Hydrogen Loading Research Articles

Recent Advances in Metal-Hydride-Based Disease Treatment.

In comparison to traditional antioxidant treatment methods, the use of hydrogen to eliminate reactive oxygen species from the body has the advantages of high biological safety, strong selectivity, and high clearance rate. As an energy storage material, metal hydrides have been extensively studied and used in transporting hydrogen as clean energy, which can achieve a high hydrogen load and controlled hydrogen release. Considering the antioxidant properties of hydrogen and the delivery ability of metal hydrides, metal-hydride-based disease treatment strategies have attracted widespread attention. Up to now, metal hydrides have been reported for the treatment of tumors and a range of inflammation-related diseases. However, limited by the insufficient investment, the use of metal hydrides in disease treatment still has many shortcomings, such as low targeting efficiency, limited therapeutic activity, and complex material preparation process. Particularly, metal hydrides have been found to have a series of optical, acoustic, and catalytic properties when scaled up to the nanoscale, and these properties are also widely used to promote disease treatment effects. From this new perspective, we comprehensively summarize the very recent research progress on metal-hydride-based disease treatment in this review. Ultimately, the challenges and prospects of such a burgeoning cancer theranostics modality are outlooked to provide inspiration for the further development and clinical translation of metal hydrides.

A multi-core fiber coupler without a central core

An efficient method for fabricating multi-core fiber couplers based on the thermal diffusion technique is proposed to realize the connection of single-mode fibers to multi-core fibers without a central core. The fabrication efficiency of the multi-core fiber coupler is improved by fiber-loaded hydrogen. The simulation results show that the single-mode fiber and the multi-core fiber can be coupled stably and efficiently by using the designed double-clad fiber to connect the single-mode fiber and the multi-core fiber. Double-clad fiber and multi-core fiber were loaded with hydrogen to enhance the dopant diffusion rate. Three-dimensional refractive index measurements of the multi-core fiber coupler show that the dopant diffusion rate and the diffusion zone length of the hydrogen-loaded fiber are significantly increased compared to the original fiber. These enhancements contributed to the shorter fabrication time of multi-core fiber couplers. The multi-core fiber couplers fabricated by thermal diffusion technology have the advantages of high coupling efficiency, high integration, simple manufacture, and high mechanical strength. Enhancing the diffusion rate of optical fibers by using the hydrogen loading method will increase the application potential of multi-core optical fiber couplers prepared by thermal diffusion technology, and accelerate the translation of multi-core fibers toward optical communication and optical fiber sensing.

Evaluation of lithium as a tritium storage medium for betavoltaics

Lithium foils were demonstrated to absorb surrogate protium for tritium-powered betavoltaics. 20 μm thick lithium foils were hole-punched from a ribbon of electrodeposited lithium on copper foil. The lithium foils were loaded with hydrogen in a custom Sievert apparatus where the pressure drop showed full hydriding at a hydrogen pressure of 2 bar and at all loading temperatures above the lithium melting point at 190, 200, 225, 250, and 300. Lithium hydride formation was confirmed with Raman spectroscopy after hydrogen loading. The kinetics of experimental hydride formation was compared to the diffusion-limited Mintz–Bloch model. While the Mintz–Bloch model showed good fit with the experimental loadings, the model overpredicted the loading kinetics starting at 250 °C and at higher temperatures. The overprediction was either caused by lithium hydride outgassing due to some reduction with some residual lithium hydroxide created from brief air exposure when sealing the lithium in the reactor or a transition from diffusion-limited hydride growth to surface or metal–hydride interface-limited hydride growth.

Experimental investigations on a coupled metal hydride based thermal energy storage system

Thermal energy storage using coupled metal hydride reactors is attractive because it offers several advantages such as one-time hydrogen loading, high thermal storage density, compactness and possibility of simultaneous heating and cooling. This study presents experimental investigations on a coupled metal hydride based thermal energy storage system. Based on compatibility criteria of hydrides described in this work, LaNi4.25Al0.75 for thermal energy storage and La0.75Ce0.25Ni5 for hydrogen storage were chosen. The study employed two novel cartridge type coupled reactors with enhanced heat transfer surfaces. The effects of heat source and ambient temperatures on the system performance were investigated. The study reveals that coupled hydride systems with suitable pairs of hydrides can deliver high energy storage capacities at good thermal efficiencies. The heat output of 227.7 kJ was achieved with a heat transfer rate of 130.7 W at 55.7 % efficiency. The hydrogen storage alloy exhibited good compatibility with the energy storage alloy with fast hydrogenation and dehydrogenation. It also produced a cooling effect of 171.8 kJ while desorbing hydrogen.

Low-Carbon Economic Dispatch of Virtual Power Plant Considering Hydrogen Energy Storage and Tiered Carbon Trading in Multiple Scenarios

Reducing carbon emissions and increasing the integration of new energy sources are key steps towards achieving sustainable development. Virtual power plants (VPPs) play a significant role in enhancing grid security and promoting the transition to clean, low-carbon energy. The core equipment of the VPP, the CHP unit, utilizes a thermal engine or power station to generate electricity and useful heat simultaneously. However, the intermittent and volatile nature of renewable energy sources, as well as the “heat-driven power generation” mode of combined heat and power (CHP) units, presents contradictions that severely affect their peak-shifting capability and lead to high carbon emissions. To address these issues, a novel VPP is established by integrating traditional power plants with carbon capture and hydrogen energy storage. This approach utilizes a “hydrogen energy storage–electric boiler” decoupling method to address the operational mode of CHP, strengthens the coupling relationship between electric and thermal hydrogen loads, and considers a tiered carbon-trading mechanism. With the net profit of the VPP as the optimization objective, the model balances economic and environmental considerations and establishes a low-carbon economic dispatch model for the VPP. A genetic algorithm is employed for solving, and three different dispatch strategies are set for simulation in three distinct seasonal scenarios. The comprehensive comparative analysis of the dispatch results reveals a reduction in carbon emissions and an increase in net profit to varying degrees across all three seasons. Overall, the proposed dispatch strategy demonstrates the ability to enhance the new energy-integration capacity and total revenue of a VPP while simultaneously achieving the goal of reducing carbon emissions.

Hydrogen Production using a Hybrid System Built with Renewable Energy Resources in Yenice

Benefits of hybrid renewable energy; has a continuous power supply, has a better return on investment, is independent of the grid, has fewer operating hours of the diesel generator, requires less maintenance than a diesel generator system, and does not need frequent refueling, one-time initial capital required, protects from ever-increasing grid electricity tariffs. On the other hand, the demand for renewable energy sources such as wind, solar, hydrogen, biomass, and geothermal, which are the least harmful to nature and natural life, has increased due to the depletion of fossil fuels used in energy production and the greenhouse gases they have released to the environment. Thus, with the inclusion of renewable energy sources in the system, a rich structure in terms of energy diversity has emerged. An area that simulates a system consisting of renewable energy sources using HOMER Pro software and has an annual average electrical energy need of 3997104 kWh/day was selected. Solar radiation and wind data belonging to the region were taken from NASA Surface and used. The energy system of the area where the feasibility study was conducted consists of a generator, wind turbine, solar panel, hydrogen tank, electrifier inverter, and battery system. The energy produced by the resulting system will be used by 11.26 kg/day hydrogen load and 3997104 kWh/day electrical load. The economic evaluation criteria of the hybrid renewable energy system are the energy unit cost of energy production, the net present value (NPC), and the payback period; The environmental evaluation criteria were determined as the renewable energy rate and emission values evaluation criteria. When the renewable energy rate is at the lowest level, the most economical system is the Gen/PV/WT/Bat/300Htank/ H loaded hybrid system when emissions are not considered, while the Gen/PV/WT/Bat hybrid system has the lowest emissions without considering the cost. When the renewable energy rate is high, the most economical system has been the PV/WT/Bat hybrid system when emissions are not considered.

Tuning Hydrogen Storage Properties in La1−xYxNi4.5Cu0.5 (x = 0.1; 0.2; 0.3; 0.4, 0.5) Alloys

Metal hydrides of AB5 compositions have been investigated over the years as they offer extraordinary volumetric hydrogen densities with high cycling stability and purity of released hydrogen. Moreover, by doping with different elements, the sorption properties of alloys can be significantly changed according to their foreseen applications. In this contribution, we report the synthesis routes and hydrogenation characteristics of La1−xYxNi4.5Cu0.5. The synthesized alloys exhibit excellent structural purity with all reflections indexed by the hexagonal P6/mmm structure. It was found that the Y content can easily tune (raise) the equilibrium pressures of the pressure–composition isotherms, while overall gravimetric density remains at a level exceeding 1.5 wt.% up to x = 0.3 then strongly decreases. The pressure range for desorption can be tuned from 1.5 to 5 bars at room temperature. Some alloys (x = 0; 0.2) exhibit very good stability during 1000 cycles of hydrogen loading and unloading. Furthermore, activation of the alloys is prompt, making them good candidates for stationary hydrogen storage, non-mechanical hydrogen compressors, or soft actuators.

Generation Coordination and Planning of New Power System Considering Industry Hydrogen Load

Considering the impact of industrial hydrogen load on the consumptive capacity of new energy, it is necessary to research the generation coordination and planning of new power systems considering industry hydrogen load. Firstly, considering the energy consumption in the hydrogen production and storage process, as well as the energy storage for hydrogen addition/use, hydrogen load transfer, and interruptible flexibility, an equivalent electrical load conversion model for multiple forms of hydrogen loads is established. Secondly, considering the impact of industrial hydrogen load on the absorption capacity of new energy, the investment decision-making problem of power supply, hydrogen production, and storage equipment is unified with the operation simulation problem of the system at the planning level, to minimize the annual cost of the system. To reduce the complexity of the model, the proposed model plan to the expansion capacity of various types of power sources from the perspective of power types. Finally, by using actual data from a power grid in a certain province as an example, the results verified the rationality and effectiveness of the model compared with the power grid planning without hydrogen load.

Benefit allocation of electricity–gas–heat–hydrogen integrated energy system based on Shapley value

Abstract The integrated energy system is an important development direction for achieving energy transformation in the context of the low-carbon development era, and an integrated energy system that uses renewable energy can reduce carbon emissions and improve energy utilization efficiency. The electric power network and the natural gas network are important transmission carriers in the energy field, so the coupling relationship between them has been of wide concern. This paper establishes an integrated energy system considering electricity, gas, heat and hydrogen loads; takes each subject in the integrated energy system as the research object; analyses the economic returns of each subject under different operation modes; applies the Shapley value method for benefit allocation; and quantifies the contribution value of the subject to the alliance through different influencing factors to revise the benefit allocation value. Compared with the independent mode, the overall benefits of the integrated energy system increase in the cooperative mode and the benefits of all subjects increase. Due to the different characteristics of different subjects in terms of environmental benefits, collaborative innovation and risk sharing, the benefit allocation is reduced for new-energy subjects and increased for power-to-gas subjects and combined heat and power generation units after revising the benefit allocation, to improve the matching degree between the contribution level and the benefit allocation under the premise of increased profit for each subject. The cooperative mode effectively enhances the economic benefits of the system as a whole and individually, and provides a useful reference for the allocation of benefits of integrated energy systems. The analysis shows that the revised benefit distribution under the cooperative model increases by 3.86%, 4.08% and 3.13% for power-to-gas subjects, combined heat and power generation units, and new-energy units, respectively, compared with the independent function model.

Techno-economic optimization of hydrogen generation through hybrid energy system: A step towards sustainable development

The present study aims to design and optimize a Hybrid Renewable Energy System (HRES) to facilitate a remote community's electricity and hydrogen load demand at Dungri, Uttarakhand, India. The methodology includes an assessment of energy demand, local resource availability, and the nature of the inhabitant. The findings shows techno-economically an optimal HRES, consisting of 90 kW PV, 25 kW Bio-generator, 30 kW electrolyser, 15 kW hydrogen tank, 10 kWh storage and a 30 kW converter with Net present value (NPV) of Rs. 78.4 lakhs, cost of energy (COE) as Rs. 7.61/kWh and cost of hydrogen (COH) Rs. 330/kg. Annual electricity generation is of 250641 kWh/year and yearly average hydrogen generation of 1838 kg through electricity consumption of 80462 kWh/year and can be utilized for 26280 km/year of operation of hydrogen fuelled buses. Furthermore, sensitivity analysis reveals that, rise in the hydrogen load, boost up the system's NPV and COE, whereas,the COH reduces. Amount of annual CO2 emission and avoided are 53.9 kg, 209.12 t, respectively. Moreover, it infers that the proposed system serves isolated rural communities with high-quality energy and satisfies local hydrogen fuel demand in the transportation sector in economically viable manner and achieves the SDG 7 & 8.

A multi-criteria design framework for sustainable electric vehicles stations

The world is facing severe climate threats due to continuous increases in greenhouse gas emissions. Around one-fifth of global emissions are produced by the transport sector alone. Electric vehicles, as a potential replacement for conventional vehicles, can reduce global emissions. Pakistan is among the few countries severely affected by climate change impact. Therefore, Pakistan announced a national policy to increase the electric vehicles market share, calling for the development of electric vehicles charging stations nationwide. This work addresses this urgency by investigating renewable-based electric vehicles charging and hydrogen fueling stations (ECHFS). Seven possible ECHFS configurations are introduced. Then, a four-level sustainable design framework is developed, with the help of pre-feasibility analysis, HOMER optimization tool, and a multi-criteria decision-making method, to identify the most optimal ECHFS configuration. Solar PV with biogas generator configuration emerged as an optimal ECHFS, which is cost-effective (0.475 $/kWh cost of energy and 3.62 $/kg cost of hydrogen), reliable (unmet electric and hydrogen loads are 0.14 % and 0 %), eco-friendly (reduced 942 tons CO2 annually), and socio-politically acceptable. Sensitivity analysis showed that the optimal system is economically sensitive to simultaneously increasing charging and hydrogen fueling demands. The breakeven distance is estimated to be 59.6 km compared to the grid. The outcome of this work contributes to United Nations sustainability goals 7a, 8, 11, 13, and 13.2 and holds the potential to aid the sustainable development of ECHFS infrastructure.

Modeling of local hydrogen concentration on microscopic scale to characterize the influence of stress states and non-metallic inclusions in pipeline steels

Hydrogen as an energy carrier plays an important role in achieving the ambitious climate targets associated with decarbonization. The main challenge is to ensure safe transport of gaseous respectively liquid hydrogen through the already existing natural gas pipelines. Since experimental methods, such as hydrogen-induced-cracking tests, fail to provide quantitative answers to the question of which local effects/mechanisms trigger failure under hydrogen loading, complex numerical multi-scale approaches are needed. In this work, a phenomenological crystal plasticity model based on dislocation slip mechanisms was implemented in Abaqus/Implicit and coupled with a hydrogen diffusion model to investigate the influence of microstructural characteristics in terms of grain size, texture, phase fraction but also lattice defects such as dislocations, grain boundaries, carbides, and non-metallic inclusions on hydrogen-induced-damage behavior. As a driving force for hydrogen diffusion, both hydrostatic stresses and plastic strains associated with mechanically and thermally induced residual stresses under various stress states were investigated. It was found that the impurity degree of the steel in terms of non-metallic inclusions plays an important role in hydrogen susceptibility in two aspects, namely geometrically (notch-effect) and in the generation of residual stresses. The effect of matrix shrinkage on the inclusions and the resulting stress field after cooling leads to the accumulation of hydrogen atoms around the inclusions, resulting in locally high critical concentrations. The simulations performed on microstructures with and without non-metallic inclusions under different stress states demonstrated the notched effect that the presence of non-metallic inclusions increases the local hydrogen concentration up to 28 %.

Enrichment of Microbial Consortium with Hydrogenotrophic Methanogens for Biological Biogas Upgrade to Biomethane in a Bubble Reactor under Mesophilic Conditions

The biological upgrading of biogas to simulate natural gas properties contributes to the sustainable establishment of biogas technology. It is an alternative technology to the conventional physicochemical methods applied in biomethane plants and has been studied mainly in thermophilic conditions. Developing an enriched culture for converting the CO2 of biogas to CH4 in mesophilic conditions was the subject of the present study, which could facilitate the biological process and establish it in the mesophilic range of temperature. The enrichment took place via successive dilutions in a bubble bioreactor operated in fed-batch mode. The methane percentage was recorded at 95.5 ± 1.2% until the end of the experiment. The methane production rate was 0.28–0.30 L L−1 d−1 following the low hydrogen loading rate (1.2 ± 0.1 L L−1 d−1) applied to avoid acetate accumulation. Hydrogenotrophic methanogens, Methanobrevibacter sp., were identified at a proportion of 97.9% among the Archaea and 60% of the total population of the enriched culture. Moreover, homoacetogens (Sporomusa sp.) and acetate oxidizers (Proteiniphilum sp.) were also detected, indicating that a possible metabolic pathway for CH4 production from CO2 is via homoacetogenesis and syntrophic acetate oxidation, which kept the acetate concentration at a level of 143 ± 13 mg L−1. It was found that adding NaHCO3 was adequate to sustain the pH at 8.25.

Hydrogen storage mechanism of metal–organic framework materials based on metal centers and organic ligands

AbstractThe effective storage and utilization of hydrogen energy is expected to solve the problems of energy shortage and environmental pollution currently faced by human society. Metal–organic framework materials (MOFs) have been shown by scientists to be very potential hydrogen storage materials. However, the current design methods and strategies for MOFs are still generally in the trial‐and‐error stage, and the research works are at the overall level. To solve the problems of directional design and rational construction of new MOFs, this work uses the principles and methods of coordination chemistry and crystal engineering to carry out the theoretical design and mechanism research of new MOFs for high‐efficiency hydrogen storage application scenarios. In this study, the structures selected for theoretical calculation were divided into two types: different ligands for the same metal (IRMOFs, MOF‐205, and DUT‐23‐Zn) and different metals for the same ligand (DUT‐23‐M [(M = Co, Ni, Cu, and Zn]). The model construction process, hydrogen loading with temperature, specific surface area, hydrogen adsorption energy, charge density and hydrogen storage mechanism of the above structures were analyzed, and the key indicators that may affect the hydrogen storage performance of MOFs were summarized: type and quantity of coordination metals, temperature, pressure, adsorption site and specific surface area.

Numerical Investigation of the Influence of Nonmetallic Inclusions on the Local Hydrogen Concentration under Consideration of Residual Stress Fields

Hydrogen as an energy carrier is politically supported and essential for the planned energy turnaround, but requires infrastructure for transport and storage of hydrogen on a large scale, which in turn requires the development of steels resistant to hydrogen‐induced damage. Since the experimental characterization of local hydrogen concentration is nearly impossible, but microstructure level effects are significant for damage initiation, it becomes essential to further develop accompanying numerical evaluation methods. These have to be able to quantitatively describe the effect of nonmetallic inclusions on the local hydrogen concentration as the detrimental effect of nonmetallic inclusions governs the resistance against hydrogen‐induced cracking. To capture this influence, the modeling approaches available in the literature are extended and made usable for tetrahedral elements. Validation is performed using numerical studies with specimens of different stress states. Submodels are exposed to a virtual cooling and then to a hydrogen loading. Based on the resulting residual stress fields, the local hydrogen concentrations around nonmetallic inclusions with different chemical compositions and geometry are investigated and evaluated. Herein, it can be shown that especially the hydrostatic stress has a large influence on the development of the local hydrogen concentration and that the influence is particularly strong for Al2O3‐inclusions.

Optimal stochastic scheduling of a multi-carrier multi-microgrid system considering storages, demand responses, and thermal comfort

This paper focuses on the day-ahead scheduling of a multi-carrier multi-microgrid that delivers electricity, heat, and hydrogen to its customers. The microgrids are equipped with renewable sources, combined heat and power, gas boiler, electric boiler, multi-energy storage, and power-to-hydrogen facilities, and aim at minimizing their operational and environmental costs. Demand response for electrical and hydrogen loads as well as thermal comfort for heat demand have been considered to increase flexibility. The distribution company, which aims at maximizing its profit, imports electricity and natural gas from the main grid. Stochastic optimization is proposed, and the generated scenarios were reduced using the mixed-integer linear programming method. Considering that the problem possesses two conflicting objective functions, the problem was two-level with nonlinear terms. The Karush–Kuhn–Tucker conditions, duality theory, and Fortuny–Amat transformation were implemented to transfer the problem into a single-level mixed-integer linear programming problem. The effectiveness of the proposed framework in four cases has been tested on a hypothetical multi-carrier multi-microgrid. Energy storage, demand response, and thermal comfort resulted in a microgrid cost reduction of 12.31 % and a distribution company profit reduction of 17.25 %. According to the results, thermal comfort can reduce MGs costs remarkably since it adds more flexibility.

Optimal energy management of an integrated energy system with multiple hydrogen sources

Hydrogen is considered a promising alternative to fossil fuels in an integrated energy system (IES). In order to reduce the cost of hydrogen energy utilization and the carbon emissions of the IES, this paper proposes a low-carbon dispatching strategy for a coordinated integrated energy system using green hydrogen and blue hydrogen. The strategy takes into account the economic and low-carbon complementarity between hydrogen production by water electrolysis and hydrogen production from natural gas. It introduces the green hydrogen production–storage–use module (GH-PSUM) and the blue hydrogen production–storage–use module (BH-PSUM) to facilitate the refined utilization of different types of hydrogen energy. Additionally, the flexibility in hydrogen load supply is analyzed, and the dynamic response mechanism of the hydrogen load supply structure (DRM-HLSS) is proposed to further reduce operating costs and carbon emissions. Furthermore, a carbon trading mechanism (CTM) is introduced to constrain the carbon emissions of the integrated energy system. By comprehensively considering the constraints of each equipment, the proposed model aims to minimize the total economic cost, which includes wind power operation and curtailment penalty costs, energy purchase costs, blue hydrogen purification costs, and carbon transaction costs. The rationality of the established scheduling model is verified through a comparative analysis of the scheduling results across multiple operating scenarios.

Economic Analysis of a Photovoltaic Hydrogen Refueling Station Based on Hydrogen Load

With the goal of achieving “carbon peak in 2030 and carbon neutrality in 2060”, as clearly proposed by China, the transportation sector will face long–term pressure on carbon emissions, and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However, true “zero carbon” emissions cannot be separated from “green hydrogen”. Therefore, it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations, especially photovoltaic hydrogen production, which is applied to hydrogen refueling stations (hereinafter referred to “photovoltaic hydrogen refueling stations”). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day, this paper studies and analyzes the system configuration, operation strategy, environmental effects, and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD, the photovoltaic hydrogen refueling station has good economic benefits. Additionally, compared with the conventional hydrogen refueling station, it can reduce carbon emissions by approximately 1237.28 tons per year, with good environmental benefits.

Controlled Release of Hydrogen-Carrying Perfluorocarbons for Ischemia Myocardium-Targeting 19 F MRI-Guided Reperfusion Injury Therapy.

Hydrogen gas is recently proven to have anti-oxidative and anti-inflammation effects on ischemia-reperfusion injury. However, the efficacy of hydrogen therapy is limited by the efficiency of hydrogen storage, targeted delivery, and controlled release. In this study, H2 -PFOB nanoemulsions (NEs) is developed with high hydrogen loading capacity for targeted ischemic myocardium precision therapy. The hydrogen-carrying capacity of H2 -PFOB NEs is determined by gas chromatography and microelectrode methods. Positive uptake of H2 -PFOB NEs in ischemia-reperfusion myocardium and the influence of hydrogen on 19 F-MR signal are quantitatively visualized using a 9.4T MR imaging system. The biological therapeutic effects of H2 -PFOB NEs are examined on a myocardial ischemia-reperfusion injury mouse model. The results illustrated that the developed H2 -PFOB NEs can efficaciously achieve specific infiltration into ischemic myocardium and exhibit excellent antioxidant and anti-inflammatory properties on myocardial ischemia-reperfusion injury, which can be dynamically visualized by 19 F-MR imaging system.Moreover, hydrogen burst release induced by low-intensity focused ultrasound (LIFU) irradiation further promotes the therapeutic effect of H2 -PFOB NEs with a favorable biosafety profile. In this study, the potential therapeutic effects of H2 -PFOB NEs is fully unfolded, which may hold great potential for future hydrogen-based precision therapeutic applications tailored to ischemia-reperfusion injury.

Demonstration and kinetics of hydrogen loading in titanium thin films

Experimental hydrogen loadings in titanium thin films were compared to the Mintz-Bloch model. 500 nm titanium thin films were deposited with an electron-beam evaporator onto sapphire substrates and were capped with a 10 nm palladium thin film. The titanium films were loaded with hydrogen in a custom Sievert apparatus where the pressure drop showed full hydriding at a hydrogen pressure of 2 bar and loading temperatures of 100 °C, 150 °C, 200 °C and 250 °C. Comparisons of X-ray diffractions of loaded and unloaded films showed the presence of titanium hydride in loaded films. The experimental loadings were compared to the Mintz-Bloch model where the Mintz-Bloch model overpredicted experimental loadings. This was due to the Mintz-Bloch assuming that hydride forms immediately upon hydrogen exposure in the metal. However, the difference between the experimental loading kinetics and Mintz-Bloch model was reduced as loading temperatures increased until the temperature reached 250 °C where some titanium hydride outgassing occurred.