Intense Electron Research Articles

G-Value of Hydrogen Peroxide Generated by Water Radiolysis with Irradiation of Pulsed Intense Relativistic Electron Beam

G-Value of Hydrogen Peroxide Generated by Water Radiolysis with Irradiation of Pulsed Intense Relativistic Electron Beam

The anomalous state of Uranus’s magnetosphere during the Voyager 2 flyby

AbstractThe Voyager 2 flyby of Uranus in 1986 revealed an unusually oblique and off-centred magnetic field. This single in situ measurement has been the basis of our interpretation of Uranus’s magnetosphere as the canonical extreme magnetosphere of the solar system; with inexplicably intense electron radiation belts and a severely plasma-depleted magnetosphere. However, the role of external forcing by the solar wind has rarely been considered in explaining these observations. Here we revisit the Voyager 2 dataset to show that Voyager 2 observed Uranus’s magnetosphere in an anomalous, compressed state that we estimate to be present less than 5% of the time. If the spacecraft had arrived only a few days earlier, the upstream solar wind dynamic pressure would have been ~20 times lower, resulting in a dramatically different magnetospheric configuration. We postulate that such a compression of the magnetosphere could increase energetic electron fluxes within the radiation belts and empty the magnetosphere of its plasma temporarily. Therefore, the interpretation of Uranus’s magnetosphere as being extreme may simply be a product of a flyby that occurred under extreme upstream solar wind conditions.

The effect of dilution on the energy dissipation in water interstellar ice analogues

Context. Interstellar ices and their energetic processing play an important role in advancing the chemical complexity in space. Interstellar ices covering dust grains are intrinsically mixed, and it is assumed that physicochemical changes induced by energetic processing – triggered by photons, electrons, and ions – strongly depend on the content of the ice. Yet, the modelling of these complex mixed systems in experiments and theory is complicated. Aims. In this paper, we investigate the effect of infrared irradiation on a series of different molecules mixed with porous amorphous solid water (pASW) to study the release of vibrational energy in the hydrogen-bonding network of water as a function of mixing ratio and ice content. Particularly, we select mixtures of 20:1 H2O:X and 5:1 H2O:X with X=CO2, NH3, or CH4. Methods. Infrared radiation was supplied by the intense and tunable free electron laser (FEL) 2 at the HFML-FELIX facility. We monitored the structural changes in the interstellar ice analogue after resonant infrared excitation using Fourier-transform reflection absorption infrared (FT-RAIR) spectroscopy. Results. We observed that on-resonance irradiation at the OH-stretching vibration of pASW results in quantitatively identical changes compared to pure pASW for all investigated mixtures. The structural changes we observed closely resemble the previously reported local reordering. The 5:1 mixtures show weaker changes compared to pure pASW, with a decrease in strength from NH3 to CO2. Conclusions. Since the hydrogen-bonding network of pASW restructures similarly upon FEL irradiation, regardless of the mixing component, treating ice layers in models that simulate energy dissipation in the hydrogen-bonding network as pure H2O ice layers can be a justified approximation. Hence, complex systems might not always be necessary to describe the infrared energetic processing of ices.

Catalytic behavior, electronic structure and spectroscopic (FT-IR, Raman, UV–vis) properties for the new ionic liquid imidazolium hydrogen sulfate

Catalytic performance, chemical reactivity, vibrational modes and electronic transitions of the ion pair [H–Im]+[HSO4]– were investigated in the current paper. Hence, a combined experimental (Hammett acidity function, infrared, Raman and ultraviolet-visible spectroscopies) and theoretical (molecular electrostatic potential surface, reduced density gradient, frontier molecular orbital analysis, quantum theory of atoms in molecules, net atomic charges, global and local reactivity descriptors) study was conducted. In terms of the catalytic performance, the acetic acid esterification with butanol was evaluated. Important kinetic (rate constant, activation energy, pre-exponential factor) and thermodynamic (enthalpy, entropy, Gibbs free energy barrier) factors for ester production as a function of the temperature and catalyst loading have been determined. Results revealed intensive electron density distribution in [H–Im]+[HSO4]– due to chemical interactions between the cationic and anionic moieties. These bonds were established as electrostatic in nature. The pronounced charge transfers within [H–Im]+[HSO4]– managed the title compound acidity (H0) and its catalytic behavior towards butyl acetate synthesis. Using the thermodynamic and kinetic measurements, a mechanism for acetic acid esterification with butanol in the presence of imidazolium hydrogen sulfate ionic liquid was offered.

Local Time Distribution and Activity Dependence of Extreme Electron Densities in the Auroral D‐Region as an Image of Energy‐Dependent Energetic Electron Precipitation

AbstractStudying the episodes with the most elevated electron density (Ne) values provides valuable information about spatial distribution and drivers of intense energetic electron (EE) precipitation, which has important space weather implications. By combining EISCAT‐Tromso UHF observations in different modes made in 2001–2021, we survey Ne occurrences and study statistical properties of EE precipitation, producing the highest 10% and 1% of Ne values at the altitudes between 100 and 75 km (corresponding to EE energies of ∼20–∼200 keV). We found that the highest Ne values occur in the nightside‐morning local time sector at the altitudes 90–100 km and in the morning‐noon sector at low altitudes (75–85 km). Although this bimodal pattern could partly be contributed by the suppressed Ne in the dark ionosphere, by analyzing measurements in the twilight conditions at all MLTs together with published patterns of EE precipitation, we argue that a dominance of pre‐noon maximum at low altitudes reflects the enhanced precipitation of >100 keV electrons in this local time sector. At all altitudes (especially below 90 km), the appearance of the highest Ne values favors enhanced auroral activity and shows a strong correlation with fast solar wind (V > 550 km/s) events. These properties mimic the well‐known driving characteristics of energetic electrons. From the correlation of Ne with integral magnetic activity indexes we found that the memory of preceding magnetic activity increases with decreasing altitude, reaching roughly one day at H = 75 km. We discuss the advantages of exploring Ne data at specific altitudes (compared to direct measurements of EE precipitation) to investigate statistically the effects of specific precipitated energy components and the evolution of EE energy spectra.

Non-radiative recombination centres in InGaN/GaN nanowires revealed by statistical analysis of cathodoluminescence intensity maps and electron microscopy

The methodology of statistical analysis of cathodoluminescence (CL) intensity mappings on ensembles of several hundreds of InGaN/GaN nanowires (NWs) used to quantify non-radiative recombination centres (NRCs) was validated on InGaN/GaN NWs exhibiting spatially homogeneous cathodoluminescence at the scale of single NWs. Cathodoluminescence intensity variations obeying Poisson's statistics were assigned to the presence of randomly incorporated point defects acting as NRCs. Additionally, another type of NRCs, namely extended defects leading to spatially inhomogeneous cathodoluminescence intensity at the scale of single InGaN/GaN NWs are revealed by high resolution scanning transmission electron microscopy, geometrical phase analysis and two-beam diffraction conditions techniques. Such defects are responsible for deviations from Poisson's statistics, allowing one to achieve a rapid evaluation of the crystallographic and optical properties of several hundreds of NWs in a single cathodoluminescence intensity mapping experiment.

Outer Zone Relativistic Electron Response to Mesoscale Periodic Density Structures in the Solar Wind: Van Allen Probes Measurements

AbstractWe investigate the relativistic and the ultra‐relativistic outer radiation belt electron response to the Periodic Density Structures (PDS) in the solar wind. We have studied four intervals between 0000 UT and 1500 UT during 17 January 2013 interplanetary coronal mass ejection (ICME) sheath event following the passage of an interplanetary shock (IP) on 16 January, at 2240 UT. Earlier studies limited to geosynchronous orbit have shown that PDS induce Ultra‐Low‐Frequency (ULF) oscillations in the magnetosphere and modulate energetic electron intensities. Our study shows for the first time, using pitch angle resolved electron intensity measurements, that PDS modulate relativistic and ultra‐relativistic electron intensities in the heart of the radiation belts (L ≈ 4). We find that the modulation of electron intensities occur at frequencies close to those of interplanetary PDS. Furthermore, electron intensity modulations occur over a wide range of energy (≈200 keV to 4 MeV) and pitch angles (≈20–120°). This event study suggests that relativistic and ultra‐relativistic electron intensity modulations driven by PDS may be largely energy and pitch angle independent.

Electron Acceleration via Secondary Reconnection in the Separatrix Region of Magnetopause Reconnection

AbstractMagnetic reconnection is a fundamental process known to play a crucial role in electron acceleration and heating, however, the mechanism of electron energization during reconnection is still not fully understood. This study introduces a novel electron acceleration mechanism in which electrons can be accelerated by secondary reconnection in the separatrix region. The secondary reconnection occurs in a thin current sheet resulted from the shear of the out‐of‐plane Hall magnetic fields of the primary magnetopause reconnection. It results in the intense electron energy fluxes toward the primary X‐line. This mechanism will likely be an important piece in the puzzle of particle acceleration by reconnection.

Complex electron-ion-plasma surface modification of high-alloy stainless steel

The work is devoted to identification and analysis of patterns of change in the elemental and phase composition, defective substructure, mecha­nical (microhardness) and tribological (wear resistance and friction coefficient) properties of stainless high-chromium steel subjected to complex processing, combining vacuum irradiation of the samples surface layer with an intense pulsed electron beam of submillisecond exposure duration and subsequent nitriding under electron-ionic heating conditions. High-chromium steel AISI 310S, which in the initial state is a polycrystalline aggregate based on γ-iron, was used as the research material. Pulsed electron beam treatment of steel was carried out on a “SOLO” installation equipped with an electron source with a plasma cathode based on a low-pressure pulsed arc discharge with grid stabilization of the cathode plasma boundary and an open anode plasma boundary. Steel nitriding was carried out on a “TRIO” installation with a chamber size of 600×600×600 mm, equipped with a switching unit to implement the electron-ionic processing mode. Nitriding was carried out at 723, 793, and 873 K temperatures for 1, 3 and 5 h. It was found that electron-ionic nitriding of the samples pre-irradiated with an electron beam (10 J/cm2, 200 μs, 3 pulses at 723 and 793 K for 3 h) is accompanied by the formation of a ceramic layer containing only iron and chromium nitrides. The highest values of steel wear resistance after electron-ionic nitriding, exceeding the wear resistance of the initial steel by more than 700 times, are observed at nitriding parameters of 793 K, 3 h.

Regulating Aggregation-Induced Emission Luminogen for Multimodal Imaging-Navigated Synergistic Therapy Involving Anti-Angiogenesis.

As a new avenue for cancer research, phototheranostics has shown inexhaustible and vigorous vitality as it permits real-time diagnosis and concurrent in situ therapy upon non-invasive light-initiation. However, construction of an advanced material, allowing prominent phototheranostic outputs and synchronously surmounting the inherent deficiency of phototheranostics, would be an appealing yet significantly challenging task. Herein, an aggregation-induced emission (AIE)-active luminogen (namely DBD-TM) featured by intensive electron donor-acceptor strength and twisted architecture with finely modulated intramolecular motion, is tactfully designed and prepared. DBD-TM simultaneously possessed fluorescence emission in the second near-infrared (NIR-II) region and high-efficiency photothermal conversion. By integrating DBD-TM with anti-angiogenic agent sorafenib, a versatile nanomaterial is smoothly fabricated and utilized for trimodal imaging-navigated synergistic therapy involving photothermal therapy and anti-angiogenesis toward cancer. This advanced approach is capable of affording accurate tumor diagnosis, complete tumor elimination, and largely restrained tumor recurrence, evidently denoting a prominent theranostic formula beyond phototheranostics. This study will offer a blueprint for exploiting a new generation of cancer theranostics.

Electronic interaction between sub-nanometric Ru entity and TiO2 support regulates the hydrogenation chemistry for selective C-O bond cleavage

Selective C-O bond cleavage without ring saturation is the pillar pursuit in the hydrotreating process for lignin valorization/depolymerization since it avoids the consumption of excessive hydrogen. In this work, the sub-nanometric cluster and nanometric particle of Ru were supported on TiO2 for the hydrogenolysis of C-O bond in aromatic ether. The experimental and theoretical results reveal that, in the catalyst of larger Ru nanoparticles, less electron transfer occurs from individual Ru atom to TiO2, making the Ru-related domains retain the nature of bulky Ru for deep hydrogenation. Sub-nanometric Ru cluster shows more intense electron transfer for individual Ru atom, leading to a stronger modification to Ru domain by TiO2. Such electronic hybridization makes Ru gain the catalytic property of TiO2 to attenuate the activation of aromatic ring, inhibiting ring saturation with maintained C-O cleavage activity. This work implies that further decrease of Ru entity size to single-atom level may achieve the complete inhibition of ring saturation.

Quantifying Covalency and Environmental Effects in RASSCF-Simulated O K-Edge XANES of Uranyl.

A RASSCF approach to simulate the O K-edge XANES spectra of uranyl is employed, utilizing three models that progressively improve the representation of the local crystal environment. Simulations successfully reproduce the observed three-peak profile of the experimental spectrum and confirm peak assignments made by Denning. The [UO2Cl4]2- model offers the best agreement with experiment, with peak positions (to within 1 eV) and relative peak separations accurately reproduced. Establishing a direct link between a specific electronic transition and peak intensity is complicated, as a large number of possible transitions can contribute to the overall peak profile. Furthermore, a relationship between oxygen character in the antibonding orbital and the strength of the transition breaks down when using a variety of orbital composition approaches at larger excitation energy. Covalency analysis of the U-O bond in both the ground- and excited-state reveals a dependence on the crystal environment. Orbital composition analysis reveals an underestimation of the uranium contribution to ground-state bonding orbitals when probing O K-edge core-excited states, regardless of the uranyl model employed. However, improving the environmental model provides core-excited state electronic structures that are better representative of that of the ground-state, validating their use in the determination of covalency and bonding.

MeV Electron Precipitation During Radiation Belt Dropouts

AbstractTo gain deeper insights into radiation belt loss into the atmosphere, a statistical study of MeV electron precipitation during radiation belt dropout events is undertaken. During these events, electron intensities often drop by an order of magnitude or more within just a few hours. For this study, dropouts are defined as a decrease by at least a factor of five in less than 8 hours. Van Allen probe measurements are employed to identify dropouts across various parameters, complemented by precipitation data from the CALorimetric Electron Telescope instrument on the International Space Station. A temporal analysis unveils a notable increase in precipitation occurrence and intensity during dropout onset, correlating with the decline of SYM‐H, the north‐south component of the interplanetary magnetic field, and the peak of the solar wind dynamic pressure. Moreover, dropout occurrences show correlations with the solar cycle, exhibiting maxima at the spring and autumn equinoxes. This increase during equinoxes reflects the correlation between equinoxes and the SYM‐H index, which itself exhibits a correlation with precipitation during dropouts. Spatial analysis reveals that dropouts with precipitation penetrate into lower L‐star regions, mostly reaching L‐star <4, while most dropouts without precipitation don't penetrate deeper than L‐star 5. This is consistent with the larger average dimensions of dropouts associated with precipitation. During dropouts, precipitation is predominantly observed in the dusk‐midnight sector, coinciding with the most intense precipitation events. The results of this study provide insight into the contribution of precipitation to radiation belt dropouts by deciphering when and where precipitation occurred.

Symmetrical vortices and laminar dust flow induced by an intense electron beam interacting with a strongly coupled dusty plasma

A strongly coupled quasi-two-dimensional dusty plasma confined electrostatically in the plasma sheath of a radio frequency (RF) plasma is irradiated by a collimated and mono-energetic pulsed electron beam (e-beam) with an energy of 13 keV and a high peak current per pulse of 30 mA. A stream of rapidly moving charged dust particles is created inside the dust crystal due to the drag force of the electrons in the e-beam. The dust flow is split into two symmetrical branches when it reaches the boundary of the round dust crystal, each following the limit of the circular confining region. This results in the formation of a double vortex flow pattern with the dust particles being transported along the irradiation direction and then aside, eventually back to the entrance position of the e-beam. The observed flow regime is laminar at all times, with the speed in the central region increasing up to 12 mm s−1 in the first 200 ms and then diminishing gradually to a steady value of about 5–6 mm s−1 during a stress relaxation time period of 360 ms. The vorticity follows a similar trend with peak values −3.8 and 3.8 s−1 and steady state values between −2.5 and 2.5 s−1 in the two symmetrical vortices. Time-resolved particle-image-velocimetry and particle-tracking-velocimetry are used to characterize the flow. Molecular dynamics simulations confirm qualitatively the experimental observations showing dust stream and double vortex formation.

Automated Sample Drift Correction for Low Intensity Electron Counted TEM Images

Automated Sample Drift Correction for Low Intensity Electron Counted TEM Images

The effects of sweet potato (Ipomoea batatas L.) extract and stevia extract on the physicochemical characteristics of effervescent granules

This study aims to determine the effects of the ratio of sweet potato extract and stevia on the physicochemical characteristics of effervescent granules. This study uses the Factorial Randomized Group Design with three repetitions. The treatment design carried out in this study consists of one factor, namely, the comparison of sweet potato extract consisting of six levels, namely, (37.5:7.5), (35:9), (32.5:11.5), (30:14), (27.5:16.5), and (25:19). Responses in this study include chemical responses, namely, water content, pH value test, total sugar content, and anthocyanin content. Physical responses include dissolving time, hygroscopicity, color intensity, and scanning electron microscope. The comparison of sweet potato extract with stevia results showed an effect on effervescent granule characteristics, namely, total sugar content, dissolving time test, hygroscopicity level, and color intensity. This includes a moisture content of 2.56%, pH value of 3.45, total sugar content of 1.61%, and anthocyanin content of 21.19 mg/g. The best physical response results are dissolving time of 39.96 s, hygroscopicity level of 0.33%, and color intensity L* 49.46, color a* 16.55, and color b* -4.21.

Enhanced through-plane thermal conductivity of graphene membranes by the interlayer microstructure manipulation: Multiscale numerical simulations and experimental verifications

Graphene, with ultrahigh in-plane thermal conductivity (IPTC), has been widely applied in the thermal dissipation of integrated circuits. However, the extremely low through-plane thermal conductivity (TPTC) of graphene limits its further application. In this work, a novel strategy was proposed to enhance the TPTC of graphene membranes (GNMs) by improving the interlayer bonding state through interlayer decoration with metal elements. Molecular dynamics simulations demonstrated that decoration with interlayer elements (Al, Ti, and Ni) enhanced the interfacial thermal conductance. This was attributed to interfacial chemical bonding through strong interfacial interactions (intensive electron localization) formed at the interface between metal and GN sheets as implied by the first principles calculations. Furthermore, the composite GNMs decorated with interlayer metal nanoparticles (Al, Ni, and Co) were prepared through co-reduction using thermal decomposition method. The corresponding TPTC was tested using time-domain thermoreflectance (TDTR) method which was much higher for the composite GNMs (175–400 W/m·K) than for pure GNM (∼140 W/m·K), and this was in consistent with the simulation results. Interlayer decoration, which enhanced the TPTC of GNMs, provides a novel and effective strategy for enhancing the overall thermal management performance of graphene-based materials in both vertical and horizontal directions.

Simultaneous Real and Momentum Space Electron Diffraction from a Fullerene Molecule.

Plane-wave electrons undergo momentum transfer as they scatter off a target in overlapping spherical waves. The transferred momentum leads to target structural information to be encoded in angle and energy differential scattering. For symmetric, periodic, or structured targets this can engender diffraction in the electron intensity both in real and momentum space. With the example of elastic scattering from a C_{60} molecule we show these simultaneous diffraction signatures. Simulated angle-momentum diffractograms can be imaged in experiments with a two-dimensional detector and an energy-tunable electron gun. The result may inspire the invention of technology to extend scopes of electron diffraction studies, open a track of electron crystallography using the momentum-differential diffraction, and motivate research about controlling the time delay between the pump laser pulse and probe electron pulse by tuning the electron impact speed in ultrafast electron diffraction experiments.

Design of a compact coaxial distributed intense relativistic electron beam focusing system

In order to achieve the objectives of compactness and miniaturization in high-power microwave systems, along with reducing system energy consumption, this paper presents a design of a compact coaxial distributed intense relativistic electron beam (IREB) focusing system based on the transit time oscillator. The design methodology integrates theoretical analysis with a 2.5-dimensional particle simulation method. The entire IREB focusing system is composed of three sets of distributed magnetic rings and front-end focusing structures. The layout of this magnetic system is optimized based on periodic permanent magnets, leading to the formation of a quasi-trapezoidal wave magnetic field configuration. This optimization reduces the required number of magnetic rings while ensuring the efficient transmission of the IREB. To prevent the breakdown of the loaded magnetic rings and to optimize the radial electric field in the diode region, an additional front-end focusing structure was added. Based on the aforementioned structural configuration, a 100% electron beam transmission rate was achieved within a 150 mm range.

Regulation of particle generation processes in a pyroelectric accelerator using geometry

The generation of electrons and X-rays using a pyroelectric accelerator is highly appealing from a practical point of view due to the potential for compact and energy-efficient devices. This study focuses on investigating the influence of accelerator geometry, particularly the position and area of the target. We have determined that a smaller target area enhances X-ray intensity and monoenergetic electron flux, while the balance between positive and negative polarity exhibits weak dependence on geometry. Altering the position of the target-collimator enables regulation of the energy of the collimated electron flow. The focal spot of the electron flow in a pyroelectric accelerator exhibits a complex longitudinal structure, as demonstrated by both experimentation and computer modelling. Furthermore, increasing the distance between the crystal and the target enhances the stability of the pyroelectric accelerator. Consequently, the combined effect of target area and its position relative to the crystal significantly influences the observed particle flux, and we propose approaches for their regulation in practical devices.