Increasing Discharge Voltage Research Articles

Stimulation characteristics of natural reservoir system under high-voltage electropulse-assisted fluid injection

This study elucidates the findings of a computational investigation into the stimulation characteristics of natural reservoir systems enhanced by high-voltage electropulse-assisted fluid injection. The presented methodology delineates the comprehensive rock-fracturing process induced by electropulse and subsequent fluid injection, encompassing the discharge circuit, plasma channel formation, shockwave propagation, and hydro-mechanical response. A hydromechanical model incorporating an anisotropic plastic damage constitutive law, discrete fracture networks, and heterogeneous distribution is developed to represent the natural reservoir system. The results demonstrate that high-voltage electropulse effectively generates intricate fracture networks, significantly enhances the hydraulic properties of reservoir systems, and mitigates the adverse impact of ground stress on fracturing. The stimulation-enhancing effect of electropulse is observed to intensify with increasing discharge voltage, with enhancements of 118.0%, 139.5%, and 169.0% corresponding to discharge voltages of 20 kV, 40 kV, and 60 kV, respectively. Additionally, a high-voltage electropulse with an initial voltage of U0 = 80 kV and capacitance C = 5 μF has been shown to augment the efficiency of injection activation to approximately 201.1% compared to scenarios without electropulse. Under the influence of high-voltage electropulse, the fluid pressure distribution diverges from the conventional single direction of maximum stress, extending over larger areas. These innovative methods and findings hold potential implications for optimizing reservoir stimulation in geo-energy engineering.

Plasma Dynamics and Electron Transport in a Hall-Thruster-Representative Configuration with Various Propellants: I—Variations with Discharge Voltage and Current Density

The results from a wide-ranging parametric investigation into the behavior of the collisionless partially magnetized plasma discharge of three propellants—xenon, krypton, and argon—are reported in this two-part article. These studies are performed using high-fidelity reduced-order particle-in-cell (PIC) simulations in a 2D configuration that represents an axial–azimuthal cross-section of a Hall thruster. In this part I paper, we discuss the effects of discharge voltage and current density (mass flow rate). Our parametric studies assess the spectra of the resolved instabilities under various plasma conditions. We evaluate the ability of the relevant theories from the literature to explain the variations in the instabilities’ characteristics across the studied plasma parameter space and for various propellants. Moreover, we investigate the changes in the electrons’ cross-magnetic-field transport, as well as the significance of the contribution of different momentum terms to this phenomenon across the analyzed cases. In terms of salient observations, the ion acoustic instability (IAI)-related modes are found to be dominant across the simulation cases, with the ion transit time instability also seen to develop at low current density values. Across the explored parameter space, the instabilities have the main contributions to the electrons’ transport within the plume region. The peak of the electric momentum force term, representing the effect of the instabilities, overall shifts toward the plume as either the current density or the discharge voltage increases. The numerical findings are compared against relevant experimental observations reported in the literature.

Effect of solution plasma process on microorganism sterilization, physicochemical properties and nutrients of milk

Solution plasma process (SPP) was used for sterilizing Staphylococcus aureus (S. aureus) in raw milk (RM). The sterilization efficacy analysis and kinetics analysis showed bacterial concentration and the distance between electrodes were negatively correlated with the sterilization effect, while discharge voltage was positive. The better sterilization effect was achieved at 4 kV. The electrochemical indices analysis indicated that pH value of RM had no changed. The DO content decreased. The conductivity increased with the increasing discharge voltage. The nutrient content analysis revealed that the content of acidity, lactose, fat, and protein decreased. RM after SPP treatment exhibited higher values of sourness and slightly lower values of astringency than the control. The higher discharge voltage and narrower distance between electrodes presented the stronger effect. The structural characterization of CMs and MFGs was carried out using a laser particle sizer, FTIR, 1H NMR, XRD, and AFM. The results showed that the main chemical structure of CMs was unchanged basically. The SPP with the narrower distance between electrodes and lower discharge voltage significantly reduced the size and aggregation of MFGs at the molecular level. At 4 kV/2 mm, the particle sizes of CMs and MFGs were reduced from 238 nm and 523 nm to 224 nm and 302 nm, respectively. The average diameter of MFGs was reduced from 45 nm to 18 nm. Therefore, SPP is a potential method in the milk industry and provides a new idea for the preservation and processing of beverage.

Trends in mass utilization of a magnetically shielded Hall thruster operating on xenon and krypton

The trends in mass utilization with increasing discharge voltage and current are investigated for a magnetically shielded Hall thruster operating on xenon and krypton. A 9 kW class shielded thruster is operated with discharge voltages from 300 to 600 V and discharge currents from 15 to 30 A on xenon and krypton. Experimental measurements of discharge current, thrust, anode efficiency, and ion velocity as a function of axial position are used to calibrate a multi-fluid 2D Hall thruster code at all operating conditions. The results of these calibrated simulations are employed to interrogate the plasma properties inside the thruster channel. A simplified 0D model for mass utilization evaluated on spatial averages of the simulated plasma parameters is employed to interpret the response of this efficiency mode with power for each propellant. It is found that with both higher voltage and current, mass utilization increases for both gases and their relative gap in this efficiency decreases. This can be attributed to the higher plasma densities and ionization rate coefficients at high voltage, and solely to higher plasma densities at high current. The driving factors for the increase in mass utilization are examined in the context of its nonlinear response to internal plasma properties. The behavior of mass utilization is also discussed in context of the gap in overall efficiency between the propellants. Finally, the implications of these results for improving the performance of high power Hall thrusters operating on krypton are examined.

Maze-solving in a plasma system based on functional analogies to reinforcement-learning model.

Maze-solving is a classical mathematical task, and is recently analogously achieved using various eccentric media and devices, such as living tissues, chemotaxis, and memristors. Plasma generated in a labyrinth of narrow channels can also play a role as a route finder to the exit. In this study, we experimentally observe the function of maze-route findings in a plasma system based on a mixed discharge scheme of direct-current (DC) volume mode and alternative-current (AC) surface dielectric-barrier discharge, and computationally generalize this function in a reinforcement-learning model. In our plasma system, we install two electrodes at the entry and the exit in a square lattice configuration of narrow channels whose cross section is 1×1 mm2 with the total length around ten centimeters. Visible emissions in low-pressure Ar gas are observed after plasma ignition, and the plasma starting from a given entry location reaches the exit as the discharge voltage increases, whose route converging level is quantified by Shannon entropy. A similar short-path route is reproduced in a reinforcement-learning model in which electric potentials through the discharge voltage is replaced by rewards with positive and negative sign or polarity. The model is not rigorous numerical representation of plasma simulation, but it shares common points with the experiments along with a rough sketch of underlying processes (charges in experiments and rewards in modelling). This finding indicates that a plasma-channel network works in an analog computing function similar to a reinforcement-learning algorithm slightly modified in this study.

Modeling of the influence of field electron emission from a cathode with a thin insulating film on its sputtering in a gas discharge in a mixture of argon and mercury vapor

A model of the low-current gas discharge in a mixture of argon and mercury vapor in the presence of a thin insulating film on the cathode surface is proposed. The model takes into account that in such a mixture a substantial contribution to the ionization of the working gas can come from the ionization of mercury atoms during their collisions with metastable excited argon atoms. In the discharge, positive charges accumulate on the film surface, creating an electric field in the film sufficient to cause field emission of electrons from the cathode metal substrate into the insulator. Such electrons are accelerated in the film by the field and can escape from it into the discharge volume. As a result, the effective yield of ion-electron emission from the cathode increases. The temperature dependences of discharge characteristics are calculated and it is shown that, due to a rapid decrease in the concentration of mercury vapor in the mixture with decreasing temperature, the electric field strength in the discharge gap and the discharge voltage increase. The presence of a thin insulating film on the cathode can result in an improvement in its emission characteristics and a significant reduction in the discharge voltage. This causes a decrease in the energies of the ions and atoms bombarding the cathode surface, and, consequently, in the intensity of cathode sputtering in the discharge.

Fast-activating reserve power sources: is lead dead indeed?

The purpose of this research is to improve the performance and reduce the activation time of reserve power sources based on lead-acid systems at lower temperatures, down to –50 °C. Physico-chemical factors affecting the activation speed of reserve power sources based on Pb–HClO4–PbO2 and Zn–HClO4–PbO2 systems are investigated using chronopotentiometry, scanning electron microscopy, and standard contact porosimetry. Two approaches to the improvement of the low-temperature performance of power sources are used. The first one is based on the substitution of lead as anodic material with zinc. This allows the increase in discharge voltage and simultaneous decrease in activation time, but brings about the instability of discharge characteristics and, finally, deteriorates the reliability of power sources. The second approach is based on the use of PbO2 cathode material with enhanced nanoporosity. The chronopotentiometric method in galvanostatic mode is applied to the quality estimation of cathodes. The criterion of applicability of cathodes for reserve power sources consists in the low discharge overvoltage (0.1–0.2 V). Efficient performance of reserve power sources possessing the stable discharge voltage (1.5–1.8 V per cell) and the unprecedentedly short activation time (under 30 ms) even at lower temperatures (down to –50 °C) is achieved. The results are verified by fabrication and testing of pilot batches of miniaturized reserve power sources having microcells’ volume of 0.02 ml. The second approach to the improvement of power sources is transferred into the industrial production.

Distribution and dynamics of antibiotic resistance genes in sludge under discharge plasma oxidation

Antibiotic resistance genes (ARGs), emerging environmental contaminants, have been largely accumulated in sludge during wastewater treatment. Discharge plasma oxidation, an advanced oxidation technology, has been demonstrated as an effective strategy in sludge pretreatment. However, the effect of plasma oxidation on the distribution and dynamics of ARGs in sludge is unknown. Herein, the variations of four typical ARGs (tetC, tetW, blaTEM-1, aac(3)-Ⅱ) and one integron (intI-1) in sludge during discharge plasma treatment were investigated. The results showed that under low discharge voltage or short treatment time, weak plasma oxidation enriched the contents of ARGs and intI-1 in sludge (with 1.14 log unit maximum increment) via proliferating biomass or promoting horizontal gene transfer. Further increasing discharge voltage or prolonging treatment time, strong plasma oxidation eliminated target genes due to the destroyed bacteria or inhibited horizontal transfer of ARGs. Especially, the homogeneous condition greatly promoted the reduction of ARGs in liquid phase (up to 1.52 log unit reduction). Furthermore, the correlation analysis between intI-1 and ARGs implied that tetC and tetW abundances might be significantly affected by intI-1 through horizontal transfer. At the same time, the microbial communities in sludge were investigated to help understand the effect of plasma oxidation on ARGs variation. Notably, the most predominant phylum Proteobacteria and genus Acinetobacter resisted the oxidative infringement from plasma to maintain high relative abundances (52.05 % in solid phase and 84.10 % in liquid phase for Proteobacteria, 13.82 % in solid phase and 78.00 % in liquid phase for Acinetobacter at 20 kV). Meanwhile, the co-occurrence analysis between genes and dominant genera further showed that Romboutsia sp. might be a potential host bacteria of ARGs and intI-1 in solid phase, and Acidovorax sp., Parachlamydia sp., and Armatimonadetes_gp5 sp. might be the potential hosts of tetW, tetC, and intI-1 in liquid phase.

Study on the influence of discharge voltage on the performance of Hall propulsion system

The discharge characteristics of the Hall thruster are numerically studied at different discharge voltages when the magnetic field does not change based on the particle in cell plus Monte Carlo collision methods. The distributions of electrons and Ar+ ions densities at different discharge voltages show that the change of the discharge voltage significantly influences the distribution of electrons and Ar+ ions. The electron density is relatively large when the discharge voltage is 100 V, up to 6.01 × 1018 m−3. At a discharge voltage of 400 V, the high-density region formed by electrons is significantly smaller than in other cases. The ion density rises less when reaching a steady state with increasing discharge voltage. The Ar+ ions density decreases after the discharge voltage reaches 400 V, up to 4.42 × 1018 m−3. After calculation, it was found that under a specific mass flow, the discharge voltage significantly impacts the thrust of the Hall thruster. The results have reference values for the performance testing and application of Hall thrusters.

Review on the Applications of Biomass-Derived Carbon Materials in Vanadium Redox Flow Batteries.

The development of vanadium redox flow batteries (VRFBs) requires the exploration of effective and affordable electrodes. In order to increase the electrochemical activity of these electrodes and decrease the polarizations, they are doped with an electrocatalyst. In this context, the use of biomass-derived materials as electrocatalysts in VRFBs has received much attention recently due to their widespread availability, renewable nature, low cost, and high energy efficiency. This paper aims to review the synthesis methods of biomass-derived carbon materials and their applications in VRFBs. In line with this aim, recent developments in carbon-based electrode modification methods and their electrochemical performance in VRFBs are summarized. The studies show that porous carbon electrocatalysts increase energy efficiency by reducing overpotentials and improving electrocatalytic activation. In addition, it is thought that biomass carbon doped electrocatalysts can improve the hydrophilicity of the electrodes, the transfer of vanadium ions, and the reaction kinetics. The highest charge voltage decrease rate of 8.61% was obtained in the Scaphium scaphigerum, whereas the highest discharge voltage increase rate of 14.29% was observed in the twin cocoon, as in all reviewed studies. Furthermore, the maximum energy efficiency (75%) was achieved in a VRFB equipped with an electrode doped with carbon derived from Scaphium scaphigerum and cuttlefish. It can be concluded from the reviewed studies that the electrochemical performances of electrodes doped with biomass-derived carbons in VRFBs are more effective than those of the bare electrodes.

Boosting Active Species Ru‐O‐Zr/Ce Construction at the Interface of Phase‐Transformed Zirconia‐Ceria Isomerism toward Advanced Catalytic Cathodes for Li‐CO2 Batteries

AbstractOptimized structural support widely affects the improvement of interface structure, promoting the quantity and quality of active species simultaneously for Lithium battery cathodes. Herein, a highly dispersed and anchored active species at the interface of the Zr/CeO2(111) are achieved and are used for advanced Li‐CO2 batteries cathodes. Benefiting from the abundant Ru‐O‐Zr/Ce site, the CO2 adsorption and reduction is enhanced by the migration of the electron density in the C═O of CO2 to Ru. The established Li‐CO2 batteries exhibit excellent activity of 21 075 mAh g−1 and outstanding durability of over 167 cycles as well as low overpotential with 1.03 V at a discharge/recharge rate of 100 mA g−1. The executed experiments combined with DFT calculations unveil that the cubic bimetallic oxide supported Ru exhibits optimized electronic structure at the interface compared to the monoclinic or tetragonal monometallic oxide support, promoting the increase of discharge voltage (from ≈2.5 to 2.73 V). Fundamentally, the redistribution of electron density on the active species Ru‐O‐Zr/Ce are intrinsic to above positive change, which are promoted by the synergistic interaction of Zr and Ce. This investigation provides an approach for the advancement of Li‐CO2 batteries catalytic cathodes and for the promotion of “carbon neutral” goals.

In-Memory Transposable Multibit Multiplication Based on Diagonal Symmetry Weight Block

A possible approach to overcome the von Neumann bottleneck and meet the increasing demand for better computing performance is to computing in-memory (CIM). The results of the in-memory calculations are primarily reflected in the vertical bitline (BL) analog voltage. However, the nonlinearity of the BL discharge deteriorates with the increase in discharge voltage. In this study, we propose a diagonal symmetry weight block (DSWB) based on an eight-transistor (8T) static random access memory (SRAM) that can achieve multibit transposable operations. In addition, to guarantee linearity and complete multibit multiplication operations, we propose a cascode current mirror (CCM)-based multiplier. To achieve low-overhead and more efficient quantification, our proposed CIM macro uses a counter-type quantization circuit to read out the analog calculation results. We simulated the performance of the proposed 8T SRAM in a 28-nm complementary metal–oxide–semiconductor process. The integral nonlinearity (INL) of the proposed CCM-based CIM decreased by approximately 54.4% compared with the traditional CIM. Furthermore, the proposed in-memory multibit multiplication throughput density was 6.74 GOPS/kb; this throughput density improvement is approximately 3.3–10.5 times higher than the existing CIM works.

Experimental study on crushing of concrete slabs by high-voltage pulse discharge

To investigate the effectiveness of high voltage pulse discharge (HVPD) in crushing concrete slabs, HVPD in-liquid tests were conducted in pre-drilled holes in three double-layer bi-directionally reinforced and twelve single-layer bi-directionally reinforced concrete slabs. The parameters that were varied in the tests included the concrete strength, discharge hole diameter and spacing, discharge voltage and number of copper wires discharged. The results showed that the explosion caused by HVPD using copper wires increased the crack width by more than 34.8% compared to that caused by the electrohydraulic effect. After 10 explosions caused by HVPD using copper wires, the single-layer reinforced concrete slab was split into several slabs by cracks to achieve the crushing effect. The single discharge energy, i.e., discharge voltage, had a significant effect on the crushing of concrete slabs, and the width of concrete cracks produced by a 100 kV discharge was more than twice that of a 40 kV discharge. The increase in concrete strength acted as a crack arrestor for the slabs, and the crack width of C20 concrete slabs increased by approximately 10% to 25% compared to C40 concrete slabs. The increase in crack width with increasing number of discharged copper wires decreased with increasing discharge voltage. The width of concrete cracks produced by the explosion of 60 copper wires compared to 30 copper wires increased by approximately 10% at 100 kV and by approximately 20% from 60 to 80 kV. The crack width of concrete slabs with discharge holes of diameter 40 mm increased by approximately 5% to 15% compared to concrete slabs with holes of 50 mm. Expressions for the relationships between the damage degree of the concrete slab (i.e., the width of the concrete cracks around the holes on the outside of the slab) and the key parameters such as the output voltage, the number of discharged copper wires, and the strength grade of the concrete were established based on the experimental results.

Magnetic field optimization of hall thruster with large height-radius ratio for high specific impulse operation

Hall thrusters with large height-radius ratio not only have incalculable application values in reducing the volume and weight of thrusters, but also have the potential advantages of higher discharge performance and longer service life. However, the lower propellant density in the main ionization zone and the higher electron temperature in the channel aggravate the loss of propellant and current under high voltage, and significantly reduce the discharge efficiency under high specific impulse mode. To improve the discharge performance of Hall thrusters with large height-radius ratio under high voltage, an optimization scheme of internally loaded magnetic field was proposed in this work. The simulation results show that under the internally loaded magnetic field, both the ionization zone and the acceleration zone move toward the inside of the channel. Although the ion loss on the walls increases, the higher propellant density at the channel upstream greatly promotes the increase of ionization rate and significantly improves the propellant utilization efficiency. The second zone crossed by magnetic field lines in the channel can be established by the internally loaded magnetic field, which enhances the magnetic field intensity on the inner and outer walls, and reduces the electron temperature near the channel outlet significantly. So that the axial conduction of electrons is effectively restrained and the current utilization efficiency is greatly improved. With the introduction of internally loaded magnetic field, the total efficiency of HEP-1350PM can be increased by 7.2% at 400 V. Moreover, the performance optimization effect brought by the internally loaded magnetic field will be gradually amplified with the increase of discharge voltage, which makes the Hall thruster with large height-radius ratio expected to achieve high-efficiency discharge under higher specific impulse.

Erosion Performance of TiAlSiN Coatings Prepared by High-Power Pulsed Magnetron Sputtering

Erosion seriously threatens the safety of high-speed rotating mechanical components in very harsh service environments, particularly for lightweight titanium alloy matrix material. In order to improve the erosion resistance of titanium alloy, TiAlSiN coatings with different phase compositions are deposited on TC6 titanium alloy using a high-power pulse magnetron sputtering discharge (HPPMS) system under various discharge voltages. The componential and microstructural evolution as well as mechanical properties of the TiAlSiN coatings are evaluated by X-ray diffraction, scanning electron microscopy, and nanoindentation, respectively. The erosion performance relative to titanium alloy is investigated by a sand blasting tester. With the increase in discharge voltage from −500 to −600 V, the peak of discharge current increases from 105 to 225 A. The prepared TiAlSiN coatings show a shift of the preferred crystallographic orientation from (220) to (200), but all of them have a dense nanocomposite structure. Their hardness (H) and elastic modulus (E) gradually increase before decreasing, arriving at maximum values of 35.34 and 360.5 GPa at −570 V. The erosion resistance of the TiAlSiN coatings dependent on the discharge voltage is consistent with the H/E ratio change. The TiAlSiN coatings prepared at −560 V exhibit the optimal erosion resistance, which is 15 times that of the TC6 substrate. The erosion behavior of the coatings is positively correlated with their hardness and toughness. Adjusting the discharge voltage of the HPPMS pulse is finally proved to be an effective way of tailoring the coating phase compositions to improve the erosion resistance of titanium alloy.

Comparative study on the degradation of phenol by a high-voltage pulsed discharge above a liquid surface and under a liquid surface

The degradation of phenol by pulsed discharge plasma above a liquid surface (APDP) and under a liquid surface (UPDP) was compared. The effects of discharge voltage, discharge distance, initial solution conductivity and initial pH on the removal of phenol were studied. It was concluded that the removal of phenol increases with increasing discharge voltage and with decreasing discharge distance in both APDP and UPDP systems. An increase in the initial solution’s conductivity has a positive effect in the APDP system but a negative effect in the UPDP system. In addition, alkaline conditions are conducive to the degradation of phenol in the APDP system, while acidic conditions are conducive in the UPDP system. Free radical quenching experiments revealed that ·O− 2 has an important influence on the degradation of phenol in the APDP system, while ·OH plays a key role in the UPDP system. This paper verifies the differences in the two discharge methods in terms of phenol removal.

Analysis of Electrostatic Discharge Interference Effects on Small Unmanned Vehicle Handling Systems

Electrostatic discharge is a common phenomenon in daily life, and the electromagnetic pulse radiation generated during discharge can cause great harm to power, communication, sensing, and other equipment, resulting in systems not working properly. To verify the safety and reliability of unmanned vehicle handling systems in complex electromagnetic environments, the interference effect of electrostatic discharge, a common source of electromagnetic interference in life, on unmanned vehicle systems was studied. According to the electrostatic discharge interference mechanism, typical electrostatic discharge mode, and discharge model, an unmanned vehicle handling system was tested for electrostatic discharge according to the ISO10605-2008 standard. Based on the measured data, the effect of electrostatic discharge on the safety and functionality of the unmanned vehicle handling system and its sensors was analyzed, and threshold values for the failure of the unmanned vehicle handling system under different discharge methods, discharge models, and discharge polarity were obtained. When the electrostatic discharge voltage amplitude is only 2 kV, the vehicle’s LiDAR data sensor cannot work normally due to the echo reception circuit, and the failure rate of LiDAR continues to increase with increasing discharge voltage. When the discharge voltage is only 4 kV, the millimeter-wave radar is disconnected from the vehicle module due to the electrostatic discharge interference of the transmission cable, and when the discharge voltage is 12 kV, the unmanned vehicle is unable to provide stable and accurate environmental information to avoid collisions. This study provides a reference for the design of electromagnetic protection of unmanned equipment and will have a guiding role in enhancing the construction of reliable, safe, and intelligent equipment in complex electromagnetic environments.

Study on the influence of magnetic field on the performance of a 5 kW hall thruster

Hall thruster is a kind of plasma optics device, which is used mainly in space propulsion. To study the influence of magnetic field on the performance of a 5 kW hall thruster, a two-dimensional PIC-MCC model was built. The Bohm diffusion was modeled by using a Brownian motion instead of the Bohm collision method and the near-wall conduction was modeled by a secondary electron emission model. When the mass flow rate is 5 mg/s, the thruster performance like thrust, efficiency and discharge current was simulated under a discharge voltage from 300 to 1,000 voltage. At first, the performance under constant magnetic field was simulated. The results showed that the magnetic field could not restrain the electrons as the discharge voltage increased. Later, the performance under varied magnetic field was simulated. The results showed that increasing the magnetic field strength with the increasing discharge voltage could restrain the electrons more efficiently, which proved that increasing the magnetic field strength is necessary for high specific impulse operation of hall thruster. At last, the performance measurement experiment of the thruster was carried out, and the experimental results verified the accuracy of the simulation results.

Numerical simulation study of ionization characteristics of argon dielectric barrier discharge

In order to better analyze the characteristics of particle distribution and its influencing factors in the ionized space during the process of coaxial dielectric barrier discharge, a self-designed two-dimensional axisymmetric structure exciter was used to carry out optical diagnosis, with the electron temperature calculated through Gaussian fitting. A plasma model was applied to conduct research on the discharge process through numerical simulation, with the changes in electron density and electron temperature were analyzed by using different discharge parameters. The research results show that with an increase in discharge voltage, pressure inside the reactor and relative permittivity, the discharge process is promoted. In addition, a rise in current density leads to an increase in the number of charged particles on the surface of the medium during the discharge process, while a rise in discharge intensity causes an increase in the electron density. Electron temperature decreases due to the increased loss of collision energy between particles. These results were confirmed by comparing experimental data with simulation results.

Transition mechanisms between selective O3 and NO x generation modes in atmospheric-pressure plasmas: decoupling specific discharge energy and gas temperature effects

Two modes of the atmospheric-pressure plasma discharge, distinguished by the dominant O3 and NO x species are studied numerically and experimentally. To investigate the mode transition mechanisms, here we develop a global chemical kinetics model for the atmospheric-pressure dielectric barrier discharge involving 63 species and 750 reactions. Validated by the experimental results, the model accurately describes the mode transition. The N, O, O2(a), and O2(b) are the essential transient intermediate species for the O3 and NO x production and loss reactions. The individual and synergistic effects of the specific discharge energy and the gas temperature on the species density and the relative contributions of the dominant reactions are quantified under the increasing discharge voltage conditions. The modeling results indicate that the gas temperature and specific discharge energy both contributed to the discharge mode transition, while the decisive factors affecting the change of the O3 and NO x density are different in the respective modes. These insights contribute to diverse plasma applications in biomedicine, agriculture, food, and other fields where selective and controlled production of O3 and NO x species is the key for the desired plasma performance.