Studies have shown that Sentinel-2 images have advantages over Landsat images in impervious surface area (ISA) extraction. The performance of index-based methods can be affected by different binary methods and subject to seasonal variation. This study marks the first attempt to assess the performance of different spectral indices for ISA extraction using multiseasonal Sentinel-2 images. Specifically, five indices (i.e., the biophysical composition index calculated using the Gram-Schmidt orthogonalization method, biophysical composition index calculated using a principal component-based Procrustes analysis, Normalized Built-up Area Index (NBAI), combinational build-up index, and perpendicular impervious surface index (PISI)) and three impervious surface binary methods (i.e., Otsu's method, manual method, and Iterative Self-Organizing Data Analysis Technique Algorithm (ISODATA) classification method) were tested on multi-seasonal Sentinel-2 images in the main urban area of Wuhan, China. Results showed that PISI combined with the ISODATA classification method achieved the highest accuracy with 92.64% OA, and 0.8410 Kappa coefficient, and NBAI combined with Otsu's method achieved the lowest accuracy with 35.37% OA, and 0.013 Kappa coefficient. Regarding the seasonal sensitivity, PISI is relatively more stable than the other methods. The superior performance of PISI is largely due to its capability in separating ISA from soil and vegetation. In addition, summer is the best season to map ISA from Sentinel-2 images when the impervious surface is generally less confused with bare soil. This study serves as a reference for the selection of spectral indices for ISA extraction from Sentinel-2 images in relation to binary methods and seasonal effects.
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