An in-fiber Mach–Zehnder interferometer (MZI) was proposed and experimentally demonstrated for refractive index (RI) and relative humidity measurements. The sensor is composed of a hollow-core fiber (HCF) sandwiched between two single-mode fibers (SMFs) with a length of 8mm. A well-defined interference pattern was obtained as a result of fiber–core mismatch and core–cladding mode interference. The selected interference dip was extremely sensitive to the ambient RI and provided a stable RI response with sensitivities of up to 155.6nm/RIU and 163.1dB/RIU for water-based solutions close to the RI of 1.33, which makes it capable of environment humidity measurements with a sensitivity of 1.29pm%−1 and 0.00542dB%−1.
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