particles which were encapsulated by N-doped carbon (NC). In particular, (MoCoFeNiZr)CN@NC core–shell structure delivered a low overpotential of 246 mV at a current density of 10 mA cm−2 in 1 M KOH during OER. Importantly, operando differential electrochemical mass spectrometry (DEMS), together with multiple microscopic and spectroscopic analyses, indicated that the NC shells effectively maintained the crystalline stability of carbonitride via suppressing the surface reconstruction during catalysis. The highly graphitic NC also demonstrates excellent stability against oxidation. This work shows a promising strategy of stabilizing electrocatalyst at high anodic potential, paving the way for the development of robust electrode materials for energy conversion.

Lead (Pb) removal from gold mining-impacted water utilizing palm oil fuel ash (POFA)

Mining, particularly gold mining, is a lucrative industry. However, it poses significant environmental risks, such as releasing heavy metal elements into the soil and water. After gold mines are exhausted, whether they are small or large scale, the excavated sites often need to be repaired. This situation has led to a global concern regarding the presence of heavy metals from mining activities, which are known to be carcinogenic and harmful to living organisms. The concentration of heavy metals in these areas often surpasses safety limits, necessitating advanced treatment methods for their removal, especially lead (Pb) compounds from gold mining waste. One effective treatment method is the adsorption process. This study examined POFA's inherent capacity to remove lead from water contaminated by gold mining without modification. This method was preferred due to its high efficiency and cost-effective option for removing heavy metal compounds. According to the experiment's results, the largest adsorption capacity of 0.816 mg/g was followed by the greatest removal efficiency of 91.837%. The isotherm analysis found that the Langmuir model provided an outstanding fit for the experimental data. Thus, this relationship suggested that on the surface of the POFA, a monolayer and an adsorption process suitable for physical adsorption took place.