Open circuit corrosion testing of austenitic stainless steels, AISI types 304, 310 and 316, and of an Inconel alloy in boiling 5% NaCl solution at pH 2.5 was carried out. The influences of aeration and the introduction of Cl 2 and/or H 2S were also examined. Cl 2 accelerated corrosion, pitting and crack formation whereas H 2S had an inhibiting effect on the corrosion rates and pitting but induced hydrogen attack, which appeared in the form of blisters on the surface specimen. H 2S in the absence of oxygen resulted in the growth of corrosion product on the specimen surface, instead of dissolution, but the cracking tendency also increased due to hydrogen penetration. Addition of trisodium phosphate to the corrosive solution markedly reduced pitting and lowered the corrosion rate by approximately half. Throughout the various tests it was found that the resistance of different alloys to hot chloride corrosion was in the order 310 > 316 > 304 > Inconel.
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