Inorganic Fraction Research Articles

How bone degradation, age, and collagen extraction methods affect stable isotope analysis

Stable isotope analysis from bone collagen and carbonate is a crucial tool in archaeometry for dietary and provenance studies. However, an expedient evaluation and interpretation of results have to rely on the integrity of the isotopic values, reflecting the in vivo signal of the tissue. In this context, postmortem bone breakdown can affect measurement results and add uncertainty. This study investigates the effects of bone breakdown and the use of two different extraction methods on the isotopic composition of carbon, nitrogen, and oxygen from collagen and the structural carbonate. The main goal of this study was to test the efficiency of commonly applied quality markers to identify alterations of the isotopic in vivo signal in the organic and inorganic bone fraction. Three fresh human femur diaphyses from different age groups with a known in vivo signal were degraded experimentally to simulate diagenetic processes. One batch was heated in water to induce hydrolytic breakdown; the other one was inoculated with several aerobic and anaerobic bacterial strains for biodeterioration. Furthermore, 60 long-bone samples from natural burial conditions, representing different age groups and burial times, were analyzed. The collagen extraction method proved to have a relevant effect. For bones already compromised by degradational processes, the common gelatin extraction protocol using pulverized bone and a 1 M HCl demineralization step was shown to be too harsh and damaging to the extract. Additionally, the age of the individual might play a role in the resistance of the tissue against degradational factors. The investigation of the commonly used quality criteria revealed that the C/N molar ratio is well suited to identify diagenetically modified isotopic data from collagen carbon and nitrogen. However, no valid marker could be assessed for the reliable prediction of altered δ18O values from the structural carbonate fraction, but oxygen isotopic values proved to be considerably affected by in vitro degradation.

On the separation between inorganic and organic fractions of suspended matter in a marine coastal environment

A central aspect of coastal biogeochemistry is to determine how nutrients, lithogenic and organic matter are distributed and transformed within coastal and estuarine environments. Analyses of the spatio-temporal changes of total suspended matter (TSM) concentration indicate strong and variable linkages between intertidal fringes and pelagic regions. In particular, knowledge about the organic fraction of TSM provides insight to how biogenic and lithogenic particulate matter are distributed in suspension. In our study we take advantage of a set of over 3000 in situ Loss on Ignition (LoI) data from the Southern North Sea that represent fractions of particulate organic matter (POM) relative to TSM (LoI ≡ POM:TSM). We introduce a parameterization (POM-TSM model) that distinguishes between two POM fractions incorporated in TSM. One fraction is described in association with mineral particles. The other represents a seasonally varying fresh pool of POM. The performance of the POM-TSM model is tested against data derived from MERIS/ENVISAT-TSM products of the German Bight. Our analysis of remote sensing data exhibits specific qualitative features of TSM that can be attributed to distinct coastal zones. Most interestingly, a transition zone between the Wadden Sea and seasonally stratified regions of the Southern North Sea is identified where mineral associated POM appears in concentrations comparable to those of freshly produced POM. We will discuss how this transition is indicative for a zone of effective particle interaction and sedimentation.The dimension of this transition zone varies between seasons and with location. Our proposed POM-TSM model is generic and can be calibrated against in situ data of other coastal regions.

Phosphorus Fractions and Their Transformations in Entisol

The availability of phosphorus in the soil is a factor that directly interferes with its absorption by plants. This availability can be influenced by the texture, dose of the phosphate fertilizer and the time of contact with the soil. This study aimed to quantify the organic and inorganic fractions of P accumulated in a sandy soil receiving doses of phosphorus, incubated and grown with rice. The experimental design was a completely randomized design, in a 4 × 3 factorial scheme, with four replicates, and four P doses (0, 80, 240, and 410 mg dm-3) and three evaluation times (before sowing, after harvest, and incubated). Soil samples were collected before, after incubation, and after rice harvesting, and then submitted to a chemical fractionation of P. P fractions were influenced by soil collection times. The inorganic fractions prevailed before sowing and after incubation, and the organic fractions prevailed after harvest. Phosphate fertilization favored mineralization of organic P and redistributes the inorganic and organic P fractions, between labile and non-labile compartments. The application of phosphate fertilizer in an Entisol Quartzipsamment contributes to the accumulation of inorganic fractions, especially in the most labile fractions.

Structural and Chemical Attributes of Soil Inorganic Fractions for Environmental Characterization in the Brazilian Semiarid Region

Soil structure affects plant growth factors in agroecosystems. The relationships of these factors with soil texture and chemical attributes are important to differentiate environments. The objective of this work was to evaluate the relationship of soil structural attributes with physical and chemical attributes of different soils to differentiate environments, using multivariate statistics. The research was carried out in the Terra da Esperança Settlement Project, in Governador Dix-Sept Rosado, RN, semiarid region of Brazil. Ten soil profiles were evaluated: Haplustepts in a conventional area (1CA); Haplustepts in a collective area with (2CA); Haplustepts in an agroecological area with native forest (3AGRO); Eutrustox in a native forest (4NF); Calciustolls in a conventional area of pasture (5CAP); Haplustepts in a native forest (6NF); Haplustepts in an native forest (7NF); Usticfluvents in a permanent conservation area with Licania rigida (8PPA); Haplustepts in a native forest (9MN); and Haplustepts in a collective area with Spondias spp. (10SP). Ten soil samples were collected and analyzed by horizons in volumetric rings and in soil blocks (aggregate analysis), with three replications. Structural, physical, and chemical attributes were evaluated. The data were subjected to multivariate statistical analysis, using correlation matrix, cluster analysis, and factorial analysis considering the factors as principal components. According to the factorial analysis, Factor 1 (F1) and Factor 2 (F2)—F1 consisting of clay, Ca2+, Na+, sum of bases, and base saturation (V), and F2 consisting of cation exchange capacity (CEC), total organic carbon, macroporosity, particle density, K+, and microporosity—were essential to differentiate the environments. The cluster analysis formed four groups. The structural groups showed greater similarity, denoting the relationship between source material and land use, followed by the chemical groups P, K+, CEC, Ca2+, V, and pH for the Calciustolls; the structural weighted mean diameter, geometric mean diameter, soil aggregates larger than 2 mm, plasticity index, and plasticity limit for the Eutrustox; and the physical and chemical attributes EC, Na+, Silt, macroporosity, total calculated porosity, aluminum saturation, total sand, volumetric moisture, Mg2+ and particle density for the Haplustepts and the Usticfluvents. The clay fraction presented correlation with chemical attributes (F1) for the distinction of soil classes and land uses. The soil classes presented eutrophic character (V ≥ 50%) as a function of the Na+ and Ca2+ contents, including the Eutrustox (4NF), despite its lower contents when compared to the other soil classes. This is a local peculiarity due to the climatic pattern of the Brazilian semiarid region.

Evaluation of the DGT technique for predicting uptake of metal mixtures by fathead minnow (Pimephales promelas) and yellow lampmussel (Lampsilis cariosa)

Diffusive gradients in thin films (DGT) were assessed for their predictive capability of fathead minnow and yellow lampmussel bioaccumulation in copper (Cu) and lead (Pb) mixed metal exposures. Nine treatments with a matrix of 3 Cu and 3 Pb concentrations were utilized. Exposures were coupled, with organisms and DGT exposed in tanks for 6 days. The Cu measured in fish, mussel, and DGT was found not to be influenced by Pb treatment, whereas Pb accumulation was impacted by the interaction of Cu and Pb treatment. The Pb accumulation increased with increasing Cu concentration, which was attributed to the different speciation of Cu and Pb in the water where Cu binds preferentially to ligands, decreasing its bioavailability and concomitantly displacing Pb from complexing sites. The DGT values were significantly correlated with accumulated Cu and Pb in the fish, but not with Pb in the mussel. In addition, DGT was determined to better predict aquatic organism bioaccumulation of Cu than the inorganic Cu fraction calculated by the speciation model, because DGT accumulated not only inorganic metal fractions but also complexes of metal and organic matter. The present study provides insights into metal speciation in polluted environments, extends the understanding of using DGT as a tool for estimating metal bioavailability, and provides implications for the selection of geochemical modeling, biological sampling, and passive sampling techniques for monitoring trace metal contamination. Environ Toxicol Chem 2019;38:61-70. © 2018 SETAC.

Evaluating the Quality of Mine Water Using Hierarchical Fuzzy Theory and Fluorescence Regional Integration

The quality of mine water samples from Hongliulin, Shaanxi Province, China was comprehensively evaluated. The inorganic fraction was analyzed by an analytic hierarchy process, while the main types of dissolved organic matter (DOM) were identified and quantified using fluorescence regional integration. Of the eight samples evaluated, those collected from surface water as well as one coal roof water sample (from the no. 52 seam) were classified as type I. These samples had much lower fluorescence integral values than their counterparts. One water sample from the no. 42 coal face and one from the no. 52 coal haulage roadway were type V, with much higher fluorescence integral values. All of the other water samples evaluated were classified as type II, with intermediate fluorescence integral values. This study showed that sedimentation can improve water quality from type II to type I, allowing it to be safely used for both human consumption and agricultural production. This strategy also reduced DOM by 37.17%.

The influence of traffic density on heavy metals distribution in urban road runoff in Beijing, China.

The concentrations, potential risk, and distributions of heavy metals in urban road runoff from different traffic density were determined and compared in Beijing, China. It showed that the concentrations of heavy metals in road runoff were strongly influenced by traffic density, resulting in total concentrations of Cu, Zn, Fe, Mn, and Pb in the runoff from highway higher than those from the road nearby campus. The potential ecological risk of heavy metals in the runoff from highway was higher than those from the road nearby campus. The distributions of heavy metals were not influenced by the traffic density. Cu, Zn, Cr, Cd, Pb, and Mn in road runoff transported predominantly in particulate-bound form and the dissolved form mainly distributed in colloidal fraction (1kDa to 0.45μm). Traffic density did not change the speciation of heavy metals in the road runoff, in which Cr and Zn mainly expressed in organic colloidal fraction while Fe, Mn, Cd, Pb, and Cu expressed in inorganic colloidal fraction. The traffic activities would contribute to the strong correlations between Fe, Zn, Mn, Cr, and Pb because of the similar sources.

Procedure for Organic Matter Removal from Peat Samples for XRD Mineral Analysis

Ombrotrophic peatlands are recognized archives of past atmospheric mineral dust deposition. Net dust deposition rates, grain size, mineral hosts and source areas are typically inferred from down-core elemental data. Although elemental analysis can be time efficient and data rich, there are some inherent limitations. X–ray diffraction (XRD) analysis allows direct identification of mineral phases in environmental samples but few studies have applied this method to peat samples and a well–developed protocol for extracting the inorganic fraction of highly organic samples (>95%) is lacking. We tested and compared different levels of pre–treatment: no pre–treatment, thermal combustion (300, 350, 400, 450, 500 and 550 °C) and chemical oxidation (H2O2 and Na2S2O8) using a homogenised highly organic (>98%) composite peat sample. Subsequently, minerals were identified by XRD. The results show that combustion is preferred to chemical oxidation because it most efficiently removes organic matter (OM), an important pre–requisite for identifying mineral phases by XRD analysis. Thermally induced phase transitions can be anticipated when temperature is the only factor to take into consideration. Based on the data required in this study the recommended combustion temperature is 500 °C which efficiently removes OM while preserving a majority of common dust minerals.

Assessing the pore structure and surface area of allophane-rich and non-allophanic topsoils by supercritical drying and chemical treatment

We have investigated the effect of supercritical drying (SD) on the porosity and the BET-N2 specific surface area (SSA) of five allophane-rich and three non-allophanic topsoils. The contribution of organic matter (OM) and short-range ordered (SRO) constituents to the nanoscale porosity (<100 nm size) and SSA was also evaluated following chemical treatments to oxidise OM and then remove the SRO phase. The average pore volume and SSA of the soils, measured after SD, are greater than the values obtained after air drying. For soils that are rich in SRO constituents, oxidation of OM leads to an increase in SSA. This observation is attributed to the unblocking of pore necks previously covered by OM, while the subsequent removal of SRO constituents causes a sharp decrease in SSA. The SRO constituents containing oxalate-extractable Al, are the major contributors to the SSA of the inorganic fraction. Besides confirming that SD can help preserve the nanoscale porosity of allophane-rich soils, the results highlight the contribution of SRO constituents to the SSA of soils and their ability to accumulate OM.

Influence of Inundation and Suspended-Sediment Concentrations on Spatiotemporal Sedimentation Patterns in a Tidal Freshwater Marsh

Long-term marsh sustainability is threatened by environmental changes, especially accelerated rates of sea-level rise (SLR) and changing fluvial sediment supplies. Although direct observations of long-term marsh responses to these changes are challenging, this study examines shorter-term responses via bimonthly sedimentation measurements over 5 years in Dyke Marsh Preserve (DMP), a tidal freshwater marsh in the Potomac River (Chesapeake Bay tributary, USA). Observed patterns are evaluated with physical drivers (winds, river discharge, water-level changes, suspended-sediment concentrations (SSC)) that influence spatiotemporal variability within the marsh. Linear regression models reveal that water-level changes exert more influence on this variability than SSC in a system with plentiful sediment supply. Sedimentation rates increase linearly with inundation time, but a quadratic regression model explains more of the variability, especially for the inorganic fraction of sediment. This result indicates that fluvial sediment supply is key for marsh accretion and suggests an optimal response of sedimentation to increased inundation that non-linearly affects marsh vulnerability to future SLR. Ultimately, the SSC in adjacent waters is not available to nourish the marsh unless it is transported and retained on the platform. Self-sustaining feedbacks among inundation, sedimentation, elevation, and plants likely aid in maintaining equilibrium elevations over time and thus also marsh sustainability.

X-ray powder diffraction of mineral pigments and medicines from the 17th century pharmacy (Spezieria) Santa Maria della Scala in Rome, Italy

The pharmacy (spezieria) Santa Maria della Scala was founded in Rome by the Discalced Carmelites Order in the 17th century, and during the 18th and 19th centuries it became the official supplier of medicines for Vatican Popes. The laboratory and the cases of this spezieria still preserve glass jars with organic and inorganic materials, which were presumably used for medicine and artistic material preparation, whose composition is unknown to date. A research project was initiated with the aim to study the stored materials and the role that the pharmacy played in regional, national and international contexts. In this manuscript, the compounds were analysed through X-ray powder diffraction with the scope to derive the quantitative mineralogical composition of the inorganic fraction, their possible use in pharmacopoeias and as mineral pigments. Most of the analysed samples are salts (sulphates, chlorides, carbonates, phosphates, borates, sulphides), sulphates being the predominant class; oxides were also detected.

Efficiencies and mechanisms of chemical cleaning agents for nanofiltration membranes used in produced wastewater desalination

A spiral-wound nanofiltration (NF) membrane module harvested from a full-scale produced wastewater desalination plant was examined and cleaned to explore appropriate chemical cleaning protocols. Foulant identification and cleaning efficiency and mechanisms were investigated. For total foulants, the organic components, including anionic polyacrylamide (APAM) and crude oil, accounted for a weight percentage of 86.3%, while the remaining foulants constituted the inorganic fraction, including Na, Mg, Ca, Ba, Al, Fe and Si. Short-term cleaning experiments were designed to identify effective reagents that could be used for further evaluations of their cleaning efficiencies in long-term cleaning. For citric acid and ethylenediaminetetraacetic acid tetrasodium (EDTA-4Na), the long-term cleaning efficiencies were relatively slight or even negative, while said values varied with different surfactants. Dodecyltrimethylammonium chloride (DTAC) achieved the greatest flux recovery; conversely, cetyltrimethylammonium chloride (CTAC) provided insignificant, even negative effects, on flux recovery, as well as salt rejection, of the fouled NF membranes. FTIR and zeta potential analyses of the fouled membranes indicated that all the tested surfactants were identically effective in removing the foulants from the membrane surface, but their cleaning efficiencies differed. Moreover, a strong correlation between the flux ratio (Sf) and concentration of surfactant in the permeate (Cps) was observed. Among the tested chemical reagents, DTAC yielded the highest Cps and the greatest flux recovery, with an Sf of 2.25. Considering this correlation and the characteristics of the fouled membranes and surfactants, it is proposed that DTAC molecules penetrated the membrane pores and removed the foulants that were attached to the pore walls.

Carbon and nitrogen pools in Padanian soils (Italy): Origin and dynamics of soil organic matter

Carbon and nitrogen elemental (C-N, wt%) and isotopic (δ13C-δ15N, ‰) investigation has been carried out on alluvial and deltaic soils from the Padanian plain (northern Italy), an area interested by intensive agricultural activities, to refine previous inferences on depositional facies, pedogenetic processes and anthropogenic influences. Soil analysis, carried out by EA-IRMS, have been focused on inorganic and organic fractions properly speciated by a thermally-based method, whereas further insights on the organic matter constituents have been obtained by sequential fractionation. The bulk EA-IRMS analyses reveal a remarkable compositional heterogeneity of the investigated soils (TC 0.89 to 11.93 wt%, TN 0.01 to 0.78 wt%, δ13CTC -1.2 to -28.2‰, δ15N -1.2 to 10.0‰) that has to be explained as an integration between inorganic and organic pools. The latter have been subdivided in Non-Extractable Organic Matter (NEOM, δ13C -16.3 to -28.6‰) and in extractable fractions as Fulvic (FA, δ13C -24.7 to -27.5‰, δ15N 0.6 to 5.7‰) and Humic (HA, δ13C -24.6 to -27.0‰, δ15N 1.0 to 9.7‰) Acids, which have been used to infer soil dynamics and Soil Organic Matter (SOM) stability processes. Results indicate that SOM at depth of 100 cm was generally affected by microbial reworking, with the exception of clayey and peaty deposits in which biological activity seems inhibited. Peaty and clayey soils display an organic fraction loss of ca. 20% toward the surface, suggesting deterioration possibly induced by intensive agricultural activities. These latter may be the cause of the ubiquitous losses of organic fraction throughout the investigated area over the last seventy years, evaluated by the comparison with historical data on corresponding topsoils. The obtained insights are very important because these soils are carbon (and nitrogen) sinks that are vulnerable and can be degraded, loosing agricultural productivity and potentially contributing to greenhouse gases fluxes.

Study of factors controlling the amount of 0.01 M CaCl2 extractable Norg fraction

The use of new methods describing the “readily available” nutrient content of the soil is spreading on a global scale. The 0.01 M CaCl2 extractant is a dilute salt solution in which the easily soluble inorganic (nitrate-N and ammonium-N) and organic N fractions, P, K and micronutrients are also measurable. The 0.01 M CaCl2 has been tested in the University of Debrecen, Institute of Agricultural Chemistry and Soil Sciences since the 90’s. The results of the researches related to organic N fraction, performed in the last decades, and the results of the present study (originating from the long-term experiment of Karcag, 2007–2009) can be concluded as follows:&#x0D; The measurement of easily soluble and oxidizable organic nitrogen (Norg), besides inorganic fractions, could improve the nutrient management.&#x0D; The amount of the Norg fraction is determined by the soil conditions, therefore it is considered to be a site-specific parameter.&#x0D; Management practices and cropyear affect the amount of Norg as well. The present research confirmed that, the effect of fertilization on the amount of Norg can be explained by the changing of the yield (related to total biomass production), while the effect of cropyear is related to the differences in mineralization circumstances and yield as well.&#x0D; The measurement of the Norg fraction is increases the accuracy of N-supply, therefore it could prevent the environmentally harmful excess N application as well.

Physical–mechanical evaluation of a microhybrid and a nanofilled composite light activated by quartz-halogen tungsten and light-emitting diode

The aim of this study was to characterize organic and disperse phase of a microhybrid (Mh – Filtek Z250) and a nanofilled (Nf – Filtek Z350) dental composite and analyze the influence of two LCUs (QHT-quartz-halogen tungsten and LED – light-emitting diode) on its physical–mechanical properties (degree of conversion, polymerization shrinkage, Vickers hardness and diametral tensile strength). Surface morphology was studied by scanning electron microscopy. The disperse phase content was measured using thermogravimetric analysis (TGA) and the organic fractions were qualitatively analyzed by nuclear magnetic resonance spectroscopy. Physical–mechanical properties were analyzed varying dental composite and LCU: Mh-QHT, Nf-QHT, Mh-LED and Nf-LED. The degree of conversion was evaluated using Raman spectrophotometry and polymerization shrinkage was measured by water picnometry. Mechanical behavior was analyzed by Vickers microhardness and diametral tensile testing. Scanning electron microscopy analysis showed similar microstructure of the materials mainly composed with different-sized particles dispersed within methacrylate matrix. Thermogravimetric analysis shows 80.13% of inorganic fraction for microhybrid composite and 75.29% for nanofilled. Nuclear magnetic resonance analysis showed similar organic structure for composites and did not show the presence of the monomer TEGDMA. Different light sources did not influence the tested properties, but considering different composites, nanofilled showed the highest degree of conversion (Gr 2:77%, Gr 4: 79.4%). The study shows that when the optimum radiant exposure (24 J/cm2) was used for polymerization of composites, regardless of the polymerization source, the properties of these resin materials showed satisfactory and similar results in relation to the conversion of polymers, polymerization shrinkage and mechanical behavior.

Determining the sources of nutrient flux to water in headwater catchments: Examining the speciation balance to inform the targeting of mitigation measures

Diffuse water pollution from agriculture (DWPA) is a major environmental concern, with significant adverse impacts on both human and ecosystem health. However, without an appropriate understanding of the multiple factors impacting on water, mitigation measures cannot be targeted. Therefore, this paper addresses this gap in understanding, reporting the hydrochemical monitoring evidence collected from the UK Government's Demonstration Test Catchments (DTC) programme including contrasting chalk and clay/mudstone catchments. We use data collected at daily and sub-daily frequency over multiple sites to address: (1) How does the behaviour of the full range of nitrogen (N) species and phosphorus (P) fractions vary? (2) How do N species and P fractions vary inter- and intra-annually? (3) What do these data indicate about the primary pollution sources? And (4) which diffuse pollution mitigation measures are appropriate in our study landscapes?Key differences in the rates of flux of nutrients were identified, dependent on catchment characteristics. Full N speciation and P fractionation, together with dissolved organic carbon (DOC) enabled identification of the most likely contributing sources in each catchment. Nitrate (NO3-N) was the dominant N fraction in the chalk whereas organic and particulate N comprised the majority of the load in the clay/mudstone catchments. Despite current legislation, orthophosphate (PO4-P) was not found to be the dominant form of P in any of the catchments monitored. The chalk sub-catchments had the largest proportion of inorganic/dissolved organic P (DOP), accompanied by episodic delivery of particulate P (PP). Contrastingly, the clay/mudstone sub-catchments loads were dominated by PP and DOP. Thus, our results show that by monitoring both the inorganic and organic fractions a more complete picture of catchment nutrient fluxes can be determined, and sources of pollution pin-pointed. Ultimately, policy and management to bring nutrient impacts under control will only be successful if a multi-stressor approach is adopted.

Heteroaggregation of CeO2 nanoparticles in presence of alginate and iron (III) oxide

When manufactured nanoparticles are released to natural waters, heteroaggregation between nanoparticles and water compounds is expected to occur and play a key role in nanoparticle fate, transport and transformation. In this work, the heteroaggregation between CeO2 nanoparticles and Fe2O3 inorganic colloids, which represent the main inorganic fraction from Lake Geneva water, is studied. The heteroaggregation processes between CeO2, Fe2O3 and alginate in multiple water samples are investigated using zeta potential and z-average diameter measurements. The kinetics of heteroaggregation of individual components as well as mixtures of CeO2 nanoparticles and Fe2O3 colloids and alginate are studied using time resolved dynamic light scattering. The global attachment efficiency (αglobal) is calculated using data from kinetic experiments. αglobal for pristine CeO2 nanoparticles varied from 0.5 to 0.7 in lake and synthetic waters and is found around 1 for pristine Fe2O3 and mixture CeO2 and Fe2O3. Our findings demonstrate that heteroaggregation is highly dependent on environmental conditions and resulting electrostatic scenarios. No heteroaggregation at pH 8 between CeO2, Fe2O3 and alginate is observed in ultrapure water, because of electrostatic repulsions between negatively charged compounds. In synthetic and lake waters, the situation is opposite. Indeed, specific adsorption of divalent cations and presence of salt are found to promote heteroaggregation via cation bridging and screening effects. The kinetic experiments indicate that aggregation rate of pristine Fe2O3 is higher (89 nm/min in lake water) compared to pristine CeO2 nanoparticles (50 nm/min) and on the same level as mixture of CeO2 and Fe2O3 (96 nm/min). Low alginate concentration, 0.25 mg/L, has no effect on heteroaggregation in mixture of CeO2 and Fe2O3 in lake and synthetic waters. On the other hand, in natural water, the presence of higher alginate concentration, 2 mg/L, is found to reduce the heteroaggregation rate.

Multielemental composition and arsenic speciation in low rank coal from the Velenje Basin, Slovenia

Coal is one of the main fossil fuel resources and remains the most important contributor to global power generation but coal utilization has severe negative impacts, mostly due to the release of CO2 and toxic elements into the environment. This means that determining the quality of coal is important to address the environmental and health problems related to coal combustion. Coal samples from the Velenje coalmine, one of the largest actively mined coal basins in Central Europe, were divided into organic rich and inorganic rich fractions according to the percentage of carbon. Oxides of the major elements (SiO2, Al2O3, Fe2O3 MgO, CaO, Na2O, K2O, TiO2, P2O5, MnO, Cr2O3), toxicologically and environmentally relevant elements (As, Ba, Co, Cu, Hg, Mo, Ni, Pb, Th, U, V, Zn, Se) and other trace elements (Ce, Cs, Dy, Er, Eu, Gd, La, Nb, Nd, Pr, Rb, Sm, Sr, Tb, Y, Zr) were measured in sample digests using inductively coupled plasma mass spectrometry (ICP-MS). The concentrations of the majority of analyzed elements were either equal to or below the global average for coal. Exceptions were Sr (1090 ± 510 μg g−1, 9 times higher), Ba (301 ± 184 μg g−1, 2 times higher) and Pb (9.12 ± 17.0 μg g−1, 1.4 times higher) in inorganic rich coal and Mo (7.76 ± 4.76 μg g−1, 3.5 times higher) and U (5.24 ± 3.23 μg g−1, 1.8 times higher) in organic rich samples. Eighteen elements (Ag, Au, Be, Bi, Cd, Ga, Hf, Ho, Lu, Sb, Sc, Se, Sn, Ta, Ti, Tm, Yb, W) were below the limit of detection in >70% of the samples. Speciation analysis revealed the presence of several organoarsenic compounds in the organic rich samples, with the tetramethylarsonium ion (TETRA, 0.01–1.10 μg g−1) and trimethylarsine oxide (TMAO, 0.01–0.29 μg g−1) as the most abundant. A comparison with coal samples from the Senovo, Kanižarica, and Trbovlje coal mines in Slovenia and from the Sokolov Basin, (Czech Republic) revealed that Velenje contains much higher amount of organoarsenic compounds (34.8 ± 16.9%) in comparison to the others (4.45 ± 4.19%).

Soil Water Retention in the Semiarid Region of Brazil

From the physics point of view, soil structure is a dynamic attribute that is affected by genetic conditions and anthropogenic changes and requires an integrated approach. Soil water retention curve is one of the main tools used in soil structure evaluations. The objective of this work was to evaluate the structural and chemical attributes of soils of different classes and agroecosystems in the Terra de Esperança Settlement (Governador Dix Sept Rosado, Rio Grande do Norte, Brazil) to distinguish these environments. Disturbed and undisturbed soil samples were collected in horizons of 10 soil profiles of the soil classes: Cambissolo Háplico (Haplustepts), Latossolo Vermelho-Amarelo (Eutrustox), Chernossolo Rêndzico (Calciustolls), and Neossolo Flúvico (Usticfluvents). The soil physical attributes evaluated were granulometry, soil density, total porosity, aeration porosity, macroporosity, microporosity, field capacity, permanent wilting point, available water, and water retention curve. The results were expressed in averages of four replicates per horizon (in laboratory) by multivariate analysis, which detected the most sensitive attributes for the distinction of the environments. The soil physical attributes of the different classes and its inorganic fractions, especially silt and clay, were determinant to distinguish the environments; they affected the microporosity; aeration porosity; and available water. The source material of the Chernossolo Rêndzico, which is rich in calcium and magnesium, affected its physical attributes, characterized by the predominance of the silt fraction. Clay was the determinant fraction of the Cambissolo Háplico, and Neossolo Flúvico; and the sand fraction on the surface layer, and clay fraction in the Bw horizon were determinant of the Latossolo Vermelho-Amarelo. The more expressive physical attributes were soil density, sand content, macroporosity (Latossolo Vermelho-Amarelo), microporosity, field capacity, available water, permanent wilting point, total organic carbon, mass-based moisture, volume-based moisture, clay, aeration porosity (Cambissolo Háplico, and Neossolo Flúvico), and silt (Chernossolo Rêndzico).

Lead (II) Removal from Contaminated Soils by Electrokinetic Remediation Coupled with Modified Eggshell Waste

Electrokinetic remediation deserves particular attention in soil treatment due to its peculiar advantages, including the capability of treating fine and low permeability materials, and achieving consolidation, dewatering and removal of salts and inorganic contaminants like heavy metals in a single stage. In this study, the remediation of artificially lead (II) contaminated soil by electrokinetic process, coupled with Eggshell Inorganic Fraction Powder (EGGIF) permeable reactive barrier (PRB), was investigated. An electric field of 2 V cm-1was applied and was used an EGGIF/soil ratio of 30 g kg-1 of contaminated soil for the preparation of the permeable reactive barrier (PRB) in each test. It was obtained high removal rates of lead in both experiments, especially near the cathode. In the normalized distance to cathode of 0.2 it was achieved a maximum removal rate of lead (II) of 68, 78 and 83% in initial lead (II) concentration of 500 mg-1, 200 mg-1 and 100 mg-1, respectively. EGGIF (Eggshell Inorganic Fraction) proved that can be used as permeable reactive barrier (PRB) since in all the performed tests were achieved adsorptions yields higher than 90%.