Intermediate Composition Research Articles

Review of bomb and ash flows: Genesis and case studies of a subset of block and ash flow deposits

Pyroclastic density currents with an abundance of cauliflower-shaped bombs are an uncommon type of deposit, called bomb and ash flow (BoAF) deposits in several papers. Although they are similar to block and ash flow (BAF) deposits (e.g., rich in juvenile blocks and breadcrusted bombs), they are often related to eruptions of mafic to intermediate magmas. In the current study, we analyze and compare historical and prehistorical BoAF-generating eruptions at Asama and Aso (Japan), Mayon (Philippines), Mt. Spurr (United States), Fuego (Guatemala), Arenal (Costa Rica), Cotopaxi and Tungurahua (Ecuador), and Láscar and Tilocálar volcanoes (Chile). Our review indicates that BoAFs show a substantial contribution of juvenile rounded material but with different rheologies and fragmentation mechanisms. This juvenile material is typically basaltic or andesitic, as it is more susceptible to form volcanic bombs with scoriaceous cauliflower textures. Thus, BoAFs could be a subset of the BAF deposits. The study and recognition of this type of deposit in volcanic sequences could be misinterpreted as a ballistic bomb deposit or even a hot bomb-rich lahar deposit, therefore, its appropriate interpretation is fundamental for volcanic hazard assessment.

The REE-Zr-U-Th Minerals of the Maronia Monzodiorite, N. Greece: Implications on the Saturation and Segregation Mechanisms of Critical Metals in Intermediate–Mafic Compositions

This work delves into the presence of REE-Ti-Zr-U-Th minerals, in the mafic–intermediate rocks of the Maronia pluton, Greece, an Oligocene intrusion formed through arc-magmatism during subduction. In Maronia monzodiorite, critical metals are contained in three principal mineral groups, namely, the REE-Ti-Zr, REE-Ca-P, and U-Th assemblages. The REE-Ti-Zr group includes REE-ilmenite, chevkinite-like phases, zirconolite, and baddeleyite. The REE-Ca-P assemblage is represented by allanite-(Ce), monazite-(Ce), and huttonitic monazite-(Ce). The U-Th assemblage comprises thorite–coffinite and uraninite–thorianite solid solutions. The paragenetic sequencing of these minerals offers insights into their formation conditions and correlation with the pluton’s magmatic evolution. In the REE-Ti-Zr group, mineral formation progresses from REE-ilmenite to baddeleyite through chevkinite-like phases and zirconolite under oxidizing conditions. The REE-Ca-P sequence involves allanite-(Ce), followed by monazite-(Ce), late allanite-(Ce), and huttonitic monazite-(Ce). In the U-Th group, earlier thorite–coffinite phases are succeeded by uraninite–thorianite solid solutions, indicating Si-undersaturation at late magmatic stages. Fluctuations in Ca-activity induce alternating formations of allanite-(Ce) and monazite-(Ce). These mineral variations are attributed to early-stage interactions between high-K calc-alkaline and shoshonitic gabbroic melts, influencing critical metal enrichment and mineral speciation. The study’s insights into paragenesis and geological processes offer implications for mineral exploration in analogous geological settings.

Prediction of cosolvent effect on solvation free energies and analysis of intermolecular forces of tizanidine hydrochloride in ethyl acetate + methanol / ethanol mixtures

The solubility of small molecule drug in solvents can be dramatically affected by addition of a suitable cosolvent, which makes the screening of the best-suited cosolvent an important task for the purification and preparation. The present work aims to improve the fundamental understanding of tizanidine hydrochloride (TIZ HC) solvation by cosolvent. Solubility experimental data from TIZ HCl in mixtures of ethyl acetate + alcohols were obtained at different temperatures with the method of isothermal equilibrium. In the system of ethyl acetate + methanol, the solubility data increased firstly and then decreased with an increase in ethyl acetate content, however, the strictly monotonic decreasing of solubility in ethyl acetate + ethanol mixtures was observed. The solubility correlation fitting was performed with the Jouyban-Acree model and CNIBS/R-K model. The solvent effect analysis indicates that the hydrogen bond acidity, the polarity / polarizability and the cohesive forces of the solvent have a greater influence on the solubility, which was further validated by the local quantitative molecular surface analysis results of electrostatic potential (ESP). The dissolution process of TIZ HCl in systems with different solvent compositions was analyzed in the form of preferential solvation parameters, it was found that methanol is the preferred solvent in the solvation shell of TIZ HCl in methanol-rich and ethyl acetate-rich mixtures but the ethanol is preferred in intermediate compositions and ethyl acetate-rich mixtures. Moreover, the types of intermolecular solute–solvent interactions were discussed on the basis of the structural characteristics of TIZ HCl. The solvation free energy is a key parameter describing solvent effects, which is extremely important for understanding solution chemistry. For this part, with the aid of density functional theory (DFT) and molecular dynamics (MD) simulations, it was found that the cosolvent effect is consistent with the prediction trend of solvation free energy of TIZ HCl in each systems. The effect of the cavity formed by the solvent molecules and dipole moment of solute was calculated accordingly by the solvation model based on density (SMD) for explaining the former behavior.

Formation of lower arc crust by magmatic underplating revealed by high-precision geochronology

Abstract In modern plate tectonic regimes, continental crust is generated above subduction zones in magmatic island arcs. Models for continental growth—largely based on the modeling of geochemical processes that can transform mantle melts into the intermediate composition of bulk continental crust—have been hampered by a lack of definitive geochronology, which could clarify the temporal emplacement of igneous rocks at the base of island arc crust. The Kohistan Arc Complex (KAC) of Pakistan is a rare window into a nearly complete section of lower arc crust, revealing a sequence of igneous rocks representing discrete batches of magma underplated along the base of the arc crust. We present high-precision isotope dilution–thermal ionization mass spectrometry U-Pb geochronological data from zircon, and Lu-Hf and Sm-Nd isochron data from several mafic lower crustal cumulates within the KAC. These data establish a clear downward-younging age trend throughout this succession of cumulate complexes, demonstrating a total magmatic duration of ~20 m.y., corresponding to a rate of lower crust formation of up to 200–260 km3 km–1 Ma–1. These results provide the first direct evidence of a sequential process of underplating, revealing a fundamental mechanism responsible for building the root of island arc crust.

Post-collisional ultrapotassic volcanic rocks and ultramafic xenoliths in the Eslamieh Peninsula, NW Iran: Petrological and geochemical constraints on mantle source and metasomatism

The Eslamieh Peninsula in NW Iran exposes Miocene potassic to ultrapotassic volcanic rocks that are often associated with a variety of ultramafic xenoliths. Based on geochemical features, the rocks investigated in this study can be subdivided into two main groups: 1) MgO-rich (8.0–13.9 wt%) basic (SiO2 = 46.1–50.9 wt%) rocks, which comprise mafic lamprophyres and pyroxenite xenoliths, and 2) MgO-poor (1.5–6.4 wt%) basic to intermediate (SiO2 = 48.2–61.2 wt%) rocks, mainly consisting of trachytes, felsic lamprophyres, and analcime-bearing tephriphonolites and phonotephrites. Rocks in both groups have variable but generally low Ni (10–115 ppm; mostly <60 ppm) and Cr (6–628 ppm; mostly <200 ppm), and display enrichment in LREE over HREE (e.g., La/Yb = 17–55), with a large overlap between the MgO-rich and MgO-poor types. These features are coupled with enriched LILE/HFSE ratios (e.g., Ba/Nb mostly 16–116), negative Nb-Ta-Ti anomalies and positive Pb peaks in primitive mantle-normalised diagrams (e.g., Nb/Nb* mostly <0.7). Both high-and poor-MgO samples have strongly radiogenic (87Sr/86Sr)i ratios (0.7078–0.7086), (143Nd/144Nd)i below the Chondritic Uniform Reservoir (CHUR) = 0.51235–0.51244, and ɛHfi ranging from −3.1 to −11.1‰, suggesting involvement of a lower continental crust component in their genesis. The major oxide and trace element contents the high-MgO and high-CaO rocks indicate derivation from a subcontinental lithospheric mantle source, variably metasomatised by fluids and melts released by a subducted slab in a mantle wedge. Primitive melts evolved via mafic mineral fractionation and possible assimilation of lower crust, generating the SiO2 higher and CaO-MgO-poorer group. We suggest that small degree partial melting of the enriched mantle sources could have been triggered by Neo-Tethys slab roll-back during the Arabian-Iranian collision.

Tracing titanomagnetite alteration with magnetic measurements at cryogenic temperatures

SUMMARY Titanomagnetite containing up to 0.6–0.7 Ti atoms per formula unit is a primary magnetic mineral phase in submarine basalts and in some terrestrial volcanic rocks. On a geological timescale, it often undergoes alteration, forming new magnetic phases that may acquire (thermo)chemical remanent magnetization. The initial stage of this natural process can be modelled by prolonged laboratory annealing at moderately elevated temperatures. In this study, our goal is to characterize the alteration products resulting from annealing a submarine basalt containing homogeneous titanomagnetite Fe3−xTixO4 (x ≈ 0.46) at temperatures of 355, 500 and 550 °C for up to 375 hr, by examining their magnetic properties over a wide range of temperatures. The effect of extended annealing is most apparent in the low-temperature magnetic properties. In the fresh sample, a magnetic transition is observed at 58 K. Below the transition temperature, the field-cooled (FC) and zero-field-cooled (ZFC) saturation isothermal remanent magnetization (SIRM) curves are separated by a tell-tale triangular-shaped area, characteristic for titanomagnetites of intermediate composition. The room-temperature SIRM (RT-SIRM) cycle to 1.8 K in zero field has a characteristic concave-up shape and is nearly reversible. For the annealed samples, the magnetic transition temperature shifts to lower temperatures, and the shape of the curves above the transition changes from concave-up to concave-down. The shape of the RT-SIRM cycles also progressively changes with increasing annealing time. The SIRM loss after the cycle increases up to ∼30 per cent for the samples annealed for 375 hr at 355 °C, and for 110 hr at 500 and 550 °C. The Curie temperatures of the newly formed magnetic phases exceed the Curie temperature of the fresh sample (205 °C) by up to 350 °C. While this effect is most commonly attributed to extensive single-phase oxidation (maghemitization), the behaviour observed at cryogenic temperatures appears incompatible with the known properties of highly oxidized titanomaghemites. Therefore, we propose that, at least in the initial stage of the ‘dry’, that is, not involving hydrothermalism, alteration of titanomagnetite, temperature- and time-controlled cation reordering is the primary mechanism driving changes in both low- and high-temperature magnetic properties.

Thermal state of the Siberian craton marginal zone at the time of Mesozoic kimberlitic magmatism within the Kuoika field (Yakutian diamondiferous province)

Research subject. Clinopyroxene xenocrysts from the heavy-mineral concentrates of 14 kimberlite bodies (western part of the field: Obnazhennaya, Rubin, Seraya, Vodorazdelnaya, Vtorogodnitsa, Antoshka; central part of the field: Sliudyanka, Skiff II; western part of the field: Irina, Noyabrskaya, Vechernyaya, Lyusya, Dianga and Zhila 79) of the Kuoika field (Yakutian diamondiferous province, Siberian craton). Aim. To reconstruct the mantle paleogeotherms Under the six kimberlite pipes (Vodorazdelnaya, Obnazhennaya, Vtorogodnitsa, Sliudyanka, Dianga, and Zhila 79) using two independent approaches. Materials and methods. The chemical composition of clinopyroxene xenocrysts was investigated and last equilibrium temperatures and pressures were estimated using single-crystal thermobarometry. The geothermal line fitting to the P-T data set was performed using two methods. The first method is based on the D. Hasterok and D.S. Champan model, and the second - on the D. McKenzie model. Results. The value of lithosphere thickness falls within the margin of error for the two methods, being also comparable with earlier reconstructions for the Vtorogodnitsa, Dyanga, and Obnazhennaya pipes. The obtained results indicate that, during the Mesozoic kimberlitic magmatism, the lithosphere thickness beneath the Kuoika field was about 200 km. Conclusion. The determined peculiarities of the chemical composition of clinopyroxene xenocrysts indicate heterogeneity of the lithospheric mantle composition. Different depths of transported mantle material for kimberlite pipes of the Kuoika field, which are coeval and are located a few km apart, may be related to peculiarities of kimberlite magma ascent to the surface and the presence of intermediate magma chambers. The eastern part of the Kuoika field contains more garnet and garnet-spinel peridotites compared to the central and western parts, which may indirectly indicate a greater diamondiferous potential of the eastern block, where the diamondiferous Dianga pipe is located. The absence of diamonds in other discovered pipes of the Kuoika field may be connected with the metasomatic enrichment of the lithospheric mantle in the area of the “diamond window”, which is confirmed by a large number of high-temperature clinopyroxenes at these depths.

Effects of pH and ascorbic acid on the synthesis of Bi-modified bismuth oxyiodide composite catalysts

Multi-heterojunction composites exhibit unparalleled superiority in light absorption and spatial separation of charges, but their synthesis remains a challenge. Herein, we report the one-step hydrothermal synthesis of Bi-modified bismuth oxyiodide composites by modulating the pH of the reaction system using ascorbic acid (AA) as reducing agent. The pH highly influences the composition, morphology and properties of the samples. AA can reduce Bi3+ to metallic Bi, inhibit grain growth of BiOI and help to form Bi4O5I2, thus realizing the one-step synthesis of ternary composites. The sample obtained at pH 6.5 and AA of 0.24 g is the BiOI/Bi/Bi4O5I2 composites with flower-like hierarchical structure, which has the highest degradation efficiency for bisphenol A and RhB. In addition, formation mechanism of the composites was systematically researched based on the composition of intermediates, and an indirect Z-scheme photocatalytic mechanism of BBI-AA-0.24 based on the electronic bridge of metal Bi was proposed.

Concurrent adakitic and non-adakitic Late Miocene-Quaternary magmatism at the Sahand volcano, Urumieh-Dokhtar Magmatic Arc (NW Iran)

The Sahand volcano in NW Iran is characterised by voluminous Late Miocene to Quaternary magmatic activity. Petrographic, mineral chemical, whole-rock geochemical and Sr-Nd-Pb isotope data allowed to identify two rock groups, continuously emplaced from the ancient Paleo-Sahand to the later Neo-Sahand stages. These are represented by abundant evolved rocks, with dacitic to rhyolitic compositions and less common intermediate (andesitic) rocks. Both rock types have the typical LILE-enriched and HFSE-depleted fingerprints of magmas originated from subduction-modified mantle sources, as well as radiogenic Sr- and Pb- (18.8–18.9 206Pb/204Pb, 15.6–15.7 207Pb/204Pb and 38.8–39.2 208Pb/204Pb) isotope compositions. Nevertheless, the evolved rocks have lower 87Sr/86Sr (0.70437–0.70491 vs 0.70494–0.70585) and display an evident high Sr/Y vs Y and high La/Yb vs Yb “adakitic” signature, suggesting derivation from the partial melting of lower continental crust rocks, rather than from the differentiation of the non-adakitic intermediate rocks. The latter would be the derivative melts of magmas generated by the partial melting of lithospheric mantle sources modified by metasomatic fluids released by the subducted Neotethyan oceanic lithosphere. During their ascent and differentiation, these magmas likely provided the heat necessary to induce partial melting of the lower continental crust, eventually producing adakitic evolved magmas. Quantitative models and geothermobarometric calculations suggest that differentiation processes for both rock groups occurred mainly by polybaric fractional crystallisation (in the 29–4 km depth range), possibly coupled with minor assimilation of local crustal rocks.The peculiar style of the Sahand magmatic activity (with both adakitic and non-adakitic products) and its temporal evolution (with an overall increase of the degree of evolution and a decrease of the non-adakitic melts) are somewhat different with respect to those of the coeval neighbouring districts of Saray, Sabalan and Bijar-Qorveh. These can be reconciled within a general model for NW Iran where magmatism is triggered by upwelling of the sub-lithospheric mantle as a consequence of slab break-off (or the opening of a slab tear). The progressive propagation (and subsequent exhaustion) of the thermal pulse and the increasing thickness of the continental crust played a main role in determining both the progressively later inception of active magmatism (from ∼11 to 4.5 Ma) and the change in magma types (from largely variable to adakitic only) at increasing distance from the Iran-Arabia suture.

Modification of rosin resin acids to improve their hydrophobizing action on paper and cardboard

The modification of rosin resin acids, which improves their hydrophobic effect on paper and cardboard, is based on the implementation of 6 stages. Control of chemical processes at each stage is carried out by monitoring and regulating temperature and flow parameters, which determine the achievement of the required physical and chemical properties and composition of intermediates and final substance. One of the main indicators is the acid number, which for the final substance should be 60–70 mg KOH/g, which corresponds to the content of free resin acids in the functional substance of 40–45 %. The fulfillment of the specified temperature and consumption parameters for the modification of resin acids of rosin and the achievement of the necessary physicochemical properties of intermediates at each stage ensures the production of a functional substance with an improved hydrophobic effect on paper and cardboard. Compared to the traditionally used TM adhesive-paste, the developed functional substance in the production of paper with absorbency at one-sided wetting of not more than 21 g/m2 provides a reduction in the content of particles of the dispersed phase of the rosin emulsion by 1.4–2.0 times, which indicates its improved properties, and maximum preservation of the original strength of the paper by reducing the distance between the fibers due to a 3.3–3.8 times reduction (from 4200–5000 to 1100–1480 nm) in the size of sizing complexes.

A bimodal source for the generation of tonalitic to granitic magmas in a non-subduction-related magmatic belt: An example from the Sierra Chica of Córdoba, Argentina

A notable consensus prevails about the hybrid nature of intermediate calc-alkaline magmatism. Accordingly, petrogenetic models envisage the addition of young mantle material and cortical recycling in those geological settings where intermediate magmas are dominant. Most exhaustively studied examples are: 1) magmatic arcs associated with subduction zone settings where oceanic crust and sediments are introduced into the mantle wedge, and 2) deep crustal sections are pervaded by hot, H2O-rich mantle-derived liquids. Nevertheless, back-arc or foreland terranes of several hundred kilometers in width, frequently characterized by high heat flux, crustal melting, recycling and melt fractionation, are crucial areas to evaluate the generation of intermediate magmatism. The Sierra Chica of Córdoba (Argentina) provides an excellent example to study these processes. The high-grade crustal segment shows metamorphosed pelitic and basaltic protoliths that were part of an old sedimentary succession. We evaluate the evolution of this bimodal source during two consecutive early Paleozoic orogenic periods when it was established as the source area of intermediate to silicic magmatism far from the contemporary magmatic arcs. Field relations and new geochemical and geochronological data revealed the occurrence of two magmatic events during Cambrian and early Ordovician periods. Cambrian migmatization and partial melting (∼528 to 505 Ma) is represented by irregular-shaped monzogranites and tonalites, while early Ordovician magmatism (∼480 Ma) is characterized by dyke-shaped pegmatites and tonalite-trondhjemites. The preservation of two contrasting igneous lineages suggests a genetic linkage between metapelitic and amphibolitic migmatites and between granitic and tonalitic-trondhjemitic partial melts. Coeval with this magmatism, Famatinian tonalitic-trondhjemitic to monzogranitic magmas intruded upper crustal levels in Sierra Chica and other parts of Sierras of Córdoba. Geochemical signatures point to a bimodal (mafic/felsic) source for this intermediate to silica-rich magmatism. The evolution of partial melts studied in the Sierra Chica is depicted on the basis of geochemical projections with fractionation and hybridization models, in order to establish the primary liquids of this Famatinian magmatic belt. Trends defined by Famatinian tonalites, trondhjemites and granodiorites suggest that primary Ca-rich melts (tonalites and trondhjemites of this study) evolved through fractionation of plagioclase (30–50 vol%) compatible with the preservation of inferred co-magmatic Pl-cumulates within these plutonic bodies. Peraluminous granites and monzogranites can be explained by a simple restite unmixing process involving alkali-rich liquids generated in the metapelitic part of the source. The addition (hybridization) of up to 30 vol% of granitic melts to the tonalite-trondhjemite end-member may account for the composition of other Famatinian granodioritic to monzogranitic intrusive rocks from the plutonic belt. The crustal segments of the Sierra Chica have undergone metamorphism and partial melting in out-of-arc settings: the Cambrian fore-arc and the early Ordovician back-arc. The voluminous magmatic belt rooted in the paired metapelitic-amphibolic source area is involved in the origin of intermediate to silicic Famatinian magmatism without significant mass transfer from the mantle and crustal growth, instead it is dominated by crustal melting, recycling and fractionation.

Geochemical signatures of the Neoarchean and Paleoproterozoic copper systems in the Carajás Mineral Province, NW Brazil: Implications for metal endowment

The main copper deposits of the Carajás Mineral Province are grouped into: i) iron oxide-copper-gold (IOCG), and ii) granite-related Cu-Au. They were formed during multiple mineralizing events in the Neoarchean (ca. 2.7; ca. 2.5 Ga) and Paleoproterozoic (ca. 2.1; ca. 1.8 Ga). A combination of non-composition and composition data analysis, molar element ratio, and principal component analysis using a lithogeochemical dataset (n = 1040) has been applied to recognize geochemical associations in these deposits. The Neoarchean IOCG deposits in the Northern and Southern Copper Belts of the Carajás Domain are controlled by ductile structures and comprise high-temperature hydrothermal associations within sodic (albite-scapolite), sodic-calcic (albite-actinolite-scapolite±hastingsite), calcic-iron (magnetite-actinolite-apatite), potassic (biotite-tourmaline±scapolite), potassic-iron (biotite-magnetite; almandine-grunerite-biotite) and iron-rich alteration zones. These zones envelop chalcopyrite-magnetite-actinolite-apatite (e.g., Sequeirinho orebody), magnetite-chalcopyrite-siderite (i.e., Igarapé Bahia deposit) breccias, or massive magnetite bodies with bornite-chalcocite (i.e., Salobo). The Fe-Cu-Au-P-REE association is common to all Neoarchean IOCG deposits of the province. Nevertheless, the IOCG deposits from the northern sector (ca. 2.5 Ga) are also enriched in Ba-Pb-Zn-Ag-Mo-REE ± Sn ± W ± Bi±U ± Nb ± Ta ± Y. Conversely, the chemical signature of Neoarchean (ca. 2.7 Ga) IOCG deposits from the southern sector display enrichment in V-Ni-Co-Cr. Part of these chemical variations may be due to differences in the nature of 7host rocks, including greenstone belt sequences in the south and metasedimentary exhalative rocks in north. Both in the northern and southern sectors, the sodic alteration is marked by Na, Ga, Ti, Sr, Th and Mo. The sodic-calcic displays Na, Ca, Mo, Mn, Mg, Pb, Zn and Sn enrichment. The iron-rich alteration zones (grunerite-almandine-magnetite) from the northern sector display a Fe, Mg, Ba, V, Ni, Co, Cr, Cu association. The calcic-iron alteration within the southern sector is marked by enrichment in Ca, Fe, V, Ni, Co, Cr, Mn, Mg, Th, P, HREE and Cu. The Fe-V-Ni-Co signature typical of the iron-rich and calcic-iron alteration stages is thus a lithogeochemical footprint of early Neoarchean IOCG mineralization, providing a useful proxy for exploration. Significant amounts of K, Rb, Ba, Al, Si, Nb, Ta, Th, U, Zr, Pb, Zn and Cu are common in potassic-iron alteration zones from Neoarchean deposits in both northern and southern sectors. The Paleoproterozoic IOCG and granite-related deposits are controlled by brittle structures and represent oxidized (muscovite-potassium feldspar-pyrite-hematite-chlorite), low temperature, sulfur-rich (pyrite-rich) and iron-deficient hydrothermal systems. The Paleoproterozoic IOCG deposits display potassic or potassic-iron alteration (potassium feldspar-biotite±magnetite), generally overprinted by chlorite alteration with late chalcopyrite-rich vein/breccia containing calcite-quartz-albite-chlorite-epidote-sericite. The Paleoproterozoic IOCG mineralized zones display enrichment in granitophile elements, defined by Sn-Mo-REE ± W ± Be±Bi±Nb ± Y. The granite-related deposits are marked by chlorite-rich or greisen alteration types characterized by enrichment in K, Sn, W, Mo, and Bi. The ore zones within these deposits are related to the Cu-Au-Mo-W-Sn-Bi-Be-Nb-U-Y signature. The recurrence and superposition of multiple hydrothermal events at a deposit-scale is evidenced by hybrid geochemical signatures, marked by an intermediate composition between the Neoarchean (Fe-V-Ni-Co-Ba-Pb-Zn) and Paleoproterozoic (Sn-W-Mo-Bi) signatures. The results obtained provide insights on the chemical evolution of the Carajás copper systems and demonstrate the influence of the multiple hydrothermal episodes on the geochemical signature of these deposits.

Geochemical characterisation of mangrove sediments in Tiko (SW, Cameroon, West Africa): Implication for provenance, paleoweathering and sediment maturity

Geochemistry was performed on clastic core sediments from the Tiko Mangroves estuary, South western region of Cameroon, to categorise the rock source composition, tectonic setting, past weathering intensity of the source area in relation to past climate and sediment maturity in relation to sedimentary cycle. Plots of La/Co, La/Sc, Cr/Th, discriminant function (DF1&2), TiO2vs Al2O3 and TiO2 vs Zr point to an acid (felsic) and mixed (intermediate) rock source composition for the Tiko sediments. The acid composition portrayed by the sediments is also confirmed by their LREE (Light rare earth elements) abundance, and a negative Europium anomaly on chondrite normalisation, while the intermediate (mix) composition reflects the multiple sources of the sediments (Douala Basin and basaltic debris from Mount Cameroon). Binary plots Discriminant function (A-P) M, and Discriminant function (A-P) MT signpost active tectonic domain for the studied sediments, that resulted from the tectonothermal of the Pan African orogenic history and eruptive activity of the mount Cameroon. The weathering indexes denoted as CIX (chemical index of weathering) and PIX (plagioclase index of weathering) for the Tiko sediments advocate an intense source area weathering in a humid hot climate. The PIX advocate a high-level plagioclase lixiviation. The low values of ICV (index compositional variation) less than 1 (<1) couple with correlation plots Zr/Sc vs Th/Sc, and Zr vs (La/Yb)N confirms that Tiko mangrove sediments are matured recycled sediments with compositional variations. This is the first comprehensive provenance study of mangrove ecosystem sediments in Cameroon.

Early Paleozoic Tectonothermal Evolution of the Khan-Khukhay Metamorphic Complex (Northern Mongolia)

A reconstruction of metamorphic stages of Moren and Erzin metamorphic Complexes in the Khan-Khuhay block of Nothern Mongolia presented in the paper. Based on it a general geodynamic history of Sangilen terrain of Tuva-Mongolia Massif discussed. Reconstructed “clock-wise” P-T trend demonstrated two stage of metamorphism, the first of which is due to collision metamorphism with P-T parameters of 9 kbar, 740°C, the second one is due to regional magmatic episode with P-T parameters of 6-7 kbar, 860–880°C. Geochemical and petrological peculiarities of rocks in the Khan-Khuhay block demonstrates resemblance with metamorphic block of Western Sangilen in South-East Tuva. In the first time quartz monzodiorite intrusive bodies founded within Khan-Khuhay block. Their geochemical peculiarities are similar to Ordovician gabbro-monzodiorite intrusives of Western Sangilen. Quartz monzodiorite intrusives of Khan-Khuhay are likely a small apophysis of a deep-crust intermediate magma chamber and can present probable thermal source of metamorphic stage M2 in the Khan-Khuhay block. Numerical thermo-mechanical model of metamorphism in the Khan-Khuhay block explain heating in the thickening crust during collision due to higher radiogenic heat source of 1.52 μW/m3. Using computer modeling was show that the P-T parameters of second metamorphic stage can realize only by means of magmatic heat from monzodiorite intrusion. Reconstruction of P-T parameters using mineral thermobarometry, similarity of geochemical characteristics, as well as the results of thermomechanical modeling allow us to conclude that the Erzin and Moren complexes have undergone a joint tectono-metamorphic evolution.

Granites

Granites are coarse‐grained igneous intrusive rocks, which, although present in most tectonic settings, are most characteristic of continental crust. While basalts are the most abundant volcanic rocks, granites are the most abundant intrusive rocks. On the scale of the Solar System, while basalts are ubiquitous, granites seem to be restricted to the Earth. The volcanic equivalent of granite is rhyolite, although rhyolites are of much lower abundance than granite, probably because such magmas are more viscous and less likely to reach the surface. In addition, many pyroclastic rocks have a granitic composition and are likely to have their origins in underlying granitic plutons. Granites may originate by differentiation of a basaltic magma, but the abundance of granites and the low abundance of intermediate rocks argues in general against this possibility and granite magmas are generally thought to have formed by melting of pre‐existing rocks. Several distinct types of granite are recognized depending on their origin.

The origin, nature and fluid characteristics of the hydrothermal veining crosscutting the Yzerfontein gabbro-diorite, Cape Granite Suite, South Africa

Abstract The mafic to felsic rocks at Yzerfontein form part of a composite 535 Ma post-orogenic pluton belonging to the Cape Granite Suite (CGS) of the Pan-African Saldania Belt of southwestern Africa. The pluton ranges from olivine gabbros (mostly at the northern end) to quartz monzonites, with monzonites the most abundant rock type. Minor felsic rocks in the form of quartz microsyenites and monzogranite occur more toward the southern end. The comparatively unaltered gabbro/monzonite has pyroxene δ18O values of 6.4‰, consistent with a mildly crustal-contaminated mantle-derived magma. Published εNd values of -1.9 to -0.3 similarly reflect crustal contamination of these mafic to intermediate rocks. The pluton is crosscut by extensive hydrothermal veining. Early quartz veining was followed by the precipitation of pyrite, calcite, tourmaline, jasper, epidote and a final stage involving the formation of barren quartz veins. The veins contain low-salinity (3 to 11 wt.% NaCl eq.), three phase (liquid + vapour ± opaques) fluid inclusions with total homogenisation temperatures of 125 to 320°C. The δ18O values of the quartz veins range from 9.8 to 14.7‰ and the fluid inclusion δD values range from -9 to -17‰. These ranges, together with the low salinities, are consistent with a meteoric origin for the vein fluids. Bulk-rock δ18O values range from 7.3 to 13.3‰ consistent with interaction of near surface fluids at temperatures of &amp;lt;300°C with the magmatic rocks. Open-space filling textures in quartz veins suggest vein formation in a hydrostatic regime. These, together with fluid inclusion isochores, suggest temperature-pressure conditions of no more than 170 to 300°C at ~0.5 kbar and no more than 1.6 kbar. The mineralised veins represent a shallow, poorly developed and possibly low-grade epithermal system. The mineralisation is likely related to drawdown of meteoric fluids during sub-solidus cooling of the dominantly intermediate pluton with little to no magmatic fluid influence. The mineralisation is poorly developed, possibly due to a lack of mixing between different fluid types. The various magmatic rocks, varying from mafic through dominantly intermediate to minor felsic, represents a minor mantle-derived mafic component of the Cape Granite Suite and likely related to the heat source that gave rise to voluminous crustal melting that generated the granitic magmas of the majority of the CGS.

Provenance, weathering, climate and tectonic setting of Padma River sediments, Bangladesh: A geochemical approach

The major, trace, and rare earth element (REE) compositions of sediments from the Padma River, Bangladesh have been examined using XRF and INAA analysis to determine their geochemical compositions, provenance, climate, weathering intensity and tectonic setting. The Padma River sediments from the region were remarkably comparable, demonstrating elemental depletion and pointing to a low geochemical maturation. Sediment samples are classified as arkose which are considered as chemically immature sediments, deposited under semi-arid to semi-humid climatic conditions due to the weakening of Indian summer monsoon. The low CIA values (48.6–58.8), PIA (48.1–63.4) and Rb/Sr ratios of the river sediments suggest low intensity of chemical weathering in the source area. The Padma River is originated from the Higher Himalaya and the sediments derived from metasediments (Higher Himalayan Crystalline Series) as are evident by major, trace elements discriminate diagram and REE pattern. Most of the sand samples were derived from felsic source rock (granite) whereas some samples are plotted in the intermediate rock types (granodiorite) in the A-CNK-FM and discriminant function diagrams. High LREE enrichment and relatively flat HREE fractionation in chondrite-normalized REE patterns (LaN/YbN = 7.50–13.20) demonstrated felsic source origin. TiO2 versus Zr plot shows that Padma River sediments have felsic to intermediate provenance. According to Log (K2O/Na2O) vs. SiO2 discriminant diagram and La–Th–Sc, Th–Sc–Zr/10 ternary plot, the Padma River sediments were deposited in passive continental margin. The Padma River sediments have been compared with Yarlung Zangbo River (YZR), Brahmaputra-Jamuna River (BJR), Ganges River (GR) and Upper Meghna River (UMR), which results suggest that there is contrast among the sediments of different Himalayan Rivers in relation to provenance, weathering intensity and tectonic setting.

The Neoproterozoic Agudos Grandes granitic batholith, SE Brazil: Inferences on source areas from elemental and Sr-Nd-Pb isotope geochemistry

I-type, K-rich calc-alkaline hornblende-biotite granitoids (HKCA) suites are typical of both pre- and post-collisional tectonic settings, and their petrogenesis is challenging, since they are dominated by rocks with intermediate composition (e.g., 60–68 wt% SiO2; 10–20 vol % mafic mineral) that are neither typical products of crust nor of mantle partial melting. These granitoids are particularly abundant as the main components of Ediacaran batholiths intruding the Neoproterozoic Ribeira Fold Belt in SE Brazil, e.g. constituting ∼70% of the exposition of the Agudos Grandes Batholith, where they were emplaced at 620-610 Ma, as indicated by U–Pb zircon dating from our previous work and new data presented here. Two types of coeval granitoids comprise an expanded suite of mafic to felsic titanite and allanite-rich biotite granitoids (Itapevi-type) and a single occurrence of biotite-muscovite leucogranite (Turvo-type). Elemental and isotope whole-rock data indicate that different sources were involved in the genesis of their parent magmas, with crust with old residence predominating for the HKCA and Itapevi types, as indicated by very negative (−16 to −20) εNd(t) and low initial 206Pb/204Pb (16.4–16.7), and younger metasedimentary rocks as the source of the Turvo leucogranite (εNd(t) (∼-14); initial 87Sr/86Sr = 0.717). This “syn-orogenic” magmatism was immediately followed, as demonstrated by field and geochronological data, by ∼605-600 Ma circumscribed plutons dominated by more fractionated (±muscovite)-biotite granites that derive from melts generated in the middle crust from sources that are slightly younger than those of the HKCA granitoids, as indicated by slightly less negative (εNd(t) (similar to those of the Turvo leucogranite) and higher 206Pb/204Pb (17.1–17.3). After a ∼15 Myr lull, A-type plutons were emplaced in a post-orogenic setting, probably from mantle and crust sources. The syn-to late-orogenic (620-600 Ma) magmatism of the Agudos Grandes was produced by a thermal anomaly, probably associated with a continental arc. A combination of elemental and isotope geochemistry and inherited zircon data suggests that crustal melting was probably induced by ascension of mantle-derived basic magmas, and initiated in hot zones at the lower portions of a previously thickened crust, formed by old Paleoproterozoic to Archean material (the basement of the Apiaí-São Roque Domain of the Ribeira Belt?), and progressed to the middle portions of the crust, where it provoked partial melting of a different crustal domain with younger age and crustal residence (Embu Complex orthogneisses and metasediments).

Structure and Lithium Insertion in Oxides of Molybdenum

Oxides MoOx of molybdenum have a rich structural chemistry arising from the accommodation of oxygen deficiency as MoO3 is reduced, and varied redox behavior arising from the ability of Mo to take on several different oxidation states. We have reviewed MoO3, MoO2, and all the reduced Mo oxides with intermediate compositions for their performance as Li-ion battery electrode materials. These reduced oxides are perhaps the most structurally diverse in the field of energy storage materials, taking on structures ranging from ones with crystallographic shear to bronze-like structures and distorted rutile. Crystal structure can have a significant impact on the performance of battery materials, which makes the reduced Mo oxides a promising domain of study. Electrochemical studies of these oxides from as early as 1971 to as recently as 2022 have been compiled, and characteristics of capacity, capacity retention, and rate performance have been compared. We found that certain oxides indeed display promising and highly reversible capacities for Li+ storage. Typical redox voltages for Mo oxides lie in a regime that hinders maximizing energy density when they are paired with higher-voltage cathodes or lower-voltage anodes. The possibility of decreasing the redox voltage in the future will expand the promise of these materials, while offering an alternative to more critical elements such as Nb. Figure 1

Typology of Indonesian Stratovolcanoes: Insights from Geomorphological and Geological aspects

This study aims to provide the first general typology of Indonesian stratovolcano (number of analyses=154), including various types of rock compositions and diverse volcanic hazards. Several parameters were evaluated, including average radius (r), average slope (S), surface roughness (RMS), rock compositions, mineralogy, and deposit characteristics. Four types were identified as follows: (1) small-least dissected cones, (2) broad-dissected cones, (3) extremely broad-dissected cones with caldera, and (4) residual-highly dissected cones. Type I is typically small (r=2.1 km), steep (S=19.8ᵒ), rough (RMS=88.8), less evolved (predominantly basic to intermediate), having abundant mafic (olivine, clinopyroxene) and minor hydrous (amphibole, biotite) minerals, with rare pumice and lava domes (mostly scoria and lava flows). Type II has moderate values of r, s, and RMS (8.8 km, 15.2ᵒ, and 47.7, respectively) with predominantly intermediate rocks, minor olivine with abundant hydrous minerals, and abundant pumice and lava domes. Type III is typically large (r=18.1 km), gentle (S=9.2ᵒ), smooth (RMS=40.1), producing abundant felsic rocks and felsic minerals (quartz and sanidine), and characterized by the occurrence of thick ignimbrite deposits. Type IV has relatively similar size to type II (r=8.2 km), but the slope is gentler with coarser surface textures (S=10.7ᵒ and RMS=56.8), includes more portion of ultrabasic rocks and mafic minerals, and has no feature of lava domes with common exposure of intrusions (e.g., dyke). We suggest that the evolution from type I to type III corresponds to maturation stage, whereas the formation of type IV represents erosional stage.