Initial Modulus Research Articles

Effect of epoxidation level on rheological properties of epoxidized natural rubber-based magnetorheological elastomer

Epoxidized natural rubbers (ENR)are potential to be an alternative of natural rubber as matrix of magnetorheological elastomers (MREs). These ENR-based MREs offer various advantages such as excellent mechanical properties and damping characteristics that are well-suited for applications in vibration control and noise reduction devices. However, there is a paucity information in regard to the effect of different epoxidation levels on rheological properties of MRE. Therefore, the main aim of this study is to explore the influence of epoxidation level on rheological properties of MRE using commercialized ENR corresponding to ENR 25 and ENR 50. ENR-based MREs were created by blending with carbonyl iron particles (CIPs) and other additives, followed by curing at 150 °C for 30 min. The study involved producing ten MRE samples with various weight percentages of CIP (0,10,30,50 and 70 wt%). The storage modulus of ENR 50 exhibited a significant increment from 0.73 MPa to 1.04 MPa as compared to ENR 25 which caused the storage modulus to increase from 0.77 to 0.88 MPa. This showed that ENR 50-based MRE are stiffer in comparison to ENR 25-based MRE. Initial loss modulus value for ENR 50 (0.098 MPa) was lower than that of ENR 25 (0.112 MPa), consequently less energy is dissipated to surrounding for ENR 50-based MRE compare ENR 25-based MRE. The loss factor that represents damping properties showed that ENR 50 reached higher values (0.120 MPa) compared to ENR 25 (0.106 MPa). The increasing of CIPs content from 0 to 70 wt% contributed to increasing of magnetorheological effect for both ENR-based MRE where ENR 25 produced slightly higher with increment of 1.88 % to 22.6 % than ENR 50-based MRE with increment of 2.47 % to 18.18 % due to rise of magnetic forces generated from interaction of magnetic moments in magnetic domains of each CIPs. The results and analysis indicate that different levels of epoxidation in ENR have a marginal impact on the rheological properties of ENR-based MREs.

Side Illumination Behavior and Mechanical Properties of Twisted End‐Emitting Polymer Optical Fiber Bundles

AbstractPolymer optical fibers (POFs), including side‐emitting POF (SEPOF) and end‐emitting POF (EEPOF) are developed for luminous textiles. The SEPOF is more common for usage but suffers from significant intensity decay, which limits its effective usage length. In contrast, the EEPOF can provide a much more stable side illumination behavior than SEPOF since the light is largely confined within the EEPOF, while its side illumination requires special treatment. In this work, 0.5 mm diameter EEPOFs were firstly assembled into bundles with 10 EEPOFs (B10) and 15 EEPOFs (B15), and then twisted. The morphology, tensile properties, and side illumination behavior of the twisted EEPOF bundles are evaluated. With an increased twisting degree, the initial modulus of twisted sample B10 increases (due to shortening of bundle diameter) from 1.06 to 1.17 GPa while the initial modulus of twisted sample B15 decreases from 1.01 to 0.91 GPa. The increased twisting degree also results in the higher flexibility (indirectly connected with modulus) of the twisted EEPOF bundles. Besides, the increased twisting degree results in a higher side illumination intensity meantime causes a decreased side illumination intensity along the light penetration path. When the twisting degree is low (e.g., 10 T m−1), the highest decrease rate of side illumination intensity along the light penetration path is found.

The strength and hydraulic conductivity characteristics of sewage sludge ash and natural soil mixtures – a sustainable alternate landfill liner material

ABSTRACT This paper examines the feasibility of the natural soil and sewage sludge ash (SSA) mixtures, which satisfy the criteria to be used as landfill liners. The effect of SSA content on hydraulic conductivity and strength characteristics of natural soil and SSA mixtures has been investigated through a series of laboratory tests. The results demonstrate that mixtures exhibit an increase in both hydrodynamic diffusion coefficient and strength with the increasing SSA content. With the content of SSA from 0% to 5%, the values of the hydrodynamic diffusion coefficient ( D ) ranged from 3.5 × 10−10 to 15 × 10−10 cm2/s. The increase in the hydrodynamic diffusion coefficient is minor for low SSA content and significant for SSA content exceeding 5%. The inclusion of 5% SSA content results in a hydrodynamic diffusion coefficient that is approximately three times higher than that observed in natural soil. The results were obtained from soil triaxial tests, revealing that the mixtures containing SSA exhibited a significant increase in both the initial tangent modulus and the ultimate principal stress difference compared to those of natural soil. The SSA content with the highest value exhibits maximum initial tangent modulus and ultimate principal stress. The comprehensive analysis of the strength and hydraulic diffusion conductivity of the mixtures demonstrates that the incorporation of 3% SSA results in a significant enhancement in strength, while marginally increasing hydrodynamic diffusion coefficients. Therefore, it can be inferred that the utilization of mixtures containing 3% SSA content as a liner material is suitable.

Variability in individual native fibrin fiber mechanics

Fibrin fibers are important structural elements in blood coagulation. They form a mesh network that acts as a scaffold and imparts mechanical strength to the clot. A review of published work measuring the mechanics of fibrin fibers reveals a range of values for fiber extensibility. This study investigates fibrinogen concentration as a variable responsible for variability in fibrin mechanics. It expands previous work to describe the modulus, strain hardening, extensibility, and the force required for fiber failure when fibers are formed with different fibrinogen concentrations using lateral force atomic force microscopy. Analysis of the mechanical properties showed fibers formed from 1 mg ml-1and 2 mg ml-1fibrinogen had significantly different mechanical properties. To help clarify our findings we developed two behavior profiles to describe individual fiber mechanics. The first describes a fiber with low initial modulus and high extensible, that undergoes significant strain hardening, and has moderate strength. Most fibers formed with 1 mg ml-1fibrinogen had this behavior profile. The second profile describes a fiber with a high initial modulus, minimal strain hardening, high strength, and low extensibility. Most fibrin fibers formed with 2 mg ml-1fibrinogen were described by this second profile. In conclusion, we see a range of behaviors from fibers formed from native fibrinogen molecules but various fibrinogen concentrations. Potential differences in fiber formation are investigated with SEM. It is likely this range of behaviors also occursin vivo. Understanding the variability in mechanical properties could contribute to a deeper understanding of pathophysiology of coagulative disorders.

Development patterns of the dynamic elastic modulus of saturated coral sand under different drainage conditions

Long-term cyclic loading can have a significant effect on the modulus of sand, and the influence on saturated coral sand has yet to be established. In this paper, the significant influence of non-plastic fines content (FC) and relative density (Dr) on dynamic elastic modulus (E) of saturated coral sand has been evaluated by a series of cyclic triaxial drainage tests. The results show that the dynamic elastic modulus increases rapidly at the beginning of loading; then the growth slows down and finally stabilizes. In general, the development of E is influenced collectively by FC, Dr and cyclic stress ratio (CSR). The initial dynamic elastic modulus Ed-1 and steady-state dynamic elastic modulus Ed-s increase with the increase of Dr, and decrease as FC increases. The linear fitting equations are given by introducing the equivalent skeleton void ratio esk*. Furthermore, the relative dynamic elastic modulus Er is defined as the ratio of Ed-N to Ed-s, and the prediction equation for Er was developed to provide a basis for the engineering mechanical parameters of coral sands under long-term loads.

Phase behavior and synergistic gelation of scallop (Patinopecten yessoensis) male gonad hydrolysates and gellan gum driven by pH.

Previous studies have investigated complexation and coacervation of scallop Patinopecten yessoensis male gonad hydrolysates (SMGHs) and polysaccharides influenced by pH and blending ratio. It has been found that SMGHs/polysaccharide composite shows better gel properties under strongly acidic conditions. Thus, the complexation and coacervation of SMGHs and gellan gum (GG) were investigated via turbidimetric titration at different pH values (1-12) and biopolymer blending ratios (9.5:0.5-6:4). Both pHc and pHφ1 exhibited ratio-independent behavior with constant values at approximately pH 5.8 and pH 3.8, respectively, dividing SMGHs/GG blends into three phases named mixed polymers, soluble complexes and insoluble coacervates, respectively. Overall, SMGHs and GG exhibited synergistic gelation under neutral and acidic conditions, with the initial storage modulus (G') increasing by approximately 42.5-, 573.7- and 3421-fold and 97.7-, 550.3- and 0.5-fold, respectively, at pH 7, 5 and 3, compared with SMGHs and GG. As pH decreased from 7 to 3, the initial G' and viscosity η values of SMGHs/GG gels increased by 20.1- and 2.3-fold, respectively, exhibiting the greatest increase in gel strength. Moreover, the free water in the SMGHs/GG system significantly shifted toward lower relaxation times attributed to the immobilization of the outer hydration layers. SMGHs/GG gels in the insoluble phase exhibited denser networks and rougher surfaces, supporting the enhanced rheological properties and water retention capacity of the gel. This work provides a basic foundation for the development of pH-driven SMGHs/GG gelation by examining complexation and coacervation processes. © 2024 Society of Chemical Industry.

Investigation of Titanium Nitride as an Effective Interphase for Carbon-Fiber-Reinforced Silicon Carbide Ceramic Matrix Composites.

Ceramic matrix composites (CMCs) have played a significant role in increasing the efficiency of gas turbine engines. CMCs combine the high temperature resistance of ceramics with the high mechanical strength of ceramic fibers into a single unit. Interphase layers are a crucial component in CMCs, as they prevent ceramic fibers from oxidation and introduce strengthening mechanisms into the composite. Hexagonal boron nitride and pyrolytic carbon are the most commonly used interphase layers in the aerospace industry. Other than that, very few materials have been evaluated as interphase layers. In this study, we explore the possibilities of using titanium nitride as an interphase layer in single-tow CMCs (mini composite) representative of a unidirectional composite at a smaller scale. T-300 carbon fibers were coated with TiN by atmospheric pressure chemical vapor infiltration using TiCl4, N2, and H2. The deposition temperature, precursor flow rate ratio, total precursor flow rate, and deposition time were optimized to obtain high-quality coatings. The best coating was produced at 800 °C, 4:1 H2 [TiCl4]/N2 ratio, 125 standard cubic centimeters per minute (N2 + H2 [TiCl4]) total flow precursor flow rate, and 2 h of deposition time. At these conditions, the coatings displayed good fiber coverage, good fiber adhesion, minimum fiber linkage, and minimum surface roughness. There was minimum fiber degradation after TiN coating, with a retention of 95% of the initial Young's modulus and 26% of the ultimate tensile strength of the carbon fiber. Adding the TiN interphase coating to the Cf/SiC CMC increased the ultimate tensile strength of the composite by 1122% and Young's modulus by 150%.

Compressive stress-strain response of freshly compressed rubberized concrete: An experimental and theoretical study

Although using crumb tire rubber concrete (CTRC) in constructing structural elements is accompanied by various environmental and economic advantages, it always comes with challenges due to a significant loss in some mechanical properties of this concrete type. To tackle this challenge, a novel technique of compressing fresh concrete was used, and its impacts on improving the mechanical features of CTRC were investigated. For this purpose, concrete specimens containing crumb tire rubber (CTR), as the fine aggregate substitute, were constructed considering the variables of the water-to-cement ratio (w/c), volume percentage of CTR, and the fresh concrete pressure level as a fraction of steel tube (mold) yielding stress. After the application of a specified short-term pressure to the fresh mix inside the steel molds and the time required for the concrete setting, the steel tubes were removed after curing, and the concrete core alone was exposed to an axial compressive load. According to the test results, the mechanical properties, weight loss resulting from compressing the fresh concrete, energy absorption, failure pattern, the concrete microstructure, water absorption, and porosity were evaluated. By applying an initial axial pressure of 25–80 MPa on the mixes containing 0 %, 15 %, and 30 % CTR replacing the fine aggregate, the compressive strength, the ultimate strain, the toughness, and the initial modulus of elasticity experienced 100–140 % increase, 130–420 % increase, 120–1140 % increase, and 66–70 % decrease, respectively, compared with the uncompressed specimen. Finally, a regression analysis was employed to propose prediction models for the compressive capacity, modulus of elasticity, peak strain, ultimate strain, and relative toughness of freshly compressed concrete containing CTR particles; these models show proper agreement with the experimental results.

Electrospun zeolitic imidazole framework-8 loaded silk fibroin/polycaprolactone nanofibrous scaffolds for biomedical application

The development of electrospun nanofibrous scaffolds (NFSs) have aroused much attraction in the field of biomedical engineering, due to their small fiber diameter, high specific surface area, and excellent extracellular matrix comparability. The main focus of this study is to design and fabricate novel zeolitic imidazole framework-8 (ZIF-8)-loaded silk fibrin/polycaprolactone (SF/PCL) nanofiber composite scaffolds by using the electrospinning strategy. Firstly, ZIF-8 was synthesized and characterized, which showed remarkable features in terms of shape, size, chemical and physical properties. Then, three different amounts of ZIF-8 were encapsulated into SF/PCL nanofibers during electrospinning, to investigate how the addition of ZIF-8 affected the morphology, and structure, as well as physical, mechanical, and biological properties of the nanofiber composite scaffolds. It was found that the addition of ZIF-8 didn't change the nanofibrous morphology of the composite scaffold, and no bead-like structure were found for the SF/PCL composite scaffolds loading with or without ZIF-8. The appropriate addition of ZIF-8 could significantly increase the mechanical properties of SF/PCL NFSs. The SF/PCL NFS containing 5% ZIF-8 showed high ultimate stress and initial modulus, which were 40.31 ± 2.31 MPa, and 569.19 ± 21.38 MPa, respectively. Furthermore, the MTT assay indicated that the pure SF/PCL scaffold and one with 1% ZIF-8 exhibited nearly identical cell compatibility toward human dermal fibroblast (HDF) cells, but some obvious cytotoxicity was observed with the increase of ZIF-8 content. However, the incorporation of ZIF-8 into SF/PCL NFSs was found to have excellent antibacterial rate against both E. coli and S. aureus. In all, the incorporation of 1% ZIF-8 could impart the SF/PCL NFS with balanced bio-function, making it a promising candidate for diverse biomedical applications such as tissue engineering and wound healing.

Research on mechanical properties of HTPB propellants

Abstract Slat propellants with different sizes and shapes are designed to investigate the strength criteria of HTPB propellants. According to the calculation and simulation results, with the increase of multiple, the designed size slat specimens can achieve equivalent biaxial tensile stress ratios of 1:2, 1:2.5, 1:3, 1:3.5, and 1:4 under uniaxial tensile conditions. The biaxial mechanical properties of the slab with a stress ratio of 1:2 were tested at low temperatures (25°C, −30°C, −50°C, and 0.4 s−1, 4.0 s−1, 14.29 s−1, 42.86 s−1). It was found that as the temperature and the strain rate rise, an increase is observed in the maximum tensile strength and the initial modulus, a decrease is observed in the maximum elongation of the propellant, and the strength envelope is constructed according to the typical mechanical parameters: the strength envelope of HTPB propellant increases as the temperature decreases. The research findings are expected to provide statistical support for the analysis of the structural integrity of HTPB propellants under low-temperature ignition.

Elastoplastic plate shakes down under repeated impulsive loadings

When subjected to repeated dynamic impacts at identical load level, a metallic monolithic beam/plate may reach a stable state wherein measurable deformation ceases (i.e., shakedown in elastic state) after undergoing a sequence of elastoplastic deformations, which has been termed as “pseudo-shakedown” (P-S) (Jones, 1973, Shen and Jones, 1992). While the response of a single beam/plate under repeated low-velocity impacts has been thoroughly studied, its dynamic behavior under high-velocity impacts, such as explosive or alternating impulsive loads, is difficult to measure experimentally, due mainly to high costs and setup challenges. In the current study, the method of metallic foam projectile impact was employed to produce repeated impulsive loadings on a fully-clamped elastoplastic monolithic plate made of L907A (a Chinese standard shipbuilding steel). Its dynamic responses, including mid-point deflection versus time histories, final deflections, and deformation modes after each impact, were systematically measured. The phenomenon of dynamic shakedown was observed. To further explore this phenomenon, the method of finite elements (FE) was employed to simulate the repeated impulsive impact test, and its prediction accuracy was validated against experimental results. Unlike an elastoplastic (e.g., steel) monolithic plate subjected to repeated low-velocity impacts, which exhibits zero plastic energy dissipation in the P-S (pseudo-shakedown) state, the same plate under repeated high-velocity impacts shows a small level of plastic energy dissipation in the P-S state, mainly due to more extreme loading conditions. The initial impact momentum, yield strength, and tangent modulus of the material the plate is made of significantly affect both the stable deflection in the P-S state and the number of impacts needed to reach it, while the elastic modulus has limited influence. A modified dimensionless impulse loading number, accounting for the strain-hardening effect, is proposed. An approximately linear relationship between stable deflection in the P-S state and impulsive loading is found in dimensionless form.

Enhancing wind turbine blade protection: Solid particle erosion resistant ceramic oxides-reinforced epoxy coatings

Wind energy has been regarded as one of the renewable energy sources to rely on in the future. In this aspect, wind turbine blade maintenance is quite a challenge in tropical areas like India. One of the main reasons why wind turbine blades get damaged and produce less energy is solid particle erosion. In the present work, nanocomposite epoxy (EP) coatings reinforced with Al2O3, ZrO2, and CeO2 nanoparticle fillers have been applied on glass fiber reinforced polymer (GFRP) substrates using a simple spray coating method. These nanoparticles have been prepared in-house by solution combustion synthesis (SCS) route using urea, glycine, and oxalyl dihydrazide fuels. X-ray diffraction, field emission scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy have been used to characterize the materials and coatings. EP coatings with different Al2O3, ZrO2, and CeO2 nanoparticle concentrations have been subjected to solid particle erosion resistance tests at impinging angles of 30°, 60° and 90°. ZrO2 and CeO2 nanoparticle-reinforced EP coatings show better resistance to solid particle erosion than Al2O3-reinforced coatings. Estimated average erosion rates are 17 and 11.3 × 10−3 mm3 g−1, respectively, for epoxy coatings with 20 and 40 wt% ZrO2 nanoparticles. However, GFRP substrate and neat EP coating show much higher erosion rates with respect to nanoparticles-reinforced EP coatings. To ascertain a correlation between H3/E2 and the solid particle erosion rates of the coatings, nanoindentation tests have been carried out. Tensile strength and initial modulus of all the coatings are found to be directly proportional to the average erosion rates, whereas, elongation at break shows an inverse relationship with the average erosion rate. This correlation of mechanical properties with solid particle erosion performance can play a critical role in the development of realistic simulation of protective coatings for wind turbine blades.

Development of a ternary high-temperature resistant geopolymer and the deterioration mechanism of its concrete after heat exposure

A geopolymer paste (GP) synthesised using fly ash, slag, and metakaolin was developed to enhance the heat resistance of industrial by-product-based geopolymers. The GP exhibited a 28-day strength of 60 MPa and maintained at least 80 % of its initial strength and elastic modulus even at temperatures up to 900°C. Subsequently, the GP was blended with aggregates (sands and stones) to produce geopolymer concrete (GPC) with a 28-day strength of 45 MPa. Compressive tests on the GPC after exposure to 100–1000°C revealed that the GPC retained 90 % of its compressive strength up to 500°C, but experienced a 60 % loss in elastic modulus and a fourfold increase in peak strain after 300°C exposure. Stress-strain relation, physical properties, and microstructure were analysed to explore the property evolution mechanisms after heat exposure. The combined effect of geopolymer shrinkage (100–780°C), stone expansion (> 200°C), and stone decomposition (> 500°C) was the primary factor for the GPC property decline. At 800°C, a complete loss of mechanical properties in both the stone and interface transition zones led to significant deterioration of the GPC. These findings offer valuable insights for developing durable construction materials suitable for high-temperature applications, ensuring structural integrity and performance under extreme thermal conditions.

Performance Properties and Finite Element Modelling of Forest-Based Bionanomaterials/Activated Carbon Composite Film for Sustainable Future

Thanks to its highly crystalline structure and excellent thermal, optical, electrical and mechanical properties, carbon and its derivatives are considered the preferred reinforcement material in composites used in many industrial applications, especially in the forest and forest products sector, including oil, gas and aviation. Since hydroxyethyl cellulose (HEC) is a biopolymer, it has poor mechanical and thermal properties. These properties need to be strengthened with various additives. This study aims to improve the thermal and mechanical properties of hydroxyethyl cellulose by preparing hydroxyethyl cellulose/activated carbon (HEC/AC) composite materials. With this study, composites were obtained for the first time and their mechanical properties were examined using a 3D numerical modeling technique. The thermal stability of the prepared composite materials was investigated via thermal gravimetric analysis (TGA). The samples were heated from 30 °C to 750 °C with a heating rate of 10 °C/min under a nitrogen atmosphere and their masses were measured subsequently. The mechanical properties of the composites were investigated via the tensile test. The viscoelastic properties of the composite films were determined with dynamic mechanical thermal analyses (DMTA) and their morphologies were examined with scanning electron microscopy (SEM) images. According to the results, the best F3 sample (films containing 3 wt.% activated carbon) had an elastic modulus of 168.3 MPa, a thermal conductivity value of 0.068 W/mK, the maximum mass loss was at 328.20 °C and the initial storage modulus at 30 °C was 206.13 MPa. It was determined that the hydroxyethyl cellulose composite films containing 3 wt.% activated carbon revealed the optimum results in terms of both thermal conductivity and viscoelastic response and showed that the obtained composite films could be used in industrial applications where thermal conductivity was required.

Application of Wave Methods for Determining Comprehensive Soil Model Parameters

Comprehensive hardening soil models are widely used in geotechnical design. Some of the stiffness parameters of such models, characterizing the behavior under very small and small strains, should be determined by wave (dynamic) methods. These techniques can be implemented both in the laboratory and in the field scale. Each of the methods has its advantages and disadvantages, which directly affect the quality of the initial data obtained for calculations and the results of geotechnical forecasts and the reliability of construction facilities. The article provides an overview of wave methods applicable for stiffness parameters of complex soil models estimation. The scope of application of test methods is given depending on the geotechnical task, the defined parameters and engineering-geological conditions. The comparison of the test results by field and laboratory methods at the experimental site is given. It is shown that the results obtained by field methods require additional reference to the initial stress state in the soil mass before their application as input parameters of comprehensive soil models. Recommendations are given for correcting the initial soil shear modulus based on the integration of laboratory and field wave methods.

Visceral pleura mechanics: Characterization of human, pig, and rat lung material properties

Pulmonary air leaks are amongst the most common complications in lung surgery. Lung sealants are applied to the organ surface and need to synchronously stretch with the visceral pleura, the layer of tissue which encompasses the lung parenchymal tissue. These adhesives are commonly tested on pig and rat lungs, but applied to human lungs. However, the unknown mechanics of human lung visceral pleura undermines the clinical translatability of such animal-tested sealants and the absence of how pig and rat lung visceral pleura compare to human tissues is necessary to address. Here we quantify the biaxial planar tensile mechanics of visceral pleura from healthy transplant-eligible and smoker human lungs for the first time, and further compare the material behaviors to pig and rat lung visceral pleura. Initial and final stiffness moduli, maximum stress, low-to-high strain transition, and stress relaxation are analyzed and compared between and within groups, further considering regional and directional dependencies. Visceral pleura tissue from all species behave isotropically, and pig and human visceral pleura exhibits regional heterogeneity (i.e. upper versus lower lobe differences). We find that pig visceral pleura exhibits similar initial stiffness moduli and regional trends compared to human visceral pleura, suggesting pig tissue may serve as a viable animal model candidate for lung sealant testing. The outcomes and mechanical characterization of these scarce tissues enables future development of biomimetic lung sealants for improved surgical applications. Statement of significanceSurgical lung sealants must synchronously deform with the underlying tissue and with each breath to minimize post-operative air leaks, which remain the most frequent complications of pulmonary intervention. These adhesives are often tested on pig and rat lungs, but applied to humans; however, the material properties of human lung visceral pleura were previously unexplored. Here, for the first time, the mechanics of human visceral pleura tissue are investigated, further contrasting rarely acquired donated lungs from healthy and smoking individuals, and additionally, comparing biaxial planar material characterizations to animal models often employed for pulmonary sealant development. This fundamental material characterization addresses key hindrances in the advancement of biomimetic sealants and evaluates the translatability of animal model experiments for clinical applications.

Experimental and numerical investigations of bending mechanical properties and fracture characteristics of cemented tailings-waste rock backfill under three-point bending

The bending mechanical properties and fracture characteristics of cemented tailings-waste rock backfill (CT-WRB) have a significant impact on efficient mine production. In this study, the effects of waste rock content (WRC) and waste rock size (WRS) on the bending mechanical properties and macroscopic failure characteristics of CT-WRB were investigated through experiments. Concurrently, PFC3D numerical simulation software was used to establish a three-point bending numerical model of CT-WRB with actual waste rock shapes to explore the crack evolution law and microscopic damage characteristics. Results showed that adding appropriate waste rock improved the initial stiffness, flexural strength, and modulus of the backfill, with optimal WRC and WRS at 40 % and 4–6 mm, respectively. Simulations indicated that under load, the displacement field of CT-WRB formed a vortex, with tensile stress in the middle and lower parts and compressive stress in an upper arch. Cracks started at the bottom and extended upward, leading to failure. Compared to OCTB (without waste rock incorporation), CT-WRB had more total cracks and tension-shear composite failure of internal particles. Waste rock altered stress distribution and crack paths, resulting in curved, bifurcated, and discontinuous main cracks. These findings provide a reference for efficiently recycling tailings, waste rock and ensuring safe mine production.

Cellulose nanofiber powered interface engineering strategy to manufacture mechanically stable, moldable, recyclable, and biodegradable cellulose foam

In this work, an ingenious and energy-efficient interface engineering strategy is developed to manufacture pulp cellulose foam via incorporating cellulose nanofiber/alkyl ketene dimer (CNF/AKD) Pickering emulsions. In this strategy, CNF/AKD emulsion can uniformly anchor onto pulp microfiber surface, not only achieving interfacial exoskeleton reinforcement, but also enabling low energy surface, which facilitates the direct and large-scale production of lightweight pulp/CNF/AKD (PCA) foam by oven drying without requiring any harmful crosslinking chemistries. By simply regulating the mass fractions of CNF and AKD in emulsion, the prepared PCA foams can achieve excellent and tunable 3D porous structure, mechanical performance, water resistance and wet stability. The dry compressive modulus and wet compressive modulus underwater of PCA foams with low density of 0.09 g/cm3 can reach 0.67 and 0.57 MPa, respectively. Even 1 week in water, the compressive modulus still retains 76.2 % of initial modulus. Notably, the proposed interface engineering strategy provides remarkable formability, moldability and structural designability, enabling cellulose foam to be customized into complex and delicate 3D macroscopic structures for different scenarios. Furthermore, the PCA foam displays economically feasible closed-loop recyclability by easy hot-water disintegration and natural biodegradability in soil. Therefore, this work proves a cost-effective and viable interface engineering strategy for scalable production of lightweight, mechanically stable, recyclable, biodegradable cellulose foams with high environmental benefits and low petrochemical consumption.

Mussel-inspired tough ionogel with robust adhesion and mechanical adaptivity for impact resistance

Intrinsic adhesiveness and mechanical adaptivity allowing spontaneous anchoring and impact-stiffening, which facilitate safer impact protection, remain challenges for the design and synthesis of advanced tough impact-resistant materials. Herein, a novel biomimetic mechanically robust impact-resistant ionogel with the mussel-inspired diphasic structure was elaborately developed. The salt-bridge hydrogen bonds between carboxyl and imidazole groups inside rigid clusters serve as reversible crosslinking sites and prime energy-dissipation motifs, leading to strong noncovalent cohesion. Furthermore, the hydrophobic ionic liquid enriches surface interactions, providing extensive adhesive performance for in-situ attachment under external impact. Benefitting from the dynamic nature of the salt-bridge hydrogen bonds, the ionogel possesses impressive energy dissipation, self-healing, and recyclable properties. Notably, the prepared ionogel exhibits rate-dependent mechanical adaptivity and outstanding impact-stiffening performance with extraordinary initial modulus (∼6.3 GPa), impact strength (∼178.5 MPa), and impact toughness (∼89.6 MJ m−3) under high-speed impact (∼5200 s−1). This work offers promising biomimetic design inspirations for the future development of advanced, flexible, sustainable, and protective materials.

Study on crack propagation mechanism and acoustic-thermal sensitivity analysis of pre-cracked weakly cemented rock

As the intensity and depth of coal mining gradually increase, environmental disturbances become more complex, and the degree of crack development in weakly cemented surrounding rocks continues to increase. In order to study the influence mechanism of crack angle on the fracture mechanism and acoustic − thermal precursor information of weakly cemented rocks, visual biaxial loading tests were conducted on pre-cracked weakly cemented rocks based on a transparent servo loading device, combined with digital speckle correlation method (DSCM), acoustic emission (AE), and infrared thermal imaging (ITI). The research results indicate that as the inclination angle of cracks increases, the initial strength, peak strength, and elastic modulus of rocks exhibit a logarithmic relationship of first decreasing and then increasing. When the inclination angle of the crack increases from < 30° to > 75°, the failure mode of weakly cemented rocks changes from shear to tension. The propagation path of deformation localization is consistent with the propagation trajectory of surface cracks, and the extension length and time of tensile cracks are longer than those of shear cracks. The acoustic − thermal sensitivity of weakly cemented rocks with crack inclination angle of > 45° is higher than that with crack inclination angle of ≤ 30°. The research results contribute to further understanding and mastering the mechanism of crack initiation and propagation in weakly cemented rocks containing joints, and provide theoretical guidance for engineering methods to control the deformation of weakly cemented surrounding rocks.