Influence Of Soil Composition Research Articles

Elemental chemical composition of soils and plants of Northern Yakutia, its ecological and biogeochemical assessment

This study investigated the composition and properties of the main soil types in the natural biogeocenoses of tundra and taiga in the coastal lowlands of the Arctic zone of Northern Yakutia. We have identified the total content of biologically important chemical elements in the soils and resource plants (N, P, K, Ca, Mn, Zn, Cu, Co, Mo, B, As, Be, Cd, Cr, Ni, Pb, Hg, V, Sb, and Sr), and the concentration of mobile forms of S, P, K, Fe, Mn, Zn, Cu, Co, Cd, Cr, Cr, Ni, and Pb in different extractants. We also specified the influence of soil composition and properties on the content of macro- and microelements. Various mobilities of chemical elements in soils and their availability to plants have been revealed. The amounts of chemical elements in the studied soils and plants were estimated according to agrochemical, biogeochemical and hygienic criteria and standards.

Influence of Soil Composition on the Profile and Content of Polyphenols in Habanero Peppers (Capsicum chinense Jacq.)

Capsicum chinense Jacq. obtained the designation of origin in 2010 due to the unique organoleptic properties given by the characteristics of soils in the Peninsula of Yucatán. So, the aim of this work was to investigate the effect of soil composition on the profile and concentration of polyphenols, antioxidant activity, and its relationship with the degree of maturity in habanero pepper (Capsicum chinense Jacq.). Pepper plants were grown in three soils named according to the Maya classification as: K’ankab lu’um (red soil); Box lu’um (black soil); and Chich lu’um (brown soil). The crops were cultivated in four different dates. The peppers were analyzed for antioxidant activity, profile and content of polyphenols. The results indicated that peppers grown in black soil had the highest concentration of total polyphenols (122.78 ± 12.60 mg of gallic acid 100 g−1), catechin (61.64 ± 7.55 mg 100 g−1) and antioxidant activity by DPPH (86.51 ± 0.82%). Physicochemical characterization indicated that black soil has the highest concentration of organic matter (10.93 ± 0.23%), nitrogen (52.01 ± 7.05 mg kg−1), manganese (5.24 ± 0.45 mg kg−1) and electric conductivity (2.32 ± 0.16 d Sm−1) compared to the other soils evaluated. These results demonstrate that the physicochemical composition of soils could be related to the biosynthesis of polyphenols in the habanero pepper.

Influence of Structure and Liquid Limit on the Secondary Compressibility of Soft Soils

The macroscopic mechanical properties of natural sedimentary soft soils, which are usually linked to their microstructure, are different from those of remolded soils. The interaction between soil structure and mechanical behavior is a manifestation of structural mechanics effects. It is essential to understand the effects of secondary compressibility to predict long-term foundation deformations. The effects of soil composition on secondary compression deformation are little studied, and the soil structure is rarely involved in the compression process. The sedimentary environment creates the initial composition and structure of soft soil, and it also basically determines its grain size and mineral composition, while different depths give soft soil different overburden pressures, and the soil composition and depth directly affect its yield stress during compression. So, natural sedimentary soft soils sampled at different depths and from different sedimentary environments (such as marine-neritic facies, sea shore facies and limnetic facies) were selected to study the influence of structure on the secondary compression coefficient Cα during pressure change and the relationship between soil composition and Cα. One-dimensional compression and consolidation creep tests were carried out on undisturbed and remolded samples. The undisturbed samples were obtained by the thin-wall samplers in rotary wash borings, and the quality of the samples met the test standard. Based on the concept of the void index Iv and the intrinsic compression line (ICL) proposed by Burland, the role of structure in the compression process was studied, and the influence of soil composition and structure on secondary compression characteristics was summarized. The Cα/Cc values are 0.031, 0.034, 0.030, and 0.036 for Shanghai, Tianjin, Suzhou, and Ningbo soft soils, respectively, within the range of inorganic clays and silts (0.04 ± 0.01) given by Mesri. According to the compression index Cc obtained by compression test, Cα/Cc can be used to estimate Cα. The yield stress of normal consolidated soil is near pre-consolidation pressure, while that of structural soft soil is greater than its pre-consolidation pressure. Natural sedimentary soft soils show over-consolidation characteristics due to the action of the structure; the soil structure resists the external load and hinders secondary compression. When the soil structure is almost destroyed, the pressure reaches the structure full yield stress P′. The tests of structural soft soils show that Cα changes with pressure before the structure completely yields, first increasing and reaching peak Cαmax near P′; the value of P′ is approximately 1.6–3.0 σ’k, where σ’k refers to the structure yield stress of soil obtained by the Casagrande method. After the structure disappeared, Cα gradually decreased and then stabilized, which is considered to be independent of the load. The Cαmax is positively correlated with the liquid limit, indicating that the peak value that can be reached by the Cα is related to the maximum content of bound water in soft soil, thus the soil composition has a significant influence on secondary compressibility, which contributes to the prediction of long-term foundation deformation.

The effects of warming and soil chemistry on bacterial community structure in Arctic tundra soils

Soil microbial communities in the Arctic play a critical role in regulating the global carbon (C) cycle. Vast amounts of C are stored in northern high latitude soils, and rising temperatures in the Arctic threaten to thaw permafrost, making relatively inaccessible C sources more available for mineralization by soil microbes. Few studies have characterized how microbial community structure responds to thawing permafrost in the context of varying soil chemistries associated with contrasting tundra landscapes. We subjected active layer and permafrost soils from upland and lowland tundra sites on the North Slope of Alaska to a soil-warming incubation experiment and compared soil bacterial community profiles (obtained by 16S rRNA amplicon sequencing) before and after incubation. The influence of soil composition (characterized by mid-infrared [MIR] spectroscopy) on bacterial community structure and class abundance was analyzed using redundancy and correlation analyses. We found increased abundances of Alphaproteobacteria, Gammaproteobacteria, and Bacteroidetes [Sphingobacteriia] post incubation, particularly in permafrost soils. The categorical descriptors site and soil layer had the most explanatory power in our predictive models of bacterial community structure, highlighting the close relationship between soil bacteria and the soil environment. Specific soil chemical attributes characterizing the soil environments that were found to be the best predictors included MIR spectral bands associated with inorganic C, silicates, amide II (CN stretch), and carboxylics (C–O stretch), and MIR peak ratios representing C substrate quality. Overall, these results further characterize soil bacterial community shifts that may occur as frozen environments with limited access to C sources, as is found in undisturbed permafrost, transition to warmer and more C-available environments, as is predicted in thawing permafrost due to climate change.

Experimental Analysis of the Influence of Soil Composition on Strength Characteristics

This study investigates the influence of soil composition on soil strength by performing direct shear test on various samples, including artificial soil with different components, artificial mixed soil with different amounts, natural soil with different moisture contents, and sandy soil with different sizes. The test results show that soil strength is determined by the joint effect of inter-particle friction and cohesion. Mineral composition and water content are the main factors affecting clay strength. Changes in the mineral composition and water content of clay alter the contact state and connection of its particles, thereby significantly affecting the macroscopic properties of the soil. Different grain compositions modified the shear deformation characteristics by altering the arrangement and intergranular engagement of the particles, consequently affecting the strength. The results of this study provide further insight into the micro and fine mechanism of the soil shear strength characteristics of different components. This study also offers guiding significance in engineering practice.

Influence of soil composition and drying methods on chemical and physical quality evaluation of saffron

Influence of soil composition and drying methods on chemical and physical quality evaluation of saffron

Critical evaluation of distillation procedure for the determination of methylmercury in soil samples

In the present work, the efficiency of distillation process for extracting monomethylmercury (MMHg) from soil samples was studied and optimized using an experimental design methodology. The influence of soil composition on MMHg extraction was evaluated by testing of four soil samples with different geochemical characteristics. Optimization suggested that the acid concentration and the duration of the distillation process were most significant and the most favorable conditions, established as a compromise for the studied soils, were determined to be a 70 min distillation using an 0.2 M acid. Corresponding limits of detection (LOD) and quantification (LOQ) were 0.21 and 0.7 pg absolute, respectively. The optimized methodology was applied with satisfactory results to soil samples and was compared to a reference methodology based on isotopic dilution analysis followed by gas chromatography-inductively coupled plasma mass spectrometry (IDA-GC-ICP-MS). Using the optimized conditions, recoveries ranged from 82 to 98%, which is an increase of 9–34% relative to the previously used standard operating procedure. Finally, the validated methodology was applied to quantify MMHg in soils collected from different sites impacted by coal fired power plants in the north-central zone of Chile, measuring MMHg concentrations ranging from 0.091 to 2.8 ng g−1. These data are to the best of our knowledge the first MMHg measurements reported for Chile.

Influence of soil composition on the major, minor and trace metal content of Velebit biomedical plants

The use of medical herbs for the treatment of many human diseases is increasing nowadays due to their mild features and low side effects. Not only for their healing properties, but also for their nutritive value supplementation of diet with various herbs is recommended. Thus also their analysis is of rising importance. While total elemental compositions are published for many common herbs, the origin of toxic as well as beneficial elements is not yet well investigated.Thus different indigenous medicinal plants, namely Croatian spruce (Picea abies), savory (Satureja montana L.), mountain yarrow (Achillea clavennae), showy calamint (Calamintha grandiflora), micromeria (Micromeria croatica), yellow gentian (Gentiana lutea) and fir (Abies alba) together with soil samples were collected in the National Park Northern Velebit. The macro- and trace elements content, after microwave digestion, was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and inductively coupled plasma mass spectroscopy (ICP-MS).The study focuses on the one hand on essential elements and on the other hand on non-essential elements which are considered as toxic for humans, covering in total Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Sr and Zn.

Changes in macrominerals, trace elements and pigments content during lettuce (Lactuca sativa L.) growth: Influence of soil composition

Changes in macrominerals, trace elements and photosynthetic pigments were monitored at 5 stages of lettuce growth. Plants were grown in three experimental agriculture greenhouse fields (A1, A2 and A3). Soil composition was also monitored to understand its influence on lettuce composition. In general, the content of macrominerals, trace elements, chlorophylls and carotenoids decreased during lettuce growth and consequently, high nutritional value was observed at younger stages. A2 lettuces showed an increase of Fe, Al, Cr, V and Pb due to the different soil physicochemical parameters. Multiple linear regression analysis with stepwise variable selection, indicated that soil characteristics, namely, pH(CaCl2) for Fe and Cr, silt and fine-sand for Al and V, OM for Al and Pb, coarse-sand and CEC for Cr, had a key role determining element bioavailability and plant mineral content. Thus, lettuce nutritional value was strongly dependent of growth stage and soil characteristics.

The influence of soil composition on the leachability of selected hydrophobic organic compounds (HOCs) from soils using a batch leaching test

The influence of soil composition (peat and clay content) on the leachability was investigated in batch leaching experiments for chemically diverse hydrophobic organic compounds (HOCs: PCP, PAHs, HCB, HCHs, PCBs, and TCDD/Fs). An experimental design was applied to generate 8 diverse soil matrices, and the results were evaluated by orthogonal projections to latent structures (OPLS), as well as compound specific response surface models. Overall, the distribution coefficients (logKd) of model HOCs were in the range of approx. 2.0–5.7. The Kd-values of HCHs, phenanthrene and PCP were positively correlated with the peat content. Kd-values of benzo(a)anthracene, HCB, and PCB 47 were positively correlated with both peat and clay content. The Kd-values of 1,3,6,8-TCDD and 1,3,6,8-TCDF were positively correlated with peat content but negatively correlated with clay content, while for PCB 153 and PCB 155 the correlations were reversed. The correlation between the Kd-values and the compounds’ Kow-values was linearly for compounds with log Kow <6. For HOCs with log Kow>6, the Kd-values were leveling off, possibly due to small particles in the leachates. Our study demonstrated how complex interaction between both the organic matter and clay components influences the leachability of HOCs in a compound-specific manner.

Effects of soil composition on solid phase microextraction determination of triazine and organophosphorus pesticides

The influence of organic matter and clay contents on headspace solid phase microextraction (HS-SPME) determination of triazine and organophosphorus pesticides in different soils was studied. The results of the study showed that content of soil organic matter dominantly participated in sorption of triazines (simazine, atrazine and prometryn) to soil, while sorption of organophosphorus pesticides (phorate and tebupirimfos) could not be explained only by contents of dominant soil sorption components (soil organic matter and clay). Sorption of all pesticides studied to different soil types was similar at their lower concentrations while the influence of soil composition was expressed at higher concentration levels. Except for phorate, the obtained sorption trends were different from those obtained by direct SPME mode (DM-SPME) and exhaustive liquid-solid extraction (LSE) method. These results indicated that most likely co-extractants from the analyzed medium complicated evaporation and diffusion of the pesticides to the PDMS fiber during HS-SPME sampling.

Burrow types of the European wild rabbit in southwestern Spain

Burrows play an essential role for the European wild rabbit. They provide shelter, a safe breeding place and protection against climatic extremes. However, little is known about burrow structure and the environmental factors influencing it. In this work we analyse the structure of rabbit burrow tunnels in southwestern Spain and search for structural types. In addition, we study the influence of soil composition on burrow tunnel structure. For this purpose, a total number of 122 burrow tunnels were located and measured. A principal component analysis and a two-step cluster analysis were performed to identify burrow tunnel types. Three different types of natural burrow tunnels have been identified. Furthermore, the texture and composition of the soil were found to notably influence burrow tunnel structure. This study shows that rabbits tend to excavate bigger burrow tunnels in soils characterised by sandy soils of a mostly large particle composition, while the higher proportion of small particles in silty soils promotes shorter and narrower burrow tunnels.

Cement stabilised rammed earth. Part A: compaction characteristics and physical properties of compacted cement stabilised soils

Rammed earth is used for load bearing walls of buildings and there is growing interest in this low carbon building material. This paper is focused on understanding the compaction characteristics and physical properties of compacted cement stabilised soil mixtures and cement stabilised rammed earth (CSRE). This experimental study addresses (a) influence of soil composition, cement content, time lag on compaction characteristics of stabilised soils and CSRE and (b) effect of moulding water content and density on compressive strength and water absorption of compacted cement stabilised soil mixes. Salient conclusions of the study are (a) compaction characteristics of soils are not affected by the addition of cement, (b) there is 50% fall in strength of CSRE for 10 h time lag, (c) compressive strength of compacted cement stabilised soil increases with increase in density irrespective of moulding moisture content and cement content, and (d) compressive strength increases with the increase in moulding water content and compaction of CSRE on the wet side of OMC is beneficial in terms of strength.

Infiltration characteristics of volcanic sloping soils on Mt. Elgon, Eastern Uganda

Water infiltration is an important hydrological process that influences runoff and soil loss patterns in mountain ecosystems. In this paper, we present results on spatial variation in infiltration in croplands on the volcanic soils of Mt. Elgon, in Eastern Uganda. Twelve experimental sites with slope gradients ranging from 12 to 32% were established. Infiltration tests were carried out with a double ring infiltrometer and three measurements were taken at the upper, middle and lower sections of each experimental site to assess the local variability of infiltration. In addition soil information was collected on each experimental site. The soil infiltration data were then evaluated to fit to four commonly used water infiltration models: (1) Philip (1957), (2) Green-Ampt (1911), (3) Horton (1940) and (4) Kostiakov (1932). The twelve experimental sites cover two cropping systems: annual (6 sites) and perennial (6 sites) crops. Based on the results, we examine the spatial variability of infiltration, the relationship of infiltration to landscape position, and the influence of soil composition on infiltration rates on the slopes. The factors affecting spatial variability of soil infiltration were analysed using correlation and regression techniques. Steady state infiltration rates generally increased with the slope gradient and were crop type independent (P<0.05). The performance of the four applied water infiltration models was generally good with mean R-2 values ranging from 0.79 to 0.87, although all the models tended to over-predict the steady state infiltration rates at most sites. Overall, the Philip's and Kostiakov gave better results than the Horton and Green-Ampt models in reproducing the infiltration process on Mt. Elgon. (C) 2009 Elsevier B.V. All rights reserved.

Influence of soil texture on the binding energies of fine mineral dust particles potentially released by wind erosion

Models of the two aeolian processes (saltation and sandblasting) that lead to emission of fine dust particles (PM20) by wind erosion in arid and semi-arid areas have been combined to form the so-called ‘Dust Production Model’ (DPM). In this model, the size dependent binding energies of PM20 embedded within the wind-erodible loose soil aggregates or in the soil surface itself are key input parameters. Indeed, their values condition at the same time the intensity of emissions and their initial size distribution. Previous comparisons of vertical mass fluxes measured on-field with the model predictions suggest that these energies might be relatively independent of soil texture and also probably composition. Because this would greatly facilitate application of the DPM at regional or global scale, the objective of this work is to check experimentally the veracity of this result. The strategy that has been designed for this has involved selecting four natural soil samples collected in various source areas of the world and covering a wide range of textures and compositions. Then, these soil samples have been used to perform carefully controlled wind erosion simulations in a wind tunnel. During the experiments, which were carried out at different wind speeds with each soil, the horizontal flux ( F h) of saltating soil aggregates has been monitored. At the same time, number concentrations ( C i) of PM20 released by the sandblasting process were recorded in the 6 size classes of an optical size analyzer. Thus, the efficiency of the sandblasting process (defined as the ratio of C i to F h) could be determined for each of these size classes. Analysis of the results obtained in similar saltation conditions shows that for the four tested soils, and within the range of contents in clay and other components favoring aggregation (mostly organic matter and carbonates), the influence of soil composition and texture on binding energies of the PM20 particles within soil aggregates is at best a second order effect that can be neglected in large scale modeling of wind erosion by the DPM.

THE KINETICS OF MIGRATION OF DIESEL FUEL THROUGH THE SOIL DURING THE TECHNOLOGICAL SPILLS AND TRANSPORT ACCIDENTS

The article considers the environmental consequences of transport accidents with oil products, which take place in Ukraine. A considerable influence of soil composition, the degree of its compaction, and also the soil examination procedure onto migration of oil products has been demonstrated. Some hypotheses on different mechanisms of oil products migration through soils have been suggested. The obtained data allow formulating recommendations regarding measures to eliminate the consequences of such accidents.

Influence of soil composition on adsorption of glyphosate and phosphate by contrasting Danish surface soils

SummaryThe herbicide glyphosate and inorganic phosphate are strongly adsorbed by inorganic soil components, especially aluminium and iron oxides, where they seem to compete for the same adsorption sites. Consequently, heavy phosphate application may exhaust soil's capacity to bind glyphosate, which may lead to pollution of drain‐ and groundwater. Adsorption of phosphate and glyphosate to five contrasting Danish surface soils was investigated by batch adsorption experiments. The different soils adsorbed different amounts of glyphosate and phosphate, and there was some competition between glyphosate and phosphate for adsorption sites, but the adsorption of glyphosate and phosphate seemed to be both competitive and additive. The competition was, however, less pronounced than found for goethite and gibbsite in an earlier study. The soil's pH seemed to be the only important factor in determining the amount of glyphosate and phosphate that could be adsorbed by the soils; consequently, glyphosate and phosphate adsorption by the soils was well predicted by pH, though predictions were somewhat improved by incorporation of oxalate‐extractable iron. Other soil factors such as organic carbon, the clay content and the mineralogy of the clay fraction had no effect on glyphosate and phosphate adsorption. The effect of pH on the adsorption of glyphosate and phosphate in one of the soils was further investigated by batch experiments with pH adjusted to 6, 7 and 8. These experiments showed that pH strongly influenced the adsorption of glyphosate. A decrease in pH resulted in increasing glyphosate adsorption, while pH had only a small effect on phosphate adsorption.

Thermal treatment of soils contaminated with gas oil: influence of soil composition and treatment temperature

Samples of two soils containing different organic matter contents, neat or contaminated with gas oil (diesel fuel oil) at 2.5 wt.% were heated from room temperature to different final temperatures (200–900 °C). The experiments, performed in an anaerobic media, simulate conditions pertinent to ex situ thermal desorptive and thermal destructive treatments. The products generated during the heating were collected and light gases were analyzed by gas chromatography. The results indicate that the chemical composition of the soil is a key factor since it strongly influences the quantity and composition of the off-gases. According to the liquid and light gas yields, the gas oil does not affect appreciably the generation of pyrolysis products of the own soil constituents and the gas oil does not suffer significant chemical transformations even at high operating temperatures (e.g. 900 °C). With surface areas of 16 000 cm 2/g (Soil A) and 85 000 cm 2/g (Soil B) based on the monolayer adsorbed model, 4 and 20%, respectively, of the original gas oil can be adsorbed. These values are in good agreement with experimental data. Even for high temperatures, the employed thermal treatment is capable to practically remove the gas oil from the soil bed without changing appreciably the original chemical composition of the contaminant.

Partitioning and speciation of chromium, copper, and arsenic in CCA-contaminated soils: influence of soil composition

This study focused on the influence of soil composition and physicochemical characteristics on the retention and partitioning of Cu, Cr and As in nine chromated copper arsenate (CCA) artificially contaminated soils. A statistical mixture design was used to set up the number of soils and their respective composition. Sequential extraction and modified solvent extraction were used to assess Cu and Cr partitioning and As speciation [As(III) or As(V)]. It was found that peat had a strong influence on CEC (232 meq/100 g), on buffer capacity and on Cu and Cr retention, whereas kaolinite's contribution to the CEC was minor (38 meq/100 g). Average metal retention in mineral soils was low (58% for Cu and 23% for Cr) but increased dramatically in highly organic soils (96% for Cu and 78% for Cr). However, both organic and mineral soils demonstrated a very high sorption of added As (71–81%). Levels of Cu and Cr in a soluble or exchangeable form (F1) in highly organic soils were very low, whereas the levels strongly bound to organic matter were much higher. Conversely, in mineral soils, 47% of Cu and 18% of Cr were found in F1. As a result, Cr and Cu in moderately and highly organic contaminated soils were present in less mobile and less bioavailable forms, whereas in mineral soils, the labile fraction was higher. The modified method used for selective determination of mineral As species in CCA-contaminated soils was found to be quantitative and reliable. Results revealed that arsenic was principally in the pentavalent state. Nevertheless, in organic soils, arsenite was found in significant proportions (average value of 29% in highly organic soils). This indicates that some reduction of arsenate to arsenite occurred since the original species in CCA is As(V).

Influence of soil carbonates in lead fixation

Abstract Despite the progressive decrease in emissions coming from a variety of sources, lead continues to be one of the toxic metals more often found as environmental pollutants. Of particular concern is lead migration through the soil which may result in contamination of water supplies through the leaching caused by water infiltration. Carbonate minerals are frequently found in soils and those of heavy metals are usually insoluble so carbonates in the soil could act as a sink for heavy metals for as long as the environmental conditions guarantee their stability. The influence of soil composition on the fixation of lead from aqueous solutions of this metal has been studied. Two clayey soils with different carbonate content have been used in the tests. The kinetics and equilibrium of retention of lead in the soils under different conditions of pH and salinity have been determined using batch and fixed‐bed column experiments. Carbonate precipitation and ion exchange were the main processes responsible for ...