Rapid, accurate, and non-destructive acquisition of the distribution of reclaimed soil moisture information can provide data for the rapid monitoring of reclaimed soil in areas experiencing coal mining subsidence. However, the water content inversion methods based on ground penetrating radar (GPR) are mostly single-attribute analysis methods, which are easily affected by the soil structure. This paper proposes a multi-attribute joint analysis method, which can reduce the influence of complex soil structure on the prediction results. Surveys and soil sampling using GPR were performed on a subsided reclamation area in Huaibei City, Anhui Province, China. Correlation analysis of GPR attribute information and volumetric water content (VWC) showed that frequency peak (FP), average envelope amplitude (AEA), energy, instantaneous amplitude area, instantaneous frequency area, and average instantaneous frequency values were significantly related to the VWC of reclaimed soil. The applicability of different single-attribute analysis methods under the condition of reclaimed soil was compared. Results showed that the predictive effects of FP and AEA attributes were better than other attributes. Generally, the single-attribute analysis method was greatly affected by the structure of reclaimed soil, so the accuracy and reliability of this method need to be further optimized. The prediction results of the single- and multi-attribute joint analysis methods in the structure of reclaimed soil were compared and analyzed. This showed that the prediction accuracy and model reliability of the multi-attribute method are both higher than those of the single-attribute method. The multi-attribute method can overcome the problem of insufficient accuracy of water content detection of ground-seeking radar in soil with a complex structure. Finally, the multi-attribute method was used to obtain the water distribution information in the reclamation area. Results of this study provide new methods and ideas for the prediction of water content by GPR in soils with complex structure.