Interfacial Area Research Articles

Development of Silicalite-1 encapsulated Cu-ZnO catalysts for methanol synthesis by CO2 hydrogenation

Converting CO2 into fuels and valuable chemicals such as methanol has been gaining significant attention as a favorable solution for reducing greenhouse gas emissions. Although Cu-ZnO-based catalysts are promising candidates for this reaction since methanol is selectively produced at the Cu-ZnO interface, Cu are not stable at elevated temperatures (500–600 K), leading to decrease in the surface areas of Cu and Cu-ZnO interface due to thermal aggregation of Cu. Furthermore, the generation of H2O as a by-product in the CO2 hydrogenation does not only accelerate the aggregation of Cu, but also inhibits an intermediate (formate species) formation for methanol. This paper reports the development of a novel catalyst, annotated as CuPS@S-1 by immobilizing Cu phyllosilicate (CuPS) as the Cu source within hydrophobic zeolite of Silicalite-1 particles (S-1). Cu@S-1 was obtained after the reduction CuPS@S-1 and the size of the Cu particles was approximately 2.4 nm. Cu@S-1 exhibited a higher CO2 hydrogenation activity and methanol selectivity than Cu/S-1 prepared by an impregnation method. To further improve the methanol production activity, ZnO was loaded onto Cu@S-1 to form a Cu-ZnO interface. ZnO/Cu@S-1 was obtained by the impregnation of CuPS@S-1 powder with an ethanol solution containing zinc acetate, followed by calcination and reduction. The obtained catalyst exhibited a better methanol production yield where the space–time yield for methanol based on the Cu weight exceeded 1200 mgmethanol gCu−1h−1.

Morphology evolution of P-Ti3AlC carbides and their influence on creep properties in a crept Ti-45Al-5Nb-0.75C alloy

In this study, the influence of the Ti3AlC carbide morphology on the creep properties, the interaction between carbides and dislocations during creep deformation as well as the influence of external stress on carbide morphology evolution were investigated in a Ti-45Al-5Nb-0.75C alloy. The results show that the best creep properties are obtained after annealing at 800 °C for 336 h. This is probably due to the splitting of the carbides into conglomerates of sub-particles, which provides an increased number of interfacial area and interfaces to hinder dislocation glide. After prolonged annealing for 1054 h at 800 °C, although the carbide splitting still existed, the matrix grains coarsened and the lamellar structure was decomposed, which counteracted the positive effect of carbide splitting and led to a reduction in the creep resistance. By comparing the carbide morphology evolution after creep and after annealing alone, it can be concluded that the external stress does not significantly affect the morphology evolution. During creep at 800 °C the Ti3AlC carbides obviously interact with dislocations, and the majority of them were identified to be ½<110] ordinary dislocations. The glide of these dislocations was strongly hindered, and thus the creep properties of the alloy can be improved by carbide precipitation.

Experimental investigation on local flow structures of upward cap-bubbly flows in a vertical large-size square channel

Gas–liquid two-phase flows are typical in engineering systems involving heat and mass transfers. The cross-sectional geometries and sizes of these flow channels vary, exerting a notable impact on the thermofluid behavior. To develop thermofluid models, it is imperative to obtain local measurements of two-phase flows and gain insights into their characteristics from these measurements. Numerous experimental studies have investigated the local flow characteristics in circular pipes and rectangular channels; however, few studies on square channels have been conducted, particularly for flow regimes beyond bubbly flows, such as cap-bubbly flows. Given the importance of two-phase flows in large square channels for advanced nuclear reactors, such as the economic simplified boiling water reactor (ESBWR), we experimented with upward cap-bubbly flows in a large square channel. Detailed cross-sectional distributions of the void fractions, axial gas velocities, and interfacial area concentrations for two bubble-size groups were obtained at three axial locations using local measurements of a four-sensor optical probe. Based on the database, the cap-bubbly flow characteristics were understood, including flow development in a large square channel. In addition, the existing drift-flux correlations for large circular pipes predicted the measured void fraction with an accuracy of approximately ± 10 %, whereas the existing interfacial area concentration correlations reasonably correlated with the measured interfacial area concentration with an accuracy of approximately ± 30 %. Furthermore, the database was used to calculate the covariances of the void fractions. The correlations for large circular pipes significantly underestimated the void fraction covariance of the larger bubble group, probably because of the peculiar void fraction distribution of the group in a large square channel. The other covariances were well predicted.

Facet-dependent dispersion and aggregation of aqueous hematite nanoparticles.

Nanoparticle aggregates in solution controls surface reactivity and function. Complete dispersion often requires additive sorbents to impart a net repulsive interaction between particles. Facet engineering of nanocrystals offers an alternative approach to produce monodisperse suspensions simply based on facet-specific interaction with solvent molecules. Here, we measure the dispersion/aggregation of three morphologies of hematite (α-Fe2O3) nanoparticles in varied aqueous solutions using ex situ electron microscopy and in situ small-angle x-ray scattering. We demonstrate a unique tendency of (104) hematite nanoparticles to maintain a monodisperse state across a wide range of solution conditions not observed with (001)- and (116)-dominated particles. Density functional theory calculations reveal an inert, densely hydrogen-bonded first water layer on the (104) facet that favors interparticle dispersion. Results validate the notion that nanoparticle dispersions can be controlled through morphology for specific solvents, which may help in the development of various nanoparticle applications that rely on their interfacial area to be highly accessible in stable suspensions.

Hydrodynamics and mass transfer performance of microbubble flow in the bubble column with a contraction section

Bubble columns have many applications in the biochemical, petrochemical, and metallurgical industries. The gas-liquid system composed of microbubbles is characterized by significant phase interfacial area, high mass transfer efficiency, fast dissolution rate, strong adsorption capacity, and long self-sustaining time. This paper investigated the performance of pressurized dissolved gas microbubble generation (PDG) using a Venturi tube as the releaser using a plug-in online imaging instrument. The hydrodynamic and mass transfer characteristics of the microbubble flow generated by PDG in a bubbling column with a contraction section (BCS) were then investigated. One of the primary studies was the effect of the contraction section on the flow performance of the bubbles, the mass transfer performance, and the aeration efficiency of the PDG versus the throat inlet Venturi bubble generator (VBG). The results show that the initial bubble Sauter mean diameter is essentially constant with dissolved gas pressure, and the bubble size distribution(BSD) is similar. The bubble stream passing through the contraction section exhibits two different BSD at the center and side walls of the BCS outlet section. Microbubbles in the inlet section in the absence of external forces almost do not occur in bubble coalescence. The flow of bubbles in the contraction section is subject to a slight coalescence effect. The diameter of bubbles in the contraction section is mainly larger than 20 μm. In the contraction section, coalescence occurs mainly at the side wall. The way of occurrence is adsorption coalescence and collision coalescence. The bubbles move in a gradually confined space with a high degree of interference with each other's bubbles, and the liquid linear velocity acts as an ‘external force’ that benefits the flow of the bubbles out of the confined space. The standard aeration efficiency of PDG is 3–11 times higher than that of the VBG. At 0.3 MPa, the highest standard aeration efficiency for the PDG method was between 0.18 and 0.64 kgO2/kW∙h.

Pore-scale study of the effects of grain size on the capillary-associated interfacial area during primary drainage

This study investigates the capillary-associated interfacial area during primary drainage in unconsolidated porous media for different mean grain diameters, employing pore-scale numerical simulation with the phase-field method. Five, two-dimensional porous media are generated with the same grain/pore size uniformity, but different mean grain diameters, ranging between 0.24 mm and 0.94 mm. Three cases are considered, representing stable displacement, crossover zone and viscous-fingering regimes. The findings reveal that the capillary-associated interfacial production rate increases with decreasing grain size. Specifically, the capillary-associated interfacial production rate is higher for the viscous-fingering regime compared to the stable displacement. The maximum capillary-associated interfacial area obtained for different grain sizes agrees with the correlation established in our previous study using the kinetic interface-sensitive tracer. Furthermore, the capillary-associated interfacial area is divided into two parts: one related to the disconnected water clusters and the other related to the connected water. The disconnected capillary-associated interfacial area correlates with the average volume of the clusters, following an exponential function. Furthermore, the average volume of the clusters depends on both, the grain size and displacement regime. Moreover, it is found that the displacement regime has a great impact on the connected capillary-associated interfacial area. For stable displacement, the connected capillary-associated interfacial area is larger for larger mean grain diameter. In contrast, for fingering, the connected capillary-associated interfacial area is smaller for increasing mean grain diameter.

Experiment of droplet contact angle hysteresis on PTFE fibrous membrane in pore-scale

The present paper aims to study the influence of pore-scale fiber structure on the Cassie-Baxter contact angle of droplets on PTFE fibrous hydrophobic membranes. The fiber structure is obtained by the Confocal Laser Scanning Microscope (CLSM), and an optical test bench is built to measure the Cassie-Baxter contact angles of a droplet on a PTFE membrane. The free energy of the solid-liquid interface is measured by the surface tension integral on the droplet profile. An iterative algorithm for liquid-vapor interface shrinking is brought forward to analyze the liquid-vapor interface area between the droplet and the membrane, and the interface parameters of the Cassie-Baxter model are recognized. The experiment shows that the Cassie-Baxter contact angles and the contact line radii along the droplet circumference are in a normal distribution due to random fiber structures, and the variance of the normal distribution increases with the membrane pore diameter. The normal distribution of Cassie-Baxter’s contact angle indicates the constraint of the solid-liquid interface to the liquid-vapor interface. On the same normal contact pressure condition, the liquid-vapor area ratio of the droplet and membrane interface changes little, and Cassie-Baxter’s contact angle increases with the solid-liquid interface area ratio.

Hydrodynamics, mass transfer, and hydrogenation performance of a HiGee‐aided fixed bed reactor

AbstractMicrobubble shows great potential for hydrogenation reaction in fixed bed reactors (FBRs). However, the lack of understanding of the hydrodynamic behaviors of microbubble swarm in FBR limits the reactor design. In this work, a pilot‐scale HiGee‐aided fixed bed reactor (HFBR), including a HiGee microbubble generator (HMG) and a catalyst bed, has been developed and then applied for poly alpha olefin 4 (PAO 4) hydrogenation. An empirical correlation of Sauter mean diameter (d32) of microbubbles at the inlet and outlet of catalyst bed was established. The gas holdup (φb) of catalyst bed with HMG was 5–10 times higher than that without HMG. Based on d32 and φb, the effective interfacial area in HFBR was calculated as 2000–6000 m2/m3. Compared with static mixer‐aided fixed bed reactor, the aromatic content of PAO 4 hydrogenated in the HFBR was 56%–69% lower, which shows bright future for industrial application.

High-performance pneumatic solid–liquid triboelectric nanogenerator

In the field of blue energy harvesting, solid-liquid triboelectric nanogenerators (SL-TENG) show significant potential. However, their low output performance in energy applications is limited due to the relatively small contact area and slow separation speed during the friction process. To overcome these limitations, we develop a pneumatic solid-liquid triboelectric nanogenerator (PSL-TENG) with ultrahigh output performance based on pneumatic solid-liquid triboelectrification and electrostatic breakdown. The pneumatic design effectively increases the solid-liquid interface area and the solid-liquid contact and separation rate, which can enhance solid-liquid triboelectrification effect. The synergistic design of the horn and the bent pipe can converge positively charged mist into large droplets, which can enhance electrostatic breakdown effect. This innovative design approach has achieved outstanding output performance, with a peak instantaneous voltage of 6436 V and a peak instantaneous current of 3.05 mA. This exceptional output performance is sufficient to directly power 3000 LED lights or a 55 W commercial lamp. These research achievements provide new insights for SL-TENG in energy harvesting, as significant output can be generated by collecting the inherent charges of liquids themselves.

Influence of pin-perforation shape on thermohydraulic performance of circular pin-fin heat sinks under turbulent flow

The impact of pin-perforation shape on the thermohydraulic performance of circular pin–fin heat sinks (CPFHS) under turbulent flow conditions is numerically assessed using a computational fluid dynamics software. The convective heat transfer efficiency, hydraulic resistance, and thermohydraulic performance of four pin-perforation shapes: square diamond, triangle, hexagon, and circle, are evaluated under various turbulent flow conditions (Reynolds number between 24,484 to 55,088). The sizes of all pin-perforation shapes are under a constraint that the ratio of the air–solid interfacial surface area to the total volume of pin-perforated CPFHS must be the same. The results show that all pin-perforated CPFHS demonstrate a higher Nusselt number compared to unperforated CPFHS. Those with circular perforations exhibit the highest Nusselt number with up to 39% improvement compared to unperforated CPFHS, followed by those with hexagonal, triangular, and diamond perforations, respectively. The Nusselt numbers correlate with the ease of fluid flow within perforations which is expressed using the average air velocities through perforations. In terms of hydraulic resistance, all pin-perforated CPFHS exhibit a reduction in friction factor compared to unperforated CPFHS. Among these, the largest decrease in friction factor, up to 15.8%, is observed in CPFHS featuring circular perforations, followed by those with hexagonal, diamond, and triangular perforations, respectively. The friction factors are influenced by the ratio of perforation perimeter to cross-sectional area. All pin-perforated CPFHS have a thermal performance factor greater than 1, indicating an improvement in thermohydraulic performance compared to unperforated CPFHS. CPFHS with circular perforations yield the highest thermal performance factor, reaching up to 1.44, followed by hexagonal, triangular, and diamond pin configurations, in descending order. With increasing Reynolds numbers, thermal performance factors of pin-perforated CPFHS initially rise, then gradually decline, suggesting that thermohydraulic advantages due to pin–fin perforations are diminishing as the flow become more turbulent.

Facile Approach for Designing Icephobic Coatings Using Polymers/Silica Nanoparticle Composites via Self‐Formation of Superhydrophobic Surfaces

AbstractIce accumulation and proliferation adversely affect the activities of various residential, commercial, and polar research stations. Although significant efforts are devoted to preventing ice adhesion to various surfaces by developing various anti‐icing coatings, it is still necessary to enhance overall performance and durability. Herein, a facile approach is proposed for fabricating an icephobic coating on an aluminum 6061 (Al) substrate, by coating a poly(dimethylsiloxane) (PDMS)/ poly(tetrafluoroethylene) (PTFE) composite through a spin‐coating method, followed by sprinkling of SiO2 nanoparticles (NPs). Crosslinker/binder‐free adhesion between PDMS and PTFE is achieved by utilizing secondary‐induced electrostatic dipole‐dipole interactions, these interactions are supported by density functional theory (DFT) calculations as well as structural studies. Moreover, the controlled addition of PTFE powder to PDMS improves the water‐repellency, mechanical strength, and surface roughness of the coating. The self‐formation of the superhydrophobic state of the PDMS/PTFE composite is achieved by sprinkling SiO2 NPs. The sprinkled SiO2 NPs are protected by the PDMS/PTFE composite, which serves as a stress concentrator to achieve low ice adhesion. Furthermore, freezing at low temperatures can be delayed by controlling the heat flow rate, interfacial contact area, and surface texture. This indicates the feasibility of the proposed method for various promising anti‐icing applications.

The diversification and potential function of microbiome in sediment-water interface of methane seeps in South China Sea.

The sediment-water interfaces of cold seeps play important roles in nutrient transportation between seafloor and deep-water column. Microorganisms are the key actors of biogeochemical processes in this interface. However, the knowledge of the microbiome in this interface are limited. Here we studied the microbial diversity and potential metabolic functions by 16S rRNA gene amplicon sequencing at sediment-water interface of two active cold seeps in the northern slope of South China Sea, Lingshui and Site F cold seeps. The microbial diversity and potential functions in the two cold seeps are obviously different. The microbial diversity of Lingshui interface areas, is found to be relatively low. Microbes associated with methane consumption are enriched, possibly due to the large and continuous eruptions of methane fluids. Methane consumption is mainly mediated by aerobic oxidation and denitrifying anaerobic methane oxidation (DAMO). The microbial diversity in Site F is higher than Lingshui. Fluids from seepage of Site F are mitigated by methanotrophic bacteria at the cyclical oxic-hypoxic fluctuating interface where intense redox cycling of carbon, sulfur, and nitrogen compounds occurs. The primary modes of microbial methane consumption are aerobic methane oxidation, along with DAMO, sulfate-dependent anaerobic methane oxidation (SAMO). To sum up, anaerobic oxidation of methane (AOM) may be underestimated in cold seep interface microenvironments. Our findings highlight the significance of AOM and interdependence between microorganisms and their environments in the interface microenvironments, providing insights into the biogeochemical processes that govern these unique ecological systems.

Pore-scale Simulation of Two-phase Flow in Foamed Porous Materials

This paper establishes a pore cell model of foamed silicon carbide material based on a tetradecahedron structure, and uses FLUENT software to numerically study the flow rate and pressure drop changes in the porous structure at different flow rates and the gas-liquid two-phase flow state of the channel. The research results show that the porous skeleton structure has a great influence on the velocity and pressure distribution in the calculation domain; the inlet flow velocity has a certain impact on the gas-liquid mixing zone and gas-liquid interface area in two-phase flow. The application of tetradecahedral porous media increases the thickness of the gas-liquid mixing zone and the phase interface area are increased, with a maximum increase of 11.5%, thus promoting gas-liquid heat and mass transfer.

Non-intrusive, transferable model for coupled turbulent channel-porous media flow based upon neural networks

Turbulent flow over permeable interfaces is omnipresent featuring complex flow topology. In this work, a data-driven, end-to-end machine learning model has been developed to model the turbulent flow in porous media. For the same, we have derived a non-linear reduced order model (ROM) with a deep convolution autoencoder. This model can reduce highly resolved spatial dimensions, which is a prerequisite for direct numerical simulation, by 99%. A downstream recurrent neural network has been trained to capture the temporal trend of reduced modes; thus, it is able to provide future evolution of modes. We further evaluate the trained model's capability on a newer dataset with a different porosity. In such cases, fine-tuning could reduce the efforts (up to two-order of magnitude) to train a model with limited dataset (10%) and knowledge and still show a good agreement on the mean velocity profile. Especially, the fine-tuned model shows a better agreement in the porous domain than the channel and interface areas indicating the topological feature is less challenging for training than the multi-scale nature of the turbulent flows. Leveraging the current model, we find that even quick fine-tuning achieves an impressive order-of-magnitude reduction in training time by approximately O(102) and still results in effective flow predictions. This promising discovery encourages the fast development of a substantial amount of data-driven models tailored for various types of porous media. The diminished training time substantially lowers the computational cost when dealing with changing porous topologies, making it feasible to systematically explore interface engineering with different types of porous media.

Sphingosine-1-phosphate receptor 1-mediated odontogenic differentiation of mouse apical papilla-derived stem cells

Background/purposeSphingosine-1-phosphate (S1P) exhibits receptor-mediated physiological effects by facilitating the differentiation of mesenchymal stem cells toward the osteoblast lineage. This study aimed to determine the effect of S1P on odontogenic differentiation of mouse immortalized stem cells of dental apical papilla (iSCAP) and assess the distribution of the S1P receptor 1 (S1PR1) in the apical papilla and the root canal wall of immature rat molars. Materials and methodsImmunostaining for S1PR1 was conducted at the apex of the rat mandibular first molar and within the root canal wall. The iSCAP was treated with S1P and bone morphogenetic protein (BMP)-9 (for comparison), and the expression levels of the odontogenic differentiation marker were evaluated via real-time reverse-transcriptase quantitative polymerase chain reaction and enzyme-linked immunosorbent assay. Mineralization and lipid droplet formation were evaluated via Alizarin red and Oil red O staining. ResultsS1PR1-positive cells were expressed in areas of both apical papilla and dentin-pulp interface of root canal wall. During the odontogenic differentiation of iSCAP, S1P and BMP-9 increased the expression of the differentiation marker mRNA and secreted proteins including dentin sialophosphoprotein, dentin matrix phosphoprotein 1, and matrix extracellular phosphoglycoprotein. The S1PR1 signaling pathway is involved in the action of S1P, but not that of BMP-9. S1PR1 signaling also facilitated mineralization in iSCAP and suppressed the differentiation of these cells into adipocytes. ConclusionS1P induced odontogenic differentiation of iSCAP through S1PR1. Furthermore, S1PR1-positive cells were expressed in the apical papilla of immature rat molars and in the dentin-pulp interface where odontoblast-like cells exist.

Controlling gas–liquid flow and enhancing heat transfer in a T-junction microchannel by wettability-engineered walls

Characteristics of gas–liquid flow and heat transfer in a cross-flow T-junction microchannel with wettability-engineered walls are numerically investigated in this paper. The validated diffuse interface method is adopted for interface capture. First, the effects of wall wettability on bubble formation and transportation are studied. Three flow patterns are observed due to different combinations of the bottom and the top wall contact angles. On this basis, two methods are proposed to enhance the heat transfer. One is to increase the two-phase interfacial contact area by dividing the microchannel into three functional regions, which can promote the heat exchange at the two-phase interface. The other is to increase the velocity fluctuation intensity by alternating the contact angle along the channel, which can enhance mixing between the hot liquid layer adjacent to the wall and the cool liquid core. These two methods are applicative for steady and unsteady problems, respectively. The flow states, velocity vectors, and streamlines are used to analyze the fluid and thermal mixing mechanism. Meanwhile, a quantitative comparison of the wall temperature is made at a given wall heat flux. The obtained results can provide fresh insights into the gas–liquid flow control and the heat transfer enhancement in a microchannel, which are valuable for the design of microreactors and radiators.

Pickering emulsion stabilized with charge separation and transfer modulated photocatalyst for enzyme-photo-coupled catalysis

Biocatalytic reduction is extensively employed in chemical and pharmaceutical industries due to its notable advantages including high activity, selectivity and mild reaction conditions, however, the stoichiometric use of the expensive NADH (reduced form of nicotinamide adenine dinucleotide) hinders its widespread application. Despite the persisting challenges of low charge separation efficiency and limited solubility of organic substrates in aqueous phase, in situ photocatalytic NADH regeneration remains a promising solution. Herein, we report the construction of an enzyme-photo-coupled catalytic system in Pickering emulsion droplet, which was stabilized by a charge separation and transfer modulated photocatalyst. The photocatalyst integrated with visible light driven conjugated polymer, TiO2 and electron mediator greatly enhanced the cascade electron transfer from photocatalyst to NAD+. Consequently, NADH production rate over the integrated photocatalyst reaches as high as 2.4 mmol·g−1·h−1 under visible light irradiation, 12 folds higher than the corresponding physical mixture. Furthermore, the enzyme-photo-coupled catalytic system was constructed with alcohol dehydrogenase/NAD+ confined in the emulsion droplet and photocatalyst assembled at the oil-water interface. The photoactive emulsion continuously catalyzed the n-butyaldehyde reduction to accumulate 16.1 mmol·L−1 butanol, equivalent to 14 cycles for NADH regeneration under visible light irradiation. The primary result demonstrates the potential application prospect of Pickering emulsion in enzyme-photo-coupled catalysis due to the facilitated charge transfer from photocatalyst to NAD+ and fast mass diffusion attributed to the large interfacial area of water and oil.

Mixing dynamics in the synthesis of nanoparticle-stabilized water-in-water emulsion: Impact on size and stability

This communication presents a comprehensive investigation into the impact of mixing on the synthesis of water-in-water Pickering emulsions. The approach employs commercial-grade oppositely charged nanoparticles within two distinct fluid phases, facilitating self-assembly and the formation of aggregates with variable sizes and compositions. Enhanced interfacial area, achieved through aggregate adsorption at the interface, elevates the Gibbs detachment energy of particles between the two aqueous phases, leading to stable emulsion formation. We further explore the effect of various mixing devices, including high-pressure and sonic wave mixing. Our findings reveal that mixing within the aqueous phase critically influences emulsion size, with sonicator-assisted mixing producing smaller droplets than homogenizer mixing. Both devices yield poly-dispersed droplet size distributions. Interestingly, the droplet size correlates well with the Hinze scale (hd), and the Kolmogorov length scale (ld) exhibits good correspondence within a specific operating range. The proposed method introduces a streamlined, one-step synthesis process for easy preparation, demonstrating excellent stability for a minimum of 30 days. This study pioneers the investigation of mixing effects within an aqueous two-phase system utilizing a Pickering emulsion template.

Investigation of hydrodynamic performance in a staggered multistage internal airlift loop reactor

The multistage internal airlift loop reactor (MIALR) has shown promising application prospects in gas–liquid–solid reaction systems. However, traditional MIALRs have a global circulation with strong interstage liquid-phase exchange. This paper proposes a staggered multistage internal airlift loop reactor (SMIALR) that incorporates special guide elements to create a staggered flow. Both experiments and computational fluid dynamics-population balance model simulations were conducted to investigate the hydrodynamic performances of MIALR and SMIALR. The results demonstrate that SMIALR exhibits a local circulation at each stage. Bubbles have a longer residence time in SMIALR, resulting in a 28.35%–55.54% increase in gas holdup and a 7.27%–13.69% increase in volumetric mass transfer coefficient. The gas–liquid mass transfer coefficient of SMIALR was improved by increasing the gas–liquid interfacial area. Additionally, the radial distribution of solids was found to be more uniform. This study offers insights for optimizing MIALR and provides a theoretical foundation for the design and scale-up of SMIALR.

Effects of viscosity on hydrodynamics and mass transfer under a wire mesh-coupled solid particles method

Many practical industrial processes require gas–liquid mass transfer in highly viscous liquids, and liquid viscosity affects bubble characteristics and gas–liquid mass transfer. The current study investigated the effects of liquid viscosity on bubble dynamics and gas–liquid mass transfer via shadow imaging and dynamic oxygen dissolution methods, and the influence of fluid viscosity on the hydrodynamic effect when using a wire mesh-coupled solid particles method. The coupling strategy was associated with a bubble size regulation effect, with greater viscosity increasing the gas–liquid interface area by 27%–55% compared with unreinforced gas–liquid flow, which was superior to embedded wire mesh and added solid particles methods. Increased viscosity weakened the mass transfer enhancement effect of the coupling method, but the coupling method still effectively enhanced the gas–liquid mass transfer process, increasing the volumetric mass transfer coefficient (KLa) by 80%–130% compared to non-enhanced gas–liquid flow. Novel empirical KLa correlation equations were developed to predict the effects of the coupling method on gas–liquid mass transfer processes, and those equations exhibited good reliability and predictive capacity.