The current-voltage ( I - V ) and capacitance-voltage ( C - V ) characteristics of metal-organic compound conductive polymer-semiconductor Al/P2ClAn(C 2 H 5 COOH)/ p -Si structures were measured in the temperature range 80–340 K. P2ClAn: the poly(2-chloroaniline). The P2ClAn emeraldine salt was synthesized chemically by using propionic (C 2 H 5 COOH) acid. The analysis of I - V characteristics based on the thermoionic emission (TE) mechanism has revealed a decrease of zero-bias barrier height and a increase of the ideality factor at lower temperatures. Temperature dependence of the barrier height (BH) has shown a disagreement with those calculated from C - V characteristics. This behaviour is attributed to Schottky barrier inhomogeneities at interface. The temperature coefficient of BH has been found to be -2.9×10 -4 eV/K for Al/P2ClAn(C 2 H 5 COOH)/ p -Si. ln( I 0 / $T^{2})$ versus 1/ T plot gives activation energy and Richardson constant $A^{\ast}$ as 0.12 eV and 3.82×10 -9 A/K 2 cm 2 , respectively.