The application of liquid metals such as gallium, tin and lithium as plasma-facing materials is a potential means to resolve the technical issues associated with power exhausting and particle handing in magnetic fusion devices. GaInSn alloy with melting point of 10.5°C, is employed as a modeling material to explore the plasma-driven permeation (PDP) method to study the hydrogen isotopes (hydrogen and deuterium) transport parameters in a liquid metal. Static liquid GaInSn membranes sitting on a mesh sheet are exposed to hydrogen/deuterium plasmas in the linear plasma device VEHICLE-1 with the temperature range of 280–496°C. Hydrogen/deuterium diffusivity are obtained by fitting the time evolutions of permeation fluxes. The dynamic hydrogen/deuterium retention in the liquid GaInSn are found to be low (∼1015D/cm3), which are consistent with the thermal desorption spectroscopy (TDS) measurement following plasma exposure. The hydrogen and deuterium transport parameters are found to be close to each other.