Whispering gallery mode optical microresonators represent a promising avenue for realizing optical analogs of coherent light–atom interactions, circumventing experimental complexities. All-optical analogs of Autler–Townes splitting have been widely demonstrated, harnessing coupled optical microresonators, also known as photonic molecules, wherein the strong coupling between resonant fields enables energy level splitting. Here, we report the characterizations of Autler–Townes splitting in waveguide-coupled microring dimers featuring mismatched sizes. By exploiting backscattering-induced coupling via Rayleigh and Mie scatterers in individual rings, high-order Autler–Townes splitting has been realized, yielding supermode hybridization in a multi-level system. Upon resonance detuning using an integrated phase shifter, intra-cavity coupling-induced splitting becomes almost indistinguishable at the zero-detuning point where the strong inter-cavity coupling counteracts the imbalance of backscattering strengths in individual rings. Through demonstrations on the maturing silicon photonics platform, our findings establish a framework of electrically tunable photonic molecules for coupling-mediated Autler–Townes splitting, offering promising prospects for on-chip signal generation and processing across classical and quantum regimes.