► Effects of heat treatment on the ageing response of a Ti–6Cr–5Mo–5V–4Al alloy. ► Temperatures of 440–500 °C result in the greatest strengthening. ► Ageing response declines at higher temperatures as α precipitates coarsen. ► Fast heating rates result in coarser, more uneven distributions of precipitates. ► Fast heating rates exhibit rapid loss of hardness due to coarsening. A study of the effects of temperature and heating rate upon the ageing response of a Ti–6Cr–5Mo–5V–4Al alloy was undertaken. The degree of strengthening declined with increasing ageing temperature as the precipitate morphologies became coarser, while the extent and thickness of grain boundary α increased with temperature. Ageing at temperatures between 440 °C and 500 °C result in the greatest age hardening response in times of around 4 h due precipitation of the α phase. At 440 °C the hardness increases from the initial solution treated value of 275 H V to more than 450 H V . The rate of heating to reach the isothermal ageing temperature has a substantial impact on the ageing response. Greater scatter was observed in hardness results for the samples aged using a faster heating rate at 500 °C. For ageing at 560 °C a faster rate of heating to the ageing temperature led to rapid declines in the hardness after the peak, equivalent to around 20% of the peak value. Slower heating rates (5 °C min −1 ) appear to increase the number of nucleation sites for precipitation of the α phase, forming finer, more even distributions of precipitates. Faster heating rates (∼100 °C min −1 ) produce coarser, less evenly distributed precipitates which coarsen more rapidly.