Hydration Process Research Articles

Synergistic hydration mechanism of steel slag-metakaolin based on ionic dissolution properties combined with industrial CT analysis

Replacing cement with solid waste materials is a key approach to preserving natural resources and mitigating carbon dioxide emissions. In this research, we explored elemental complementation as an eco-friendly and low-carbon approach to develop composite cementitious materials (CCMs) by partially substituting cement with steel slag (SS) and metakaolin (MK), thereby overcoming the low reactivity of SS and facilitating its broader application. We scrutinized the synergistic effects of SS-MK CCMs on parameters such as solubility, water demand, setting time, compressive strength, the formation of hydration products, and microstructure. Employing a suite of analytical techniques, including Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES), X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), measurement of hydration heat, and X-ray computed tomography. The findings revealed that the alkaline environment produced by SS-cement powder promoted the breakdown of Si-O and Al-O bonds within MK, facilitating both the early hydration process and the development of strength.MK compensates for the lack of strength caused by the slow hydration of SS in the early stage, while the SS accelerated a pozzolanic reaction of MK, leading to a 28d compressive strength of 54.77 MPa for the composite, while the 28d strength of SS20 was 39.74 MPa; MK effectively utilized portlandite, enhancing the hydration of SS and increasing the production of calcium silicate hydrate, which optimized the pore structure and improved sphericity. Furthermore, the SS-MK CCMs addressed the issues of f-CaO excess and prolonged setting times in the SS-cement system, while also ameliorating the high calcium demand and reduced fluidity in the MK-cement system. Additionally, its lower cumulative heat release from hydration enhances the material’s volumetric stability. This study presents a strategy for the large-scale application of SS and contributes to the value-added, eco-friendly use of industrial solid wastes.

Influence of Early Hydration Process on the Hydrostatic Pressure Change of Cement Pastes at Different Temperatures.

In cementing operations, a rapid decrease in the hydrostatic pressure of cement paste is one of the main causes of early gas channeling. In response to this issue, tests were conducted on the variation in the hydrostatic pressure of cement paste over time at different temperatures (30 °C-180 °C), and it was found that the curve of its rapid decrease time point with temperature change conforms to the Boltzmann function. The relationship between the early hydration process and the microstructure of paste at 90 and 150 °C, as well as the changes in hydrostatic pressure, was studied using X-ray powder diffraction, thermogravimetry, and scanning electron microscopy. The results show that the hydrostatic pressure curve of the paste shows a trend of first stabilization and then rapidly decreasing at medium and low temperatures (30 and 90 °C). At high temperatures (150 °C), the pressure curve initially increases until stabilization, enters a stable period, and finally rapidly decreases. In the early stage of hydration induction, there is a large amount of free water between hydration products, and the hydrostatic pressure of the paste remains stable. In the process of hydrostatic pressure reduction, the microstructure of the paste develops from the particle hydration products to a "gel framework", which isolates the pressure transfer of part of the free water. During the acceleration period of hydration, the hydration products enhance the "framework" and reduce the porosity of the paste, completely cutting off the transmission of water pressure, resulting in a rapid decrease in the hydrostatic pressure of the paste. A method for predicting the rapid decrease in hydrostatic pressure of the paste was proposed using the hydration reaction process.

Impact of pressure and temperature on the hydration resistance of rice

Crop soaking, a hydration process driven by diffusion, is essential for applications such as milling and germination. This study investigated the moisture absorption of rice kernels during soaking, considering factors like pressure and temperature. The experimental data were analyzed using the Peleg model to understand hydration kinetics, revealing a strong correlation between empirical and regression data, with determination coefficients mostly exceeding 0.99. The study also assessed soaking hydration resistance, identifying contributions from various rice layers, including the husk and bran. Moisture content increased gradually with soaking time, with higher temperatures enhancing absorption. Under normal pressure, white rice absorbed water faster than paddy and brown rice, with brown rice exhibiting higher hydration resistance. Interestingly, paddy rice soaked faster than brown rice under certain conditions due to the air layer between husk and bran, which was eliminated under vacuum or higher temperatures, though the water replacing the air remained unabsorbed. This study aggregated hydration resistance from each kernel to determine layer resistance and specific diffusivity of husk and bran.

Mesoscopic simulation of concrete drying shrinkage with hydration kinetics

Shrinkage-induced cracking significantly impacts the durability of mass concrete structures. Quantitatively evaluating drying shrinkage of concrete proves challenging due to the time-consuming experiments and overlooked microstructure changes during the hydration process. To address this concern, this study initially characterized the long-term hydration products and microstructure of low-heat Portland cement (LHPC) through microstructural experiments. Subsequently, a novel high-resolution mesoscale framework is developed to investigate the drying shrinkage with hydration kinetics. High-resolution models consist of realistic-shaped aggregates are validated by the aggregate morphology and gradation parameters of core sample from mass concrete. Concurrently, the quantitative effects of internal and external factors on LHPC drying shrinkage are explored. Results indicated that LHPC possesses a denser microstructure, lower porosity, higher carbonation resistance, and 20% lower drying shrinkage compared to moderate-heat Portland cement, suggesting promising applications. Furthermore, experimental and computational findings suggested that increasing aggregate volume, controlling aggregate morphology, and adjusting curing time and humidity could be employed to reduce and manage drying shrinkage, ensuring concrete structure durability.

A Review on the Curing of Concrete using Different Methods

The hardened properties and durability of concrete are dependent on the moisture and temperature condition of the concrete during its hydration process. This review explores various methods of curing concrete focusing on their effectiveness in improving the performance and sustainability of concrete structures. Traditional methods of curing (such as ponding, sprinkling) and the modern curing techniques (such as curing compounds, self-curing agents and steam curing) are compared. The advantages and disadvantages of these methods are highlighted and water curing is found to be the most effective method of concrete curing, for it allows for the maintenance of adequate moisture and temperature, and it does not change the macro and microscopic structure of the concrete. The research methodology includes extensive literature, experimental studies and performance evaluations. The review aimed at providing a comprehensive understanding of the best curing practices for different projects and working conditions.

Deep learning neural networks for monitoring early-age concrete strength through a surface-bonded PZT sensor configuration

Monitoring the immediate evolution of concrete’s strength is essential to ensure structural integrity and construction efficiency, requiring Forecasting to avoid unforeseen and severe failures during construction. The present investigation introduces an Equivalent structural parametric (ESP) study using a surface-bonded piezo sensor and electromechanical impedance (EMI) methodology to monitor and forecast the strength of concrete by implementing machine learning and deep learning methods. The concrete hydration processes are simulated using COMSOL™ 5.5. The concrete cube’s hydration is represented by altering Young’s modulus and damping ratio to show the rate of curing. Concrete strength development is examined in terms of conductance resonant frequency (CRF) and Conductance resonant peak (CRP). Continuous conductance signature monitoring and data analysis show that CRF and CRP increase with compressive strength. The system’s mechanical impedance is measured, and EMI signatures vs. frequency plots within a specific frequency range are compared to healthy impedance graphs. A mass-spring-damper system with identical properties is identified, and relevant structural parameters are computed. Modern ML algorithms include linear regression (LR), interaction LR, fine, medium, and coarse Gaussian SVM, etc. reliably predict strength with an error rate of less than 2%. Convolutional neural networks (CNN) have advanced image-based recognition, but their usage in EMI-based structural strength assessment is still being studied. A unique strategy using 2D CNN, 2D CNN– Long short-term memory (LSTM), and 2D CNN Bidirectional-LSTM to forecast concrete structure compressive strength shows the potential of deep learning. The proposed 2D CNN-Bi-LSTM model excels in compressive strength prediction, obtaining an R2 value of 0.99 and stabilizing loss error over a few epochs.

The Hydration Activity Enhancement Method of Mayenite in Ladle Slag: A Review

As a byproduct of the steelmaking process, ladle slag has the potential to be used as an auxiliary cement material in the construction field. However, ladle slag generated after secondary refining is typically handled by air cooling and stacking, leading to the presence of the typical mineral phase mayenite (Ca12Al14O33, abbreviated as C12A7) in a crystalline form within the slag. This reduces its early hydration activity, which adversely affects the compressive strength of concrete and consequently lowers the resource utilization rate of ladle slag. Based on this, this article provides a comprehensive review of the generation process and composition of ladle slag. By discussing the hydration process and hydration products of the typical mineral phase C12A7 in ladle slag, as well as the mutual transformation of hydration products, it is shown that hydration products undergo transformation with increasing temperature. Compared to crystalline C12A7, amorphous, C12A7 exhibits excellent hydration activity. Building upon this, methods for amorphizing C12A7 are elucidated, wherein thermal activation or chemical activation is employed to alter the ordered arrangement of atoms within the crystal structure, thereby reducing the stability of the crystal structure to achieve amorphization of C12A7.

Experimental investigation on mechanical property and hydration process of sintered sludge cement paste at different water‐binder ratios and curing ages

AbstractThis research investigated the mechanical property and hydration process of sintered sludge cement (SSC) paste, focusing on the effects of calcination temperature of sludge, sintered sludge ash (SSA) content, curing age, and water‐binder ratio using isothermal calorimetry, X‐ray diffraction, scanning electron microscopy, and multiple regression. Increasing calcination temperature enhanced the compressive strength of SSC paste due to the decomposition of minerals like Clinochlore and Muscovite. The compressive strength decreased by 2.4%–49.4% when the SSA content increased from 0% to 50%, with more significant declines noted at higher water‐binder ratios. Notably, the 7‐day compressive strength of the cement paste with 10% SSA showed little change, and the 28‐day compressive strength actually increased at a water‐binder ratio of 0.4. SSA slowed down the hydration rate of cement and induced more Monocarbonate to form in the early stage. A multiple linear regression model was developed to predict SSC compressive strength with a 12% error margin.

Magnesium-modified starch cryogels for the recovery of nitrogen and phosphorus from wastewater and its potential as a fertilizer substitute: A novel nutrient recovery approach

Nitrogen (N) and phosphorus (P) are primary pollutants contributing to water quality degradation and eutrophication but are also indispensable resources for agricultural production. In this study, we synthesized porous MgO/Mg(OH)2-modified starch gels (SC-M/SC-OM) to facilitate the simultaneous removal of N and P from wastewater and address the challenges associated with separating and recycling powdered materials. By immobilizing magnesium powder within the matrix of starch gel, with the addition of 1.7 % w/w of MgO and 2.4 % w/w of Mg(OH)₂, the adsorbent can be efficiently recovered from the liquid phase, minimizing material loss. Due to their inherent pH-regulating capabilities, the modified starch gels exhibited excellent removal performance over a wide pH range. At the appropriate adsorbent dose, the maximum recovery of SC-M was 70.072 mg/g P and 25.517 mg/g N, whereas SC-OM was marginally inferior to SC-M. The pseudo-first kinetic model more accurately represented the adsorption of the two materials, showing that N and P concentrations mainly affected the adsorption efficiency, which benefits nutrient recovery at higher concentrations. Starch gels function as carriers for powdered magnesium and contribute to the synergistic removal of N and P, particularly enhancing P removal. SC-OM primarily facilitates the recovery of N and P by forming struvite. At the same time, the adsorption during the hydration process of MgO also plays a crucial role in the recovery with SC-M. Finally, the pot experiment confirmed the feasibility of using the recovered SC as a sustained release fertilizer. This study reveals the significant potential of SC-M/SC-OM for environmentally friendly nutrient removal and recovery, providing a promising approach for wastewater treatment and nutrient recycling.

Shrinkage and Creep Properties of Low-Carbon Hybrid Cement.

Hybrid cements combine clinker with large amount of supplementary cementitious materials while utilizing hydration and alkali activation processes. This paper summarizes shrinkage and creep properties of industrially produced H-cement, containing only 20% of Portland clinker. In comparison with a reference cement CEM II/B-S 32.5 R, autogenous shrinkage is smaller after 7 days, and drying shrinkage is similar at similar times. A different capillary system of H-cement leads to faster water mass loss during drying. Basic and total creep of concrete remains in the standard deviation of B4 and EC2 creep models. The results demonstrate that shrinkage and creep properties of concrete made from H-cement have similar behavior as conventional structural concrete or high-volume fly ash concrete.

Effect of Calcium on the Setting Time and Mechanical Property of a Red Mud-Blast Furnace Slag-Based Geopolymer.

This study aims to compare the effects of three calcium compounds on the workability, setting time and mechanical properties of red mud (RM)-blast furnace slag (BFS)-based geopolymers. The crystalline phase, hydration process and microstructure of RM-BFS-based geopolymers were characterized by X-ray diffraction (XRD), heat evolution, X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) tests. The results showed that an appropriate amount of calcium compounds can improve the flowability and compressive strength of the geopolymers, but the excessiveness causes a decrease in strength due to rapid hardening. Other than calcium carbonate, both calcium oxide and calcium chloride played important roles in accelerating the setting times of RM-BFS-based geopolymers. The acceleration in the setting times of geopolymers could be attributed to the calcium hydroxide produced by the dissolution of the calcium compounds, which also provides nucleation sites for the geopolymerization reaction. This study gives new insights into the effect of calcium on the setting times and mechanical properties of geopolymers in the geopolymerization process.

Chitosan-tethered liposomes for sinapic acid delivery

Sinapic acid (SA) is a poorly water-soluble bioactive compound with numerous therapeutic applications. SA-loaded liposomes were prepared by varying soybean phosphatidylcholine (SPC) and sodium deoxycholate (SDC) ratios by the thin-layer hydration process. The formulated SA-loaded liposomes were assessed for size, polydispersity index (PDI), zeta potential, entrapment efficiency (EE), and in vitro drug release studies. The optimized formulation SA-loaded liposomes formulation SA-L3 was further coated with chitosan. Further, chitosan coated SA-loaded liposomes (SA-L3-CS1) were estimated for surface morphology, in vitro drug release, antioxidant and cell viability studies. The optimized SA-loaded liposomes formulation exhibited particles size of 166.24 ± 6.69 nm, PDI 0.222 ± 0.020, zeta potential −12.66 ± 2.15 mV, EE of 74.33 ± 4.63 % and in vitro drug release of 87.78 ± 5.04 %. Chitosan coated SA-loaded liposomes demonstrated substantial changes in particles size (223.13 ± 14.94 nm), PDI (0.295 ± 0.021), zeta potential (19.67 ± 3.27 mV), and EE (80.79 ± 2.96 %) and prolonged drug release was observed (67.54 ± 4.40 % at 8 h). Chitosan coated SA-loaded liposomes demonstrated improved antioxidant and cell viability activities in contrast to pure SA; this could be due to the escalated solubility of SA. In conclusion, the current research revealed that chitosan coated liposomes enhance SA's antioxidant and cytotoxicity activity.

Development sustainable concrete with high-volume wastes tile ceramic: Role of silica nanoparticles amalgamation

As the global concrete industry shifts towards sustainable practices, there is an increasing focus on mitigating the environmental impacts of ordinary Portland cement (OPC)-based concrete, which is notorious for its significant greenhouse gas emissions, high energy consumption, and substantial demand for natural resources. This urgency is compounded by the growing production of waste tile ceramic materials due to rapid urban development, leading to enhanced research into their recyclability within concrete for improved durability and sustainability. This study explores the development of high-strength concrete utilizing waste tile ceramic aggregates (WTCAs) and waste tile ceramic powder (WTCP) as replacements for natural aggregate and OPC, respectively. To further enhance the concrete's mechanical properties and microstructure, silica nanoparticles derived from waste bottle glass (WBGNPs) were integrated in varying proportions ranging from 2 % to 10 % of the binder content. Optimal results were achieved with a full replacement of natural aggregate by WTCAs, 60 % substitution of OPC by WTCP, and the inclusion of 4 % WBGNPs, which collectively exhibited superior compressive, splitting tensile, and flexural strengths. Microstructural analyses revealed that the addition of WBGNPs improved the hydration process, increased gel density, and reduced porosity. From the obtained numerical results, the coefficient of determination value of 0.92 further confirms the model's predictive strength, demonstrating that the Random Forest algorithm can reliably estimate the compressive strength. The findings indicate that the concrete formulated with WTCP and WBGNPs not only meets diverse construction demands but also significantly contributes to environmental sustainability by reducing impacts on global warming and minimizing landfill usage. This study advocates for the strategic incorporation of WTCP and WBGNPs in concrete applications to promote environmentally sustainable construction practices. It is highly recommended that WTCP be utilized in sustainable binders as a replacement for OPC and natural aggregates to enhance it strength and durable properties, reduce the environmental issues, costs, and the depletion of natural resources.

The research progress and Hotspot analysis of polymer cement mortar based on bibliometrics

Ordinary cement mortar is commonly used in building engineering due to its high strength, affordability, and easy access to raw materials. However, it suffers from high shrinkage and poor impermeability, which result in reduced building service life and significant carbon dioxide emissions during production. Polymer additives have been found to enhance the mechanical properties of cement mortar, leading to increased interest in polymer cement mortar by researchers. This study collected and analyzed 420 papers published between 1995 and 2023 in the field of polymer cement mortar. The analysis included publication trends, author cooperation networks, national cooperation networks, published journals, co-citation of references, and keywords. The findings reveal a rapid publication growth from 2018 to 2023, with China making the most significant contribution in this field. Among the scholars, Ru Wang has published the highest number of articles in the field of polymer cement mortar, while Ohama’s papers have been cited the most. The journal with the most articles is Construction and Building Materials. Research in polymer cement mortar focuses on mechanical properties, performance, hydration process, microstructure, and other related aspects. The reinforcement effect of polymer-modified cement mortar on reinforced concrete and applying superabsorbent polymer-modified cement mortar and polymer fiber in cement mortar have emerged as recent research frontiers. This study can help scholars quickly identify high-quality references and research frontiers in the field of polymer cement mortar while also providing research directions and ideas.

Recycling of waste glass powder: Effects on microstructure, mechanical properties and sustainability of seashell powder calcined sludge cement

The massive accumulation of waste seashells, waste sludge and waste glass not only occupies a large amount of land resources, leading to a shortage of land resources, but also causes serious soil-water-air composite pollution over a long period of time with the role of the surrounding environment, which poses a serious hazard to the ecological environment and public health. In this study, the effect patterns of waste glass powder (WGP) on the workability, mechanical properties, microstructure and carbon emission of seashell powder calcined sludge cement (SCSC) slurries prepared using waste sludge and waste seashells as supplementary cementitious materials in place of part of the cement clinker were investigated. The hydration process and microstructure of the materials were characterized by heat of hydration tests, thermogravimetry (TG-DTG), infrared Fourier transform (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the addition of WGP improved the fluidity of SCSC slurries and reduced the shear stress of SCSC slurries without changing the flow pattern of SCSC slurries, and all the slurries conformed to the power law model. The compressive strength of SCSC slurries increased by 25.26 % with 5 % WGP addition. The CO2 emissions per cubic meter of SCSC slurries were reduced by 4.43 %, 8.81 %, 13.5 % and 18.23 % for WGP additions of 5 %, 10 %, 15 % and 20 %, respectively. These results can provide a new way for the efficient resource utilization of waste seashells, waste sludge and waste glass, and reduce the CO2 emission during the cement production process, promoting the clean production of cement.

Multi-objective optimization of seawater mixing in cement-based materials with supplementary cementitious materials using response surface methodology

Seawater instead of freshwater to produce concrete is an effective measure to save freshwater resources. However, the presence of harmful ions in seawater restricts its broader application. The incorporation of supplementary cementitious materials (SCMs) has the potential to significantly mitigate these adverse effects. Consequently, there is a growing interest in understanding the mechanisms by which SCMs function in seawater-mixed cementitious systems. In this study, a quadratic polynomial prediction model with the mechanical properties and dry shrinkage of the composite matrix as the response target was analyzed by the response surface method (RSM). Tests and analytical techniques elucidated the effects of metakaolin (MK) and ground granulated blast-furnace slag (GGBS) on the hydration process of the pastes after seawater mixing. The results revealed that the compressive strength and dry shrinkage were influenced by single-factor or multi-factor interactions. The optimal mix design (MK=20.2 % and GGBS=10.0 %) was experimentally validated, showing an absolute error of 1.5 %. The microstructural analysis indicated that MK and GGBS expedited essential pozzolanic reactions. Enhanced strength in mixtures before 3 d was attributed to cation exchange and initial flocculation. In the 28 d specimens, the increase in strength was related to the growth of Friedel’s salt crystals and C-(A)-S-H gels. Due to the presence of the C-(A)-S-H gels and AFm phases, chloride ions were efficiently immobilized, and the shrinkage of the matrix was reduced.

Early length changes and microscopic phase analysis of phosphorus hemihydrate gypsum fireproof mortar

Abstract Coating the surface of steel structures with phosphohemihydrate gypsum fireproof mortar can improve the fire resistance of steel structures. The hydration curve of phosphorus hemihydrate gypsum (PHG) showed a monotonic increasing trend, and the hydration time was about 1 day. In order to study the hydration process of phosphorus hemihydrate gypsum fireproof mortar, its length change in the early hardening stage was experimentally investigated. The results showed that compared with the hydration time of phosphohemihydrate gypsum, the duration of early length changes in phosphohemihydrate gypsum fireproof mortar was significantly prolonged to about 4 days, and four intervals were clearly observed during this process. Hydroxypropyl methyl cellulose (HPMC) as a water retaining agent, hydroxypropyl starch ether (HPS) as a thixotropic agent, and dispersed latex powder (LP) can all make the four intervals of length changes of fireproof mortar more significant. After adding HPMC, HPS, and LP, it can promote the formation of dihydrate gypsum mainly in fireproof mortar, but dihydrate gypsum crystals were more likely to grow along the [021] direction. The addition of additives can also effectively improve the pore structure of phosphogypsum fireproof mortar.

Effect of additional Al sources on early-age strength of fly ash-based geopolymer containing calcium carbide residue and Glauber’s salt as activators

Alkali-activated materials are more environmentally friendly than cementitious composites and are used in the construction and building sector. However, their intrinsic low early strength under ambient temperatures hinders their practical applicability. More research is needed on the possibilities of increasing early strength at ambient temperatures. In this study, aluminum sulfate (AS) was used as an additional aluminum source to improve the early-age properties of fly ash (FA)-based geopolymers incorporating calcium carbide residue (CCR) and Glauber’s salt (GS) as activators. XRD, TG, SEM, ICP and isothermal calorimetry analyses were carried out to characterize the phase composition, microstructure and hydration process of the prepared materials. The results showed that the 1d strength of AS1-CCR10 was increased by 260.7 % compared with the control material, and the effect on the late strength was negligible. The relative content of AFt increased by 2.97 %, creating a more compact microstructure. During the extraction process, insufficient dissolved Al3+ in the composite led to a decrease in initial strength. In the hydration process, the induction period of AS1-CCR10 was advanced by 40.92 % and that of t50 was advanced by 57.74 %, which accelerated the early reaction rate. However, the Krstulovic-Dabic model could not accurately describe the initial stage of the hydration reaction of composite materials. This study is helpful to broaden the utilization of geopolymer composites and provide a theoretical basis for the preparation and reaction mechanism of alkali-activated materials.

Novel insights on the setting process, hardened properties, and durability of sustainable ultra-high-performance seawater sea sand concrete

Using seawater and sea sand to prepare concrete could effectively alleviate the shortage of freshwater and river sand resources and promote the sustainable development of concrete. However, the current research on the setting process, hardened properties, and sustainability of ultra-high-performance seawater sea sand concrete (UHPSSC) remain considerably limited. In this paper, the UHPSSC was designed to mitigate the autogenous shrinkage and enhance the sustainability, and the effect of seawater, untreated and desalinated sea sand on the setting process, mechanical properties, durability, and sustainability was explored by various tests. Results show that the abundant ions (e.g., Cl- and SO42-) in seawater and untreated sea sand promote the dissolution and nucleation of cement, accelerating the hydration process, and seawater provides a high pH hydration environment, which enhances the pozzolanic reaction activity of silica fume and fly ash. This leads to the enhanced flexural and compressive strengths at early age, reduced flowability, and increased autogenous shrinkage. Although the seawater and untreated sea sand considerably alleviate the natural raw materials consumption, the mechanical performance at 28 d and durability are reduced, thereby decreasing the sustainability index by 7.8 %. The desalination treatment of sea sand decelerates the hydration process of UHPSSC with untreated sea sand due to the lower ion content in desalinated sea sand. The application of desalinated sea sand mitigates the adverse impact of untreated sea sand on the workability, mechanical properties, and durability. However, this desalination process requires more energy and freshwater consumption, thereby decreasing sustainability index. The fly ash incorporation could improve the workability of UHPSSC, and decrease the autogenous shrinkage value by 17.9 %. Moreover, it mitigates the environmental effect without compromising the mechanical properties and durability, leading to an impressive 42.8 % improvement in sustainability. Durability assessment reveals that the prepared UHPSSC specimen maintains outstanding mechanical properties even after 360 d of exposure to severe marine environment, indicating its excellent durability. This paper provides novel insights for achieving a cleaner and more sustainable concrete production.

Non-Destructive Monitoring of Hydration Characteristics in Alternative Materials and Seawater-Based Cementitious Pastes Using Electrochemical Impedance Spectroscopy

This study investigates the hydration behavior of cementitious materials incorporating fly ash, limestone and calcined clay (LC2), and seawater, aiming to understand the individual and synergistic effects of these components on hydration kinetics. The motivation behind this research lies in the growing interest in enhancing the performance and sustainability of cement-based materials by incorporating supplementary materials and utilizing seawater. To achieve this, the hydration process was meticulously examined using electrochemical impedance spectroscopy (EIS). An innovative equivalent circuit model was developed to analyze the results. The experimental data indicated that, with ongoing hydration, the diameter of the impedance arc in the high-frequency range gradually increases. A noteworthy observation is that increasing the proportion of fly ash and LC2 in the cement paste leads to a corresponding enlargement of the high-frequency arc, indicating a significant influence of these supplementary materials on the hydration process. Additionally, LC2 was found to be more effective in accelerating the hydration process compared to fly ash.