Hydrogen-free Diamond-like Carbon Research Articles

Novel method for quantifying the ratios of sp3/sp2 hybridized carbon in diamond-like carbon films using soft X-ray emission spectroscopy

This study presents a pioneering method for quantifying the ratios of sp3/sp2 hybridized carbon in diamond-like carbon (DLC) films. The novelty lies in using soft X-ray emission spectroscopy (SXES), a technique not widely employed in this context. The DLC films, obtained through various deposition methods, were characterized for hydrogen content, film density, and sp3/sp2 ratio using Rutherford backscattering spectroscopy/Elastic recoil detection analysis (RBS/ERDA), X-ray reflectivity (XRR), and SXES, respectively. To ensure the reliability of the SXES method, it was validated through comparative analysis with near-edge X-ray absorption fine Structure (NEXAFS) spectroscopy, providing confidence in its accuracy. While NEXAFS provided consistent sp3/sp2 ratio measurements in hydrogen-free DLC films, its accuracy in hydrogenated DLC films was impacted due to poor accuracy when applied to this film group. In contrast, SXES demonstrated greater precision in hydrogenated and hydrogen-free DLC films, revealing sp3/sp2 ratios ranging from 36 % to 62 %, corresponding variations in hydrogen contents and film densities. These findings highlight the superior utilization of SXES in accurately determining the sp3- and sp2-hybridized carbon ratios, particularly in hydrogenated DLC films, offering a robust alternative to NEXAFS and paving the way for enhanced characterization and application in various industrial fields.

Extremely enhanced friction and wear performance of hydrogen-free DLC film at elevated temperatures via Si doping

Hydrogen-free diamond-like carbon (DLC) films have garnered significant attention as a highly efficient solid lubrication material, but poor high-temperature lubrication and wear resistance limit their further application. Here, silicon-doped DLC (Si-DLC) films with different Si contents were deposited using a superimposed HiPIMS-DCMS deposition system to improve their high-temperature lubrication and wear resistance performance. The influence of Si content on the microstructure, mechanical and high-temperature friction and wear behavior of Si-DLC films was investigated. The results showed that Si-DLC films had a dense structure and nanoscale smooth surface. The Si doping enhanced the adhesion strength and relieved the residual stress of Si-DLC films, but decreased the hardness and Young's modulus. Meanwhile, Raman and XPS spectroscopy revealed significant local structural changes in Si-doped DLC films. Furthermore, the results showed that DLC films doped with low Si content displayed excellent tribological performance at elevated temperatures due to the graphite lubricating layer on the surface of wear marks. Specifically, Si-DLC film with 3.31 at% Si had an ultra-low average friction coefficient of 0.04 at 450 °C and still provided effective lubrication at temperatures up to 500 °C. In contrast, pure DLC film failed to lubricate at 450 °C due to the severe graphitization transition and Si-DLC film with 17.47 at% Si quickly failed to lubricate at 200 °C due to the SiC and SiO2. This work sheds light for the high-temperature application of DLC films doped with low Si content by superimposed HiPIMS-DCMS deposition system.

Highly radiation-stable DLC coatings for a new class of detectors: Structural and morphological features

Within the framework of the FTM-NEXT INFN (Fast Time Micropattern gaseous detectors - next of Nuclear Physics National Institute) experiment, we produced hydrogen-free diamond-like carbon films through pulsed-laser deposition to serve as resistive layers in modern resistive micro-pattern gaseous detectors that must work in extreme radiation environments at future colliders. To obtain homogeneous diamond-like carbon coatings, over medium-to-large size (3 cm × 3 cm), with excellent adhesion to the substrate and with typical surface resistivity values in the range of 1–100 MOhm/sq, growth conditions had to be optimized. In this paper we report on the stability of resistive diamond-like carbon layers subjected to increasing doses of irradiation with proton beams accelerated to an energy of 2 MeV. The morphological, structural, and electrical properties, also at the nanoscale level, of diamond-like carbon coatings following ion irradiation were studied by electron microscopy, electron diffraction, electrical transport characterization and scanning tunneling spectroscopy.

Friction and wear behavior of molybdenum-disulfide doped hydrogen-free diamond-like carbon films sliding against Al2O3 balls at elevated temperature

Diamond-like carbon (DLC) films quickly experience lubrication failure due to oxidation and mechanical degradation when used above 300 °C, which limits their application. Molybdenum disulfide (MoS2) doping is considered as a feasible method to improve high-temperature properties of DLC films. However, the effect of MoS2 doping on the high-temperature friction behavior of MoS2-DLC composite films and its mechanism remain unclear. Here, MoS2-DLC composite films with different contents of MoS2 were synthesized by a superimposed deposition system consisting of high-power impulse magnetron sputtering (HiPIMS) and direct current magnetron sputtering (DCMS). The MoS2 content in the films was controlled by varying the number of MoS2 pellets in the graphite-MoS2 (C–MoS2) mosaic target. The effect of MoS2 doping content on the structure and mechanical properties of MoS2-DLC films was analyzed. In addition, the friction and wear behavior and mechanism of MoS2-DLC composite films sliding against Al2O3 balls at 25–450 °C were studied. The results indicated that MoS2 was successfully incorporated into DLC matrix, and the content of Mo in the films ranged from 0 to 6.15 at. %. The as-deposited MoS2-DLC composite films exhibited a dense and featureless structure. The doping of MoS2 improved the adhesion strength and released the internal stress of MoS2-DLC composite films, but reduced the hardness and elastic modulus of the films. In particular, MoS2-DLC composite films with 3.78–6.15 at. % Mo maintained excellent anti-friction and anti-wear performances in the temperature range of 25–450 °C. Abrasive wear and fatigue wear occurred in the friction test of the films at different temperatures. However, the friction mechanism of the films varied with the temperature of friction test. At 25 °C, MoS2-DLC composite films showed excellent lubrication and anti-wear abilities due to the carbon suspension bond was passivated by H2O molecules. At 250 °C, MoS2 phase precipitated on the surface of the films, resulting in low friction. At 350 °C, MoS2-xOx solid solution was generated on the surface of the wear track to maintain lower friction and wear. Interestingly, MoS2-DLC composite films with high Mo content still achieved relatively low coefficient of friction and wear rate up to 450 °C due to the continuous availability of MoS2-xOx generated on the surface of wear track.

Comparative study on tribocorrosion behavior of hydrogenated/hydrogen-free amorphous carbon coated WC-based cermet in 3.5 wt% NaCl solution

In this work, the tribocorrosion performance of hydrogenated and hydrogen-free diamond-like carbon (DLC) coated thermal sprayed WC-based cermet/carbide were investigated comparatively. The results showed that, regardless of hydrogen containing, both coatings demonstrated the improvement of anti-tribocorrosion capability of WC-based cermet in 3.5 wt% NaCl solution, by suppressing the corrosion of Ni-based binder phases. Particularly, the hydrogenated DLC coating presented the better tribocorrosion resistance under low load due to the high hardness and excellent corrosion resistance, but it suffered from the catastrophic delamination and protective degradation at heavy load arisen from the high brittleness and large residual stress. In contrast, the hydrogen-free DLC duplex coating exhibited a low COF of ∼0.06 under higher load (10 N) with long time friction (12 h), because of its gradually shearing characteristic. This work provides theoretical basis and design principles for DLC combinations with remarkable corrosion inhibition used in harsh marines.

Nanoscale friction of tetrahedral amorphous diamond-like carbon film after thermal annealing

Diamond-like carbon (DLC) coatings have demonstrated significant potential as solid lubricants for a wide range of applications. However, thermal-induced structural changes lead to alterations in its mechanical and frictional properties. In this study, we investigate the friction properties of DLC films after high-temperature annealing, by conducting reciprocating single asperity scanning experiments of self-mated hydrogen-free DLC tribopair under ultra-high vacuum (UHV) conditions. As the annealing temperature increases, the coefficients of friction (COFs) first increase owing to the desorption of water molecules; while, with the further increase of temperature, friction shows a decreasing trend because of the high-temperature-induced sp3-to-sp2 rehybridization which lowers the interfacial shear strength. The insights gained from this study provide a better understanding of the frictional properties of DLC films.

Corrosion and Tribological Performance of Diamond-like Carbon-Coated ZK 60 Magnesium Alloy

In this work, hydrogenated and hydrogen-free Diamond-Like Carbon (DLC) coatings were deposited into ZK60 magnesium alloy using the promising coating method High-Power Impulse Magnetron Sputtering (HiPIMS). CrC and WC were used as interlayers of the thin films, and their influence was studied. The structure and composition of the coatings were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Raman spectroscopy. Tribological tests, scratch tests, and nanoindentation were performed to obtain information about the mechanical and tribological properties of the coatings. Finally, immersion and electrochemical tests were performed to evaluate the corrosion behavior of the samples. The results showed a homogeneous layer with improved wear resistance, toughness, and hardness in addition to good adhesion to the substrate of the ZK60 magnesium alloy. The hydrogenated DLC coating showed better results that the hydrogen-free thin layer, and relevant differences were observed depending on the interlayer. In this work, the improvement in the tribological and corrosive properties of Mg alloys was studied by using thin layers of DLC and different intermediate layers, achieving similar or even better wear and adhesion values than with thicker layers.

Hydrogen-free DLC films fabricated using superimposed HiPIMS-DCMS deposition system: Bias voltage effects

Diamond-like carbon (DLC) films were grown using a superimposed high-power pulse magnetron sputtering and direct current magnetron sputtering (HiPIMS-DCMS) deposition system at various bias voltages from 0 to −350 V. The microstructure, mechanical and tribological properties of the films were studied in relation to bias voltage. The results suggested that the deposition rate of DLC films decreased gradually with the enhancement of bias voltages. The surface roughness of DLC films decreased from 2.81 nm to 0.54 nm. The values of ID/IG of DLC films decreased first and increased later with the enhancement of bias voltages, and the value of ID/IG was the minimum at −150 V. Therefore, the highest sp3 CC fraction of DLC film was obtained when deposited at −150 V. Moreover, the hardness and internal stress of DLC films also show the law of increasing first and decreasing later. DLC film obtained the maximum hardness and highest internal stress of 32.0 GPa and − 2.08 GPa at −150 V. Finally, the friction test suggested that the films had excellent tribological performance. In particular, the film deposited at −150 V had excellent tribological properties, including low friction coefficient (0.095) and low wear rate (1.36 × 10−7 mm3/N·m).

Tribological behavior of H-DLC and H-free DLC coatings on bearing materials under the influence of DC electric current discharges

In automotive industry, most of the moving components and lubricants are currently being reengineered in order to meet the much harsher operating conditions of electric vehicles (EVs). Diamond-like carbon (DLC) coatings have been widely used in automotive field mainly because of their lower friction and wear coefficients, high chemical inertness, corrosion resistance, and hardness. It is also possible that DLC coatings can afford very desirable tribological properties to the bearings and gears of electric vehicles. In addition, their superior dielectric properties could also be very ideal for such applications. In EVs, current leakages in the powertrain are very common and these can adversely impact the tribological behavior of bearings and/or other moving mechanical elements. Although DLC coatings provide superior tribological performance in IC engine applications, they have not yet been evaluated under electrified sliding conditions of EVs. In this work, two different types of DLC coatings (Hydrogenated DLC (H-DLC) and hydrogen-free DLC (H-free DLC) were produced on AISI 52100 steel substrates and tested using a ball-on-disc tribometer under non-electrified and electrified (DC, 3A) both dry and lubricated sliding conditions. Coefficient of friction (CoF), wear volumes, wear modes and mechanisms have been assessed and reported. The results showed that electrification can cause a decrease in CoF for baseline steel-on-steel contacts, but an increase for H-free DLC in lubricated condition. The change in CoF of H-DLC interface was negligible. However, electrification caused a significant increase in the wear volume of steel-on-steel and H-free DLC-coated surfaces, but little or no wear was observed for the H-DLC-coated cases in both dry and lubricated test conditions. Overall, the tribological behavior of H-DLC was almost unaffected by electrification, suggesting that one has to select the right kind of DLC for applications involving electrified contact conditions.

Comparison of mechanical and tribological properties of diamond-like carbon coatings doped with Europium and Gadolinium produced by HiPIMS

Hydrogen-free diamond-like carbon (DLC) thin films can be employed for numerous applications, including engine components, once they exhibit good properties for that. They have been used as coatings due to their attractive properties, including high hardness, high wear resistance, and low CoF even under high load/pressure. One of the major limitations of hard hydrogen-free ta-C coatings applications is related to the low reactivity with oil additives used nowadays. The Ionic liquids (ILs) emerged as a novel class of lubricants that can be used in future lubricated systems due to possessing unique physical properties, like high thermal stability and conductivity. To improve the lubrication performance of DLC with ILs, the films were doped with rare earth metals such as Gd and Eu. These non-carbide-forming elements can be introduced in the DLC matrix, incorporated as single atoms, and improve the surface adsorption and reactivity of phosphorus-based IL, and consequently, the lubricating properties of DLC/ILs sliding contacts. However, many demanding applications require good performance across the different regimes (from boundary to hydrodynamic regime). Across all regimes, the boundary is the most challenging, where metal-to-metal contact occurs. Therefore, it is essential to study the influence of the doping elements on the doped-DLCs performance under the boundary regime. For comparison, a pure-DLC was used. In this study, Eu and Gd-DLC tribological systems are characterized by pin-on-disk test in dry conditions and by scratch test. Also, mechanical properties are studied through nano-indentation. Results show that samples doped with a low atomic concentration of Eu or Gd (1%–3%), despite having a CoF higher than un-doped DLC films, show typical values for pure-DLC coatings, like low specific wear rate (<10−16 m3/Nm) and high hardness (23 GPa), permitting, in the future, the combination of novel nanostructured alloyed-DLCs and ILs needed to achieve the optimal lubrication performance.

Probing Friction Properties of Hydrogen-Free DLC Films in a Nitrogen Environment Based on ReaxFF Molecular Dynamics.

In this paper, ReaxFF molecular dynamics simulations were used to look at how load and the number of nitrogen molecules affect how friction behavior in hydrogen-free diamond-like carbon (DLC). The presence of nitrogen molecules will inhibit the formation of C-C covalent bonds between the contact surfaces of the upper and lower DLC, thereby effectively suppressing the increase in friction during the initial friction phase. After the initial friction stage, the mechanical mixing of the contact surfaces brought on by the diffusion of nitrogen molecules results in considerable shear stress, which has significant impacts on the friction force. In addition, due to the existence of nitrogen molecules, the effect of graphitization of hydrogen-free DLC on friction is almost negligible.

Tailoring sheet resistance through laser fluence and study of the critical impact of a V-shaped plasma plume on the properties of PLD-deposited DLC films for micro-pattern gaseous detector applications

Diamond-like carbon (DLC) is an attractive inexpensive alternative to diamond. The control of the C (sp3)/C(sp2) ratio, influencing the material properties, is fundamental for its use in dedicated applications like, for example, the fabrication of a particular class of gas detectors for ionizing particles termed Micro-Pattern Gaseous Detectors (MPGDs).A deposition technique enabling control on the amount of C(sp3) hybridized bonds, hydrogen content and disorder is pulsed lased deposition (PLD).In this paper, we report on the preparation of hydrogen-free DLC films by nanosecond excimer laser-based ablation of a graphite target correlating the laser fluence with the electrical properties of the DLC films to be used as protective resistive layers in MPGD detectors.Moreover, unprecedented physical insight and discussion are provided about the critical aspects of both occurrence of a V-branched plume and its composition on the spatial distribution of C(sp3) bonds and film uniformity. Improvement strategies are demonstrated by comparing and discussing two classes of PLD experiments: ON-axis (coaxial plasma expansion axis and substrate symmetry axis) and OFF-axis (substrate-axis shifted with respect to the plume-axis and rotating substrate). Optimally working OFF-axis configuration conditions are shown to lead to fine tuning of resistivity and uniformity of composition of C(sp3) bonding over a few cm2 extended areas. Sheet resistance (3.1 ± 0.3) × 109 Ω/sq., corresponding to C(sp3) bonding concentration of ~86%, is reported in OFF-axis experiments at a fluence of 5.5 J/cm2 onto kapton substrates which are used for the realization of MPGDs.

Understanding the DLC film – Polyamide 12 substrate interrelation during pulsed laser deposition

High-quality hydrogen-free diamond-like carbon (DLC) films that are free of any detectable signs of cracks and delamination are produced on polyamide 12 (PA) substrates using the Pulsed Laser Deposition (PLD) technique, resulting in subplantation of the polymeric substrate by carbon species and the formation of an interphase between the DLC film and the substrate. The interrelation between the DLC films and PA substrates of different crystallinity degree is investigated using spectroscopic (NMR, IR, XPS, and Raman) techniques and the morphology and topography of the films are evaluated using SEM and AFM. It is demonstrated that the laser fluence (16 and 20 J cm−2) directly affects the subplantation intensity and the DLC film structure. Additionally, it is shown that by changing the physical characteristics of the polymer substrate, such as the degree of crystallinity, the characteristics of the DLC layer and the response of the substrate to the energetic carbon species can be influenced. The studies open up new avenues for research aimed at understanding the interaction of energetic species with polymer substrates and enable the identification of parameters that are important in obtaining hard thin films of high quality on such substrates.

Microstructure evolution and wettability regulation of air-exposed hydrogen-free diamond-like carbon films

Regulation of surface wettability is of vital significance to diamond-like carbon (DLC) serving as multi-functional coatings in many important fields. In this study, hydrogen-free DLC films with highly adjustable surface wettability induced by surface local hybridized structures were deposited on silicon substrates by RF magnetron sputtering under different substrate temperatures and RF powers. A non-monotonic dependency of surface wettability on the hybridization states, which is just inverse for polar and non-polar liquids, was found on the homogeneous DLC films with nanoscale surface roughness. In particular, the wetting transition from hydrophilicity to hydrophobicity occurred on the DLC films in contact with water. A clear picture about the essential correlation of surface wettability to microstructures of DLC films was drawn in terms of detailed analysis of surface energy components associated with the evolution of sp2-C bonds or clusters in content, type and distortion. Further, a possible mechanism accounting for the wetting transition of the DLC films was also proposed. This work aims to reveal the wetting nature of hydrogen-free DLC films versus graphite and diamond, and provide an available strategy to fabricate high-performance DLC films with special surface wettability used in aqueous environment.

Effects of diffused hydrogen atoms on thermomechanical properties and contact behavior of a diamond-like carbon film

Hydrogen atoms are doped to diamond-like carbon (DLC) to improve its thermomechanical properties and tribological performance as a surface protective coating. In this study, molecular dynamics (MD) simulations are performed to investigate the impacts of diffused H atoms on the mechanical stiffness, surface energy, specific heat, and thermomechanical contact behavior of DLC. The hydrogenated DLC (a-C:H) is prepared by adding H atoms to a fixed amount of C atoms (method 1) and by replacing C atoms in DLC with H atoms (method 2). The atomic percentage of hydrogen (at. % H) in DLC is varied from 0 to 8.6%. From the systematic MD simulation results, it is observed that the DLC's mechanical stiffness increases with at. % H due to the increasing density with a higher sp3%, but it shows a decreasing trend for method 2 due to the decreasing density. During the sliding contact with a hemispherical diamond tip, the a-C:H samples show a lower coefficient of friction (COF) than the hydrogen-free DLC (ta-C) sample for method 1 but a higher COF for method 2, which can be attributed to the changes in density and surface energy with respect to hydrogen contents in DLC.

Microstructure, erosion and tribological behaviour of thick DLC coatings by the filtered cathodic vacuum arc combined with a high-voltage pulse power

Hydrogen-free diamond-like carbon (DLC) films with thickness of 36 μm and 50 μm have been prepared on Si and AISI 304L stainless steel substrates, respectively, by filtered cathodic vacuum arc (FCVA) together with a high-voltage pulse power. The structure, chemical bonding state, mechanical properties and wear, corrosion resistance and anti-erosion performance were evaluated. The thick DLC films with compressive stress of 0.71 GPa and hardness of 3160 HV were obtained. The preparation of the low stress but high hardness coating mainly due to the appropriate high negative bias and short pulse duration, which could result in an alternate ion bombardment and deposition. The 50 μm-thick coating showed corrosion resistance with high polarization resistance of 4.69 × 108 Ω·cm2 and low corrosion current density of 5.47 × 10−8 A·cm−2. Thick coating exhibited outstanding sand particle erosion resistance with low average mass loss rate of 0.035 mg g−1. Under high-speed sand erosion conditions, the coating remains unbroken, without peeling or cracking were observed on the erosion center. In addition, DLC coatings showed good tribological performance under dry, water- and oil-lubricated condition.

On the Origin of Reduced Cytotoxicity of Germanium-Doped Diamond-Like Carbon: Role of Top Surface Composition and Bonding.

This work attempts to understand the behaviour of Ge-induced cytotoxicity of germanium-doped hydrogen-free diamond-like carbon (DLC) films recently thoroughly studied and published by Jelinek et al. At a low doping level, the films showed no cytotoxicity, while at a higher doping level, the films were found to exhibit medium to high cytotoxicity. We demonstrate, using surface-sensitive methods—two-angle X-ray-induced core-level photoelectron spectroscopy (ARXPS) and Low Energy Ion Scattering (LEIS) spectroscopy, that at a low doping level, the layers are capped by a carbon film which impedes the contact of Ge species with tissue. For higher Ge content in the DLC films, oxidized Ge species are located at the top surface of the layers, provoking cytotoxicity. The present results indicate no threshold for Ge concentration in cell culture substrate to avoid a severe toxic reaction.

Structure and optical properties of diamond like carbon films containing aluminium and alumina

In the present research both hydrogenated and hydrogen-free diamond like carbon (DLC) films containing different amounts of Al were deposited by magnetron sputtering. The composition, structure, morphology and optical properties of these films were explored. Aluminium carbide was found in hydrogen-free DLC:Al films. Formation of the AlOx or AlOx/AlCx nanoclusters embedded into the DLC:Al films was revealed. Refractive index of hydrogen-free DLC:Al was as high as 2.7. Optical absorbance in the visible wavelength range of the hydrogenated DLC films containing Al drastically decreased as a result of Al doping, while in the case of the hydrogen-free films, this kind of changes was less pronounced. Excited state relaxation dynamics studied by transient absorption spectroscopy for both types of DLC:Al films has indicated different relaxation phenomena that were related to the composition and structure of DLC:Al films.

Effect of Thickness on Tribological Behavior of Hydrogen Free Diamond-like Carbon Coating

The effects of film thickness on the tribological behavior have been investigated for hydrogen-free diamond-like carbon coating in this paper. The film was deposited on cemented carbide substrate (YG10C) by applying a high power impulse magnetron sputtering (HiPIMS) technique. The reciprocating ball on the disc test was conducted on the film with different thicknesses from 0.66~1.26 μm against the ZrO2 ball. The friction coefficient and wear resistance of the coating with different thickness showed a unimodal change. Numerous defects were observed on the surface of the film with a thickness of 0.66 μm and the wear mechanism was mainly plow-grinding. Therefore, the steady-state friction coefficient reached the maximum value of 0.22. The coating with a thickness of 1.01 μm had a higher sp3 content and a smoother, dense surface. A graphite transfer layer with low shear strength was detected on the ZrO2 ball against the film with a thickness of 1.01 μm, which led to the reduction in friction, thus the steady-state friction coefficient reached the minimum value of 0.10. However, the internal stress of the film increased with increasing thickness due to the distortion of the bond angle of internal structure when the film was bombarded by high-energy particles. The peeling coating was observed under reciprocating sliding, which both played the role of plowing and boundary lubrication film. The steady-state friction coefficient was 0.14 with a coating thickness of 1.26 μm. As a result, the hydrogen-free diamond-like carbon coating with optimized thickness shows a smooth and compact surface, low internal stress, high sp3 content, and better tribological properties.

Laser interference patterned ta-C-coated dry forming tools

PurposeThis study aims to introduce a strategy that permits well-defined contact areas in forming tools for improving both wear and friction properties by a selective laser treatment of a hydrogen-free diamond-like carbon layer (DLC), for substituting lubrication in forming processes. The need of lubricant substitution in forming processes is given because, besides the positive technological aspects, lubrication leads to numerous negative economic and ecological effects such as lubricant appliance and removal costs as well as its disposal.Design/methodology/approachHydrogen-free DLCs with an sp³-ratio of 60-70 per cent are deposited on steel surfaces and subsequently micro-structured using direct laser interference patterning (DLIP). To find the optimal structure parameters for reducing friction and wear, line-like and cross-like patterns with three different structure sizes were fabricated onto the DLC layer. Tribological measurements are performed with a ball-on-disk tribometer on the differently DLIP-structured surfaces and compared to polished steel and unstructured DLC reference surfaces.FindingsA reduction of the coefficient of friction, from 0.18 to 0.11, is observed for the laser-structured DLC surfaces, reaching values comparable to lubricated and polished steel surfaces, with a friction coefficient of 0.10.Originality/valueUsing DLIP, it was possible to show how this method can reduce friction on DLC-coated specimens. The observed characteristics are relevant to improve the tribological performance of forming processes, without usage of lubrication.