Increase In Initial Temperature Research Articles

Microstructures and properties of Pr,Ce:Gd2O2S ceramics fabricated from powders synthesized at different initial water bath temperatures

Crystallized precursor with stacked layered was synthesized in hot water bath using oxide powders and concentrated sulfuric acid as raw materials. Gd2O2S powders with high phase purity were obtained by reducing the precursor under flowing hydrogen atmosphere. The influence of initial bath temperature of Gd2O3 and H2SO4 on the microstructure of Gd2O2S powders was investigated. The Gd2O2S:Pr,Ce powders showed a stacked layered structure and as the initial water bath temperature increases, the particle size of the flaky powders also increases. Using the synthesized powders, Gd2O2S:Pr,Ce scintillation ceramics were fabricated through pre-sintering in vacuum followed by HIP post-treatment in argon atmosphere. The Gd2O2S:Pr,Ce ceramics fabricated from the powders synthesized at lower initial water bath temperature show a rapid densification rate during pre-sintering. The Gd2O2S:Pr,Ce ceramic sample fabricated from powders synthesized at 7°C showed the highest optical transmittance, XEL intensity, and light yield value of 25,800 ph/MeV @ 662 keV γ rays. The PL decay time of Pr3+3P0→3H4 transition was measured to be ∼2.87 μs for all ceramic samples. The effect of the initial water bath temperature on optical transmittance and light yield of Gd2O2S:Pr,Ce ceramics was also discussed.

Experimental study on the discharge characteristics of high-voltage nanosecond pulsed discharges and its effect on the ignition and combustion processes

Non-equilibrium plasma has been proven to expand ignition limits and enhance combustion. This paper uses high-voltage nanosecond pulsed discharge (NPD) to generate non-equilibrium plasma and experimentally studies the discharge characteristics at different parameters in a constant-volume combustion bomb. NPD is used to ignite the methane-air mixture, and the effects of pulse power output voltage and pulse interval (PI) on ignition and combustion processes are studied. In addition, the minimum ignition energy (MIE) at different ignition methods (Transistor coil ignition (TCI) and NPD) is also studied. The results show that the first pulse of NPD discharge has a higher breakdown voltage and discharge energy when using multi-pulse discharge. After the second pulse, the highest breakdown voltage and current tend to stabilize, and the discharge energy remains unchanged. As the PI increases, the breakdown peak voltage and the peak current increase slightly. The study on the MIE of NPD shows that at different mixture concentrations, the MIE of NPD is smaller than that of TCI, and NPD can expand the lean burn limit. An increase in initial temperature can significantly reduce MIE. In addition, when the discharge energy is near the MIE, the combustion stability begins to decrease, and the combustion cycle fluctuates wildly. When the ignition energy is increased, the stability improves, and the combustion fluctuation rate can be maintained within 5%.

The laminar burning velocity of propyl acetate at high pressures and temperatures

Since propyl acetate has the potential to be used as a biofuel in heat engines, it is necessary to ascertain and comprehend its combustion properties. Using equivalence ratios of 0.7–1.4, the laminar burning velocity of propyl acetate was studied in the constant volume combustion vessel at the initial pressures of 1, 2, and 4 bar and initial temperatures of 390 K, 420 K, and 450 K. The constant volume method was used to determine the burning velocity via extrapolations at the initial condition. In addition, a ten-fitted empirical correlation was formulated to calculate the burning velocity for pressures and temperatures as high as 8 bar and 534 K, respectively. The extrapolated burning velocity showed good agreement with the numerical simulation burning velocity, and the correlated burning velocity agreed well with the extrapolated burning velocity. The laminar burning flux was also investigated and was ascertained that laminar burning flux increases as the initial pressure and temperature increase. The fuel mixture density significantly influences the burning flux as the initial pressure rises, whereas the laminar burning velocity has a notable impact on the burning flux as the initial temperature rises. In summary, this study advances our knowledge of propyl acetate combustion, particularly concerning its flame propagation at higher pressures and temperatures and its potential application in combustion engines, and the data are of great engineering value for developing and understanding the combustion science of propyl acetate.

Future Global River Ice in CMIP6 Models under Climate Change

Abstract River ice changes due to climate change significantly impact river hydrology, economies, and societies. This study employed the CMIP6 data and a river ice model to predict global river ice changes in response to climate change. Results indicate significant declines in global river ice due to global warming. With each 1°C increase in surface air temperature (SAT) in the future, river ice extent of ice-affected rivers decrease by 2.11 percentage points, and ice duration shorten by 8.4 days. Under the SSP2-4.5 scenario, the long-term mean SAT is 1.2°C to 2.5°C higher than in the near-term. This leads to a 1.9 percentage points to 4.4 percentage points decrease in global river ice extent, a 6.8 to 15.1-day decrease in river ice duration, and ice-free rivers increasing by up to 4.02%. The SSP5-8.5 scenario predicts a warmer long-term mean SAT, leading to greater reductions in river ice. Geographically, river ice loss is most notable in North America, Europe, Siberia, and the Tibetan Plateau (TIB), particularly in peninsular, coastal, and mountainous regions due to the combined effects of initial temperatures and temperature increases. Overall, the E.Europe (EEU) shows the greatest loss of river ice on average. Monthly analyses show the most substantial decreases from October to June, indicating pronounced seasonal variability. This study provides valuable insights for addressing challenges related to river ice changes in high-latitude and high-elevation regions.

Chemical reaction network analysis on N2O emissions control strategies of ammonia/ methanol Co-combustion

As a kind of substitute fuel of hydrocarbon fuel, ammonia has gained increasing attention for its potential to reduce carbon emissions. Blending with carbon-neutral methanol is expected to deal with the slow flame speed of ammonia. Nevertheless, the emission of N2O, a byproduct of ammonia combustion, would undermine the carbon reduction benefits due to its high global warming potential. This study employed Chemkin to construct a Chemical Reaction Network (CRN) model to analyze the reaction kinetics of ammonia combustion when blended with a small amount of methanol. It finds that the increases in the methanol blending ratio, pressure, and temperature can reduce greenhouse gas emissions effectively. Further analysis indicates that pressure and temperature have distinct effects on the emission mechanisms of N2O and NO. Increasing the combustion pressure weakens the chain reactions, thereby reducing the formation of both NO and N2O; the increase in initial temperature raises NO emissions, but also promotes the decomposition of N2O due to the abundance of H in the post-combustion phase. Optimizing post-combustion efficiency and controlling the formation of NO are crucial for N2O emission control. Thus, a staged methanol injection strategy is proposed, where early injection reduces NO emissions and late injection facilitates the decomposition of N2O.

Effects of mixture initial conditions on deflagration to detonation transition enhanced by transverse jets

To explore the effects of mixture initial conditions on the deflagration to detonation transition (DDT) enhanced by transverse jets, numerical studies were conducted on the flame acceleration of H2/Air mixture under different initial conditions, including initial pressure, temperature, and equivalence ratio. The results indicate significant differences in flame acceleration processes under different initial pressures (0.05, 0.1, 0.15, and 0.2 MPa). Changes in jet intensity and combustion rate induced by variations in mixture initial pressure collectively influence the flame acceleration process, but the impact of jet intensity is more significant. However, effective coupling between transverse wave propagation and flame acceleration is also crucial for the DDT process. Changes in mixture initial temperature (300, 350, 400, and 450 K) and equivalence ratio (0.8, 1.0, 1.2, and 1.4) have negligible impact on jet intensity. The variation trend of flame velocity under different initial temperatures or equivalence ratios is consistent, but the detonation initiation performance is slightly different. As the initial temperature increases, the DDT distance and DDT time are shortened. With an increasing equivalence ratio, the DDT distance and DDT time initially decrease and then increase, reaching the shortest at slightly rich fuel conditions.

Study of Condensation during Direct Contact between Steam and Water in Pressure-Relief Tank

Direct contact condensation (DCC) is a phenomenon observed when steam interacts with subcooled water, exhibiting higher heat and mass transfer rates compared to wall condensation. It has garnered significant interest across industries such as nuclear, chemical, and power due to its advantageous characteristics. In the context of pressure-relief tanks, understanding and optimizing the DCC process are critical for safety and efficiency. The efficiency of pressure-relief tanks depends on the amount of steam condensed per unit of time, which directly affects their operational parameters and design. This study focuses on investigating the direct gas–liquid contact condensation process in pressure-relief tanks using computational fluid dynamics (CFD). Through experimental validation and a sensitivity analysis, the study provides insights into the influence of inlet steam parameters and basin temperature on the steam plume characteristics. Furthermore, steady-state and transient calculation models are developed to simulate the behaviour of the pressure-relief tank, providing valuable data for safety analysis and design optimization. There is a relatively high-pressure area in the upper part of the bubble hole of the pressure-relief tube, and the value increases as it is closer to the holes. The steam velocity in the bubbling hole near the 90° elbow position is higher. This study contributes to the understanding of steam condensation dynamics in pressure-relief tanks. When the steam emission and pressure are fixed, the equilibrium temperature increases linearly as the initial temperature increases (where a = 1, b = 20 in y = a x+ b correlation), the equilibrium pressure increases nearly exponentially, and the equilibrium gas volume decreases. When the steam emission and initial temperature are fixed, the equilibrium temperature does not change as the steam discharge pressure increases. The correlations between the predicted equilibrium parameters and the inlet steam parameters and tank temperature provide valuable insights for optimizing a pressure-relief tank design and improving the operational safety in diverse industrial contexts.

Studies of the diluent, temperature and pressure effect on the lower and upper flammability limits of ammonia in air

Ammonia safety and environmental protection research forms the basis for its role as a clean energy carrier. In this work, an experimental study was conducted in this work to analyze the effect of different inhibitors (nitrogen, argon and water vapor) on the flammability limits (FLs) of ammonia at elevated temperatures and pressures. In addition, the influence of diluents on the compositions and flame temperature changes was evaluated, and the temperature sensitivity coefficients of the elementary reactions and the ROP of free radicals and partial products at the FL concentrations were analyzed. The findings indicated that water vapor provided the strongest flame retardant effect on ammonia in three inhibitors. Within a certain temperature and pressure range, the FLs of ammonia in ammonia/diluent/air can be predicted using the extended Le Chatelier equation. The flame temperature decreased at the lower flammability limit (LFL) concentrations and increased at the upper flammability limit (UFL) concentrations of ammonia with increasing initial pressure. As the initial temperature increases, the flame temperature decreases during ammonia combustion. The influence of ammonia concentration on flame temperature is greater than that of diluents dilution. The elementary reactions H+O2<=>O+OH (R1) and NH2+NO<=>NNH+OH (R82) were the primary reactions that increased the flame temperature at the FL ammonia concentrations in ammonia/diluent/air. Conversely, NH2+NO<=>N2+H2O (R80) and H+O2(+M)<=>HO2(+M)(R15) were the main reactions that decreased the flame temperature. H, OH and NH2 radicals played a crucial role in the combustion reaction process at ammonia FL concentrations. At the LFL concentrations of ammonia, the molar fraction of the OH radical showed the greatest variation, while at the UFL concentrations of ammonia it was NH2 radical. The elementary reaction NH3+OH<=>NH2+H2O (R158) was the primary reaction that consumed OH radical and promoted the formation of NH2 radical. Free radical concentrations decreased with increasing pressure and temperature, while the change rate of free radical ROP accelerated with increasing pressure. In addition to nitrogen and water, the partial products were mainly nitric oxide at the LFL concentrations, while at the UFL concentrations were mainly hydrogen.

Influence of multi-walled carbon nanotubes on thermal behaviour and mechanical properties of pineapple leaf fibre-based natural rubber composites

Replacing synthetic fibres with natural fibres as reinforcement fillers in natural rubber (NR) tends to yield eco-friendly bio-composites. This study investigated the tensile and hardness properties, and the thermal behaviour of pineapple leaf fibre (PALF)-reinforced NR composites with and without the addition of multi-walled carbon nanotubes (MWCNT). The fibre content was varied at 0, 10, 20, and 30 parts per hundred rubber (phr) and the MWCNT content was fixed at 10 phr. The surface morphology of the tensile-fractured specimens was examined using scanning electron microscopy (SEM) to identify the rubber-matrix adhesion and tear mechanisms of the fibres in the NR matrix. The results revealed that including the PALF and MWCNT allowed the NR composites to exhibit excellent stretching stress at low elongations. Additionally, the composites displayed enhanced stiffness, further increasing the hardness of the composite, ranging from 46.8 to 62.8 Shore A. However, PALF reduces the thermal stability of the composite, where the initial degradation temperature increases. From the thermogravimetric analysis, the residues remaining in the NR composites ranged from 6 to 13% at various fibre loadings. Therefore, this study provides valuable insights into the tensile and hardness properties and the thermal behaviour of PALF-reinforced NR composites to improve end-use properties.

Experimental and simulation study on the expansion mechanism of polyurethane grout

Understanding the expansion mechanism of polyurethane polymer grout can supply guidance for accurate grouting. However, most of the polymer grout expansion calculations were defined simplistically by the polymer density-expansion pressure empirical relationship expression, which failed to meet the time history of the expansion pressure during the polymer reaction process. The objective of this paper was to investigate the expansion mechanism of polyurethane foam in various constraint conditions during the whole polymer reaction process. A model describing the expansion mechanism of polyurethane foam was established based on the energy conservation principle, the chemical reaction kinetic equation solved by the Runge-Kutta method, and the ideal gas state equation. The model was proved applicable compared to the experiments under fixed volume and fixed confining pressure boundaries. In addition, the effects of grouting quantity, confining pressure, initial temperature, and physical foaming agent content on the grout expansion pressure, density, and components conversions were discussed. The results showed that the expansion pressure of polymer grout gradually increased with time under the fixed volume conditions, and the grout expansion pressure increased as the density increased. The final grout expansion pressure will increase with the increase of initial temperature or the content of physical blowing agent. Under the fixed confining pressure condition, the polymer grout density gradually decreased with time, the grout density increased as the confining pressure increased while the conversions of the two components alcohol and isocyanate increased. The final density decreases with the increase of initial temperature or the content of physical blowing agent.

Preparation and characterization of halloysite nanotube‐silica/silicone rubber composites: Effect of HNTs on mechanical and thermal properties

AbstractA series of halloysite nanotube‐silica (HNTs‐SiO2) nanocomposite fillers were prepared by in‐situ assembly, and a reinforced SiO2/SR composite was obtained by filling them into silicone rubber (SR). The morphology and structural characterization of HNTs‐SiO2 and HNTs‐SiO2/SR and the properties of the HNTs‐SiO2/SR were studied. As a result, the small particle size SiO2 was firmly anchored onto the HNTs surface, and the obtained HNTs‐SiO2 nanofillers were uniformly dispersed in SR. At a 30 phr fixed filler loading, the weakest filler network and the best filler dispersion were obtained when HNTs content in HNTs‐SiO2 was 5%. This resulted in a maximum tensile strength obtained of 6.2 MPa, 1.55 times that of SiO2/SR with the same filler loading, and a maximum elongation at break of 418%, 1.67 times that of the SiO2/SR with the same filler loading, and at the same time the tearing strength and hardness are also improved. Furthermore, the silicone rubber also showed improved thermal stability, with an initial degradation temperature increase of 30°C under a nitrogen atmosphere.Highlights HNTs–SiO2 nanocomposites were successfully prepared by the self‐assembly method and used as fillers in SR as a new type of reinforcing material. The 1D HNTs act as a barrier to prevent SiO2 aggregation and improved fillers dispersion. The elongation at break and tensile strength of 5% HNTs‐SiO2/SR are 67% and 55% higher than those of SiO2/SR, respectively. The silicone rubber also showed improved thermal stability.

Experimental study on mechanical properties and evolution of fracture failure of granite considering initial temperature damage and prefabricated fissure length

With the increasing mining depth of deep mineral resources, the influence of high temperature on the fracture failure of surrounding rock with fissures becomes increasingly serious. To investigate the fracture mechanical properties and the evolutionary characteristics of fracture process of fissured rock experiencing initial temperature damage, the three-point bending experiment was conducted on the small sized granite samples with different initial damaging temperatures and prefabricated fissure lengths by applying a μTS mesoscopic testing system. Based on the digital image correlation methods, the evolution of fracture process zone of sample was revealed. Moreover, the macroscopic fracture failure of sample was predicted by the evolution of time-varying acoustic emission b-value. The results show that with the increase of initial damaging temperature and prefabricated fissure length, the peak load of granite sample has a decreasing trend and the fracture characteristics of sample experiencing initial temperature damage gradually transform from brittleness fracture to ductility fracture, resulting in a decrease in the fracture toughness of sample. The crack tip opening displacement, the critical opening displacement and the length of fracture process zone of sample all show an increasing trend. The time interval from the time when time-varying acoustic emission b-value continues to decline to the appearance moment of macroscopic cracks is selected as the warning time of fracture failure of sample, which can conclude that the warning time increases with increasing the initial damaging temperature and prefabricated fissure length, indicating an increase in ductility and a reduction in failure suddenness of sample.

Feasible Parameters of Ohmic Areas of YBaCuO Thin Films Switched via Moving Unstable Border between Superconducting and Normal States

A system of two equations based on one of the classical electricity laws was used to determine the sizes and temperatures of ohmic areas formed under action of overcritical nanosecond electrical pulses. Calculations were performed at five points for three experimentally obtained voltage–current (V-I) dependences for samples with the same geometry but different critical current density values. The system included two additional conditions to satisfy the known descriptive model of transition from superconducting (SC) to a normal (N) state—S-N switching—and to obtain physically acceptable solutions over the entire current range of V-I dependence. The solution for each point takes the form of a function, since the initial temperature increase of the primary channel across the film is entered as a parameter. Two modes of concentrated energy release in the channel were disclosed. Their random appearance leads to an unexpected degradation of the sample. As such, the obtained results correspond to the situations occurring during the experiments. The validity of applying additional conditions to the system is discussed. In the discussion, it is also explained at which moments the moving S-N border acquires the velocity of the order of ~106 m/s, comparable to the Fermi velocity. Consideration to describe the moving unstable S-N border as being constantly in a state of Richtmyer–Meshkov instability is presented.

Removal of broken abutment screws using ultrasonic tip - a heat development in-vitro study.

Dental implants can cause complications, including the loosening of the abutment screw or fracture. However, there is no standardized technique for removing broken abutment screws. This necessitates further research. This study aimed to measure heat generation during screw removal to better understand its implications for dental implant procedures. The experimental setup involved using synthetic bone blocks and titanium implants. An ultrasonically operated instrument tip was utilized for screw removal. Infrared thermometry was employed for accurate temperature measurement, considering factors such as emissivity and distance. Statistical analysis using linear regression and ANOVA was conducted. The findings revealed an initial rapid temperature increase during the removal process, followed by a gradual decrease. The regression model demonstrated a strong correlation between time and temperature, indicating the heat generation pattern. Heat generation during screw removal poses risks such as tissue damage and integration issues. Clinicians should minimize heat risks through an intermittent approach. The lack of a standardized technique requires further research and caution. Understanding the generated heat optimizes implant procedures.

Experimental Study on the Evolution of Fracture Aperture of Single‐Fracture Granite during Liquid Nitrogen Cold Shock Cycling

Fractures in hot dry rock (HDR) reservoirs are the locations where heating fluid flows exchange heat with the HDR matrix. Cold shock with liquid nitrogen is one method for stimulating cracks. This study investigates the evolution law of fracture aperture under cold shock with liquid nitrogen. The real‐time high‐temperature triaxial servo control rock testing machine was used to conduct permeability experiments to examine the fracture aperture of single‐fracture granite during liquid nitrogen shock cycles at various temperatures. The effects of pore pressure, temperature, and shocking cycles on the fracture aperture are analyzed, and the difference in fracture aperture variation under liquid nitrogen cooling and natural cooling modes is compared. The results showed that (1) during liquid nitrogen cooling, the fracture aperture expands as pore pressure rises; the effect of pore pressure on the fracture aperture becomes more robust as the number of liquid nitrogen shocking cycles and initial temperature increases; (2) under 1‐2 soaking cycles, fracture aperture decreases as the temperature rises. Under two or more soaking cycles, the fracture aperture first increases and then decreases with increasing temperature; (3) when the initial temperature of fractured granite is 100°C, the fracture aperture is not significantly changed by repeated cold soaking cycles. However, with a higher initial temperature, the fracture aperture develops with more liquid nitrogen cold soaking cycles. The liquid nitrogen cooling method is more conducive to increasing the fracture aperture than natural cooling. The experimental results can provide primary experimental data for future research into controlling the evolution of granite cracks.

Influence of temperature effect on properties of modified magnesium slag-based low-carbon paste backfill materials

Coal mining subsidence and bulk solid waste storage are the bottleneck problems for achieving green and low-carbon development in northern Shaanxi. Aiming at the demand of filling mining in coal mines in northern Shaanxi, a modified magnesium slag-based low-carbon paste backfill materials (MMS-PBM) was proposed, which realized the safe disposal and resource utilization of solid waste. In-depth understanding of the influence of temperature effect (initial temperature: 5 ∼ 50 °C and curing temperature: 20 ∼ 50 °C) on the performance of MMS-PBM is helpful to optimize the mix ratio and filling period of filling materials. Based on this, relevant tests and tests (including setting time test, Mini-slump test, rheological test, uniaxial compressive strength test, microscopic test and leaching toxicity test) were carried out to explore the influence mechanism of temperature effect on the performance of MMS-PBM. results showed: (1) The rheological curve of fresh MMS-PBM slurry is highly consistent with the Herschel-Bulkley (H-B) model, and the fluidity meets the pumping requirements of coal mine filling. With the increase of initial temperature, the yield stress and apparent viscosity of fresh slurry increased, while slump, expansion and thixotropy decreased. (2) The increase of initial temperature inhibits the development of early mechanical properties of MMS-PBM, which is mainly affected by the metastable film hypothesis. (3) The curing temperature is conducive to the development of mechanical properties of MMS-PBM, and meet the requirements of mechanical properties of coal mine. With the increase of curing temperature, the main growth range of mechanical properties gradually changes from 7–28 d to 3–7 d, which is consistent with the change of microstructure. (4) The leaching concentration of heavy metals in MMS-PBM meets the requirements of national standards, but the increase of curing temperature has an inhibitory effect on the solidification of heavy metals. The above results show that MMS-PBM is a safe, green and low-carbon all-solid waste filling material, which is beneficial to the coordinated development of coal resource mining and environmental protection.

Inhibition and enhancement of hydrogen explosion by perfluorohexanone

To explore the inhibition and enhancement of hydrogen explosion by perfluorohexanone (CF3CF2COCF(CF3)2), the experiments are conducted by changing the equivalence ratio, inhibitor content, initial pressure and initial temperature, and the maximum explosion overpressure (MEO), maximum rate of pressure rise (MRPR) and critical content of explosion inhibition are obtained. The adiabatic flame temperature, sensitivity coefficient and mole fraction of active radicals are calculated using CHEMKIN. The results show that on the lean side, the sub-inhibitory perfluorohexanone generates CO to be involved in the combustion, and the formation of HF releases lots of heat, which causes the combustion enhancement. On the stoichiometric and rich sides, H is captured by other fluorides, exhibiting the inhibitory effect. Increasing the initial pressure (initial temperature) causes an increase (decrease) in the MEO and the MRPR. As the equivalence ratio increases, initial pressure reduces and initial temperature increases, the critical content of explosion inhibition is effectively reduced.

Numerical analysis of temperature effect on CO2 storage capacity and CH4 production capacity during the CO2-ECBM process

Temperature is a key factor affecting the CO2 injection efficiency and CH4 production efficiency, so it is of great significance to clarify the evolution diagram of temperature change during the CO2-ECBM process. In this study, the crushed soft coal seam with low permeability in Huainan coalfield was taken as the research object. Firstly, the fully coupled mathematical models of CO2-ECBM process were constructed, and the influence of temperature field on CO2-ECBM process was emphasized. Secondly, the evolution law of CO2-ECBM process at different time was revealed. Then, the effects of injection temperature and initial temperature on the CO2-ECBM process were analyzed. Finally, the evolution mechanism of reservoir temperature during the CO2-ECBM process was illustrated, and the effect of temperature on temperature field of CO2-ECBM process was further illustrated. The results show that the longer the displacement time, the CH4 concentration gradually decreased, and the CO2 concentration gradually increased. The area where the temperature changes are more concentrated focuses on the vicinity of CO2 injection well, which are mainly determined by the dominant reaction of adsorption and desorption reactions of binary gas. Reservoir temperature and permeability are positively and negatively correlated with injection temperature, respectively. Both CO2 storage capacity and CH4 production capacity increase with the increase of injection temperature, and the sensitivity of CO2 storage capacity to temperature was greater than that of CH4 production capacity. With the increase of displacement time and injection volume, the effective displacement radius increases, but the increment of influencing radius gradually decreases. The lower the initial temperature of coal reservoir, the larger the influencing radius, and which increases with the increase of displacement time. CO2 storage capacity and CH4 production capacity decrease with the increase of initial temperature. Young's modulus and Poisson's ratio can effectively change the reservoir strength. CO2 storage capacity and CH4 production capacity decrease with the increase of Young's modulus, and increase with the increase of Poisson's ratio. This study can support the engineering landing of CO2-ECBM technology in crushed soft coal seam with low permeability, and promote the realization of China's “Dual Carbon” strategic goal.

Comparative study on the flame retardancy of CO2 and N2 during coal adiabatic oxidation process

To test the effectiveness of N2 and CO2 in preventing coal from spontaneously combusting, researchers used an adiabatic oxidation apparatus to conduct an experiment with different temperature starting points. Non-adsorbed helium (He) was used as a reference gas, and coal and oxygen concentration temperature variations were analyzed after inerting. The results showed that He had the best cooling effect, N2 was second, and CO2 was the worst. At 70℃ and 110℃, the impact of different gases on reducing oxygen concentration and the cooling effect was the same. However, at the starting temperature of 150℃, CO2 was less effective in lowering oxygen concentration at the later stage than He and N2. N2 and CO2 can prolong the flame retardation time of inert gas and reduce oxygen displacement with an initial temperature increase. When the starting temperature is the same, N2 injection cools coal samples and replaces oxygen more effectively than CO2 injection. The flame retardancy of inert gas is the combined result of the cooling effect of inert gas and the replacement of oxygen. These findings are essential for using inert flame retardant technology in the goaf.

Relationship between higher estrus-associated temperatures and the bovine preovulatory follicular fluid metabolome

IntroductionA higher estrus-associated temperature (HEAT) is a hallmark feature in sexually active females; however, its functional importance is unclear. Our objective was to examine the relationship between HEAT and the preovulatory follicular fluid metabolome. It was hypothesized that HEAT is functionally important as it affects fertility-related components in the preovulatory follicle.MethodsEstrus was synchronized in non-lactating Jersey cows. A Thermochron iButton temperature data logger was affixed to blank controlled internal drug release (CIDR) devices and intravaginally inserted after CIDR device removal. The follicular fluid was aspirated 14.9 h + 3.3 h after an animal first stood to be mounted. Regression models were performed using metabolite abundance and HEAT variables. Best-fit models were determined using backward manual selection (p &amp;lt; 0.05).ResultsA total of 86 metabolites were identified in cow follicular fluid samples. The vaginal temperature at first mount and when it was expressed as a change from baseline was positively related to the abundance of four metabolites (i.e., taurine, sn-glycerol 3-phosphate, glycine, and cysteine) and negatively related to one metabolite (i.e., serine). The vaginal temperature at the first standing mount was related to the differential abundance of two metabolites (i.e., jasmonate and N-carbamoyl-L-aspartate). Three metabolites were related to the maximum vaginal temperature (i.e., N-carbamoyl-L-aspartate, uracil, and glycodeoxycholate). When expressed as a change from baseline, the maximum vaginal temperature was related to the differential abundances of uracil, uric acid, and 6-phospho-D-gluconate. The time taken to reach maximum vaginal temperature was related to N-carbamoyl-L-aspartate, glycodeoxycholate, jasmonate, and tricarballylic acid. Pertaining to the combination of HEAT and its duration, the area under the curve associated with the time between the first increase in vaginal temperature and the maximum vaginal temperature was related to 6-phospho-D-gluconate, sulfolactate, guanidoacetic acid, and aspartate. The area under the curve associated with the time between the initial vaginal temperature increase and up to 10 h after a cow first stood to be mounted or when a cow’s temperature returned to baseline was related to the differential abundances of uracil, sn-glycerol 3-phosphate, methionine sulfoxide, and taurodeoxycholate.DiscussionOur findings support the notion that HEAT is related to changes in the preovulatory follicular fluid metabolites involved in energy metabolism, thermoregulation, and oxidative stress management.