During several decades, interest in thermal electricity has rose rapidly [1,2]. Thermoelectric devices provide unique abilities and, therefore, are used in assemblies where any other way of direct or invert conversion of heat into electricity is difficult. For example, they are used for thermovisors cooling or combustion engines efficiency increasing [3,4]. The amount of thermal electricity application would significantly increase if thermoelectric converters efficiency will be increased up to 20-30%. The most promising variant of solution for the issue is the search for new materials with maximum possible thermoelectric figure of merit Z [5]. To achieve the high values of the parameter, it is necessary to ensure the lowest thermal conductivity of the material at the highest specific electrical conductivity and thermal electromotive force coefficient of a material. The materials with high Z are constantly searched for, at that, some new pages of material science and thermal electricity are discovered.When new materials are invented, the most important part of that process is produced samples performance tests. Most traditional measuring procedures show intrinsic shortcomings preventing valid data acquisition. Thereupon, we set the goal to develop the technology of accurate and quick measurements for integrated study of thermal and electrophysical qualities of thermoelectric materials. At that, it is supposed that all necessary characteristics of material will be measured simultaneously, the procedure shall be applicable for measurements within the range 100 - 450oK, moreover, for both homogeneous, and segmented branches of thermoelectric generators (TEG).This method is a kind of transient method and one of the easiest. Such methods were introduced as a class by Maldonado [6] for measuring both thermal conductivity and thermoelectric power of bulk materials. The advantages of these technics are good noise immunity, high information content, the ability to conduct experiments with small amplitude of electrical heating current, the independence of the measurement results from the initial temperature distribution and multiple process repeatability [7].At this stage, the initial mathematical model of our method is composed, its verification by means of numerical simulation is conducted, stand model for its experimental check is manufactured, and the first measurements performed.In this work, the principle of operation of the procedure in respect to the measurement of homogeneous sample thermal conductivity.
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