Abstract
Thermal energy storage using coupled metal hydride reactors is attractive because it offers several advantages such as one-time hydrogen loading, high thermal storage density, compactness and possibility of simultaneous heating and cooling. This study presents experimental investigations on a coupled metal hydride based thermal energy storage system. Based on compatibility criteria of hydrides described in this work, LaNi4.25Al0.75 for thermal energy storage and La0.75Ce0.25Ni5 for hydrogen storage were chosen. The study employed two novel cartridge type coupled reactors with enhanced heat transfer surfaces. The effects of heat source and ambient temperatures on the system performance were investigated. The study reveals that coupled hydride systems with suitable pairs of hydrides can deliver high energy storage capacities at good thermal efficiencies. The heat output of 227.7 kJ was achieved with a heat transfer rate of 130.7 W at 55.7 % efficiency. The hydrogen storage alloy exhibited good compatibility with the energy storage alloy with fast hydrogenation and dehydrogenation. It also produced a cooling effect of 171.8 kJ while desorbing hydrogen.
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