Hornblende Biotite Gneiss Research Articles

Fold pattern analysis around Kanjamalai Salem district Tamilnadu

Kanjamalai one of the fascinating location in Southern Granulite Terrain (SGT) for studying Archaean geology and structures as the entire hill is made up of variety of rock types like two pyroxene granulite, amphibolites, quartzo - feldsapthic gneisses, banded iron formation, and intrusive rocks like dunite, peridotite and pegmatite and beautifully carved structures. The entire hill resembles a canoe shape with doubly plunging fold structure with E-W elongation. The entire hillock seems to sit pretty on mylonitised hornblende biotite gneisses which also have a common N70-95 degree trend and sub vertical dip with NE plunge which is in contradiction to centrally plunging lineations of the hill. The SW part of Kanjamalai near Chinasrirangapadi was displaying beautiful fold structures, with interference pattern out of which six domains were selected for detailed study and analysis. The multiple generation folded structure will have a clue in reconstructing the deformation history of this Kanjamalai. The observed f1, f2 and f3 folds show significant Type III interference pattern as that of Ramsay and 01 and 03 type folds of Bernhard Grasemann. Wavelength –amplitude analysis was made to generalize and regroup the observed folds in to high amplitude, high wavelength or open folds, low wavelength and Mesoscopic folds. And visual harmonic analysis was made to analyse the symmetry of the folds and analyze the geometry, symmetry and harmony and genesis of the fold in terms of relative timing of the events.

Rare Earth Elements Assessment in the Granitoids of Part of Southwestern Nigeria

The Rare Earth Elements (REE) composition of granitoids in and around Ila-Orangun area Southwestern Nigeria was assessed in order to ascertain their potential for possible exploitation. Detailed lithological mapping of the area was undertaken followed by whole rock geochemical analysis of representative samples of the granitoids using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) technique. Petrographic study of the samples was carried out as well as the interpretation of the geochemical data using diverse geochemical discrimination plots.
 The rock units mapped were biotite granite gneiss, granite gneiss and hornblende biotite granite. Biotite hornblende gneiss, quartzite, talc-chlorite-tremolite-schist, mica schist and pegmatites were the surrounding country rocks.
 The REE concentrations (in ppm) revealed higher concentrations of the light REEs compared to the heavy REEs. The fractionation ratio, (La/Yb)N ranged from 4.35-15.04 (granite gneiss) and 13.78-18.48 (hornblende biotite granite) indicating enrichment in LREEs over the HREEs. The spider plot for the REEs also showed that the granitoids are LREE-enriched and HREE-depleted suggesting fractional crystallisation and a distinct negative Eu anomaly indicating plagioclase fractionation. Enrichment plot also revealed that the REEs in the granitoids are significantly enriched. Comparison with other areas showed that the granitoids of the study area especially the hornblende biotite granite has higher concentrations of REEs and may be a possible pointer of REE mineralisation.

Field observations, magnetic fabrics and microstructures evidences of syn-kinematic emplacement of the Numba granitic pluton (western Cameroon domain)

The N–S elongated Pan-African Numba granitic pluton (NGP), hosted in banded biotite hornblende gneiss and amphibolite country-rocks, belongs to the Western Domain of the Pan-African Belt of Central African in Cameroon. It consists of biotite hornblende granite and fine-grained biotite granite crosscut by gabbroic dykes. The western border of the granite is mylonitized. Structures and microstructures recorded in granite reveal magmatic, submagmatic and high- to moderate- temperature solid-state deformations. Magnetic characterisation of the NGP reveals its ferromagnetic behaviour due to the presence of multi-domain automorphic or xenomorphic pure magnetite grains. Field and AMS measurements testify that the study area recorded three deformation events: (1) a D1 event of ENE-WSW to E-W flattening deformation; (2) a D2 event of sinistral top-towards south sense of shear movement characterised by low to moderate dips (i) NE-SW strike foliation in country-rocks; (ii) NNE-SSW to NE-SW strike of magmatic foliation marked by the preferred orientation of K-feldspar megacrysts in granite and (iii) low plunges NE-SW mineral stretching lineation in biotite hornblende gneiss parallel to the axes of SW vergence of "S" shape F2 folds and (3) a D3 event of dextral top-towards east sense of shear movement that developed narrow NNE-SSW strike mylonite corridor. The NGP emplaced in a fracture within an amphibo-gneissic country-rock and has recorded opposite sinistral top-towards south (D2 Pan-African event) to dextral top-towards east senses of shear movements (D3 Pan-African event). It can be inferred that the emplacement and the deformation of the NGP was initiated during regional D2 deformation (dated at 613-585 Ma) when its magnetic fabric was acquired, and it was completely achieved during regional D3 deformation (dated ca. 585-540 Ma). Tj vs. Pj diagram associated with Flinn diagram suggests an emplacement in dominant flattening strain regime with a considerable shear component. The different data recorded in the NGP imply that its emplacement mechanism points to a ballooning. Indeed, the eastern domain of NGP with elliptical shape represents the inner part of the architecture while its western domain represents the outer part. The moderate to high dips observed in the inner part of the elliptical domain suggest the probable location of a feeder zone, and the lineation pointing away from the centre of the intrusion in the outer part may be developed related to the magmatic flow. This concentricity is easily associated with internal microstructures that show moderate-temperature solid-state to submagmatic and magmatic microstructures from the outside of the pluton towards the centre. The magma was then emplaced by ballooning in a gneissic country-rock that was subjected to sinistral shearing. Afterwards, the deformation characterised by a dextral shearing contributed to a generation of a NNE-SSW mylonitic band at the western border of the pluton.

Lithostratigraphy of the Mesoproterozoic Yas-Schuitdrift Batholith, South Africa and Namibia

Abstract The granitic and leucogranitic Yas and Schuitdrift Gneisses occur together as a large ovoid pre-tectonic batholith that crosses the Orange River border between South Africa and Namibia. They occur in the central parts of the Kakamas Domain in the Namaqua Sector of the Namaqua-Natal Metamorphic Province where they intrude, and are deformed together with, slightly older (~1.21 Ga) orthogneisses and granulite-facies metapelitic gneisses. The Yas Gneiss occurs mainly on the outer perimeter and northern parts of the batholith and comprises equigranular leucogranite gneiss and biotite granite augen orthogneiss, whereas the Schuitdrift biotite-hornblende augen gneiss is located at the centre and southern parts of the batholith. The batholith is strongly deformed with penetrative Namaqua-aged gneissic fabrics defined by grain-flattening of quartz and feldspar in the equigranular leucogneisses and aligned K-feldspar megacrysts in the augen gneisses. The gneissic fabric is refolded during a large-scale folding event that results in the dome-shape of the batholith and controls the present outcrop pattern of its various components. Flexure along the margins of the batholith refoliated the gneisses into a zone of mylonitic rocks. The Yas and Schuitdrift Gneisses have similar geochemistry and classify as alkali granites and alkali leucogranites. They are felsic (mean SiO2: 74.5 wt%) and potassic (mean K2O: 5.8 wt%) but have low MgO, CaO and Na2O, reflecting their low mafic mineral and plagioclase contents. The Schuitdrift Gneiss yielded U-Pb zircon ages of 1 191 ± 7 and 1 187 ± 6 Ma.

Structural characterization of the Pan-African Ndieki area in the Foumban-Bankim Shear Zone (West Cameroon): constraints from field observations and microstructures

The Ndieki area displays elongated NE-SW hill which crop out along the Foumban-Bankim Shear Zone. In petrographic point of view, it is made up of amphibolites, biotite-hornblende gneisses, and two-mica granites, all of which are wrapped by mylonites. Structural data indicate (1) NE-SW (N30°E) to ENE-WSW (N70°E) trending foliation, dipping moderately (50°–60°) towards NW; (2) stretching lineation striking NNE-SSW (N12E-N25E) and moderately (25°–35°) plunging towards SSW in mylonite and biotite-hornblende gneisses. It strikes NE-SW (N40E) and plunges strongly (66°–81°) towards SW in the two-mica granites; and (3) asymmetric folds (NE-SW) and σ-type displaying dextral kinematics evolution in mylonites and biotite-hornblende gneisses, and N-S sinistral shear planes in mylonites and biotite-hornblende gneisses respectively correlated to the dextral transpressive and sinistral transcurrent deformation. All these rocks show that microstructures were acquired from the sub-magmatic to the solid-state deformation. The structural features show that the mylonitization was initiated in the early NE-SW dextral deformation event which has favored the evolution of fractures in pull-apart structures that induce the upwelling of magma and the emplacement of the Ndieki pluton, followed by the N-S trend sinistral shearing. Structural, kinematic features of the Ndieki pluton characterized deep crustal deformation, probably at the ductile-brittle boundary structural level during a major dextral shear deformation.

Heavy metals in agricultural soils developed on diverse parent materials in Cross River State, Nigeria

ABSTRACT This study investigated the current state and pollution loads of heavy metals in soils developed on diverse parent materials in southeastern Nigeria. Cu, Mn, Zn, Fe and Al were analyzed to estimate pollution loads and ecological risk of the area. The result showed soils developed on granite gneiss to have a higher concentration (measured in mg kg−1) of Cu (1.79), Mn (78.39) and Zn (28.53), while soils developed on Biotite hornblende gneiss and quartz-mica-schist had a higher concentration of Fe (≥18) compared with other parent materials. The contamination factor for Fe, Zn, Mn and Cu was low, whereas Al was moderately to considerably contaminated except for soils in S2 (0.362), S3 (0.662), S6 (0.142), S9 (0.661), S11 (0.803) and S15 (0.499). The result of the pollution load index indicated an unpolluted condition (PLI < 1). Excluding Al, the soils were practically uncontaminated with Zn, Cu, Fe and Mn, based on the Geo-accumulation index and Quartz-mica-schist was enriched by Zn in S6 (1.325) and showed low ecological risk (Er < 40) and (IR < 150). Hence, the soils in the studied communities are still in a safe state to be used for crop cultivation without any fear of metal contamination.

Rare earth elements geochemistry of groundwater from Shanmuganadhi, Tamilnadu, India: Chemical weathering implications using geochemical mass-balance calculations

Groundwater samples were collected from Shanmughanadhi in Dindigul district of Tamilnadu, India, to determine the concentration and fractionation of REEs during chemical weathering. Groundwater samples collected from aquifers hosted in weathered and fractured crystalline formations were analyzed by ICP-MS for Rare earth elements (REEs) after filtering by 0.45 μm membrane filters. ΣREEs in Charnockite accounts 8.49 × 10−4mgL−1 and 1.08 × 10−3mgL−1 in hornblende biotite gneiss signifying higher REEs in Gneiss than Charnockite, due to higher flushing rates in gneiss and relatively shorter water residence time in Charnockite aquifer. Higher LREEs were observed upstream in the study area, followed by enrichment of MREEs and HREEs in midstream and discharge areas, respectively. Irrespective of lithology, the groundwater samples mostly exhibited a positive europium anomaly, which might be due to higher dissolution and mobilization of europium from plagioclase group minerals through rock-water interaction. The plagioclase feldspar, orthopyroxene, and alkali feldspars mineral weathering rates were 124, 17.5, and 20.0 mol/hectare/year. The rare earth minerals enriched in the host rocks provided the referenced material for the REE enrichment in the groundwater. Variations in pH and redox conditions in groundwater environments have influenced the enrichment of REE aided by continuous aquifer residence time, chemical weathering, and groundwater flow path.

Field, petrographic and geochemical characteristics of Sullya alkaline complex in the Cauvery Shear Zone (CSZ), southern India: Implications for petrogenesis

Significant, but volumetrically smaller, unmetamorphosed and largely undeformed alkaline magmatic suites have been reported from the Southern Granulite Terrain in southern India. These Neoproterozoic alkaline magmatic rocks occur as lenses, dykes and plugs that are mostly within, or proximal to, major shear zones or transcrustal faults. In this contribution, field, petrographic and whole-rock geochemical data of Sullya syenites and associated mafic granulites from the Mercara Shear Zone (MSZ), which separates low-grade (greenschist to upper amphibolite facies) Dharwar Craton and high-grade (granulite facies) Southern Granulite Terrain is presented. The isolated body of the Sullya syenite, similar to other alkaline plutons of the Southern Granulite Terrain, shows an intrusive relationship with the host hornblende-biotite gneisses and mafic granulites. The Sullya syenites lack macroscopic foliations and unlike, other plutons, they are not associated with carbonatites and ultrapotassic granites. Potash feldspar and plagioclase dominates the felsic phases in the Sullya syenite and there is negligible quartz. The studied syenites show evidence of melt supported deformation, but show no evidence of recrystallization. Geochemically, they most resemble the Angadimogar syenites (situated 3 km west of the Sullya syenites) with similar major oxide and trace element concentrations. The petrogenetic studies of the Sullya syenite have indicated that they were generated by mixing of two different sources derived from the partial melting of metasomatized continental mantle lithosphere and lower crustal mafic granulites. This melt source could have been emplaced in a rift-related tectonic setting. The emplacement is considered to be controlled by shears.

Chemical weathering and atmospheric carbon dioxide (CO2) consumption in Shanmuganadhi, South India: evidences from groundwater geochemistry.

Chemical weathering in a groundwater basin is a key to understanding global climate change for a long-term scale due to its association with carbon sequestration. The present study aims to characterize and to quantify silicate weathering rate (SWR), carbon dioxide consumption rate and carbonate weathering rate (CWR) in hard rock terrain aided by major ion chemistry. The proposed study area Shanmuganadhi is marked with superior rainfall, oscillating temperature and runoff with litho-units encompassing charnockite and hornblende-biotite gneiss. Groundwater samples (n = 60) were collected from diverse locations and analysed for major chemical constituents. Groundwater geochemistry seems to be influenced by geochemical reactions combining dissolution and precipitation of solids, cation exchange and adsorption along with minor contribution from anthropogenic activities. The SWR calculated for charnockite and hornblende-biotite gneiss was 3.07tonskm-2year-1 and 5.12tonskm-2year-1, respectively. The calculated CWR of charnockite and hornblende-biotite gneiss was 0.079tonskm-2year-1 and 0.74tonskm-2year-1, respectively. The calculated CO2 consumption rates via silicate weathering were 1.4 × 103molkm-2year-1 for charnockite and 5.8 × 103molkm-2year-1 for hornblende-biotite gneiss. Lithology, climate and relief were the key factors isolated to control weathering and CO2 consumption rates.

Precambrian basement rocks of Wadi-Khuda-Shut area, South Eastern Desert of Egypt: Geology and remote sensing analysis

Wadi Khuda-Wadi Shut area in the South Eastern Desert (SED) of Egypt is mainly made up of gneisses, ophiolitic serpentinites and intermediate schistose metavolcanics. These metamorphic rock units are intruded by syn-late-tectonic diorite, granodiorite, ultramafic-mafic, and monzogranite intrusions. The gneisses comprise biotite hornblende gneiss, hornblende gneiss and migmatites. They are of granodiorite and diorite composition. The ophiolitic serpentinite with talc carbonate rocks were thrusted over the metavolcanics with NW-SE thrust contact. The late tectonic ultramafic-mafic rock units are represented in the study area by Dahanib pluton, which is consisted of layered peridotite-dunite associated with olivine gabrro, normal gabbro and gabbro-norite as well as rare hornblende gabbro. These varieties are related to the layered intrusions rather than Alaskan-types, and formed by magmatic differentiation. The granodiorite and monzogranite represent the youngest basement rock units in the study area. The principal components and band ratios of ASTER and Landsat-8 data were successfully used for the first time in lithological discrimination and geological mapping of the study area. This study concluded that, the interpreted data of ASTER and Landsat-8 combined with field study and petrographic investigation clearly discriminated the exposed rock units. Accordingly, a detailed geological map emphasizing the lithological units in Khuda-Shut area has been presented.

Health risks associated with fluoride intake from rural drinking water supply and inverse mass balance modeling to decipher hydrogeochemical processes in Vattamalaikarai River basin, South India

Preliminary investigation reveals that fluorosis is reported due to the continuous intake of fluoride-rich groundwater in Vattamalikarai River basin, Tamil Nadu, India. A detailed study was attempted for evaluating the health risks associated with the intake of fluoride-rich groundwater supplied to the rural community. Groundwater samples were collected from 60 and 58 dug and tube wells during winter and southwest (SW) monsoon seasonsrespectively. The samples were analyzed for the determination of fluoride and other chemical parameters to examine the fitness for drinking water. Spatio-temporal variation maps reveal that fluoride concentration is high during SW monsoon season when compared with the winter season in this region. The fluoride bearing minerals present in hornblende-biotite gneiss and charnockite rock formations leached into the groundwater during rock-water interaction. To understand the subsurface hydrogeochemical reactions, inverse mass balance model was developed using NETPATH code. The model output indicates that calcite dilution, silicate (hornblende and biotite) weathering, ion exchange (Ca/Na and Mg/Na) and illite precipitation are the dominant processes controlling the groundwater chemistry along the flow paths. Non-carcinogenic risks to children and adults (women and men) were evaluated by working out intake exposure of groundwater. Hazard quotient (HQ) based on fluoride intake was calculated for children and adults. It varied from 0.08 to 2.21 with an average of 1.07 for adults. For children, it varied from 0.01 to 2.99 with the mean of 1.44. About 78%, 69% and 61% of the samples fall under the risk category for children, women and men during winter season. However, more number of samples possessed health risks (83% of samples for children, 73% of samples for women and 64% of samples for men) during SW monsoon season.

Lithostratigraphy of the Copperton Formation, Areachap Group

Abstract The type area of the Copperton Formation is on the farms Vogelstruisbult 104, Somuspan 105 and Dooniespan 108 in Prieska District. Outcrop is poor and the type material is preserved in exploration borehole cores from the Prieska Copper Mines and the Annex Cu-Zn deposits. It is highly deformed and variably metamorphosed. Thus it is a lithodemic unit, but interpreted as a supracrustal sequence and described as a formation including lithologically distinct members. The Copperton Formation comprises a wide range of rock types including metabasic and intermediate gneisses with minor amounts of metapelitic and calc-silicate rocks. Metamorphic parageneses generally reflect amphibolite facies metamorphism, but granulite and retrograde greenschist facies zones also occur. The protoliths are interpreted as an arc-related volcano-sedimentary package and the Smouspan Member metadacite is dated at 1284 ± 9 Ma. Members are distinguished as follows: The Magazine Member is dominated by calc-silicate rocks which are dominant in outcrop but rarely found in borehole cores. The Smouspan Gneiss is a fairly homogeneous hornblende-biotite intermediate gneiss which is up to 400 meters thick in an isoclinal fold structure. It comprises the footwall to the Prieska Copper Mines Member, in which the massive sulphide orebody occurs, enclosed in an alteration assemblage comprising dark gedrite fels and strongly foliated, leucocratic quartz-perthite-sillimanite gneiss. The ore is interpreted as a volcanogenic massive sulphide deposit formed in a Mesoproterozoic island arc system. The Vogelstruisbult Member is the hanging wall unit, comprising mainly laminated amphibolites and metapelites, but also containing a variety of rock types including hornblende gneiss, biotite gneiss, chlorite schist, and calc-silicate gneiss. Away from the Prieska Mines orebody, a similar variety of rock types is found, and not subdivided but classified as Copperton Formation, a mappable unit. The same assemblage of rock types, including massive sulphide mineralization, was intersected in drill holes on the farms Kielder (portion of Doonies Pan 108), Eierdop Pan and Kantienpan to the north. The Copperton Formation is the southernmost unit of the Areachap Group which is exposed between Prieska Copper Mines and Areachap Mine north of Upington, where the Jannelsepan and Bethesda formations occur. The Copperton Formation is partly obscured in many places by Dwyka Group tillite cover which thickens southwards. A sequence of structural and metamorphic events affected the Copperton Formation and Areachap Group during the 1.2 to 1.0 Ga Namaqua-Natal orogeny. These involved collision of the Areachap Terrane with the Kaapvaal-Rehoboth Craton at about 1220 Ma, a thermal and deformational event coeval with the continental-scale Umkondo mantle event at about 1100 Ma, followed by uplift, erosion and the development of right-lateral shear zones of the Doornberg Lineament, with cooling below 300°C by 920 Ma. A Cambrian peneplain developed in the region which was first covered by Nama Group sandstones, then glaciated and covered by Permian Dwyka Group tillites which are presently being eroded to expose the Copperton Formation.

Risk of Fluoride-Rich Groundwater on Human Health: Remediation Through Managed Aquifer Recharge in a Hard Rock Terrain, South India

The main objective of the present research was to examine the risk of fluoride-rich groundwater in the Shanmuganadhi River basin, south India on human health. The non-carcinogenic risks were estimated into two classes: (1) risks associated with oral intake of water and (2) risks associated with dermal contact. Hazard Quotient for oral intake and dermal contact was separately calculated for adult men, adult women and children from the geochemical results of 61 representative samples collected from the wells constructed in hard rock aquifers during the post- (January-2018) and pre-monsoon (May-2018) seasons. The collected samples were analyzed immediately after the field work for all the major ions and fluoride. Finally, total hazard index was calculated for adults (men and women) and children to evaluate the risk. It directed that 41%, 49% and 74% of post-monsoon samples and 30%, 43% and 62% of pre-monsoon samples possessed a non-carcinogenic risk for men, women and children, respectively. Because the basin falls in the drought-prone region, the water supply for drinking and cultivation are commonly based on groundwater resources. The study revealed that the minerals such as apatite, fluorite, biotite and pyroxene in the hornblende–biotite gneiss formation contribute fluoride ions to the groundwater system due to water–rock interaction mechanism. The Durov diagram depicted that dissolution of silicate minerals and cation exchange are the foremost hydrogeochemical activities, which decide the overall chemical composition of groundwater in this region. The ionic concentrations including fluoride increased with respect to depth of occurrence of groundwater. Escalation of the water table due to monsoon recharge and artificial recharge through a check dam decreased the total dissolved solids and fluoride ion concentration. The investigation conducted around the existing check dam at Kaldurai village highlighted that the fluoride concentration is below the allowable limit of 1.5 mg/l (WHO in World health statistics 2017: monitoring health for the SDGs, Sustainable Development Goals. World Health Organization, Geneva, 2017) in the wells closer to the check dam toward the downstream side. The concentration increased with distance, which lead the groundwater unsuitable for consumption. Therefore, it is recommended to implement the managed aquifer recharge using check dams in the other parts of the basin to enrich the quantity and applicability of groundwater.

Geochemical evaluation of fluoride contamination in groundwater from Shanmuganadhi River basin, South India: implication on human health.

In order to assess the geochemical mechanism liable for fluoride contamination in groundwater and its health effects on the people of the Shanmuganadhi River basin, Tamil Nadu, India, 61 groundwater samples were collected during post- and pre-monsoon seasons from the wells used for drinking purposes. Collected samples were analysed for various physico-chemical parameters. The parameters estimated in the present study are hydrogen ion concentration (pH), total dissolved solids, electrical conductivity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), bicarbonate (HCO3-), chloride (Cl-), sulphate (SO42-), nitrate (NO3-), phosphate (PO43-) and fluoride (F-). The fluoride ion concentration in the groundwater samples of this region varied from 0.01 to 2.50mg/l and 0.01 to 3.30mg/l during post- and pre-monsoon seasons, respectively. Out of 61 groundwater samples, 14 samples of post-monsoon season and 16 samples of pre-monsoon season represented high, very high and extremely high classes of fluoride, which cause dental fluorosis in this region. The fluoride-bearing minerals in the granitic and gneissic rocks such as apatite, hornblende, muscovite, biotite and amphiboles are the major sources for fluoride contamination in this area. In addition to the geogenic sources, applications of synthetic fertilizers in the agricultural fields also contribute significant amount of fluoride ions to groundwater. The spatial distribution of fluoride in different geological formations clearly indicate that the wells located in charnockite terrain were possessing very low fluoride concentration when compare with the wells located in the hornblende-biotite gneiss formation. Therefore, dental fluorosis risks are mostly associated with rock types in this region. People living over the basement rock comprising of hornblende-biotite gneiss are prone for fluorosis. Fluoride exhibited good positive correlation with bicarbonate in groundwater. As fluoridated endemic regions normally acquire lot of bicarbonate in groundwater samples, Shanmuganadhi basin falls under fluoride endemic category. The present study identified 26 villages in Shanmuganadhi basin as probable fluorosis risk areas where attention should be given to treat the fluoride-rich groundwater before drinking water supply. The groundwater level fluctuation study also designates that rise in water level reduces the concentration of fluoride due to dilution mechanism. Therefore, recharge of groundwater by artificial methods will definitely improve the present scenario.

Emplacement of the Dschang granitic pluton (west-Cameroon): Constraints from microstructures and magnetic fabrics

Microstructures and Anisotropy of Magnetic Susceptibility (AMS) data were investigated in the Pan-African Dschang granitic pluton and its basement rocks in order to decipher its emplacement and time relationship within the Pan-African evolution of the Central Cameroon Shear Zone (CCSZ). The Dschang granitic pluton, emplaced in biotite-hornblende gneiss country rocks, is made of biotite megacrystic granite and fine-grained biotite granite. The pluton has mostly low susceptibility magnitude (Km ≤ 500 μSI) implying that AMS susceptibility is mostly controlled by biotite. The foliation of the pluton is underlined by platy alkali-feldspar megacrystals that strike ENE-WSW to E-W or WNW-ESE with moderate to high dips, associated with biotite schlieren and spindle-shaped xenoliths. The magnetic foliations also strike dominantly NE-SW to E-W or NNW-SSE to NNE-SSW directions with moderate to steep dips. Magnetic lineations have low to moderate plunges and show radiating pattern in the Schmidt projection diagram. The microstructures within the pluton point to continuous deformation from magmatic to sub-magmatic state. The Jelinek shape parameter Tj shows abundant triaxial and oblate shape AMS ellipsoids and uncommon negative values (42% of the stations). Low to very low values of Pj parameter associated to (i) mostly triaxial and oblate shape AMS ellipsoids and (ii) dominantly magmatic to submagmatic state microstructures suggest a syn-to post-kinematic emplacement of a high viscosity granitic magma by flow mechanism. Magnetic fabrics infer that the Dschang granitic pluton was emplaced in a ENE-WSW to E-W oriented fracture initiated during the transcurrent strike-slip CCSZ.

Anatectic origin and geological significance of the Neoarchean ~2.5 Ga charnockite in the Jining area, northern North China Craton

The Neoarchean charnockite of Yinshan Block has been a hot topic into understanding the Precambrian geology of the North China Craton. Although there is a broad consensus that the charnockite is usually related to granulite‐facies metamorphism, its petrogenesis and tectonics still remain controversial. We present a comparative study of the petrography, geochemistry, and geochronology of charnockite and intermediate–basic granulite in the Jining area along the northern margin of the North China Craton. Inclusions within hypersthene in charnockite are used to identify the peak granulite facies mineral assemblage, with the formation of charnockite being attributed to anatexis of the protolith associated with this granulite‐facies metamorphism. Anatexis occurred mainly during postpeak isothermal decompression, as inferred from the metamorphic evolution and pressure–temperature conditions (granulite and charnockite record peak pressure–temperature conditions of 750°C–1,000°C and 0.8–1.2 GPa and 850°C–975°C and 0.9–1.0 GPa, respectively) derived from analyses of metamorphic minerals using electron probe microanalysis, combined with previous zircon geochronology. Hypersthene in charnockite is interpreted to be a residual or peritectic mineral phase that was present during anatexis, and the charnockite is inferred to have been crystallized from a melt containing abundant residual minerals. Charnockite has similar geochemical characteristics to those of intermediate–basic granulite but differs in several key ways: (a) The charnockite is strongly depleted in the large‐ion lithophile element Cs, the heat‐producing elements U and Th, and the high‐field‐strength elements Nb, Ta, P, and Ti; (b) it is enriched in Sr; and (c) it exhibits both positive and negative Eu anomalies, which are characteristics of granites formed largely by in situ anatexis. Geochemical constraints indicate that the intermediate charnockite and retrograde metamorphic biotite–hornblende gneiss may both be the product of mantle‐derived magma in a magmatic subduction‐related back‐arc extensional environment. This setting provided a hot spot for metamorphic anatexis, with additional heat being provided by the upwelling of asthenospheric mantle. After the cessation of subduction by ~2,470 Ma, a magmatic arc extensional setting developed in the Jining area. The charnockite was involved in Paleoproterozoic orogenesis in the North China Craton and was strongly modified by a ~1,950‐Ma metamorphism event.

Preliminary review of the geology of the hornblende biotite gneisses of Obudu Plateau Southeastern Nigeria

The Obudu Plateau, southeastern Nigeria is dominantly underlain by gneissose rocks with migmatitic characteristics, one of which is the hornblende-biotite gneiss. The gneisses are banded with quartz and plagioclase as the major minerals in the leucosome while hornblende and biotite occur in the palaeosome. Geochemically, the rocks are enriched in silica and alumina with an average of 71.6wt% and 14wt% respectively. Geochemical plots indicate that they are calc-alkaline to tholeiitic in character and derived from protholiths of igneous origin with minor sedimentary input.KEYWORDS: Obudu Plateau, migmatitic gneiss, calc-alkaline

Chromium and fluoride contamination in groundwater around leather tanning industries in southern India: Implications from stable isotopic ratio δ53Cr/δ52Cr, geochemical and geostatistical modelling

This study investigates the contamination of groundwater by chromium and fluoride around leather tanning industries. Major ions, chromium, δ53Cr/δ52Cr and fluoride were analyzed by advanced analytical methods. High degree of variation was observed in the concentration of chloride in groundwater, which ranged between 205 and 3310 mg/L, around 56% of the samples were recorded above the acceptable limit indicating the quality of groundwater is fresh to saline and it could be due to mixing of tannery effluents with freshwater aquifers. The chromium in the groundwater around 40% of the sampling wells exceeds the permissible limit whereas, 37% of wells were with fluoride above the accepted limit. Geochemical modelling using Phreeqc suggest that the saturation index of minerals such as calcite, dolomite, fluoride, gypsum and anorthite is affected by precipitation, dissolution and ion exchange processes. Concentration of chromium isotopes δ53Cr and δ52Cr reveals the source of Cr in the groundwater is more likely from tannery effluents. Accumulation of fluoride in groundwater is contributed by bedrock, charnockite, granite, epidote hornblende gneiss, fissile hornblende biotite gneiss in the study area. Groundwater contamination in this area is caused by both natural as well as anthropogenic sources. Around 37% of the samples exceeds HQI limit (HQI>1), which indicates possible health problems to the public upon prolonged use of untreated groundwater for drinking. To overcome this situation, it's essential to improve the performance of the effluent treatment plants and recharge structure to recover the quality of groundwater.

Neoproterozoic igneous activity and Permo-Triassic metamorphism inthe Gapyeong area within the Gyeonggi Massif, South Korea, and theirimplication for the tectonics of northeastern Asia

Although Neoproterozoic rocks were recently found in the western margin of the Gyeonggi Massif, no Neoproterozoic rocks were believed to be present within the interior of this massif. However, in this study, Neoproterozoic rocks are recognized for the first time within the interior of the Gyeonggi Massif through the discovery of the Neoproterozoic volcano-sedimentary rocks of the Gapyeong Formation (GF). The GF is located in the Gapyeong area within the northern Gyeonggi Massif to the north of the Permo-TriassicHongseong-Odesan continental collision boundary in South Korea. The GF mainly consists of mafic granulite interlayered with metacalcsilicate, marble, biotite gneiss, and metatrachyandesite and contains a serpentinized ultramafic block and hornblende biotite gneiss slab. The ages and whole-rock geochemistry indicate that the interlayered metatrachyandesite and mafic granulite in the GF were trachyandesite and basalt that formed through bimodal volcanism in a continental rift tectonic setting at ca. 854 Ma, which matches the timing of the Rodinia supercontinent breakup. The GF can be correlated to the 900–850 Ma Neoproterozoic rifting sequences in the southern Nangrim and northern Gyeonggi Massifs in the Korean Peninsula, which can be correlated to the 930–830 Ma Neoproterozoic rifting sequence along the southern margin of the North China Craton. The GF is difficult to correlate with the ca. 890–790 Ma subduction-related Neoproterozoic rocks in the Hongseong area in the southwestern Gyeonggi Massif, which are considered equivalent to rocks in the northern margin of the South China Craton. The GF underwent upper granulite-facies metamorphism (816–882 °C, 9.0–10.9 kbar) at ca. 250 Ma during the collision between the North and South China Cratons. The serpentinite block in the GF formed in a suprasubduction zone, and the hornblende biotite gneiss slab in the GF was metamorphosed under lower granulite-facies conditions (725–767 °C, 7.0–8.4 kbar) at ca. 414 Ma, indicating that the block and slab were tectonically incorporated into the GF. A strong mylonitic texture is observed in the GF but not in the basement Paleoproterozoic gneiss except at its boundary contact with the GF. These data indicate that the GF, together with the serpentinite block and hornblende biotite gneiss slab, was tectonically transported to the present area after the Triassic metamorphism.

Neoarchean microblock amalgamation in southern India: Evidence from the Nallamalai Suture Zone

A collage of crustal blocks ranging in age from Mesoarchean to Neoarchean accreted to the southern margin of the Dharwar Craton in Peninsular India preserve distinct evolutionary history, but share a common metamorphic record during Archean-Proterozoic transition. Here we investigate the tectonic boundary between two of these microblocks, the Shevaroy Block to the west and the Madras Block to east, termed as the Nallamalai Suture Zone (NLSZ). We present integrated field, petrological, geochemical and zircon U-Pb and Lu-Hf data from a suite of meta-igneous and metasedimentary units along the NLSZ and its flanks. Zircon grains from the meta-monzogranite, hornblende-biotite gneiss, amphibolite, granodiorite, diorite, charnockite, BIF (banded iron formation) and BMQ from this area show magmatic emplacement ages clustering around 2.50 to 2.56 Ga, except for the meta-monzogranite showing ages up to 3.2 Ga, correlating with long-lived convergent margin magmatism through multiple slab melting episodes. All the rocks show tightly constrained early Paleoproterozoic (ca. 2.46–2.48 Ga) metamorphic ages, including the metamorphic zircon in the BIFs, marking the timing of collision of the two continental blocks with consumption of the intervening oceanic lithosphere. The εHf(t) values of magmatic zircon grains from the different rock types range from −4.1 to +5.7, and together with TDMC Hf model ages of 2672–3247 Ma, a dominantly juvenile crust growth is indicated, which initiated around 3.3 Ga and continued to 2.7 Ga, followed by crustal reworking in a continental arc towards the end of Neoarchean.The geochemical data suggest that tholeiitic to calc-alkaline parental melts for the mafic-intermediate-felsic suite were generated by low degree partial melting of a peridotitic mantle wedge metasomatized by subduction-derived fluids and sediments and continuous slab melting ensued by intracrustal fractional crystallization of melts with reworking of older continental crust. The BIF and BMQ samples display positive Eu anomalies, negative to negligible Ce anomalies, and superchondritic Y/Ho ratios suggesting their formation in an oceanic realm proximal to an active continental margin setting. The magmatic and tectonic attributes are consistent with eastward oceanic subduction and ocean closure along the NLSZ which is defined here as the trace of a suture welding the Shevaroy and Madras Blocks. We envisage that multiple subduction and amalgamation of several microblocks occurred in the Dharwar Craton and its southern domains, amalgamating several microblocks during the Archean – Paleoproterozoic transition.