Hot Springs Research Articles

Defect engineering on Ce2Co1Cu1Ox catalyst surface via NaOH modification: Boosting the catalytic oxidation toluene performance by reducing intermediates and increasing ring-open ability of benzoate

Catalytic oxidation is still an effective approach to eliminate volatile organic compound (VOCs). In order to explore the promotion mechanism for the improvement of toluene oxidation capacity over NaOH-modified Ce2Co1Cu1 catalyst (Ce2Co1Cu1-AT), NaOH-modified catalysts with similar physical-structure and chemical properties were prepared by modified co-precipitation, impregnation and etching methods, respectively. Characterization results revealed that NaOH modification could generate a large number of defects, oxygen vacancies as well as abundant active sites on the surface of Ce2Co1Cu1, the concentration of surface adsorbed oxygen species and the mobility of surface lattice oxygen species were both increased. Hence, the catalyst's redox capacity was enhanced, the accumulation rates of benzyl alcohol and benzaldehyde were much lower (reduced about 69 % and 83 %, respectively), and the negative effect of the accumulation of intermediate species covering the reactive site was weakened. Benefiting from these, the toluene oxidation performance of the NaOH-modified catalysts was significantly improved, with T90 (191 ℃) of Ce2Co1Cu1-AT was nearly 20 ℃ lower than that of the un-modified catalyst, which is among the best reported activity values. Additionally, it also exhibited excellent thermal stability and water resistance. This work may provide a new strategy to design and synthesize the high-efficiency VOCs catalyst.

Seasonal variability of groundwater contributions to fault-zone-hosted banff hot springs, Canada

Analysisof fault-zone-hosted thermal springs provides insights into deep fault-zone processes and crustal-scale fluid movements. However, shallow groundwater mixing obscures chemical signatures associated with deeply sourced groundwater, reducing the utility of thermal spring data for understanding deep fault-zone processes. The Upper Hot Spring (UH) in the Banff Hot Spring system exhibits substantial seasonal variability and is a valuable case for investigating shallow groundwater mixing in fault zones. UH chemistry aligns with binary mixing of cold tritium-rich groundwater from Sulphur Mountain and hot tritium-depleted water from the Sulphur Mountain Thrust (SMT) fault zone. Geochemical and isotopic data from lower elevation springs suggest the extension of binary mixing dynamics to lower elevations. Applying a Monte Carlo-based regression approach, strontium isotope mass balance models simulate one year of 87Sr/86Sr time series at UH within the margin of uncertainty. Utilizing mixing proportions derived from the model, tritium mass balance models successfully simulate the tritium time series at UH over the same period, providing cross-validation. Using relationships between mixing proportions and sulfate, hydrographs for the three highest elevation springs are separated into two components, revealing that the seasonal variability of both components decreases northward as spring elevation decreases. Utilizing common environmental tracers and bypassing direct sampling of inaccessible endmembers, the modeling approach used here may find global applicability for characterizing mixing in fault zones.

Design and Application of Low-Temperature Geothermal Thermoelectric Power Generation (Lotemg–TPG) in Sari Ater Hot Spring, Ciater, Subang, West Java, Indonesia

The use of surface geothermal manifestations in Indonesia is still very limited as a tourist attraction. Solid-state thermoelectric generator technology is an alternative to converting electrical energy directly from a heat source in the form of low-temperature geothermal manifestation. Low-temperature geothermal thermoelectric power generation (Lotemg–TPG) was designed, manufactured, and tested to take advantage of this opportunity. It was also applied to the Sari Ater Hot Spring, Ciater. The Lotemg–TPG unit comprises seven M8T modules in two frame blocks equipped with hot- and cold-water circulation channels. The M8T module is the main part of the Lotemg–TPG, which consists of eight TEG elements of type TEG1-241-1.4-1.2, flanked by a hot-side radiator and a cold-side radiator. The measurement results showed that at the temperature difference between the hot-side Th and the cold-side Tc of ∆T 17.38 °C, one module can produce 1.30 W of power, so the total power of the Lotemg–TPG unit is around 9.10 W. This result is quite good considering that the heat source is obtained for free, and the device can operate to produce stable electrical power.

Design and analysis of biodegradable and potentially biobased multiphase systems from starch and co-polyesters

To develop tailored and performing biodegradable multilayer systems with polyester as cap layers and thermoplastic starch (TPS)/polyester blends in the core, several TPS-based blends, with varying formulations and several biodegradable and potentially biobased polyesters, were first elaborated. Poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS) and poly(butylene succinate-co-adipate) (PBSA) were tested. The TPS-based blends for the core layer were compatibilized with a multifunctional epoxide styrene-acrylic reactive chain extender. As evidenced by tensile tests, the compatibilization was more effective with blends based on PBAT, probably due to its higher number of reactive chain ends. Multilayer films comprising neat PBAT cap layers and a TPS/PBAT blend, compatibilized or not, as a core layer were then elaborated by coextrusion. Thanks to the PBAT cap layers, the multilayer films had improved thermal stability and water vapor barrier properties, while TPS in the core layer added oxygen barrier properties to the global systems. In connection with the applications, the biocompatibility was also demonstrated through cell growth tests. The suitability of such multilayer films for biodegradable packaging linked to biomedical applications was thereby confirmed.

3D‐printed PLA/PMMA polymer composites: A consolidated feasible characteristic investigation for dental applications

AbstractThis research article focused on the blending of poly(lactic acid)/poly(methyl methacrylate) (PLA/PMMA) polymer materials to overcome PLA's inherent weaknesses, such as low glass transition temperature, brittleness, and lack of melt strength. Consolidated feasible characteristic investigations, such as mechanical, thermal, and aging behavior, were carried out for PLA/PMMA blended polymer materials. Initially, the miscibility of PLA/PMMA blend filaments was prepared at various blend ratios (91/9, 82/18, and 73/27) and samples were printed by fused deposition modeling (FDM). Differential scanning calorimetry (DSC) and Fourier infrared spectroscopy (FTIR) analysis have been utilized to evaluate the glass transition temperature (Tg) and intermolecular interaction, respectively, on blended polymer materials. Experimental tensile, compression, and flexural strength testing were performed on neat polymers and blended polymer composites. Compared to neat PLA materials, blended composites had 13.24% and 19.07% higher flexural and compression strengths. Besides, the interfacial interaction of neat and blended polymers has been done using dynamic mechanical analysis (DMA). Furthermore, Tg, storage modulus, and aging behavior of blended polymer materials have significantly improved over neat PLA materials. Altogether, the development of PMMA/PLA blends as sustainable biomaterials for dental applications aligns with environmental concerns and the need for biocompatible materials in dentistry.Highlights Blending of PLA and PMMA helps mitigate the inherent constraints of PLA. Blended composites exhibited greater compressive and flexural strengths. Better glass transition temperature and intermolecular interaction. Excellent thermal stability and water aging imply viable dental biomaterials.

Metagenomics insight into Puga geothermal geyser located in Himalayan Geothermal Belt (Trans-Himalayan Plateau) Ladakh, India.

Puga geothermal geyser and surrounding area, located in the Himalayan Geothermal Belt of the Trans-Himalayan Plateau in Ladakh, India, are very geographically isolated and considered pristine and free of anthropogenic activities. In this study, we have conducted the first metagenomic investigation of the microbes in and around the geyser. The whole genome sequencing analysis showed the presence of a total of 44.8%, 39.7% and 41.4% bacterial phyla in the PugW, PugS, and PugSo samples respectively, 8.6% of archaeal phyla (in all the samples), unclassified (derived from other sequences, PugW: 27.6%, PugS: 27.6%, and PugSo: 15.5%) and unclassified (derived from bacteria, PugW: 12%, PugS: 13.8%, and PugSo: 13.8%). The majority of archaeal sequences were linked to Euryarchaeota (2.84%) while the majority of the bacterial communities that predominated in most geothermal locations were linked to Pseudomonadota (67.14%) and Bacteroidota (12.52%). The abundant bacterial strains at the species level included Dechloromonas aromatica, Acinetobacter baumannii, and Arcobacter butzleri, in all the samples while the most abundant archaeal species were Methanosaeta thermophile, Methanoregula boonei, and Methanosarcina berkeri. Further, this geothermal geyser metagenome has a large number of unique sequences linked to unidentified and unclassified lineages, suggesting a potential source for novel species of microbes and their products. The present study which only examined one of the many geothermal geysers and springs in the Puga geothermal area, should be regarded as a preliminary investigation of the microbiota that live in the geothermal springs on these remote areas. These findings suggest that further investigations should be undertaken to characterize the ecosystems of the Puga geothermal area, which serve as a repository for unidentified microbial lineages.

Integrated Analysis by Geophysical and Spatial Data to Identify the Formation of Kepuhlegundi Hot Spring on Bawean Island

Bawean Island is a~result of volcanic activity in the back-arc volcanism zone located on the north side of Java Island. Bawean Island was formed due to the geological structure being controlled by the Paleogene-Neogene tectonic line in the Meratus Pattern. The mantle tearing resulted in the formation of the Bawean Arc. The Kepuhlegundi Hot Spring is a~component of the volcanism product on Bawean Island. To analyze the formation of hot springs in more detail, we conducted magnetic method measurements and integrated the data with gravity satellite and Fault Fracture Density (FFD) methods. The three methods were used to determine the continuity of the mapped geological structures surrounding the hot springs. The FFD method can be used to map the weak zone of the hot spring, which is caused by the lineament surrounding it. The magnetic and gravity methods reveal anomalous contrasts that extend towards the hot springs in the direction of the structure. The magnetic and gravity methods reveal anomalous contrasts that extend towards the hot springs in the direction of the structure. Based on regional anomaly analysis, spectrum analysis indicates that the structure is located at a~shallow depth of 15 to 80 meters. The drawing in each method shows a~dominant orientation in the Northeast-Southwest direction, which corresponds to the orientation of the Meratus Structure Pattern. Kepuhlegundi Hot Spring is formed due to the control of geological structures, allowing hot fluids to flow through fractures as an aquifer.

Geochemical characteristics, Li source and genesis mechanism of thermal mineral water in Sichuan Basin, SW China

Thermal mineral water (temperature >25 °C) is a valuable resource, especially when it contains a certain amount of Li. In this study, an attempt was made to elucidate the factors affecting spatial distribution of lithium (Li) resources and interpret the formation mechanisms of thermal mineral waters in the Sichuan Basin. The spatial distribution, reservoir temperatures, and hydrochemical characteristics of thermal mineral waters were systematically analyzed in the Sichuan Basin, preliminarily revealing Li sources through hydrochemical methods. Results are showed as follows: (1) The Li-bearing (Li ≥ 1 mg/L) thermal mineral waters are mainly distributed in the southwestern part of the Sichuan Basin. There are three sites of thermal mineral waters with Li content greater than 25 mg/L with the hydrochemical type of Cl–Na type: Pengji Well (37.7 mg/L), Foguanghu Well (99.5 mg/L) and Zhougongshan New Well (118.0 mg/L). Among them, the Foguanghu Geothermal Well and the Zhougongshan New Well have high Li content and low Mg/Li (10.7 and 2.5), indicating great potential for utilization. (2) The Li-bearing thermal mineral waters are mainly formed in the fissure and pore reservoirs of the Middle–Lower Triassic. They are mainly affected by the dissolution of halite minerals and the deeply buried ancient seawater of the Triassic. The Li-bearing thermal mineral waters possess high contents of total dissolve solids (TDS) (4.3–230.0 g/L), Cl (0.7–142.9 g/L), Na (0.5–76.7 g/L), K (0.1–52.0 g/L), B (4.1–739.6 mg/L), and Li (1.5–118.0 mg/L). Moreover, the temperature of the geothermal reservoir ranges from 40 to 150 °C. The geothermal reservoir temperatures calculated by K–Mg and Mg–Li geothermometers are positively correlated with the Li content. (3) The Li source of the thermal mineral waters of the Sichuan Basin are dominated by multiple factors: first, Li concentration by evaporation, concentration and deep-seated metamorphism of ancient Triassic seawater; second, water–rock interaction between deep thermal mineral waters and mung bean rock or Emeishan basalt; and third, active tectonic activity and deep faulting induced upward flow of Li in deep fluids. This research enhances understanding of the formation of thermal mineral waters in the Sichuan Basin, offering scientific basis for the exploitation of Li resource.

Biomimetic Fe-bearing nanoparticles in hot spring: morphology, origin and potential bioavailable Fe

Iron is a critical redox-active element in geothermal water, and the presence of nanoparticulate Fe is essential in comprehending the intricate cycling of iron and related elements within the natural geothermal ecosystems. In this study, we investigated the mineral properties of Fe-bearing nanoparticles in a hot spring located in Shanxi Province. High-resolution transmission electron microscopy (HRTEM) is utilized for the examination of the morphology, chemical composition, and crystalline structure of Fe-bearing nanoparticles. The findings show that Fe-bearing nanoparticles can exist as single particles measuring 50–200 nm in size, as well as aggregate to form nanoparticle aggregations. The morphology of Fe-bearing nanoparticles mainly includes triangle, axiolitic, and irregular shapes. The selected area electron diffraction patterns reveal the crystal form, amorphous form, and the transition from amorphous to crystalline forms of these nanoparticles. Energy-dispersive X-ray spectroscopy (EDS) analysis indicates that these nanoparticles primarily consist of O and Fe in composition, along with various trace elements including N, Al, Si, Ca, Zn, Cr, Ni, and Mo. These results reveal that goethite and hematite can occur in hot spring. Various in size and modality, tend to cluster into each other, and multiple crystalline states indicate that these iron-bearing nanoparticles are formed through natural processes. In addition, the iron-bearing nanoparticles with biomimetic morphologies (cell-like or microorganism-like shapes) may be produced through microbial activity. The biomimetic properties also imply that these nanoparticles may be readily available for biological processes. Significantly, our findings further validate that the shape of iron oxide nanoparticles can serve as an indicator of pH and temperature of the hot spring.

Synthesis and Evaluation of Plugging Gel Resistant to 140 °C for Lost Circulation Control: Effective Reduction in Leakage Rate in Drilling Process.

Gel plugging agents have become one of the preferred methods for plugging in complex and severe loss conditions during drilling due to their good adaptability to loss channels. To address the common issue of poor temperature resistance in gel-based plugging agents, high-temperature-resistant gel plugging materials were synthesized through the molecular design of polymers, modifying existing agents. Based on the temperature and salt resistance of the aqueous solution of an acrylamide (AM)/N-vinylpyrrolidone (NVP) binary copolymer, temperature-resistant monomer sodium styrene sulfonate (SSS) was introduced and reacted in a polyvinyl alcohol (PVA) aqueous solution. Using ammonium persulfate (APS) as an initiator and crosslinking with N,N-methylenebisacrylamide (MBA), a gel plugging material resistant to 140 °C was synthesized. The structure, thermal stability, water absorption and expansion, and plugging performance of the gel were studied through hot rolling aging, thermogravimetric analysis, infrared spectroscopy, electron microscopy scanning, sand bed experiments, and drag reduction experiments. The results show that the gel material has good thermal stability and water absorption and expansion at 140 °C, and its temperature-resistant plugging performance is excellent, significantly slowing down the loss rate of drilling fluid. This provides a basis for the further development of gel materials.

Isolation of Thermophilic Bacteria in Hot Spring of Asin, Tuel, Tublay, Benguet

Isolation of Thermophilic Bacteria in Hot Spring of Asin, Tuel, Tublay, Benguet

Detection of Thermoacidophiles from Yellowstone Hot Spring

Aerobic methanotrophic bacteria maintain an unrivalled capability of utilizing methane as their sole carbon and energy source and have been retrieved from various environments. Phylogenetically, true aerobic thermoacidophilic methane oxidizers capable of growing below pH 3 have hitherto been associated only with the phylum Verrucomicrobia. In this report, the initial detection of a moderately thermoacidophilic Methylococcus-like Type Ib methanotroph of the class Gammaproteobacteria from an acidic thermal spring (50oC and pH 2.8) in the Yellowstone National Park, USA is presented. The isolate, termed YT-MC, was identified in a methane enrichment (55°C), which may represent a novel strain in the family Methylococcaceae Type Ib. The existence of this bacterium in the enrichments was demonstrated by the detection of pmoA gene, Southern blotting technique, phase-contrast, and electron microscopy. The coccus-typed cells showed tubular membranes instead of intracytoplasmic membrane systems (ICM). The soluble methane monooxygenase (sMMO) was not detected by PCR, indicating that the biotransformation of methane to methanol is oxidized by the particulate methane monooxygenase (pMMO). Moreover, YT-MC performs in a formerly undiscovered active biological methane sink in geothermal acidic environments, magnifying our knowledge of its ecological role in methane cycling, diversity, and coexistence of aerobic methanotrophy. Furthermore, the present study also reports the isolation and identification of an alphaproteobacterial heterotroph (strain YT-AC) and a verrucomicrobial methanotroph (strain YT-VM) from the same environment. Bangladesh J Microbiol, Volume 40, Number 2, December 2023, pp 86-94

Theoretical and experimental characterization of trivalent lanthanide (La-Eu) aquacomplexes with losartan

In this work, losartan compounds with trivalent ions La(III), Ce(III), Pr(III), Nd(III), Sm(III), and Eu(III) were synthesized in the solid-state. The thermal and spectroscopic study of the compounds was performed using TG-DSC, FTIR, DRX, and evolved gas analysis (EGA) by TG-DSC/FTIR. The theoretical and experimental spectroscopic data suggested the possible modes of coordination of the ligand with the metal ions by the tetrazole ring. Thermogravimetric analyses provide information on the thermal stability, water coordination, and stoichiometry of the compounds. The minimum formulae of the compounds is [Ln(Los)3(H2O)x], where Ln=La and Ce/x = 7; and Pr, Nd, Sm, Eu/x = 6. TG-DSC coupled to FTIR in an air atmosphere suggested the release of H2O, CO2, CO, MeOH, NH3, and -NCO during the thermal decomposition of losartan from lanthanides. Amorphous compounds were obtained, and their poor solubility suggests their potential use as prodrugs in the solid-state.

Regional Hydro-Chemistry of Hydrothermal Springs in Northeastern Algeria, Case of Guelma, Souk Ahras, Tebessa and Khenchela Regions

Hydrothermal units are characterized by the emergence of several large-flow thermo-mineral springs (griffons), each with varying temperature and physico-chemical characteristics depending on the point of emergence. It seems, however, that there is variability between the different systems, although it is not easy to characterize it because the variability within each system is high. The regional dimension of the chemical composition of thermal waters is, therefore, an aspect that has received very little attention in the literature due to the lack of access to the deep reservoir. In this study, we investigated the spatial variability, on a regional scale, in the characteristics of thermal waters in northeastern Algeria, and more specifically the hydrothermal systems of Guelma, Souk Ahras, Khenchela and Tébessa. Thirty-two hot water samples were taken between December 2018 and October 2019, including five samples of low-temperature mineral spring water. Standard physico-chemical parameters, major anions and cations and lithium were analyzed. The data were log-transformed data and processed via principal component analysis, discriminant analysis and unsupervised classification. The results show that thermal waters are the result of a mixture of hot waters, whose chemical profile has a certain local character, and contaminated by cold surface waters. These surface waters may also have several chemical profiles depending on the location. In addition to the internal variability in each resource, there are differences in water quality between these different hydrothermal systems. The Guelma region differs the most from the other thermal regions studied, with a specific calcic sulfate chemical profile. This question is essential for the rational development of these regional resources in any field whatsoever.

Strategies and Models for Development of Hot Water Tourism Objects in Tombasian Village Under Kawangkoan Barat District, Minahasa Regency

Tourism development is sought to be developed in the context of economic improvement, sustainable development and technological development. Geographically, each region has different characteristics with their own uniqueness and advantages. Natural resources that are owned with all its contents, land in all its forms and the sea with all its contents. This potential can be utilized optimally through tourism. Natural resources owned with all their contents and existing potential will be utilized for development purposes. That potential can be an asset through the tourism sector. One of the attractions that attracts the attention of both domestic and foreign tourists is the hot springs in Tombasian Bawah Village. Tombasian Bawah Village is one of the villages in Kawangkoan Barat District, Minahasa Regency, where in general the people work as farmers and craftsmen on stilt houses. Furthermore, the data that has been collected is analyzed by descriptive analysis using the SWOT analysis method and breaking it down internally and externally. The stages of the research were field observations by collecting data at the physical location, conducting interviews with the government of tourist attraction locations with village programs and district governments related to the development of tourism objects, specifically hot water in the village of Tombasian Bawah and visitors to obtain data. The results of the study show that the Hot Spring Tourism Object Development Strategy is adequate which can be applied by developing tourism on holidays and other holidays. And the model is community based. The development of this hot spring tourism object can be done by diversifying tourism objects and modifying the system so that tourists can travel easily and pleasantly. The results of this research are the proceding/Sentrinov output targets and reports.

Geological modeling of a tectonically controlled hydrothermal system in the southwestern part of the Pannonian basin (Croatia)

Geothermal energy is an important resource in the green economy transition. For the preservation of a geothermal resource it is crucial to assess its renewability and the sustainability of the exploitation. These aspects are influenced by the interaction among the physical, chemical, geological, and hydrogeological processes. The reconstruction of the geological assemblage allows the detailing of the geometries of the reservoir and fracture systems that influence the fluid flow and the water/rock interaction. The control of regional/local scale fault and fold systems on the development of the Daruvar hydrothermal system (DHS), located in Croatian part of the Pannonian basin, is detailed in this work. Field investigations were conducted to collect structural data on strata orientation and fault/fracture systems. The dataset was integrated with geological and geophysical data to develop composite geological profiles and a 3D geological model. Results display a pattern of generally N-S and E-W striking folds and cogenetic fracture systems with orientations parallel to the fold axes. The geological reconstruction was integrated with geophysical, hydrogeological, and geochemical data to propose a conceptual model of the DHS. The DHS is a topographically driven system hosted in a Mesozoic carbonate reservoir where E-W striking fracture systems are regional flow paths that enable infiltration of meteoric water to 1 km depth and its reheating in its reservoir area. In Daruvar, an anticline and fault/fracture systems accommodate the uplift of reservoir to shallow depths, promoting the bedrock fracturing and increase of the permeability field. These conditions favor the localized upwelling of thermal water resulting in four thermal springs (38°C and 50°C) in Daruvar city area. This work highlights the importance of employing a multidisciplinary approach to detail the complex interaction among the processes driving the geothermal resource.

Opaline silica precipitations in the Permian Fengcheng Formation indicate hot spring environments in north Mahu Sag, NW China

The Permian Fengcheng Formation represents a series of deposits formed in an alkaline saline lake, characterized by high proportions of cherts, located in the Northwestern Junggar Basin in China. While discussions on silica-rich hot springs as sources of silica for brine and subsequent chert deposition have been extensively conducted for Quaternary and Mesozoic-Cenozoic alkaline saline lakes worldwide, investigations into Paleozoic alkaline saline lakes are scarce due to challenges associated with identifying evidences of hot spring environments. In this study, we present detailed SEM-EDS analyses and examine silica isotope compositions as well as oxygen isotope compositions to discuss hydrothermal-associated silica precipitation processes. Our findings suggest that migrating silica-rich hot springs along deep-rooted faults released silica into the brine, leading to chert deposition during cooling periods and induction of thermophilic microorganism degradation. Microorganism-associated siliceous precipitates primarily consist of opal-A spheres adhered by extracellular polymeric substances (EPS), while numerous microorganism spheres have undergone silicification. Opal-A spheres within these structures were partially transformed into well-crystallized quartz through multiple stages of dissolution-precipitation processes during prolonged burial history. Furthermore, our results indicate that deep-rooted fault-related hot springs can occur both in marginal and subaqueous areas within alkaline saline lakes, with chert formations observed in shallow-marginal saline lake settings as well as deeper regions. The findings of this study provide valuable insights into the paleoenvironmental conditions, which can be further explored in investigating the accumulation of organic matter in chert-rich successions formed within an alkaline saline lake.

Analysis of Thermal Characteristics of Potato and Hop Pollen for Their Cryopreservation and Cross-Breeding.

This study investigated the thermal properties of potato and hop pollen for cryopreservation and subsequent cross-breeding. Phase transitions and frozen water content in selected pollen samples were measured using a differential scanning calorimeter (DSC). Unlike hop pollen, potato pollen showed high variability in thermal properties and water content. Three specific types of pollen samples based on their thermal characteristics and water content were distinguished by DSC in potato: (1) 'glassy', with a water content lower than 0.21 g water per g dry matter; (2) 'transient', with a water content between 0.27 and 0.34 g of water per g of dry matter; (3) 'frozen', with a water content higher than 0.34 g of water per g of dry matter. Only the 'glassy' pollen samples with a low water content showed suitable properties for its long-term storage using cryopreservation in potato and hops. Cryopreservation of pollen did not significantly reduce its viability, and cryopreserved pollen was successfully used to produce both potato and hop hybrids. The results indicate that cryopreservation is a feasible technique for the preservation and utilization of pollen of these crops in the breeding process.

GIS-based AHP model for selecting the best direct use scenarios for medium to low enthalpy geothermal resources with hot springs in central and Western Kenya

Medium to low enthalpy geothermal resources (MLEGRs) in various Eastern African countries, Djibouti, Ethiopia, Kenya, Uganda, Tanzania, Rwanda, and Malawi, have received little attention from policymakers in the energy sector. Policymakers from these countries prioritize developing high-enthalpy resources for electric power production. Hence, many MLEGRs remain unused since they are assumed to pose higher risks of drilling unproductive deep wells. Besides, funding institutions prioritize high-enthalpy geothermal resources. Some MLEGRs have warm-to-hot springs with considerable flow rates and chemical constituents with varying concentrations. This study introduces a novel approach, using hydrogeochemical analysis of hot spring waters and a GIS-based AHP model, to select the best direct use scenarios for the warm/hot springs emanating from MLEGRs in central and western Kenya. The model is validated by contemporary commercial usage of the hot springs and similar studies in the study area. The stable isotope analysis revealed that the hydrothermal systems in Kenya are majorly recharged by meteoric water. In contrast, Kenya Rift Valley endorheic lakes, such as Lake Naivasha, Lake Nakuru, Lake Magadi, Lake Baringo, Lake Bogoria, and Lake Turkana, partly recharge some. Hence, they pose low risks of drying up during development and exploitation for thermal energy. The over 150 hot springs in Kenya produce warm to hot water with a thermal capacity of over 275 MWt. Hence, by harnessing the hot spring resources, Kenya can raise its direct use capacity from the current 18.5 MWt to about 100–200 MWt without drilling shallow or deep wells. The hot springs best suited for domestic use and aquacultural pond heating were selected as Narosura, Majimoto, Olchorro, Kipsegon, Kijabe, and Eburru. Those best suited for spas, bathing/ swimming pools, and volcanic geotourism were Lake Bogoria, Arus, Homa Hills, and Kariandusi. Overall, Lake Bogoria, Homa Hills, and Narosura hot springs were rated the best for direct use of hot springs.

Computational Evaluation of Pulsating Heat Pipe for Fluid Flow Behavior and its Thermal Performance

Computational fluid analysis of a single circuit heat pipe was undertaken to ascertain the thermal efficiency of water at various fill ratios, specifically 40%, 50%, and 60% under varying heating conditions. The analysis employed the ANSYS Fluent computational fluid dynamics software, utilizing a k-epsilon to the heat pipe as the solver. The analysis was carried out on a copper tube with an internal diameter measuring 3/16 inches. During the analysis, the thermal inflow at the adiabatic region was adjusted to zero, while the condenser region’s temperature remained constant at 25°C. Meanwhile, the heat input at the evaporator region was systematically adjusted to 105°C, 110°C, 115°C, and 120°C. Key Performance characteristics of heat pipe i.e. thermal resistance, and water volume fraction were evaluated during analysis. The temperature variations noted in both regions affirmed that the pulsating pipe’s performance was influenced by the phase transition between liquid and vapor. Furthermore, the concentration of volume within the evaporator section was monitored, confirming the presence of a dual-phase phenomenon within the heat pipe. Through the analysis, it was noted that the thermal resistance of the water is minimized at a 50% fill ratio for each level of heat input. Notably, the promising results were obtained at an input temperature of 120°C with a value of 1.025°C /W which was 7.3% and 9.8% lower than thermal resistance at 40% and 60% fill ratios, respectively. The reduced thermal resistance in this scenario is attributed to the flow dynamics within the capillary, propelled by rapid phase change mechanisms. This shows the importance of Pulsating Heat Pipes (PHPs) in thermal control, as well as the intricacies of their operating mechanisms. Experimental and theoretical investigations have investigated numerous elements influencing PHP performance, with numerical modeling providing insight into thermal resistance and water volume fraction dynamics under varying heating temperatures and fill ratios.