Interfacial Zone Research Articles

Interface and mixing zone between soil waters arising from upward and downward seepage - Part II: Heterogeneous total density.

Freshwater lenses in otherwise saline environments contain an important source of fresh water for natural vegetation and agricultural crops. Such lenses are regularly found in areas where both upward seeping saline groundwater and downward infiltrating fresh recharge water occur simultaneously during part of the year, resulting in shallow freshwater lenses which are highly susceptible to changes in recharge or seepage. In a series of two papers, we consider the water – and solute transport in a 2D cross-section between two parallel outflow faces. In this second part of the series, we build upon expressions presented in the first part to consider a situation where the density of seepage water exceeds that of recharge water, as typical for many deltaic areas around the world. Analytical expressions and approximations are given to obtain the steady state position of the interface between the two types of water using a sharp interface approximation, with a focus on the position midway between two outflow faces. Results show that the effect of a heterogeneous density distribution is limited when the seepage flux exceeds the density difference induced flux, but increases rapidly for ratios of the seepage flux over the density flux falling below 1. The heterogeneous density distribution then results in a decrease in freshwater lens thickness and, correspondingly, a decrease in fresh water availability. We also consider time-variant, oscillatory boundary conditions, and show that for heterogeneous density distributions the interface approaches its equilibrium position faster than for a corresponding situation with a homogeneous density distribution, indicating a higher vulnerability for changing boundary conditions. We also demonstrate that heterogeneous density distributions have limited effect on the amplitude of the interface oscillations. Analytical results obtained with the simplified model are validated using the numerical code SUTRA, which solves the full model for a numerical grid.

Strain rate and temperature‐dependent shear fracture mechanism of high‐energy propellant/liner interface zone

AbstractThe shear fracture of the high‐energy propellant/liner interface zone occurs in many application cases of solid rocket motors (SRMs). The shear fracture experiment development is thus a crucial issue. Here we aim to study the shear fracture mechanism of the interface zone under varying strain rates and temperatures. Shear experiments are carried out using self‐made specimens containing prefabricated cracks. Force‐displacement curves, experimental images, and fracture surface topographies are obtained at different strain rates and temperatures. The strain field of the specimen surface is analyzed using the digital image correlation (DIC) method. Additionally, the fracture surface topographies are analyzed using ImageJ software. The results show that the shear mechanical properties of the interface zone are strongly dependent on strain rates and temperatures. Specifically, the shear fracture strength and failure displacement exhibit a decrease with increasing temperature and an increase with increasing strain rate. The DIC analysis shows that the fracture strain of the interface zone typically ranges from 0.4 to 0.6. The analysis of the fracture surface topographies reveals that the shear fracture modes are predominantly mixed fractures, including propellant/liner interface fractures and propellant cohesive fractures. Since the propellant/liner interface is more sensitive to strain rate and the propellant is more sensitive to temperature, the propellant/liner interface fracture ratio increases from 1.99 % to 60.26 % with decreasing strain rate and temperature. The results show that the experimental method can effectively be used to study the shear fracture mechanism of the high‐energy propellant/liner interface zone.

Interface and mixing zone between soil waters arising from upward and downward seepage - Part I: Homogeneous total density

Thin water lenses floating on top of the main groundwater body are important for many natural and agricultural systems, owing to their different properties in terms of chemical composition or density compared to the surrounding groundwater. In settings with upward seeping groundwater, lenses may form that have thicknesses ranging from tens of centimeters to a few meters, making them prone to changing conditions in the short (seasonal) or long term (climate change). Knowing their thickness, shape, movement and mixing zone width may help in managing these lenses.In a series of two papers, we present a mathematical description of the flow of water and transport of solute in a 2D cross-section between two parallel outflow faces and compare a simplified model to a complete model as described by the numerical code SUTRA. In this first paper of the series, we consider situations with a homogeneous density distribution. In the simplified model we employ the sharp interface approximation to obtain an expression for the stream function, the interface between the two types of water and the corresponding maximum lens thickness in steady state in the domain considered. This steady state description is used for travel time analyses and forms the basis for the transient analyses. For a typical example of oscillatory (e.g. seasonal) fluctuations in boundary conditions, we obtain expressions of the movement of the interface midway between two outflow faces by separating the problem into two timescales using the interface motion equation. This analysis provides insight into the importance of parameters on the vulnerability of water lenses under changing conditions, and may easily be extended to situations with abrupt or gradual changes in boundary conditions reflecting changes in land use or climate, respectively. Finally, we derive an analytical approximation of the mixing zone midway between the drains for steady state solutions, stepping away from the sharp interface approach. For a variety of examples, we validate the obtained expressions of the simplified mathematical model against the numerical model code SUTRA, which solves the fluid and solute mass balances explicitly.

Improved high temperature energy storage density and efficiency of polyimide nanocomposites via hindering charge and molecular motions

Electric vehicles and renewable energy consumption have huge demands for high-performance polymer dielectric capacitors. However, the resistivity and breakdown strength of existing polymer dielectrics deteriorate significantly at high temperatures, reducing the energy storage density and charge-discharge efficiency of capacitors below service requirements. The charge transport and molecular chain motion characteristics in linear polymers determine their conductivity, breakdown, and energy storage properties, but the quantitative relationship between them is not clear. An in-situ polymerization method was used to prepare polyimide/Al2O3 nanocomposites (PI/Al2O3 PNCs). Experimental results show that the resistivity, breakdown strength, energy storage density, and charge-discharge efficiency of PNCs increase initially and then decrease with increasing doping content, peaking at 3 wt%. The discharged energy density of PI/Al2O3-3 wt% PNCs at 180°C is 207.52 % higher than pure PI. A conductance-breakdown-energy storage co-simulation model based on charge transport and molecular chain displacement was used to simulate the voltage-current, breakdown, and energy storage characteristics of PNCs. The simulation results are consistent with the experiments. Comparative studies between simulation and experiments show that the independent interface zone between nanofillers and PI hinders charge transport and molecular chain movement, reducing electric field distortion and molecular chain spacing, thereby improving high-temperature breakdown and energy storage performance of PNCs.

Near pixel-level characterisation of microfibres in 3D-printed cementitious composites and migration mechanisms using a novel iterative method

Microfibre reinforcement is widely used for additively manufactured composites, however, it remains a challenging task to resolve the 3D distribution of microfibres in the matrix with low contrast and resolution for image analysis. To address this challenge, we propose a novel iterative destruction–filtering–repairing (DFR) image processing method, and take glass microfibre-embedded extrusion-moulded cementitious filaments (EMCFs) as an example for 3D structural analysis with X-ray computed tomography. Results show that the DFR method enables near pixel-level microfibre diagnosis with high accuracy beyond the ordinary image processing method. The glass microfibres are unevenly distributed in the EMCFs and their orientations are different between the filament body and the interfacial zone, uncovering the mechanisms of extrusion-affected material migration, collision, and redistribution. Our findings make a breakthrough in image analysis with limited resolution and contrast, providing a broad path towards better understanding the microstructure of 3D printed fibre-reinforcement composites.

The influence of adjustable ring-mode laser on the formation of intermetallic compounds and mechanical properties of ultra-thin Al-Cu lap welded joints

Aluminum-copper dissimilar welding is a highly demanded connection process; however, welding defects and the excessive growth of intermetallic compounds (IMCs) cause pose challenges for its application. This study uses an adjustable ring-mode (ARM) laser technology to achieve lap welding of ultra-thin Al-Cu plates. Lap-welding experiments were conducted using three laser modes—fixed core power, fixed ring power, and varying welding speed—to investigate the evolution of material mixing, intermetallic compound distribution, and joint strength under different modes. Our results indicate that the high energy density of the core laser is beneficial for increasing the penetration depths of joints, whereas the large action area of the ring laser is beneficial for improving the stabilities of melt pools. The joint action of the adjustable ring-mode (ARM) laser increased the melting width and depth of the joint, and the mixing of Al and Cu was controlled in the Al-Cu mixed zone at the upper part of the weld, to limit element mixing in the Cu-rich zone of the weld interface and suppress the distribution of intermetallic compounds. In addition, the ring laser induced the aluminum in the upper part of the molten pool to invade from both sides of the interface to the bottom, forming a certain Al invasion depth. This limited the accumulation of intermetallic compounds at the interface, optimized the path of shear fracture propagation, and improved the shear strength of the joint. This study provides a research basis for further exploring the material flow mechanism and optimizing the intermetallic compound distribution during the Al-Cu adjustable ring-mode (ARM) laser dissimilar welding process.

Interfacial characterization and bonding mechanism of W/ODS-316 L steel multi-material structure fabricated by laser powder bed fusion

Interfacial characterization and bonding mechanism of W/ODS-316 L steel multi-material structure fabricated by laser powder bed fusion

Physicochemical Properties of (La,Sr)CoO3 Thick Films on Fe-25Cr Steel under Exposure to SOFC Cathode Operating Conditions.

La0.6Sr0.4CoO3 (LSC) coatings with a thickness of 50-100 µm were deposited on Fe-25Cr ferritic stainless steel (DIN 50049) via screen printing. The required suspension had been prepared using fine LSC powders synthesised using EDTA gel processes. In its bulk form, the LSC consisted entirely of the rhombohedral phase with space group R-3c, and it exhibited high electrical conductivity (~144 S·cm-1). LSC-coated steel was oxidised in air at 1073 K, i.e., under conditions corresponding to SOFC cathode operation, for times of up to 144 h. The in situ electrical resistance of the steel/La0.6Sr0.4CoO3 layered system during oxidation was measured. The products formed on the samples after the oxidation reaction resulting from exposure to the corrosive medium were investigated using XRD, SEM-EDS, and TEM-SAD. The microstructural, nanostructural, phase, and chemical analysis of films was performed with a focus on the film/substrate interface. It was determined that the LSC coating interacts with the oxidised steel in the applied conditions, and a multi-layer interfacial zone is formed. Detailed TEM-SAD observations indicated the formation of a main layer consisting of SrCrO4, which was the reaction product of (La,Sr)CoO3, and the Cr2O3 scale formed on the metal surface. The formation of the SrCrO4 phase resulted in improved electrical conductivity of the investigated metal/ceramics layered composite material, as demonstrated by the low area-specific resistance values of 5 mΩ·cm2, thus making it potentially useful as a SOFC interconnect material operating at the tested temperature. In addition, the evaporation rate of chromium measured for the uncoated steel and the steel/La0.6Sr0.4CoO3 layered system likewise indicates that the coating is capable of acting as an effective barrier against the formation of volatile compounds of chromium.

Multiphase-field analysis of the intermetallic compounds formation & evolution in friction stir welding of dissimilar Al/Mg alloys

It is essential to understand the formation and evolution mechanism of intermetallic compounds (IMCs) in friction stir welding (FSW) of dissimilar Al/Mg alloys to mitigate the deleterious effect of hard and brittle IMCs on the performance of dissimilar joints. To this end, a multiphase-field model with input variables of both temperature and strain rate is developed to study the whole IMCs formation and growth process at the Al/Mg bonding interface in weld nugget zone. The effects of diffusion, elastic deformation, and large plastic deformation on the generation and growth of IMCs are considered. The numerical simulation results indicate that due to the influence of high dislocation density, the higher diffusion coefficient of the Mg matrix leads to the nucleation of Al12Mg17 first. When IMCs grow into layers, the higher diffusion coefficient of Al3Mg2 leads to a faster growth rate of Al3Mg2 than that of Al12Mg17. The elastic energy caused by lattice mismatch between IMCs and matrix plays an inhibitory role in the growth of IMCs. Large plastic deformation in FSW causes an increase in both the stored energy which promotes the IMCs growth and the dislocation density which intensifies the diffusion process, causing IMCs to form at the interface in a short time. With the model, the IMCs evolution from generation to growth is quantitatively analyzed. The predicted thickness of IMCs matches well with the experimental measurements.

Upward migration of the shallow gas enhances the production behavior from the vertical heterogeneous hydrate-bearing marine sediments

Low gas production rates and insufficient gas yield hinder the large-scale production from natural gas hydrates; a joint production of gas hydrate and its underlying shallow gas is expected to address this limitation. This study focuses on the interaction between heterogeneous hydrate reservoirs and the upward migration of the shallow gas. The results indicated a 38.4 % increase in production efficiency with the assistance of the shallow gas. Specially, the melt water generated from extensive hydrate decomposition could potentially induce a lateral migration of the shallow gas at the interfacial zones of the heterogeneous reservoirs. Further investigation revealed that a lower production pressure would help the release of the shallow gas as well as the hydrate decomposition, thereby contributing to a 64.55 % shorter t90. A faster depressurization rate could facilitate the temperature recovery by intensifying the lateral movement of the shallow gas in the junction layer. Consequently, a proper control of the upward channeling of the shallow gas was suggested in the field test for a successive and secure gas production. Our results could be of help in elucidating the interlayer interference mechanisms and the selection of the depressurization strategy for a better recovery efficiency from the multi-gas source reservoirs.

Synergistic solid–liquid composite and rapid solidification preparation of aluminum-clad steel wires

Solid-liquid composites and rapid solidification were synergistically employed to improve the interfacial-bonding and mechanical properties of prepared aluminum-clad steel wires. The effects of the process parameters on the performance of the wires were studied. The experimental results showed that good metallurgical interfaces can be prepared because of the synergistic strengthening effects between the solid–liquid composite and rapid solidification. The interfacial diffusion zone composed of FeAl3 and Fe2Al5 increased the bonding strength of the wires by 13 % compared with that of wires prepared by using the rolling process. The equiaxed fine crystal tissue morphology of the cladding aluminum and twin crystal organization resulted in good mechanical properties. Compared with LB35 and LB40, the conductivity and tensile strength were increased by 14 % and 22 %, respectively.

Interfacial cohesion model of ultra‐high performance concrete wet joints under the influence of multiple factors

AbstractThe interfacial cohesion between precast normal concrete (NC) and cast‐in‐place ultra‐high performance concrete (UHPC) is an important index to evaluate their interfacial bond strength, which is of great importance for the application of UHPC as a connection material for precast structural bridges. Interfacial cohesion is related to several influencing factors. However, there needs to be more research on the interrelationship model between multiple influencing factors and interfacial cohesion. This study took the UHPC wet joint in a precast concrete structure as the object. First, the relationship between the interface cohesion of UHPC wet joint and substrate strength, UHPC age, interfacial roughness, interfacial moisture content, and curing method was studied; The result shows that the key factors affecting interfacial cohesion include UHPC age, interface roughness, and substrate strength, with interfacial moisture content potentially playing a secondary role. Second, the failure types of the interface zone surface by using digital image correlation (DIC) are divided into three categories. Finally, the quantitative mathematical model of interfacial cohesion under the coupling effect of multiple factors was established based on the above four factors. The model is in good agreement with the experimental data.

Mechanical, microstructural, and thermal characterization of geopolymer composites with nano‐alumina particles and micro steel fibers

AbstractCement production is responsible for 5%–7% of global CO2 emissions, highlighting the need for sustainable alternatives like geopolymer composite (GCOMP) to meet the growing demand for concrete. This study investigates the mechanical, microstructural, and thermal properties of GCOMP by incorporating nano‐alumina (n‐alumina) and MSF (MSF). The n‐alumina content was varied at 1%, 2%, and 3% by weight of the mix, while the MSF content remained fixed at 0.5% by weight. Thermal characterization was conducted up to 800°C. The performance of GCOMP blends with n‐alumina was compared to a control blend consisting of only 0.5% MSF. Various mechanical properties were evaluated for all GCOMP blends. Microstructural and mineralogical characteristics were analyzed using scanning electron microscopy (SEM), X‐ray diffraction (XRD), and Fourier‐transform infrared spectroscopy (FTIR). Thermogravimetric and differential thermal analysis were performed up to 800°C for the thermal analysis of the GCOMP mix. The results indicate that the optimal mechanical properties were achieved with 2% n‐alumina (compressive and flexural strength increased by 35.65% and 77.7%, respectively). Additionally, the incorporation of n‐alumina improves the interfacial zones and results in a denser structure. GCOMP mortars portrayed a mass loss between 25°C and 250°C, with a marginal mass loss occurring between 250°C and 715°C. No mass loss was observed between 715°C and 800°C. The MSF‐reinforced GCOMP mortars experienced an ultimate mass loss of approximately 12%, with the MSF showing negligible influence. The addition of n‐alumina particles to MSF‐reinforced GCOMP resulted in the development of stronger samples characterized by the presence of C–S–H, calcium aluminate oxide hydroxide, and quartz.

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Molecular features of uranium-binding natural organic matter in a riparian wetland determined by ultrahigh resolution mass spectrometry

Tims Branch riparian wetland located in South Carolina, USA has immobilized 94 % of the U released >50 years ago from a nuclear fuel fabrication facility. Sediment organic matter (OM) has been shown to play an important role in immobilizing U. Yet, uranium-OM-mineral interactions at the molecular scale have never been investigated at ambient concentrations. The objectives of this study were to extract, purify, and concentrate U-bound sediment OM along the stream water pathway and perform molecular characterization using Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). Out of 9614 identified formulas, 715 contained U. These U-containing formulas were enriched with Fe, N, and/or S compared to the total OM. Lignin-like and protein-like molecules accounted for 40 % and 19 % of the U-containing formulas, respectively. Phosphorus-containing formulas were found to exert an insignificant influence on complexing U. U-containing formulas in the ‘mobile’ (groundwater extractable) OM fraction had lower (reduced) nominal oxidation states of carbon (NOSC); and less aromatic moieties than OM recovered from the ‘immobile’ (sodium pyrophosphate extractable) OM fraction. U-containing formulas in the redox interfacial zones (stream banks) compared to those in nearby up-slope zones tended to have smaller molecular weights; lower NOSC; higher contents of COO and/or CONO functional groups; and higher abundance of Fe-containing formulas. Fe was present in 38 % of the U-containing formulas but only 20 % of the total OM formulas. It is postulated that Fe played an important role in stabilizing the structure of sedimentary OM, especially U-containing compounds. The identification for the first time of hundreds of Fe-U-OM formulas demonstrates the complexity of such system is much greater than commonly believed and numerically predicting U binding behavior in OM-rich systems may require greater use of statistical or artificial intelligence approaches rather than deterministic approaches limited to measuring metal complexation with well-defined individual analogue organic ligands.

Long-term performance of magnesium phosphate cement concrete prepared in the winter

Previous studies have established the strength development of magnesium ammonium phosphate cement (MAPC) concrete and magnesium potassium phosphate cement (MKPC) concrete at sub-zero temperatures. However, the long-term performance of these magnesium phosphate cement (MPC) concrete, prepared at low temperatures and exposed to complex environmental effects of cold regions, remains underexplored. This study monitored the mechanical properties and durability of MAPC concrete at different ages for 520 d, which fully demonstrated the feasibility of MAPC concrete for winter construction in cold regions. At the age of 520 d, MAPC concrete had a compressive strength of over 65 MPa and excellent resistance to chloride ion penetration with a measured charge of 129.1 C, and could endure more than 250 rapid freeze-thaw cycles. In contrast, MKPC concrete exhibited significant disadvantages in terms of freeze-thaw resistance during natural freeze-thaw cycles. No expansive substances or damage were found in MKPC concrete that was prepared at low temperatures and subsequently experienced temperature increases along with accelerated hydration. The relatively poor freeze-thaw resistance of MKPC concrete could be attributed to a combination of factors including larger capillary size and volume, reduced air content, greater air-void spacing factor, wider and weaker interface zone between cement mortar and coarse aggregate.

Effect of friction stir welding with different heat input on microstructure evolution, mechanical properties and deformation behavior of twin-induced plasticity steel

The effect of friction stir welding (FSW) with different heat input on microstructure evolution, mechanical properties and deformation behavior of twin-induced plasticity steel was investigated in this paper. The results show that compared to the basal material (BM), the grain size in the stir zone (SZ) of FSW joint with low heat input was refined, and a large amount of deformation twins was formed. The grain was refined and numerous dislocations were formed in the stir zone-heat affected zone (SZ-HAZ) interface. In the FSW joint with high heat input, the grain size in SZ increased, while no deformation twins were observed. A large number of fine equiaxed grains were formed in the SZ-HAZ interface, while the grains in HAZ coarsened. Compared to the BM, the tensile strength and yield strength of low heat input joint increased to 1108 MPa and 597 MPa, respectively, while the elongation decreased to 50.4%, resulting in a strength-elongation product of 92% of BM. The joint with high heat input experienced a decrease in tensile strength, yield strength, and elongation to 806 MPa, 465 MPa, and 22.8%, respectively, with a strength-elongation product of only 30% of BM. During the tensile deformation process, the plastic deformation in the low heat input joint was mainly concentrated in BM, followed by HAZ, while SZ exhibited minimum plastic deformation, and the tensile fracture occurred at zone between SZ and HAZ. In the high heat input joint, the maximum plastic deformation occurred in the SZ, with lower plastic deformation in BM and HAZ, and finally fractured at the SZ. The constrain effect of different micro-zones and hindrance effect of dislocations and fine grains were main responsible for the deformation behavior of low and high heat input joints.

Forearc faults in northern Cascadia do not accommodate elastic strain driven by the megathrust seismic cycle

We employ numerical models to explore the connection between subduction zone coupling or megathrust rupture and upper plate faults in the northern Cascadia forearc. Active forearc faults north of the Olympic Peninsula exhibit similar characteristics: west-northwest strike, oblique right-lateral slip senses, and low slip rates (<1 mm/yr), but a potential to generate large (M ~ 7) earthquakes. Previous hypotheses suggest that stress in the upper plate due to interseismic coupling or coseismic rupture along the subduction zone interface could drive permanent forearc strain. To test these hypotheses, we used a 3D boundary element method model to predict slip on the LRDM if interseismic coupling or coeseismic rupture cause deformation. Our model predicts reverse left-lateral slip if the strain results solely from subduction zone coupling, or normal right-lateral slip if these faults accommodate strain during a megathrust rupture. These results contradict the observed fault kinematics. Additionally, if we use our model to mimic strain partitioning, where only the strain from the strike-slip component of subduction zone coupling is accommodated in the forearc, our results are also inconsistent observed fault kinematics. These models challenge the hypothesis that subduction zone coupling or coseismic rupture are the primary driver of permanent forearc deformation in northern Cascadia.

Microanalysis of behavior characteristics for asphalt binders on different mineral surfaces based on MD and SEM

To investigate the influence of different minerals on the behavior characteristics of asphalt binders at micro scale, molecular dynamics (MD) and scanning electron microscopy (SEM) were combined to study the interaction of asphalt binders and different mineral surfaces. Firstly, commonly used aggregates were analyzed by X-ray diffraction (XRD), and the main mineral categories were obtained, including quartz, albite, biotite and calcite. Secondly, the asphalt-mineral micro models were established by combining the reasonable asphalt micro model and mineral micro model, and the interface behavior characteristics were analyzed by MD simulation. Finally, the interface structure of asphalt and minerals was observed through SEM testing, which intuitively revealed the behavior characteristics of asphalt on different mineral surfaces. The results show that the relative concentration distribution of asphalt binders at the asphalt-mineral interface is relatively high, and it can be affected by mineral category, surface structure state and asphalt type. The transition zone of biotite, albite and asphalt interface is relatively wide, which means that the influence of biotite, albite and asphalt diffusion characteristics is relatively obvious, and the interface interaction ability is relatively strong. The study reveals the behavior characteristics of asphalt binders on different mineral surfaces, and provides a research basis for exploring the structural stability of asphalt-aggregate interface.

Wettability and reactivity of liquid aluminium and highly deformed steel

The high-temperature liquid Al - solid S355J2N steel interaction was studied using a modified wettability test. A sessile drop method with a capillary purification procedure was employed for the first time, involving non-contact aluminium isothermal heating followed by the dropping of a pure liquid Al drop onto the severely deformed steel substrate and isothermal contact heating of Al with steel. The calculated contact angles and wetting kinetics curves demonstrated a good spreading and wetting of the investigated system. Scanning electron microscopy investigations played an important role in interpretation of the microstructural characteristics of the specimen, especially those located at the drop/substrate interface. The electron backscattered diffraction measurements allowed to characterize the microstructure of the interface zone to obtain more detailed information about the grain size, type of the intermetallic phases: θ-Al13Fe4, Fe2Al5, FCC Al and ferrite and their distribution in the neighborhood of the interface zone. These intermetallics were also confirmed via transmission electron microscopy studies coupled with energy-dispersive X-ray spectroscopy analysis of the drop/substrate interface. Research findings provide valuable insights into the liquid Al and steel interaction during the explosive welding process, where the local melting of metal takes place at the interface of colliding plates, strongly deformed due to the collision.