Reinforced Concrete (RC) structures eroded by chloride ions will reduce the chloride ion concentration on the concrete surface under the effect of sustained rainfall dilution and erosion, and there will be rainfall convection areas and peak chloride ion contents. In this study, the influence of rainfall environment on the transporting behavior of chloride ions in concrete is studied through capillary absorption test and rainfall experiment. A numerical prediction model of chloride ion transporting behavior in concrete was established by COMSOL Multiphysics based on the rainfall tests. The chloride behavior is analyzed and studied. It is found that the numerical simulation results are in good agreement with the experimental results, and the predicted models of chloride ion diffusion under different rainfall conditions are obtained, and the transporting behavior of chloride ions can be effectively predicted. The results also show that with the increasing of rainfall intensity and rainfall time, the chloride ion contents on the concrete surface decreases obviously. When the rainfall time and rainfall intensity increase, the chloride ion contents of concrete decreases, and the binding capacity of chloride ions in the matrix weakens. This research provides some resulting information of RC structures in rainy marine areas.